Chapter 7

1. In the following diagram of a wave a. (a) is amplitude and (b) is wavelength b. (a) is frequency and (b) is amplitude c. (a) is wavelength and (b) is frequency

c. 7.00 105 m d. 1.43 106 m e. 3.00 108 m 5. Calculate the frequency of visible light having a wavelength of 486 nm. a. 2.06 1014 /s

d. (a) is amplitude and (b) is frequency b. 2.06 106 /s e. (a) is wavelength and (b) is amplitude c. 6.17 1014 /s 2. As the frequency of an electromagnetic wave increases a. its speed must increase. b. its wavelength must increase. c. its amplitude must increase. a. 4.37 1014 /s d. its energy must increase. b. 4.37 105 /s 3. What is the wavelength of radiation that has a frequency of 5.39 1014 s1? (c = 2.9979 108 m/s) a. 1.80 103 nm b. 556 nm c. 618 nm d. 6180 nm e. 1.61 1023 nm 4. What is the wavelength of radiation that has a frequency of 2.10 1014 s 1? a. 6.30 10
22

d. 1.20 1015 /s e. 4.86 107 /s 6. Calculate the frequency of visible light having a wavelength of 686 nm.

c. 6.17 1014 /s d. 2.29 1015 /s e. 2.29 106 /s 7. What is the energy in joules of one photon of microwave radiation with a wavelength 0.122 m? (c = 2.9979 108 m/s; h = 6.626 1034 Js) a. 2.70 1043 J b. 5.43 1033 J c. 1.63 1024 J

m d. 4.07 1010 J

b. 7.00 10 nm e. 2.46 109 J

8. What is the energy in joules of a mole of photons associated with visible light of wavelength 486 nm? a. 6.46 1016 J b. 6.46 1025 J c. 2.46 104 J d. 12.4 kJ e. 246 kJ 9. What is the energy in joules of a mole of photons associated with red light of wavelength 7.00 102 nm? a. 256 kJ b. 1.71 105 J c. 4.72 1043 J d. 12.4 kJ e. 2.12 1042 J 10. The colors of the visible spectrum are blue, green, orange, red, violet, and yellow. Of these colors, ______ has the least energy. 11. What is the wavelength, in meters, of an alpha particle with a kinetic energy of 8.0 1013 J. [mass of an alpha particle = 4.00150 amu; 1 amu = 1.67 10 27 kg]

b. as the atoms condense from a gas to a liquid. c. as electrons jump from higher energy levels to lower levels. d. as they are heated and the solid melts to form a liquid. e. as the electrons move about the atom within an orbit. 15. An electron in a 3p orbital could have a value of 2 for its angular momentum quantum number (l). True False

16. A neon atom in its ground state will be diamagnetic. True False

17. Each shell (principal energy level) of quantum number n contains n subshells True False

18. For all atoms of the same element, the 2s orbital is larger than the 1s orbital. True False

19. According to de Broglie's equation, the wavelength associated with the motion of a particle increases as the particle mass decreases. 20. The frequency of the emitted light from a cesium atom is an intensive property. 21. Calculate the energy, in joules, required to excite a hydrogen atom by causing an electronic transition from the n = 1 to the n = 4 principal energy level. Recall that the energy levels of the H atom are given by En = 2.18 1018 J(1/n2) a. 2.07 1029 J b. 2.19 105 J

12. What is the wavelength of a ball bearing with a mass of 10.0 g, and a velocity of 10.0 cm/s?

13. The bonds of oxygen molecules are broken by sunlight. The minimum energy required to break the oxygen-oxygen bond is 495 kJ/mol. What is the wavelength of sunlight that can cause this bond breakage?

14. Complete this sentence: Atoms emit visible and ultraviolet light a. as electrons jump from lower energy levels to higher levels.

c. 2.04 1018 J d. 3.27 1017 J

e. 2.25 1018 J 22. Calculate the wavelength, in nanometers, of the light emitted by a hydrogen atom when its electron falls from the n = 7 to the n = 4 principal energy level. Recall that the energy levels of the H atom are given by En = 2.18 1018 J(1/n2) a. 4.45 1020 nm b. 2.16 106 nm c. 9.18 10
20

the n = 4 to the n = 1 principal energy level. Recall that for hydrogen En = 2.18 1018 J(1/n2) a. 97.2 nm b. 82.6 nm c. 365 nm d. 0.612 nm e. 6.8 1018 nm 26. The second line of the Balmer series occurs at a wavelength of 486.1 nm. What is the energy difference between the initial and final levels of the hydrogen atom in this emission process? a. 2.44 1018 J b. 4.09 1019 J c. 4.09 1022 J d. 4.09 1028 J e. 1.07 1048 J 27. A proton is roughly 1800 times more massive than an electron. If a proton and an electron are traveling at the same speed, a. the wavelength of the photon will be about 1800 times longer than the wavelength of the electron. b. the wavelength of the photon will be about (1800)1/2 times longer than the wavelength of the electron. c. the wavelength of the photon will be roughly equal to the wavelength of the electron. d. the wavelength of the electron will be about (1800)1/2 times longer than the wavelength of the photon. e. the wavelength of the electron will be about 1800 times longer than the wavelength of the photon.

nm

d. 1.38 1014 nm e. 2.16 103 nm 23. Calculate the frequency of the light emitted by a hydrogen atom during a transition of its electron from the n = 6 to the n = 3 principal energy level. Recall that for hydrogen En = 2.18 1018 J(1/n2). a. 1.64 1015 /s b. 9.13 1013 /s c. 3.65 1014 /s d. 1.82 1019 /s e. 2.74 1014/s 24. Calculate the frequency of the light emitted by a hydrogen atom during a transition of its electron from the n = 4 to the n = 1 principal energy level. Recall that for hydrogen En = 2.18 10 18 J(1/n2) a. 3.08 1015 /s b. 1.03 108 /s c. 2.06 1014 /s d. 1.35 1051 /s e. 8.22 1014 /s

25. Calculate the wavelength of the light emitted by a hydrogen atom during a transition of its electron from

28. If a hydrogen atom and a helium atom are

traveling at the same speed, a. the wavelength of the hydrogen atom will be about 4 times longer than the wavelength of the helium atom. b. the wavelength of the hydrogen atom will be about 2 times longer than the wavelength of the helium. c. the wavelength of the hydrogen atom will be roughly equal to the wavelength of the helium atom.

a. 16 pm b. 0.016 nm c. 0.16 nm d. 160 nm e. 1.6 104 m

32. A common way of initiating certain chemical reactions with light involves the generation of free d. the wavelength of the helium atom will be about halogen atoms in solution. If H for the reaction Cl2(g) 2 times longer than the wavelength of the hydrogen 2Cl(g) is 242.8 kJ/mol, what is the longest atom. wavelength of light that will produce free chlorine atoms in solution? e. the wavelength of the helium atom will be about 4 times longer than the wavelength of the hydrogen atom. 29. In an electron microscope, electrons are accelerated to great velocities. Calculate the wavelength of an electron traveling with a velocity of 7.0 103 kilometers per second. The mass of an electron is 9.1 1028 g. a. 1.0 1013 m b. 1.0 107 m c. 1.0 m d. 1.0 1010 m 30. Calculate the wavelength associated with a 20Ne+ ion moving at a velocity of 2.0 105 m/s. The atomic mass of Ne-20 is 19.992 amu. a. 1.0 1013 m c. 3.00 108 m/s b. 1.0 1016 m d. 4.41 106 m/s c. 1.0 1018 m e. 8.06 103 m/s d. 9.7 1012 m e. 2.0 1013 cm 31. Calculate the wavelength of a neutron that has a velocity of 250 cm/s. (The mass of a neutron = 1.675 1024 g; h = 6.626 1034 Js) 34. A single pulse of a laser yields an average of 5.00 1018 photons with = 633 nm. If melting ice to water at 0C requires 6.01 kJ/mol, what is the fewest number of laser pulses need to melt 10.0 g of ice? a. 3830 a. 246.3 nm b. 465.2 nm c. 349.3 nm d. 698.6 nm e. 492.6 nm 33. Electrons can be used to probe the arrangement of atoms on a solid surface if the wavelength of the electrons is comparable with the spacing between the atoms. Which of the following electron velocities would be appropriate for use in this application if the atoms are separated by 0.320 nm? a. 2.27 106 m/s b. 1.24 103 m/s

b. 3340 c. 38300 d. 2120 e. 212 37. What is the maximum number of electrons in an atom that can have the following set of quantum numbers? n = 4 l = 3 ml = 2 ms = +1/2 a. 0

c. 3 d. 5 e. 7 42. The maximum number of electrons that can occupy an energy level described by the principal quantum number, n, is a. n b. n + 1 c. 2n

b. 1 d. 2n2 c. 2 e. n2 d. 6 e. 10 38. A possible set of quantum numbers for the last electron added to complete an atom of gallium (Ga) in its ground state is 39. A possible set of quantum numbers for the last electron added to complete an atom of germanium (Ge) in its ground state is 40. Electrons in an orbital with l = 3 are in a/an a. d orbital. b. f orbital. c. g orbital. a. the Pauli exclusion principle. d. p orbital. b. Bohr's equation. e. s orbital c. Hund's rule. 41. The number of orbitals in a d subshell is d. de Broglie's relation. a. 1 e. Dalton's atomic theory. b. 2 43. How many orbitals are allowed in a subshell if the angular momentum quantum number for electrons in that subshell is 3? a. 1 b. 3 c. 5 d. 7 e. 9 44. "No two electrons in an atom can have the same four quantum numbers" is a statement of

51. How many unpaired electrons does a ground-state atom of sulfur have? a. 0 b. 1 c. 2 d. 3 e. 4 52. A ground-state atom of arsenic has a. no unpaired electrons. b. one unpaired electron. c. two unpaired electrons. d. three unpaired electrons. e. four unpaired electrons. 53. Which element has the following ground-state electron configuration? 1s22s22p63s2 a. Na

d. Bi e. Te

55. Which element has the following ground-state electron configuration? [Ar]4s23d104p5 a. aresnic b. bromine c. iodine d. selenium e. tellerium 56. Which element has the following ground-state electron configuration? [Kr]5s14d5 a. Mn b. Mo c. Nb d. Re e. Tc

b. Mg c. Al d. Si e. Ne 54. Which element has the following ground-state electron configuration? [Kr]5s24d105p3 a. Sn b. Sb c. Pb a. [Ar]4s23d7 57. Which element has the following ground-state electron configuration? [Kr]5s24d105p2 a. Sn b. Sb c. Pb d. Ge e. Te 58. The electron configuration of a ground-state Co atom is

b. 1s22s22p63s23d9 c. [Ne]3s23d7 d. [Ar]4s13d5 e. [Ar]4s24d7 59. The electron configuration of a ground-state vanadium atom is a. [Ar]4s24d3 b. [Ar]4s24p3 c. [Ar]4s23d3 d. [Ar]3d
5

a. [Ne]3s2 b. [Ne]3s23p6 c. [Ar]4s13d1 d. [Ar]4s2 e. [Ar]3d2 63. How many electrons are there in the 2nd principal energy level (n = 2) of a phosphorus atom a. 3 b. 5 c. 6 d. 8 e. 10 64. How many electrons are there in the 3rd principal energy level (n = 3) of a phosphorus atom? a. 3 b. 5.

60. The electron configuration of a ground-state copper atom is a. [Ar]4s24d4 b. [Ar]4s 4p 3d c. [Ar]4s23d9 d. [Ar]3d9 e. [Ar]4s13d10 61. The ground-state electron configuration for an atom of indium is a. [Kr]5s24p64d5 b. [Ar]4s 3d 4p c. [Ar]4s24p63d5 d. [Kr]5s25p64d5 e. [Kr]5s24d105p1
2 10 1 2 6 3

c. 6 d. 8 e. 10 65. A ground-state atom of manganese has ___ unpaired electrons and is _____. a. 0, diamagnetic b. 2, diamagnetic c. 3, paramagnetic d. 5, paramagnetic e. 7, paramagnetic 66. A ground-state atom of vanadium has ___ unpaired electrons and is _____. a. 0, diamagnetic b. 2, diamagnetic c. 3, paramagnetic d. 5, paramagnetic e. 4, diamagnetic

62. Which of the following is the ground-state electron configuration of a calcium atom?

67. A ground-state atom of iron has ___ unpaired electrons and is _____. a. 0, diamagnetic b. 6, diamagnetic c. 3, paramagnetic d. 5, paramagnetic e. 4, paramagnetic 68. Transition metal elements have atoms or ions with partially filled a. s subshells. b. p subshells. c. d subshells. d. f subshells. e. g subshells 69. Lanthanide (or rare earth elements) have atoms or ions with partially filled a. s subshells. b. p subshells. c. d subshells. d. f subshells. e. g subshells 70. Which choice lists two elements with ground-state electron configurations that are well known exceptions to the Aufbau principle? a. Cu and C b. Cr and Cu c. Cs and Cl d. Rb and Co e. Fe and Co 71. A ground-state chromium atom has how many unpaired electrons? a. 1 b. 2 c. 4 d. 5 e. 6

72. Which of the following is the electron configuration of an excited state of an oxygen atom? a. 1s22s22p4 b. 1s22s22p5 c. 1s22s22p33s1 d. 1s22s22p6 e. 1s22s22p3 73. Which of the following is the electron configuration of an excited state of an iron atom? a. [Ar]4s23d7 b. [Ar]4s23d6 c. [Ar]4s23d8 d. [Ar]4s13d7 e. [Ar]4s13d5 74. Which of the following is the electron configuration of an excited state of a copper atom? a. [Ar]4s23d9 b. [Ar]4s13d10 c. [Ar]4s13d8 d. [Ar]4s23d8 e. [Ar]4s03d10 75. The ground-state electron configuration of Cr, Mo, and Ag are exceptions to the Aufbau principle. Which of the following is the electron configuration for Mo? a. [Kr]5s14d5 b. [Kr]5s24d4 c. [Xe]6s25d4 d. [Ar]4s24d4 e. [Kr]5s24d6

76. How many electrons in a ground-state tellurium atom are in orbitals labeled by l = 1? a. 4 b. 10 c. 12 d. 16 e. 22

80. Which of the following is diamagnetic both in its ground state and in all of its excited states? a. Mg b. Ne c. Cu d. Zn

77. How many electrons in a ground-state cadmium atom are in orbitals labeled by ml = 1? a. 2 b. 10 c. 12 d. 18 e. 36 78. Which of the following ground-state atoms is diamagnetic? a. Ca b. As c. Cu d. Fe e. none of these 79. Which of the following atoms is paramagnetic both in its ground state and in all of its excited states? a. C b. N c. O d. Ti e. Cr

e. none of these 81. The electron in a hydrogen atom falls from an excited energy level to the ground state in two steps, causing the emission of photons with wavelengths of 1870 and 102.5 nm. What is the quantum number of the initial excited energy level from which the electron falls? a. 2 b. 3 c. 4 d. 6 e. 8 82. When the electron in a hydrogen atom falls from the n = 3 excited energy level to the ground state energy level, a photon with wavelength is emitted. An electron having this same wavelength would have a velocity of

a. 7.10 103 m/s b. 2.93 106 m/s c. 2.93 103 m/s d. 7.10 m/s e. 3.00 108 m/s 83. Rank the following types of electromagnetic radiation from lowest energy to highest energy: infrared, microwave, radio waves, gamma rays, visible,

and ultraviolet.

92. Calculate the energy of a photon of light with a wavelength of 360 nm.

84. An FM radio station broadcasts at a frequency of 101.7 MHz. Calculate the wavelength of the broadcast signal in meters. (c = 2.9979 108 m/s)

93. What is the difference in the electron configuration between carbon14 and carbon12? 94. With regard to electron behavior, what happens when light is absorbed or emitted by an atom? 95. What is the total number of electrons possible in the 2p orbitals?

85. An AM radio station broadcasts at a frequency of 1270 kHz. Calculate the wavelength of the broadcast signal in meters. (c = 2.9979 108 m/s)

86. Write the ground state electron configuration for the selenium atom. 87. Write the ground state electron configuration for the phosphorus atom.

96. What is the total number of electrons possible in the 6s orbital? 97. What is the ground-state electron configuration for chlorine? 98. If one electron is added to the outer shell of chlorine, it would have the same electron configuration as what element? 99. What is the electron configuration of calcium? 100. If we take away two electrons from the outer shell of calcium, it would have the same electron configuration as what element?

88. Write the ground state electron configuration for an iodine atom.

89. Write the ground state electron configuration for a lead atom.

90. Write the ground state electron configuration for Ni.

91. Write the ground state electron configuration for Cr.

The End