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2 Section A

Four suggested answers labeled A, B, C and D are given for each question. Choose one correct answer. 1. Ammonia is an example of a non-ideal gas because A. B. C. D. its molecule is small the intermolecular forces are strong the volume occupied by ammonia can be ignored ammonia is easily compressed at low temperature and high pressure

2. Which of the following statements is true regarding graphite, diamond and fullerene? A. Their atoms contain delocalized electrons. B. Covalent bonds and van der Waals forces exist in their molecules. C. Each carbon atom forms bonds with four other carbon atoms. D. Complete combustion produces water and carbon dioxide. 3. The proton number of an element X is 32. Which of the following shows the right order for the removal of electrons from their orbitals to form X4+ ion? A. B. C. D. First 4s 4px 4px 4py Second 4s 4py 4px 4pz Third 4px 4s 4s 3d Fourth 4py 4s 4s 3d

4. The diagram below shows the crystalline lattice structure of a compound.

abc 90o Which of the following types of unit cells represents the lattice structure? 962/1 *Kertas soalan ini SULIT sehingga peperiksaan ini tamat. SULIT*

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A. B. C. D.

Monoclinic Triclinic Orthorhombic Rhombohedral

5. The table below shows the proton numbers of four elements represented by letters which are not the usual symbols for the elements concerned. Element Proton number P 3 Q 11 R 13 S 19

Which element has the strongest metallic bond? A. P B. Q C. R D. S

6. Which molecule has the highest dipole moment? H H H C CCl H H A Cl C=C CH3 C Cl D CH3 Cl Cl Cl C=C Cl B Cl Cl Cl

7. The following molecules undergo the same orbital hybridization except for A. B. C. D. water ethane ehtene chloromethane

8. Which of the following statements regarding the half-life of a first order reaction is true?

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The half-life is affected by pressure The half-life depends on the concentration of the reactants The half-life is shorter at lower temperature At the end of the fourth half-life, the percentage of element left is 6.25% of the original quantity 9. Hydrazine, N2H4, is a weak base. The dissociation constant Kb of this base is 3.00 X 10-6 moldm-3. What is the pH value of a 0.100 moldm-3 aqueous solution of hydrazine? A. 3.26 B. 7.50 C. 9.46 D. 10.7

10. Which of the following solutions can retain its pH when a few drops of aqueous sodium hydroxide is added? A. B. C. D. Aqueous 2-chloroethanoic acid Aqueous aminoethanoic acid Aqueous sodium ethanoate Aqueous phenol

11. Which of the following type of chromatographies is the most suitable to analyse the percentage of alcohol contained in a blood sample? A. B. C. D. Column chromatography Gas-liquid chromatography Thin-layer chromatography Paper chromatography

12. A tribasic weak acid X dissolves in ether and in water. The relative molecular mass of X is 176. An amount of 2.34 g of X is shaken with a mixture of 100 cm3 of ether and 50 cm3 of water until an equilibrium is reached. An amount of 25.0 cm3 of the aqueous solution needs 15.00 cm3 of 0.10 moldm-3 aqueous sodium hydroxide solution for complete neutralization. Calculate the partition coefficient between ether and water of X. A. 0.08 B. 0.16 C. 1.72 D. 6.15

13. The half-reaction of dichromate (VI) ion is shown as follows. Cr2O72-(aq) + 14H+(aq) + 6e 2Cr3+(aq) + 7H2O(l) In one experiment, 45.0 cm3 of 0.2 moldm-3 aqueous M2+ solution has reacted with 15.0 cm3 of 0.1 moldm-3 aqueous potassium dichromate (VI) solution. What is the oxidation state of M after the reaction? A. +3 B. +4 C. +5 D. +7

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14. The diagram below shows the Born-Haber cycle for the formation of sodium fluoride. -574 kJmol-1 Na(s) + F2(g) NaF(s) +107 kJmol-1 +79 kJmol-1 Na(g) + F(g) -928 kJmol-1 +496 kJmol
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Na+(g) + F-(g) What is the electron affinity, in kJmol-1, of fluorine? A. -246 B. -275 C. -328 D. -820

15. Which of the following cations has the highest hydration energy? A. Li+ B. Na+ C. K+ D. Rb+ 16. Which of the following compounds is the product obtained when ethene is oxidized by oxygen at 300oC, using silver catalyst? A. HOCH2CH2OH B. HC CH O O

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SULIT* C. H2C CH2 O D. H2C O O O CH2

17. A sample of a hydrated salt (Mr = 120) loses 40% of its mass as water when heated. The relative molecular mass of the anhydrous salt is A. B. C. D. 24 28 52 72

18. Which of the following does not form hydrogen bonds when dissolves in water? A. B. C. D. NH3 HBr CH3COOH HNO3

19. Equilibrium is established when 40% of dinitrogen tetroxide in a closed vessel at temperature T decomposes according to equation N2O4(g) 2NO2(g). If the total pressure is P, what is equilibrium constant for the system?
4 P 3 16 P B. 9 16 P C. 21 32 P D. 21

A.

20. Which of the following affects the value of the solubility product, Ksp, of lead sulphide when it is precipitated by passing hydrogen sulphide into aqueous solution of lead(II) nitrate? Pb(NO3)2(aq) + H2S(g) PbS(s) + 2HNO3(aq) 962/1 *Kertas soalan ini SULIT sehingga peperiksaan ini tamat.

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A. B. C. D.

the addition of sodium sulphate the addition of lead(II) nitrate an increase in temperature an increase in the pressure of hydrogen sulphide

21. In the extraction of aluminium metal, if a current of 5A is passed for 3860 seconds through a cell that consists of molten cryolite, Na3AlF6, and carbon electrodes, what is the mass of aluminium produced? [Faraday constant, F, is 9.65 X 104 Cmol-1, relative atomic mass of Al = 27] A. B. C. D. 7.2 g 3.6 g 1.8 g 0.9 g

22. Ka is a better measure for the strengths of weak acids as compared to pH because A. B. C. D. its value is easier to measure its value does not depend on temperature its value does not depend on the concentration of the acid its value is a whole number

23. An organic compound Z undergoes a catalytic hydrogenation reaction. Z also reacts with hydrogen bromide to form 2-bromopropane. The possible structural formula of Z is A. B. C. D. CH2 = CH2 CH3CH2CH3 CH3CH = CH2 CH3CH(OH)CH3

24. Which of the following compounds reacts easily with cold water? A. Cl B. CH2Cl

C. CH3CH2Cl D. CH3CH2COCl 25. The number of possible isomers (including optical isomers) for an alcohol with molecular formula of C4H10O is 962/1 *Kertas soalan ini SULIT sehingga peperiksaan ini tamat.

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A. B. C. D.

2 3 4 5

26. When aqueous iron(III) chloride is added to phenol, A. B. C. D. chlorobenzene is formed white fumes are given off iron(III) is reduced to iron(II) a purple solution is formed

27. Which of the following reactions produces ethanol? A. B. C. D. Ethyl ethanoate and lithium tetrahydridoaluminate Methyl ethanoate and hot concentrated sulphuric acid Ethene and dilute aqueous potassium manganate (VII) solution Chloroethane and ethanoic sodium hydroxide solution

28. Which of the following compounds cannot exhibit geometrical isomerism? A. B. C. D. CH3CH = C(CH3)2 C6H5CH = CHC6H5 CH3CH = CHCH2CH3 (CH3CH2)(CH3)C = C(CH3)H

29. Benzaldehyde differs from ethanal in its reaction with A. B. C. D. HCN 2, 4-dinitrophenylhydrazine NH2OH Fehlings solution

30. The reaction between propanone and 2, 4-dinitrophenylhydrazine is an example of A. B. C. D. oxidation reduction addition condensation

31. Which of the following compounds reacts by nucleophilic addition?

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A. B. C. D.

CH3CH2OH CH3CH2Br CH3CHO C6H6

32. Compound X is oxidized to compound Y that does not reduce Fehlings solution. X could be A. B. C. D. CH3COCH3 CH3CHOHCH3 CH3CH2CH2OH (CH3)3COH

33. Which of the following is a monomer for synthetic rubber? A. B. C. D. Ethene Propene 1, 3-butadiene Methyl-2-methylpropenoate

34. Sodium hydroxide is preferred over dilute sulphuric acid in the hydrolysis of ethyl ethanoate because, A. B. C. D. the activation energy is lower the OH- ion is more reactive than the SO42- ion alkaline hydrolysis is non-reversible it requires a lower temperature

35. Phenylamine is a weak base than ammonia because A. B. C. D. ammonia is an ionic compound while phenylamine is a covalent compound the lone-pair electrons in phenylamine can be delocalized into the benzene ring ammonia is soluble in water while pheylamine is not the large phenyl group in phenylamine hinders the attack by H3O+

36. What type of hybridization are / is involved in the carbon atoms in the benzoic acid molecule? A. B. C. D. sp sp2 sp3 sp2 and sp3

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37. N-Acetylglucosamine (NAG) is the major component of the crustacean skin. Its structural formula is CH3 CONH CH(CHO) (CHOH)3 CH2OH. What is the name of the functional group of NAG which undergoes hydrolysis? A. B. C. D. Amino Carbonyl Hydroxyl Carboxamide

38. Tertiary alcohol is resistant to oxidation because A. B. C. D. they have very negative enthalpy of formation they are strong oxidizing agents they are non-polar they involve the breaking of carbon-carbon bonds

39. The structural formula of natural rubber is given below. H H CH3 H [ C C = C C ]n H H The presence of double bond in the structure of natural rubber makes this substance A. B. C. D. elastic hard resistant to heat easy to oxidize

40. A copolymer is produced A. B. C. D. through cross-linking of the polymer chains when rubber is vulcanized by heating the polymer then cooling it rapidly when two different monomers are used

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Section B For each of the questions in this section one or more of the three numbered statements 1 to 3 may be correct. Determine which of the statements is correct. The response A to D should be selected on the basis of the following. A Only 1 is correct B Only 1 and 2 are correct C Only 2 and 3 are correct D 1, 2 and 3 are correct

41. The mass spectrum of an element X is shown below. 99.63 100 Percentage of abundance 0.37 0 14 15 mass/charge

From the mass spectrum above, it can be concluded that, 1. element X consists of two isotopes with relative isotopic mass of 14 and 15 2. the nucleon number of X is 14.5 3. the isotopes of X have a different number of protons 42. Which of the following species do not have a tetrahedral shape? 1. PH4+ 2. ICl43. XeF4

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43. The advantages of ether as an extracting solvent involving organic compounds are 1. ether is flammable 2. ether is volatile 3. ether is inert

44. Which of the following enthalpy changes can be determined directly from experiments? 1. Lattice energy 2. Ionisation energy 3. Enthalpy of neutralization 45. Which of the following contain linkage of glucose units? 1. Cellulose 2. Starch 3. Protein 46. The table below shows the dissociation constant, Ka, for four organic acids at 25oC. Formula C6H5COOH CH3COOH ClCH2COOH Cl2CHCOOH data? 1. Chlorine substituted ethanoic acid is a stronger acid than ethanoic acid 2. Cl3CCOOH is expected to be a stronger acid than Cl2CHCOOH. 3. ClC6H4COOH is expected to be a stronger acid than C6H5COOH 47. Which of the following compounds will react with ethanoyl chloride? 1. water 2. phenylamine 3. propanal 48. Which of the following acids can be oxidize by acidified potassium manganate (VII)? 1. Benzoic acid 2. Methanoic acid 3. Ethanedioic acid 962/1 *Kertas soalan ini SULIT sehingga peperiksaan ini tamat. Ka/moldm-3 6.3 X 10-5 1.7 X 10-5 1.3 X 10-3 5.0 X 10-2

Which of the following statements is/are the conclusion(s) based on the above

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49. Which of the following statements are true for aminoethanoic acid and 2aminopropanoic acid? 1. Aminoethanoic acid is optically active, while 2-aminopropanoic acid is not 2. both form zwitterions in aqueous solution 3. both are insoluble in organic solvents

50. Which of the following can be used to differentiate between ethylamine and ethanamide? 1. Hot and dilute sodium hydroxide 2. Cold and dilute hydrochloric acid 3. Ethanoyl chloride

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