Chapter 5 Gases

Student: ___________________________________________________________________________ 1. A pressure that will support a column of Hg to a height of 256 mm would support a column of water to what height? The density of mercury is 13.6 g/cm3; the density of water is 1.00 g/cm3. A. 348 cm B. 1.00 102 ft C. 18.8 mm D. 33.8 ft E.76.0 cm 2. Which of the following is/are characteristic(s) of gases? A. High compressibility B. Relatively large distances between molecules C. Formation of homogeneous mixtures regardless of the nature of gases D. High compressibility AND relatively large distances between molecules E.High compressibility, relatively large distances between molecules AND formation of homogeneous mixtures regardless of the nature of gases 3. A sample of a gas occupies 1.40 103 mL at 25C and 760 mmHg. What volume will it occupy at the same temperature and 380 mmHg? A. 2,800 mL B. 2,100 mL C. 1,400 mL D. 1,050 mL E.700 mL 4. A sample of nitrogen gas has a volume of 32.4 L at 20C. The gas is heated to 220C at constant pressure. What is the final volume of nitrogen? A. 2.94 L B. 19.3 L C. 31.4 L D. 54.5 L E.356 L 5. If 30.0 L of oxygen are cooled from 200C to 1C at constant pressure, what is the new volume of oxygen? A. B. C. D. 0.150 L 17.4 L 23.0 L 51.8 L

E.6.00 103 L 6. A sample of N2 gas occupies 2.40 L at 20C. If the gas is in a container that can contract or expand at constant pressure, at what temperature will the N2 occupy 4.80 L? A. 10C B. 40C C. 146C D. 313C E.685C 7. The gas pressure in an aerosol can is 1.8 atm at 25C. If the gas is an ideal gas, what pressure would develop in the can if it were heated to 475C? A. 0.095 atm B. 0.717 atm C. 3.26 atm D. 4.52 atm E.34.2 atm 8. If the pressure of a gas sample is quadrupled and the absolute temperature is doubled, by what factor does the volume of the sample change? A. 8 B. 2 C. 1/2 D. 1/4 E.1/8 9. If the pressure on a gas sample is tripled and the absolute temperature is quadrupled, by what factor will the volume of the sample change? A. B. C. D. E.4 12 4/3 3/4 1/3

10. A small bubble rises from the bottom of a lake, where the temperature and pressure are 4C and 3.0 atm, to the water's surface, where the temperature is 25C and the pressure is 0.95 atm. Calculate the final volume of the bubble if its initial volume was 2.1 mL. A. 0.72 mL B. 6.2 mL C. 41.4 mL D. 22.4 mL E.7.1 mL

11. The temperature of an ideal gas in a 5.00 L container originally at 1 atm pressure and 25C is lowered to 220 K. Calculate the new pressure of the gas. A. 1.0 atm B. 1.35 atm C. 8.8 atm D. 0.738 atm E.0.114 atm 12. 0.820 mole of hydrogen gas has a volume of 2.00 L at a certain temperature and pressure. What is the volume of 0.125 mol of this gas at the same temperature and pressure? A. 0.0512 L B. 0.250 L C. 0.305 L D. 4.01 L E.19.5 L 13. At what temperature will a fixed amount of gas with a volume of 175 L at 15C and 760 mmHg occupy a volume of 198 L at a pressure of 640 mm Hg? A. 274C B. 214C C. 114C D. 1C E.-59C 14. At what temperature will a fixed mass of gas with a volume of 125 L at 15C and 750 mmHg occupy a volume of 101 L at a pressure of 645 mm Hg? A. -73C B. 10.4C C. 2C D. 34C E.200C 15. Calculate the volume occupied by 35.2 g of methane gas (CH4) at 25C and 1.0 atm. R = 0.0821 L atm/Kmol. A. 0.0186 L B. 4.5 L C. 11.2 L D. 49.2 L E.53.7 L

16. Calculate the volume occupied by 25.2 g of CO2 at 0.84 atm and 25C. A. 0.060 L B. 1.34 L C. 16.9 L D. 24.2 L E.734 L 17. A gas evolved during the fermentation of sugar was collected at 22.5C and 702 mmHg. After purification its volume was found to be 25.0 L. How many moles of gas were collected? A. 0.95 mol B. 1.05 mol C. 12.5 mol D. 22.4 mol E.724 mol 18. How many molecules of N2 gas can be present in a 2.5 L flask at 50C and 650 mmHg? A. 2.1 10-23 molecules B. 4.9 1022 molecules C. 3.1 1023 molecules D. 3.6 1025 molecules E.0.081 molecules 19. Calculate the mass, in grams, of 2.74 L of CO gas measured at 33C and 945 mmHg. A. 0.263 g B. 2.46 g C. 3.80 g D. 35.2 g E.206 g 20. 0.500 mole of ammonia (NH3) occupies a 1.2 L flask at 150C. Calculate the pressure of the ammonia inside the flask. A. 6.91 10-2 atm B. 5.13 atm C. 12.2 atm D. 14.5 atm E.22.4 atm 21. Gases are sold in large cylinders for laboratory use. What pressure, in atmospheres, will be exerted by 2,500 g of oxygen gas (O2) when stored at 22C in a 40.0 L cylinder?

A. 3.55 atm B. 1,510 atm C. 47.3 atm D. 7.56 104 atm E.10.2 atm 22. Calculate the number of kilograms of helium needed to inflate a balloon to a volume of 100,000 L at an atmospheric pressure of 250 mmHg and a temperature of -35C. A. 1.68 kg B. 3.36 kg C. 5.21 kg D. 6.74 kg E.5120 kg 23. Calculate the density, in g/L, of CO2 gas at 27C and 0.50 atm pressure. A. 0.89 g/L B. 1.12 g/L C. 9.93 g/L D. 46.0 g/L E.2.17 kg/L 24. Calculate the density of CO2(g) at 100C and 10.0 atm pressure. A. 1.44 g/L B. 134 g/L C. 44.0 g/L D. 53.6 g/L E.14.4 g/L 25. Calculate the density of Br2(g) at 59.0C and 1.00 atm pressure. A. 27.2 g/L B. 5.83 g/L C. 769 g/L D. 22.4 g/L E.3.45 g/L 26. Calculate the density, in g/L, of SF6 gas at 27C and 0.500 atm pressure. A. 3.38 10-3 g/L B. 2.96 g/L C. 22.4 g/L D. 32.9 g/L E.3.38 kg/L

27. Calculate the density, in g/L, of chlorine (Cl2) gas at STP. A. 2.13 10-2 g/L B. 46.9 g/L C. 1.58 g/L D. 3.16 g/L E.0.316 kg/L 28. Calculate the density of Ar(g) at -11C and 675 mmHg. A. 1.52 g/L B. 1.65 g/L C. -39.3 g/L D. 39.95 g/L E.1254 g/L 29. Which of the following gases will have the greatest density at the same specified temperature and pressure? A. H2 B. CClF3 C. CO2 D. C2H6 E.CF4 30. Which one of the following gases is "lighter-than-air"? A. Cl2 B. SO2 C. PH3 D. NO2 E.Ne 31. Two moles of chlorine gas at 20.0C are heated to 350C while the volume is kept constant. The density of the gas A. B. C. D. increases. decreases. remains the same. Not enough information is given to correctly answer the question.

32. Determine the molar mass of chloroform gas if a sample weighing 0.389 g is collected in a flask with a volume of 102 cm3 at 97C. The pressure of the chloroform is 728 mmHg. A. 187 g/mol B. 121 g/mol C. 112 g/mol D. 31.6 g/mol E.8.28 10-3 g/mol

33. What is the molar mass of Freon-11 gas if its density is 6.13 g/L at STP? A. 0.274 g/mol B. 3.64 g/mol C. 78.2 g/mol D. 137 g/mol E.365 g/mol 34. Determine the molar mass of Freon-11 gas if a sample weighing 0.597 g occupies 100. cm3 at 95C, and 1,000. mmHg. A. 0.19 g/mol B. 35.3 g/mol C. 70.9 g/mol D. 137 g/mol E.384 g/mol 35. 1.018 g of Freon-113 gas is trapped in a 145 mL container at 760. mmHg and 50.0C. What is the molar mass of Freon-113? A. 21.7 g/mol B. 28.8 g/mol C. 46.1 g/mol D. 186 g/mol E.245 g/mol 36. A 0.271 g sample of an unknown vapor occupies 294 mL at 140C and 847 mmHg. The empirical formula of the compound is CH2. What is the molecular formula of the compound? A. CH2 B. C2H4 C. C3H6 D. C4H8 E.C6H12 37. A gaseous compound is 30.4% nitrogen and 69.6% oxygen by mass. A 5.25-g sample of the gas occupies a volume of 1.00 L and exerts a pressure of 1.26 atm at -4.0C. Which of the following is its molecular formula? A. NO B. NO2 C. N3O6 D. N2O4 E.N2O5

38. A mixture of three gases has a total pressure of 1,380 mmHg at 298 K. The mixture is analyzed and is found to contain 1.27 mol CO2, 3.04 mol CO, and 1.50 mol Ar. What is the partial pressure of Ar? A. 0.258 atm B. 301 mmHg C. 356 mmHg D. 5,345 mmHg E.8,020 mmHg 39. A sample of hydrogen gas was collected over water at 21C and 685 mmHg. The volume of the container was 7.80 L. Calculate the mass of H2(g) collected. (Vapor pressure of water = 18.6 mmHg at 21C.) A. 0.283 g B. 0.572 g C. 0.589 g D. 7.14 g E.435 g 40. A sample of carbon monoxide gas was collected in a 2.0 L flask by displacing water at 28C and 810 mmHg. Calculate the number of CO molecules in the flask. The vapor pressure of water at 28C is 28.3 mmHg. A. 5.0 1022 B. 5.2 1022 C. 3.8 1023 D. 5.4 1023 E.3.8 1025 41. Air contains 78% N2, 21% O2, and 1% Ar, by volume. What is the density of air at 1,000. torr and -10C? A. 1.0 g/L B. 6.1 g/L C. 1.3 g/L D. 1.8 g/L E.0.56 g/L 42. What volume of oxygen gas at 320 K and 680 torr will react completely with 2.50 L of NO gas at the same temperature and pressure? 2NO(g) + O2(g) 2NO2(g) A. 1.25 L B. 2.50 L C. 3.00 L D. 1.00 L E.5.00 L

43. What volume of CO2 gas at 645 torr and 800 K could be produced by the reaction of 45 g of CaCO3 according to the equation? CaCO3(s) CaO(s) + CO2(g) A. 0.449 L B. 22.4 L C. 25.0 L D. 34.8 L E.45.7 mL 44. How many liters of chlorine gas at 25C and 0.950 atm can be produced by the reaction of 12.0 g of MnO2? MnO2(s) + 4HCl(aq) MnCl2(aq) + 2H2O(l) + Cl2(g) A. 5.36 10-3 L B. 0.138 L C. 0.282 L D. 3.09 L E.3.55 L 45. How many liters of chlorine gas at 200C and 0.500 atm can be produced by the reaction of 12.0 g of MnO2 with HCl as follows? MnO2(s) + 4HCl(aq) MnCl2(aq) + 2H2O(l) + Cl2(g) A. 10.7 L B. 3.09 L C. 4.53 L D. 0.138 L E.0.093 L 46. How many liters of chlorine gas at 650 mmHg and 25C can be produced by the reaction of 2.00 L of 2.50 M HCl solution with excess MnO2? MnO2(s) + 4HCl(aq) MnCl2(aq) + 2H2O(l) + Cl2(g) A. 1.25 L B. 24.2 L C. 35.7 L D. 88.6 L E.143 L

47. Chlorine gas can be prepared in the laboratory by the reaction of solid manganese dioxide with hydrochloric acid. (The other reaction products are aqueous manganese chloride and water.) How much MnO2 should be added to excess HCl to obtain 275 mL of chlorine gas at 5.0C and 650 mmHg? A. 1.18 10-4 g B. 0.896 g C. 1.22 g D. 49.8 g E.8,440 g 48. How many liters of oxygen gas at 153C and 0.820 atm can be produced by the decomposition of 22.4 g of solid KClO3? (The other decomposition product is solid potassium chloride.) A. 3.0 L B. 0.085 L C. 4.20 L D. 7.79 L E.11.7 L 49. When active metals such as magnesium are immersed in acid solution, hydrogen gas is evolved. Calculate the volume of H2(g) at 30.1C and 0.85 atm that can be formed when 275 mL of 0.725 M HCl solution reacts with excess Mg to give hydrogen gas and aqueous magnesium chloride. A. 3.4 10-3 L B. 2.2 L C. 2.9 L D. 5.8 L E.11.7 L 50. Calculate the volume of H2(g) at 273 K and 2.00 atm that will be formed when 275 mL of 0.725 M HCl solution reacts with excess Mg to give hydrogen gas and aqueous magnesium chloride. A. 0.56 L B. 1.12 L C. 2.23 L D. 4.47 L E.3.54 L 51. What mass of KClO3 must be decomposed to produce 126 L of oxygen gas at 133C and 0.880 atm? (The other reaction product is solid KCl.) A. 24.6 g B. 70.8 g C. 272 g D. 408 g E.612 g 52. Which statement is false?

A.

The average kinetic energies of molecules from samples of different "ideal" gases is the same at the same temperature. B. The molecules of an ideal gas are relatively far apart. C. All molecules of an ideal gas have the same kinetic energy at constant temperature. D. Molecules of a gas undergo many collisions with each other and the container walls. E.Molecules of greater mass have a lower average speed than those of less mass at the same temperature. 53. Complete this sentence: The molecules of different samples of an ideal gas have the same average kinetic energies, at the same ________. A. B. C. D. pressure temperature volume density

54. If equal masses of O2(g) and HBr(g) are in separate containers of equal volume and temperature, which one of the following statements is true? A. The pressure in the O2 container is greater than that in the HBr container. B. There are more HBr molecules than O2 molecules. C. The average velocity of the O2 molecules is less than that of the HBr molecules. D. The average kinetic energy of HBr molecules is greater than that of O2 molecules. E.The pressures of both gases are the same. 55. Which gas has molecules with the greatest average molecular speed at 25C? A. CH4 B. Kr C. N2 D. CO2 E.Ar 56. Which of the following gas molecules have the highest average kinetic energy at 25C? A. H2 B. O2 C. N2 D. Cl2 E.All the gases have the same average kinetic energy. 57. Deviations from the ideal gas law are greater at A. B. C. D. low temperatures and low pressures. low temperatures and high pressures. high temperatures and high pressures. high temperatures and low pressures.

58. For a substance that remains a gas under the conditions listed, deviation from the ideal gas law would be most pronounced at A. 100C and 2.0 atm. B. 0C and 2.0 atm. C. -100C and 2.0 atm. D. -100C and 4.0 atm. E.100C and 4.0 atm. 59. What is the pressure of the gas trapped in the apparatus shown below when the atmospheric pressure is 720 mmHg?

A. 12 mmHg B. 708 mmHg C. 720 mmHg D. 732 mmHg E.760 mmHg

60. Determine the pressure of the gas trapped in the apparatus shown below when the atmospheric pressure is 695 mmHg.

A. 45 mmHg B. 650 mmHg C. 695 mmHg D. 740 mmHg E.760 mmHg 61. 10.0 g of gaseous ammonia and 6.50 g of oxygen gas are introduced into a previously evacuated 5.50 L vessel. If the ammonia and oxygen then react to yield NO gas and water vapor, what is the final gas pressure inside the vessel at 23C? A. 1.79 atm B. 6.48 atm C. 3.50 atm D. 0.285 atm E.3.67 atm 62. 5.00 g of hydrogen gas and 50.0 g of oxygen gas are introduced into an otherwise empty 9.00 L steel cylinder, and the hydrogen is ignited by an electric spark. If the reaction product is gaseous water and the temperature of the cylinder is maintained at 35C, what is the final gas pressure inside the cylinder? A. 7.86 atm B. 18.3 atm C. 2.58 atm D. 6.96 atm E.0.92 atm

63. 9.45 g of liquid hexane (C6H14) is introduced into a 10.0 L vessel containing 13.15 atm of oxygen gas at 21C and ignited, yielding carbon dioxide and water. If the vessel is then cooled to -10C, what will be the gas pressure inside the vessel? A. 3.09 atm B. 13.15 atm C. 1.42 atm D. 10.9 atm E.12.6 atm 64. 10.0 g of gaseous ammonia and 6.50 g of oxygen gas are introduced into a previously evacuated 5.50 L vessel. If the ammonia and oxygen then react to yield NO gas and water vapor, what is the final density of the gas mixture inside the vessel at 23C? A. 1.68 g/L B. 3.00 g/L C. 1.32 g/L D. 2.20 g/L E.16.5 g/L 65. A method of removing CO2 from a spacecraft is to allow the CO2 to react with sodium hydroxide. (The products of the reaction are sodium carbonate and water.) What volume of carbon dioxide at 25C and 749 mmHg can be removed per kilogram of sodium hydroxide that reacts? A. 301 L B. 284 L C. 276 L D. 310 L E.620 L 66. A spacecraft is filled with 0.500 atm of N2 and 0.500 atm of O2. Suppose a micrometeor strikes this spacecraft and puts a very small hole in its side. Under these circumstances, A. O2 is lost from the craft 6.9% faster than N2 is lost. B. O2 is lost from the craft 14% faster than N2 is lost. C. N2 is lost from the craft 6.9% faster than O2 is lost. D. N2 is lost from the craft 14% faster than O2 is lost. E.N2 and O2 are lost from the craft at the same rate. 67. A spacecraft is filled with 0.500 atm of O2 and 0.500 atm of He. If there is a very small hole in the side of this craft such that gas is lost slowly into outer space, A. He is lost 2.8 times faster than O2 is lost. B. He is lost 8 times faster than O2 is lost. C. He is lost twice as fast as O2 is lost. D. O2 is lost 2.8 times faster than He is lost. E.O2 is lost 8 times faster than He is lost.

68. 1.000 atm of dry nitrogen, placed in a container having a pinhole opening in its side, leaks from the container 3.54 times faster than does 1.000 atm of an unknown gas placed in this same apparatus. Which of the following species could be the unknown gas? A. NH3 B. C4H10 C. SF6 D. UF6 E.Rn 69. 1.000 atm of oxygen gas, placed in a container having a pinhole opening in its side, leaks from the container 2.14 times faster than does 1.000 atm of an unknown gas placed in this same apparatus. Which of the following species could be the unknown gas? A. Cl2 B. SF6 C. Kr D. UF6 E.Xe 70. Samples of the following volatile liquids are opened simultaneously at one end of a room. If you are standing at the opposite end of this room, which species would you smell first? [Assume that your nose is equally sensitive to all these species.] A. ethyl acetate (CH3COOC2H5) B. camphor (C10H16O) C. diethyl ether (C2H5OC2H5) D. naphthalene (C10H8) E.pentanethiol (C5H11SH) 71. A sample of mercury(II) oxide is placed in a 5.00 L evacuated container and heated until it decomposes entirely to mercury metal and oxygen gas. After the container is cooled to 25C, the pressure of the gas inside is 1.73 atm. What mass of mercury(II) oxide was originally placed into the container? A. 913 g B. 76.6 g C. 1.51 g D. 45.6 g E.153 g 72. The mole fraction of oxygen molecules in dry air is 0.2095. What volume of dry air at 1.00 atm and 25C is required for burning 1.00 L of hexane (C6H14, density = 0.660 g/mL) completely, yielding carbon dioxide and water? A. 187 L B. 712 L C. 1780 L D. 894 L E.8490 L

73. The mole fraction of oxygen molecules in dry air is 0.2095. What volume of dry air at 1.00 atm and 25C is required for burning 1.00 L of octane (C8H18, density = 0.7025 g/mL) completely, yielding carbon dioxide and water? A. 718 L B. 367 L C. 8980 L D. 1880 L E.150 L 74. A block of dry ice (solid CO2, density = 1.56 g/mL) of dimensions 25.0 cm 25.0 cm 25.0 cm is left to sublime (i.e., to pass from the solid phase to the gas phase) in a closed chamber of dimensions 4.00 m 5.00 m 3.00 m. The partial pressure of carbon dioxide in this chamber at 25C will be A. 171 mmHg. B. 107 mmHg. C. 0.225 mmHg. D. 0.171 mmHg. E.14.4 mmHg. 75. A 2.50-L flask contains a mixture of methane (CH4) and propane (C3H8) at a pressure of 1.45 atm and 20C. When this gas mixture is then burned in excess oxygen, 8.60 g of carbon dioxide is formed. (The other product is water.) What is the mole fraction of methane in the original gas mixture? A. 0.34 B. 1.00 C. 0.66 D. 0.85 E.0.15 76. What is the definition of "gas"?

77. What is standard temperature and standard pressure?

78. What is the significance of the magnitude of the van der Waals "a" constant?

79. Liquid oxygen boils at -183C. What is this temperature in kelvins?

80. How many grams of N2O, nitrous oxide, are contained in 500. mL of the gas at STP?

81. Calculate the density of N2O gas, in grams per liter, at 110C and 12 atm.

82. Calculate the molar mass of a gaseous substance if 0.125 g of the gas occupies 93.3 mL at STP.

83. What is the density, in molecules per cubic centimeter, of N2 gas at 25C and 650 mmHg?

84. An aerosol can with a volume of 0.50 L has a bursting point of 2.6 atm. If the can contains 1.0 g CO2 and is heated to 400C, will it burst?

85. Phosgene, a gas used in World War I, consists of 12.41% C, 16.17% O, and 71.69% Cl. 1.00 L of this gas at STP has a mass of 4.42 g. What is the molecular formula of phosgene?

86. The van der Waals equation is a modification of the ideal gas equation. For what two facts does this equation account?

87. On a spring morning (20C) you fill your tires to a pressure of 2.25 atmospheres. As you ride along, the tire heats up to 45C from the friction on the road. What is the pressure in your tires now?

88. A gas-filled balloon with a volume of 12.5 L at 0.90 atm and 21C is allowed to rise to the stratosphere where the temperature is -5C and the pressure is 1.0 millibar. What is the final volume of the balloon? 1.000 atm = 1.013 bar.

89. What volume of H2 is formed at STP when 6.0 g of Al is treated with excess NaOH? 2NaOH + 2Al + 6H2O 2NaAl(OH)4 + 3H2(g)

90. What is V in the table below?

91. What is P in the table below?

92. What is T in the table below?

93. What is P in the table below?

94. Today is a beautiful day for a picnic in the mountains, so we seal our peanut butter sandwich in a plastic sandwich bag at the base of the mountain. The approximate volume of the sandwich bag not occupied by the sandwich is 200. mL. The pressure at the base of the mountain is 1.0 atm. If the pressure at the top of the mountain is 0.8 atm, what is the final volume of gas in our sandwich bag?

95. What is Boyle's law?

96. Give five examples of elements that occur as gases at room temperature and pressure?

97. Give five examples of compounds that exist as gases at room temperature and pressure.

98. Change 75C to K.

99. What is Charles' law? What effect does the relationship described in Charles' law have on a balloon that is left in the sun?

100. A balloon is blown up in the morning (23C) to a volume of 1.00 liter. If this balloon is left in a hot car with the windows left up and the car warms up to 35C, what will be the final volume of the balloon?

101. At constant pressure, the density of a gas depends on temperature. Does the density increase or decrease as the temperature increases?

102. In a weather forecast on a Seattle radio station the barometric pressure was reported to be 29.4 inches. What is the pressure in SI units? (1 inch = 25.4 mm, 1 atm = 760 mmHg)

103. At STP, 1 mole of gas has a molar volume of 22.4 L. What is the density of oxygen at STP?

104. What is Gay-Lussac's Law? How will this affect the pressure in our car tires?

105. Ammonium nitrite undergoes decomposition to produce only gases as shown below. NH4NO2(s) N2(g) + 2H2O(g) How many liters of gas will be produced by the decomposition of 32.0 g of NH4NO2 at 525C and 1.5 atm?

106. There is a power plant in Portland, Oregon that is very concerned about global warming. This plant takes all of its exhaust gases from its boilers and recycles the CO2 using the Solvay process to make sodium hydrogen carbonate. The reaction is shown below. NH3(g) + H2O(l) + CO2(g) + NaCl(aq) NaHCO3(aq) + NH4Cl(aq) How many liters each of NH3 and CO2 (both at STP) are needed to make 3.00 kg of sodium bicarbonate?

107. Baking powder is made up of sodium hydrogen carbonate and calcium hydrogen phosphate. When baking powder is wet, these components react to produce carbon dioxide. The equation for this reaction is given below. NaHCO3(aq) + CaHPO4(aq) NaCaPO4(aq) + CO2(g) + H2O(l) How many liters of carbon dioxide can be formed at room temperature from 4.00 g of NaHCO3 and excess CaHPO4?

108. Packaged cake mixes usually contain baking powder, a mixture of sodium hydrogen carbonate and calcium hydrogen phosphate that react to produce carbon dioxide gas when they come into contact with water. Many such mixes have special instructions for use at high altitudes. Why?

109. Many automobiles produce about 5 grams of NO for each mile they are driven. How many liters of NO gas at STP would be produced on a 100-mile trip?

110. A particular coal sample contains 2.32% S. When the coal is burned, the sulfur is converted to SO2 (g). What volume of SO2 (g), measured at 25C and 749 mmHg, is produced by burning 2.0 106 lb of this coal? (1 lb = 454 g)

111. At standard temperature and pressure, a given sample of water vapor occupies a volume of 2.80 L. How many moles of water vapor are present?

112. At standard temperature and pressure, a given sample of water vapor occupies a volume of 2.80 L. What is the weight of the water?

113. At standard temperature and pressure, a given sample of water vapor occupies a volume of 2.80 L. How many hydrogen atoms are present in the container?

114. Gasoline (which can be considered to be octane, C8H18) burns in oxygen to produce carbon dioxide and water. What volume of oxygen at STP is necessary to react with 1.0 gal of gasoline? (The density of gasoline is 0.81 g/mL. 1 gal = 3.78 L)

115. Gasoline (which can be considered to be octane, C8H18) burns in oxygen to produce carbon dioxide and water. What volume of carbon dioxide at STP is generated as a result of the combustion of 1.0 gal of gasoline? (The density of gasoline is 0.81 g/mL. 1 gal = 3.78 L)

Chapter 5 Gases Key

29.B 30.E 31.C 32.B 33.D 34.D 35.D 36.B 37.D 38.C 39.B 40.A 41.D 42.A 43.D 44.E 45.A 46.C 47.B 48.E 49.C 50.B 51.C 52.C 53.B 54.A 55.A 56.E 57.B 58.D 59.B 60.D 61.E

62.A 63.D 64.B 65.D 66.C 67.A 68.D 69.B 70.C 71.E 72.E 73.C 74.A 75.D 76.A "gas" is a substance in which the molecules are separated on the average by distances that are large compared with the sizes of the molecules. 77.0C and 1 atm pressure 78.The magnitude of the van der Waals "a" constant reflects the strength of the attractions between molecules of a given type of gas. 79.90 K 80.0.982 g 81.16.8 g/L 82.30.0 g/mol 83.2.1 1019 molecules/cm3 84.no 85.COCl2 86.(1) Real gas molecules exert forces on each other. (2) Gas molecules have volume. 87.2.44 atmospheres 88.1.0 104 L 89. 7.5 L 90.250 mL 91.0.28 L 92.182 K or -91.0C 93.2 atm 94.250 mL

95.At constant temperature, the volume of a gas is inversely proportional to the pressure. 96.(Answers will vary.) Oxygen, nitrogen, helium, hydrogen, argon, chlorine 97.(Answers will vary.) Ammonia, carbon dioxide, sulfur dioxide, nitrogen dioxide, methane 98.348 K 99.At constant pressure, volume is directly proportional to temperature. A balloon left in the sun will expand. 100.1.04 L 101.The density decreases. 102.0.983 atm 103.1.43 g/L 104.The law states that at constant volume, pressure is proportional to temperature. We can say that our tire pressure will increase as the friction heats up the air inside our tires. 105. 65 L 106.The volume of both NH3 and CO2 would be 800. liters. 107.Approximately 1.16 liters 108.The baking powder acts as a leavening agent. Due to the reduced atmospheric pressure, a greater volume of carbon dioxide is created. 109.400 liters of NO 110.1.6 107 liters 111.0.125 mol 112.2.25 g 113.1.51 1023 atoms 114.7,500 L 115.4,800 L

1. Name five elements that exist as gases at room temperature. A) O2, N2, Cl2, Br2, He B) O2, N2, O3, Br2, He C) O2, N2, Cl2, O3, He D) O2, Cl2, S2, O3, He 2. Name five compounds that exist as gases at room temperature. A) CO2, NH3, CH4, CCl4, CO B) HCl, NaCl, NH3, CH4, CO C) CO2, HCl, NH3, CH4, CO D) CO2, HCl, H2O, NH3, CO 3. Which is not a physical characteristic of gases? A) Gases are the most compressible of the states of matter. B) Gases assume the volume and shape of their containers. C) Gases will mix evenly and completely when confined to the same container. D) Gases have higher density than liquids and solids. 4. Define pressure. A) force applied per unit volume B) force applied per unit area C) area per unit force D) volume per unit force 5. Give the common units for pressure. A) mmHg, atm, kPa B) mmH2O, atm, Pa C) mmH2O atm, kPa D) mmHg, atm, liters 6. The column of mercury in a barometer is supported by a reservoir of water. A) True B) False 7. Most manometers are used to measure atmospheric pressure. A) True B) False 8. Why is mercury a more suitable substance to use in a barometer than water? A) mercury is less dense than water B) mercury has a higher freezing point than water C) mercury is more dense than water D) mercury doesn't vaporize

9. Which one of the following statements is ture concerning the atmospheric pressure in a mine that is 500 m below sea level? A) greater than 1 atm B) less than 1 atm C) equal to 1 atm D) approaching 0 atm 10. What is the difference between a gas and a vapor? A) A gas is a substance normally in the gaseous state at normal atmospheric conditions (25C, 1 atm); a vapor is the gaseous form of any substance that is a liquid or a solid at normal temperatures and pressures. B) A gas is the gaseous form of any substance; a vapor refers to a gas over a water surface. C) A gas is a substance normally in the gaseous state at normal atmospheric conditions (25C, 1 atm); a vapor is a gas over a water surface. D) A gas and a vapor are two interchangeable nomenclatures; they are idenctical. 11. At 25C, which of the following substances in the gas phase should be properly called a gas and which should be called a vapor: molecular nitrogen (N2), mercury (Hg)? A) N2 is a gas; Hg is a gas B) N2 is a vapor; Hg is a vapor C) N2 is a gas; Hg is a vapor D) N2 is a vapor; Hg is a gas. 12. If the maximum distance that water may be brought up a well by a suction pump is 34 ft (10.3 m), how is it possible to obtain water and oil from hundreds of feet below the surface of Earth? A) Attach a stronger vacuum pump. B) Pump something (like water or air) down into the well to equalize the pressure; then suction pump the desired substance up. C) Drill a side vent for the pressures to be released. D) Use a physical pump to scoop the water or oil up. 13. Why do astronauts have to wear protective suits when they are on the surface of the moon? A) The atmosperic pressure on the moon is too high, it would crush them. B) The atmosperic pressure on the moon is too low, their cells would all rupture and release gasses, killing them. C) The temperatures are too cold, or too hot, to sustain life for long; and there is no oxygen to breathe. D) both b and c 14. Convert 562 mmHg to atm. A) 0.739 atm B) 4.27 105 atm C) 1.05 atm

D) 0.562 atm 15. Convert 2.0 atm to mmHg. A) 150 mmHg B) 0.27 mmHg C) 150 mmHg D) 1500 mmHg 16. The atmospheric pressure at the summit of Mt. McKinley is 606 mmHg on a certain day. What is the pressure in atm and in kPa? A) 4.61 105 atm, 80.8 kPa B) 4.61 105 atm, 7.87 10-3 kPa C) 0.797 atm, 80.8 kPa D) 0.797 atm, 7.87 10-3 kPa 17. Explain why a helium weather balloon expands as it rises in the air. Assume that the temperature remains constant. A) The number of moles of gas increase as the balloon rises. B) The atmosperic pressure outside the balloon increases, and the gas inside expands to equal that pressure. C) Pressure and volume are directly proportional at constant temperature. D) The atmosperic pressure outside the balloon decreases, and the gas inside expands to equal that pressure. 18. A gas occupying a volume of 725 mL at a pressure of 0.970 atm is allowed to expand at constant temperature until its pressure reaches 0.541 atm. What is its final volume? A) 380 mL B) 1.30 103 mL C) 130 mL D) 1.34 103 mL 19. At 46C a sample of ammonia gas exerts a pressure of 5.3 atm. What is the pressure when the volume of the gas is reduced to one-tenth (0.10) of the original value at the same temperature? A) 53 atm B) 0.53 atm C) 530 atm D) 24.4 atm 20. The volume of a gas is 5.80 L, measured at 1.00 atm. What is the pressure of the gas in mmHg if the volume is changed to 9.65 L? (The temperature remains constant.) A) 457 mm Hg B) 0.074 mm Hg C) 4.25 104 mm Hg D) 0.601 mm Hg

21. A sample of air occupies 3.8 L when the pressure is 1.2 atm. What volume does it occupy at 6.6 atm? (The temperature is kept constant.) A) 30.1 L B) 0.58 L C) 0.69 L D) 20.9 L 22. A sample of air occupies 3.8 L when the pressure is 1.2 atm. What pressure is required in order to compress it to 0.075 L? (The temperature is kept constant.) A) 42 atm B) 0.24 atm C) 24 atm D) 61 atm 23. A 36.4-L volume of methane gas is heated from 25 C to 88 C at constant pressure. What is the final volume of the gas? A) 128.1 L B) 44.1 L C) 30.0 L D) 80.5 L 24. Under constant-pressure conditions a sample of hydrogen gas initially at 88 C and 9.6 L is cooled until its final volume is 3.4 L. What is its final temperature? A) 31.2 C B) 31.2 K C) 1.0 103 K D) 1.3 102 K 25. Ammonia burns in oxygen gas to form nitric oxide (NO) and water vapor. How many volumes of NO are obtained from one volume of ammonia at the same temperature and pressure? A) One B) Two C) Three D) Four 26. Molecular chlorine and molecular fluorine combine to form a gaseous product. Under the same conditions of temperature and pressure it is found that one volume of Cl2 reacts with three volumes of F2 to yield two volumes of the product. What is the formula of the product? A) Cl2F2 B) Cl2F6 C) ClF2 D) ClF3

27. Which is not a characteristic of an ideal gas? A) The molecules of an ideal gas do not attract one another. B) The molecules of an ideal gas repel one another. C) The volume of the ideal gas molecules is negligible compared to the volume of the container. D) The pressure, volume, temperature relationship of this gas fits the ideal gas equation. 28. Write the ideal gas equation. Give the units for each term in the equation. A) PV = nRT; P in torr, V in L, n in mol, R in Latm/Kmol, T in C. B) PV = nRT; P in torr, V in L, n in mol, R in Latm/Kmol, T in K. C) PV = nRT; P in atm, V in L, n in mol, R in Latm/Kmol, T in K. D) PV = nRT; P in atm, V in L, n in mol, R in Latm/Kmol, T in C . 29. What are standard temperature and pressure (STP)? A) 0 C, 1 torr B) 25 C, 1 torr C) 0 C, 1 atm D) 25 C, 1 atm 30. What is the volume of one mole of an ideal gas at STP? A) 24.5 L B) 22.4 L C) 1.0 L D) 10.0 L 31. Why is the density of a gas much lower than that of a liquid or solid under atmospheric conditions? A) There are much weaker intermolecular forces between gas molecules. B) Gas molecules are separated by distances that are large compared to their size. C) Gas molecules are not very compressible. D) Both a and b. 32. What units are normally used to express the density of gases? A) g/mL B) kg/L C) mg/L D) g/L 33. A sample of nitrogen gas kept in a container of volume 2.3 L and at a temperature of 32 C exerts a pressure of 4.7 atm. Calculate the number of moles of gas present. A) 4.1 mol B) 0.43 mol C) 0.24 mol D) 0.043 mol

34. Given that 6.9 moles of carbon monoxide gas are present in a container of volume 30.4 L, what is the pressure of the gas (in atm) if the temperature is 62 C? A) 6.2 atm B) 1.2 atm C) 1,100 atm D) 62 atm 35. What volume will 5.6 moles of sulfur hexafluoride (SF6) gas occupy if the temperature and pressure of the gas are 128 C and 9.4 atm? A) 2.0 101 L B) 6.3 L C) 2.0 102 L D) 63 L 36. A certain amount of gas at 25 C and at a pressure of 0.800 atm is contained in a glass vessel. Suppose that the vessel can withstand a pressure of 2.00 atm. How high can you raise the temperature of the gas without bursting the vessel? A) 62.5 C B) 336 C C) 472 C D) 745 C 37. A gas-filled balloon having a volume of 2.50 L at 1.2 atm and 25 C is allowed to rise to the stratosphere (about 30 km above the surface of Earth), where the temperature and pressure are -23C and 3.00 10-3 atm, respectively. Calculate the final volume of the balloon. A) 660 L B) 840 L C) 920 L D) 10,000 L 38. The temperature of 2.5 L of a gas initially at STP is raised to 250 C at constant volume. Calculate the final pressure of the gas in atm. A) 1.8 atm B) 10 atm C) 1.9 atm D) 12.5 atm 39. The pressure of 6.0 L of an ideal gas in a flexible container is decreased to one-third of its original value, and its absolute temperature is decreased by one-half. What is the final volume of the gas? A) 9.0 L B) 6.0 L C) 4.0 L

D) 1.0 L 40. A gas evolved during the fermentation of glucose (wine making) has a volume of 0.78 L at 20.1C and 1.00 atm. What was the volume of this gas at the fermentation temperature of 36.5 C and 1.00 atm pressure? A) 0.82 L B) 1.42 L C) 12.0 L D) 8.2 L 41. An ideal gas originally at 0.85 atm and 66 C was allowed to expand until its final volume, pressure, and temperature were 94 mL, 0.60 atm, and 45C, respectively. What was its initial volume? A) 97 mL B) 0.071 mL C) 7.1 mL D) 71 mL 42. Calculate the volume (in liters) of 88.4 g of CO2 at STP. A) 53.9 L B) 45.0 L C) 26.6 L D) 0.245 L 43. A gas at 772 mmHg and 35.0 C occupies a volume of 6.85 L. Calculate its volume at STP. A) 4,690 L B) 4.97 L C) 6.17 L D) 6.73 L 44. Dry ice is solid carbon dioxide. A 0.050-g sample of dry ice is placed in an evacuated 4.6-L vessel at 30 C. Calculate the pressure inside the vessel after all the dry ice has been converted to CO2 gas. A) 6.1 10-3 atm B) 12 atm C) 6.1 10-4 atm D) 1.2 atm 45. At STP, 0.280 L of a gas weighs 0.400 g. Calculate the molar mass of the gas. A) 27.8 g/mol B) 32.0 g/mol C) 10.9 g/mol D) 2.93 g/mol

46. At 741 torr and 44 C, 7.10 g of a gas occupy a volume of 5.40 L. What is the molar mass of the gas? A) 35.0 g/mol B) 20.3 g/mol C) 4.85 g/mol D) 46.0 g/mol 47. Ozone molecules in the stratosphere absorb much of the harmful radiation from the sun. Typically, the temperature and pressure of ozone in the stratosphere are 250 K and 1.0 10-3 atm, respectively. How many ozone molecules are present in 1.0 L of air under these conditions? A) 4.9 10-5 molecules B) 2.0 1017 molecules C) 2.9 1019 molecules D) 3.2 1020 molecules 48. Assuming that air contains 78 percent N2, 21 percent O2, and 1 percent Ar, all by volume, how many molecules of each type of gas are present in 1.0 L of air at STP? A) 2.1 1022 N2 molecules, 5.7 1021 O2 molecules, 2.5 1020 Ar atoms B) 1.9 1022 N2 molecules, 5.2 1021 O2 molecules, 2.5 1020 Ar atoms C) 5.7 1024 N2 molecules, 1.6 1024 O2 molecules, 7.4 1022 Ar atoms D) 2.1 1022 N2 molecules, 5.7 1021 O2 molecules, 3.0 1020 Ar atoms Use the following to answer questions 49-50: A 2.10-L vessel contains 4.65 g of a gas at 1.00 atm and 27.0 C. 49. Calculate the density of the gas in grams per liter. A) 0.452 g/L B) 0.452 L/g C) 2.21 L/g D) 2.21 g/L 50. What is the molar mass of the gas? A) 4.90 g/mol B) 54.4 g/mol C) 11.1 g/mol D) 1.00 g/mol 51. Calculate the density of hydrogen bromide (HBr) gas in grams per liter at 733 mmHg and 46 C. A) 2.98 g/L B) 28.0 g/L C) 20.7 g/L

D) 2.01 10-2 g/L 52. A certain anesthetic contains 64.9 percent C, 13.5 percent H, and 21.6 percent O by mass. At 120 C and 750 mmHg, 1.00 L of the gaseous compound weighs 2.30 g. What is the molecular formula of the compound? A) C4H10O2 B) C8H20O2 C) C4H10O D) C2H5O 53. A compound has the empirical formula SF4. At 20 C, 0.100 g of the gaseous compound occupies a volume of 22.1 mL and exerts a pressure of 1.02 atm. What is the molecular formula of the gas? A) S3F12 B) S2F8 C) SF4 D) SF2 54. Consider the formation of nitrogen dioxide from nitric oxide and oxygen: 2NO(g) + O2(g) 2NO2(g) If 9.0 L of NO are reacted with excess O2 at STP, what is the volume in liters of the NO2 produced? A) 9.0 B) 4.5 L C) 18 L D) 6.2 L 55. Methane, the principal component of natural gas, is used for heating and cooking. The combustion process is: CH4(g) + 2O2(g) CO2(g) + 2H2O(l) If 15.0 moles of CH4 are reacted, what is the volume of CO2 (in liters) produced at 23.0 degrees C and 0.985 atm? A) 450 L B) 370 L C) 189 L D) 12.6 L 56. When coal is burned, the sulfur present in coal is converted to sulfur dioxide (SO2), which is responsible for the acid rain phenomenon, S(s) + O2(g) SO2(g) If 2.54 kg of S are reacted with oxygen, calculate the volume of SO2 gas (in liters) formed at 30.5 degrees C and 1.12 atm. A) 56.6 L B) 694 L C) 981 L D) 1.76 103 L

57. In alcohol fermentation, yeast converts glucose to ethanol and carbon dioxide: C6H12O6(s) 2C2H5OH(l) + 2CO2(g) If 5.97 g of glucose are reacted and 1.44 L of CO2 gas are collected at 293 K and 0.984 atm, what is the percent yield of the reaction? A) 50.6% B) 77.2% C) 88.9% D) 100.% 58. A compound of P and F was analyzed as follows: Heating 0.2324 g of the compound in a 378-cm3 container turned all of it to gas, which had a pressure of 97.3 mmHg at 77 C. Then the gas was mixed with calcium chloride solution, which turned all of the F to 0.2631 g of CaF2. Determine the molecular formula of the compound. A) P2F4 B) PF2 C) PF D) P3F6 Use the following to answer questions 59-60: A quantity of 0.225 g of a metal M (molar mass = 27.0 g/mol) liberated 0.303 L of molecular hydrogen (measured at 17 C and 741 mmHg) from an excess of hydrochloric acid. 59. Deduce from these data the corresponding equation. A) M(s) + HCl (aq) 0.5 H (g) + MCl (aq)
2

B) M(s) + 2 HCl (aq) H (g) + MCl (aq) 2 2 C) M(s) + 3 HCl (aq) 1.5 H (g) + MCl (aq) 2 3 D) 2 M(s) + 3 HCl (aq) 1.5 H (g) + M Cl (aq)
2 2 3

60. Write molecular formulas for the oxide and sulfate of M. A) MO and M(SO4) B) M2O3 and M2(SO4)3 C) MO3 and M2(SO4)2 D) M2O3 and M2(SO4)2 Use the following to answer questions 61-63: 73.0 g of NH3 is mixed with an equal mass of HCl. 61. What is the mass of the solid NH4Cl formed? A) 53.5 g B) 107 g

C) 26.7 g D) 229 g 62. What is the volume of the gas remaining, measured at 14.0 C and 752 mmHg? A) 0.062 L B) 2.66 L C) 47.6 L D) 54.5 L 63. What is the identity of the remaining gas? A) Hydrogen B) Nitrogen C) Ammonia D) Hydrogen chloride Use the following to answer questions 64-65: Dissolving 3.00 g of an impure sample of calcium carbonate in hydrochloric acid produced 0.656 L of carbon dioxide (measured at 20.0 C and 792 mmHg). 64. Calculate the percent by mass of calcium carbonate in the sample. A) 94.7 % B) 7.2 % C) 13.9 % D) 86.1 % 65. State any assumptions that you make in calculating the percent by mass of calcium carbonate in the sample. A) Carbon dioxide behaves as an ideal gas. B) The impurities must not react with hydrochloric acid to produce carbon dioxide. C) Both a and b. D) Carbon dioxide does not act as an ideal gas. 66. Calculate the mass in grams of hydrogen chloride produced when 5.6 L of molecular hydrogen measured at STP react with an excess of molecular chlorine gas. A) 18 g B) 9.0 g C) 0.5 g D) 4.6 g

67. Ethanol (C2H5OH) burns in air: C2H5OH(l) + O2(g) CO2(g) + H2O(l) Balance the equation and determine the volume of air in liters at 35.0 C and 790 mmHg required to burn 227 g of ethanol. Assume that air is 21.0 percent O2 by volume. A) 360 L B) 571 L C) 75.6 L D) 1,710 L 68. Refer to Dalton's law of partial pressures and explain what mole fraction is. A) The number of moles of one component. B) The ratio of the number of moles of one component to the number of moles of all components present. C) The number of moles of one component divided by 100. D) The ratio of the number of moles of all components present to the number of moles of one component. 69. Does mole fraction have units? A) yes, mol B) yes, mol-1 C) no 70. A sample of air contains only nitrogen and oxygen gases whose partial pressures are 0.80 atm and 0.20 atm, respectively. Calculate the total pressure and the mole fractions of the gases. A) 2 atm; of N2 = 0.40 mol, of O2 = 0.10 mol B) 1 atm; of N2 = 0.80 mol, of O2 = 0.20 mol C) 2 atm; of N2 = 0.40 , of O2 = 0.10 D) 1 atm; of N2 = 0.80, of O2 = 0.20 71. A mixture of gases contains 0.31 mol CH4, 0.25 mol C2H6, and 0.29 mol C3H8. The total pressure is 1.50 atm. Calculate the partial pressures of the gases. A) Partial pressures: CH4 = 0.24 atm, C2H6 = 0.19 atm, C3H8 = 0.23 atm B) Partial pressures: CH4 = 0.54 atm, C2H6 = 0.44 atm, C3H8 = 0.51 atm C) Partial pressures: CH4 = 0.46 atm, C2H6 = 0.38 atm, C3H8 = 0.44 atm D) Partial pressures: CH4 = 0.21 atm, C2H6 = 0.17 atm, C3H8 = 0.19 atm Use the following to answer questions 72-73: A 2.5-L flask at 15 C contains a mixture of N2, He, and Ne at partial pressures of 0.32 atm for N2, 0.15 atm for He, and 0.42 atm for Ne. 72. Calculate the total pressure of the mixture. A) 2.2 atm B) 1.8 atm

C) 0.36 atm D) 0.89 atm 73. Calculate the volume in liters at STP occupied by He and Ne if the N2 is removed selectively. A) 2.2 L B) 2.4 L C) 1.4 L D) 1.6 L Use the following to answer questions 74-75: Dry air near sea level has the following composition by volume: N2, 78.08 percent; O2, 20.94 percent; Ar, 0.93 percent; CO2, 0.05 percent. The atmospheric pressure is 1.00 atm. 74. Calculate the partial pressure of each gas in atm. A) Partial pressures: N2 =0.781 atm; O2 = 0.209 atm; Ar = 9.3 10-3 atm; CO2 = 5 104 atm B) Partial pressures: N2 =78.1 atm; O2 = 20.9 atm; Ar = 0.93 atm; CO2 = 0.05 atm C) Partial pressures: N2 =78.1 atm; O2 = 20.9 atm; Ar = 9.3 10-3 atm; CO2 = 5 10-4 atm D) Partial pressures: N2 =0.0781 atm; O2 = 0.0209 atm; Ar = 9.3 10-4 atm; CO2 = 5 10-5 atm 75. Calculate the concentration of each gas in moles per liter at 0 C. (Hint: Because volume is proportional to the number of moles present, mole fractions of gases can be expressed as ratios of volumes at the same temperature and pressure.) A) N2: 4.46 10-2 M; O2: 1.67 10-2 M; Ar: 7.4 10-3 M; CO2: 4 10-4 M B) N2: 3.48 10-2 M; O2: 9.34 10-3 M; Ar: 4.1 10-4 M; CO2: 2 10-5 M C) N2: 17.5 M; O2: 4.68 M; Ar: 0.21 M; CO2: 0.01 M D) N2: 28.7 M; O2: 107 M; Ar: 2.4 103 M; CO2: 5 104 M 76. A mixture of helium and neon gases is collected over water at 28.0 C and 745 mmHg. If the partial pressure of helium is 368 mmHg, what is the partial pressure of neon? (Vapor pressure of water at 28 C = 28.3 mmHg.) A) 385 mmHg B) 349 mmHg C) 317 mmHg D) 364 mmHg

77. A piece of sodium metal reacts completely with water as follows: 2Na(s) + 2H2O(l) 2NaOH(aq) + H2(g) The hydrogen gas generated is collected over water at 25.0 C. The volume of the gas is 246 mL measured at 1.00 atm. Calculate the number of grams of sodium used in the reaction. (Vapor pressure of water at 25C = 0.0313 atm.) A) 0.22 g Na B) 5.3 g Na C) 0.45 g Na D) 2.7 g Na 78. A sample of zinc metal reacts completely with an excess of hydrochloric acid: Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g) The hydrogen gas produced is collected over water at 25.0 C using an arrangement similar to that shown in Figure 5.15. The volume of the gas is 7.80 L, and the pressure is 0.980 atm. Calculate the amount of zinc metal in grams consumed in the reaction. (Vapor pressure of water at 25 C = 23.8 mmHg.) A) 1.18 g Zn B) 39.6 g Zn C) 236 g Zn D) 19.8 g Zn 79. Helium is mixed with oxygen gas for deep-sea divers. Calculate the percent by volume of oxygen gas in the mixture if the diver has to submerge to a depth where the total pressure is 4.2 atm. The partial pressure of oxygen is maintained at 0.20 atm at this depth. A) 5.0 % B) 3.8 % C) 21 % D) 4.8 % 80. A sample of ammonia (NH3) gas is completely decomposed to nitrogen and hydrogen gases over heated iron wool. If the total pressure is 866 mm Hg, calculate the partial pressures of N2 and H2. A) Partial pressures: N2 = 217 mm Hg; H2 = 650 mm Hg B) Partial pressures: N2 = 433 mm Hg; H2 = 433 mm Hg C) Partial pressures: N2 = 650 mm Hg; H2 = 217 mm Hg D) Partial pressures: N2 = 289 mm Hg; H2 = 577 mm Hg 81. What does the Maxwell speed distribution curve describe? A) At a given T, the curve shows the speed of the molecules according to size. B) The curve shows T versus molecular speed at a given pressure. C) At a given T, the curve shows the number of molecules versus their molecular speed. D) At a given T, the curve shows pressure versus the molecular speed of the gas.

82. Does Maxwell's theory work for a sample of 200 molecules? A) yes B) no 83. Refer to the expression for the root-mean-square speed for a gas at temperature T. Define each term in the equation and show the units that are used in the calculation. A) urms in m/s; R in L atm/K mol; T in K; M in kg/mol B) urms in m/s; R in J/K mol; T in C; M in g/mol C) urms in m/s; R in J/K mol; T in K; M in kg/mol D) urms in cm/s; R in J/K mol; T in K; M in kg/mol 84. Which of the following statements is correct? A) Heat is transferred through molecular collisions. B) When a gas is heated at constant volume, the molecules collide with one another more often. C) Both a and b are correct. D) Neither a nor b are correct. 85. Uranium hexafluoride (UF6) is a much heavier gas than helium, yet at a given temperature, the average kinetic energies of the molecules of the two gases are the same. Explain. A) Kinetic energy is only dependent on T for all gases. B) UF6 molecules will be moving slower than the He molecules. C) UF6 molecules will be moving faster than the He molecules. D) Both a and b. E) Both a and c. 86. Compare the root-mean-square speeds of O2 and UF6 at 65 C. A) RMS speed for: O2 = 513 m/s; UF6 = 155 m/s B) RMS speed for: O2 : = 2.60 103 m/s; UF6 = 237 m/s C) RMS speed for: O2 : = 2.64 105 m/s; UF6 = 2.39 104 m/s D) RMS speed for: O2 : = 225 m/s; UF6 = 67.5 m/s 87. The temperature in the stratosphere is -23C. Calculate the root-mean-square speeds of N2, O2, and O3 molecules in this region. A) RMS speed for: N2 = 15 m/s; O2 ,= 16 m/s; and O3 = 13 m/s B) RMS speed for: N2 = 472 m/s; O2 ,= 441 m/s; and O3 = 360 m/s C) RMS speed for: N2 = 143 m/s; O2 ,= 134 m/s; and O3 = 109 m/s D) RMS speed for: N2 = 2.2 105 m/s; O2 = 1.9 105 m/s; and O3 = 1.3 105 m/s 88. The average distance traveled by a molecule between successive collisions is called mean free path. For a given amount of a gas, how does the mean free path of a gas depend on density? A) Inversely proportional to density. B) Directly proportional to density.

C) Independent of density. 89. For a given amount of a gas, how does the mean free path of its molecules depend on temperature at constant volume? A) Decreases with increasing temperature. B) Increases with increasing temperature. C) Independent of temperature. 90. For a given amount of a gas, how does the mean free path of its molecules depend on pressure at constant temperature? A) Increases with increasing pressure. B) Independent of pressure. C) Decreases with increasing pressure. 91. For a given amount of a gas, how does the mean free path of its molecules depend on volume at constant temperature? A) Increases with increasing volume. B) Independent of volume. C) Decreases with increasing volume. 92. For a given amount of a gas, how does the mean free path of its molecules depend on their size? A) Directly proportional to size. B) Inversely proportional to size. C) Independent of size. Use the following to answer questions 93-94: At a certain temperature the speeds of six gaseous molecules in a container are 2.0 m/s, 2.2 m/s, 2.6 m/s, 2.7 m/s, 3.3 m/s, and 3.5 m/s. 93. Calculate the root-mean-square speed and the average speed of the molecules. A) RMS speed = 6.8 m/s; Average speed = 16 m/s B) RMS speed = 2.8 m/s; Average speed = 2.7 m/s C) RMS speed = 16.8 m/s; Average speed = 16.0 m/s D) RMS speed = 2.9 m/s; Average speed = 2.8 m/s 94. The values for root mean square speed and for the average speed of the gas molecules are close to each other, but the root-mean-square value is always the larger of the two. Why? A) For RMS speed, squaring favors the smaller values. B) It is unexplainable, it just happens. C) For RMS speed, squaring favors the larger values.

95. Cite two ways to demonstrate that gases do not behave ideally under all conditions. A) Heating gaseous Rb atoms to an extremely high temperature. B) Putting methane gas under high pressure. C) Cooling gaseous Rb atoms to an extremely cold temperature. D) b and c E) a and b 96. Under what set of conditions would a gas be expected to behave most ideally? A) High temperature and low pressure B) High temperature and high pressure C) Low temperature and high pressure D) Low temperature and low pressure. 97. A real gas is introduced into a flask of volume V. Is the corrected volume of the gas greater or less than V? A) Greater than V. B) Less than V. C) The same as V. 98. Ammonia has a larger a value than neon does (see Table 5.4). What can you conclude about the relative strength of the attractive forces between molecules of ammonia and between atoms of neon? A) The attractive forces are lower between ammonia molecules. B) Ammonia molecules and neon atoms have approximately equal attractive forces. C) The attractive forces are greater between ammonia molecules. D) There is insufficient data to determine this. 99. Using the data shown in Table 5.4, calculate the pressure exerted by 2.50 moles of CO2 confined in a volume of 5.00 L at 450 K. Compare the pressure with that predicted by the ideal gas equation. A) P = 370 atm; P-ideal = 374 atm B) P = 18.0 atm; P-ideal = 18.5 atm C) P = 7.0 atm; P-ideal = 7.4 atm D) P = 81.0 atm; P-ideal = 92.5 atm 100. At 27C, 10.0 moles of a gas in a 1.50-L container exert a pressure of 130 atm. Does this gas behave like an ideal gas? A) Yes, the gas behaves in an ideal manner. B) No, the gas behaves in a non-ideal manner. 101. Under the same conditions of temperature and pressure, put the following gases in order from behaving most ideally to behaving least ideally: Ne, N2, or CH4. A) N2, Ne, CH4 B) Ne, CH4, N2 C) CH4, N2, Ne D) Ne, N2, CH4

Use the following to answer questions 102-103: Nitroglycerin, an explosive compound, decomposes according to the equation 4C3H5(NO3)3(s) 12CO2(g) + 10H2O(g) + 6N2(g) + O2(g) 102. Calculate the total volume of gases when collected at 1.2 atm and 25 C from 2.6 102 g of nitroglycerin. A) 170 L B) 680 L C) 14 L D) 94 L 103. What are the partial pressures of the gases when collected at 1.2 atm and 25C from 2.6 102 g of nitroglycerin? A) Partial pressures for: CO2 = 0.63 atm; H2O = 0.34 atm; N2 = 0.23 atm; O2 = 0.043 atm B) Partial pressures for: CO2 = 0.46 atm; H2O = 0.44 atm; N2 = 0.23 atm; O2 = 0.043 atm C) Partial pressures for: CO2 = 0.49 atm; H2O = 0.41 atm; N2 = 0.25 atm; O2 = 0.041 atm D) Partial pressures for: CO2 = 1.7 atm; H2O = 1.4 atm; N2 = 0.86 atm; O2 = 0.14 atm 104. The empirical formula of a compound is CH. At 200 C, 0.145 g of this compound occupies 97.2 mL at a pressure of 0.74 atm. What is the molecular formula of the compound? A) C6H6 B) C4H4 C) C8H8 D) C10H10 Use the following to answer questions 105-106: When ammonium nitrite (NH4NO2) is heated, it decomposes to give nitrogen gas. This property is used to inflate some tennis balls. 105. Write a balanced equation for the reaction. A) 2 NH4NO2 (s) 2 N2 (g) + H2O (l) B) NH4NO2 (s) N2 (g) + 2 H2O (l) C) NH4NO2 (s) N2 (g) + H2 (g) + O2 (g) D) 3 NH4NO2 (s) 6 N2 (g) + 6 H2O (l)

106. Calculate the quantity (in grams) of NH4NO2 needed to inflate a tennis ball to a volume of 86.2 mL at 1.20 atm and 22 C. A) 0.301 g B) 0.273 g C) 0.737 g D) 0.067 g 107. The percent by mass of bicarbonate (HCO3-) in a certain Alka-Seltzer product is 32.5 percent. Calculate the volume of CO2 generated (in mL) at 37C and 1.00 atm when a person ingests a 3.29-g tablet. (Hint: The reaction is between HCO3- and HCl acid in the stomach.) A) 223 mL B) 297 mL C) 445 mL D) 890 mL 108. The boiling point of liquid nitrogen is 196 C. On the basis of this information alone, do you think nitrogen is an ideal gas? A) Yes B) No Use the following to answer questions 109-110: In the metallurgical process of refining nickel, the metal is first combined with carbon monoxide to form tetracarbonylnickel, which is a gas at 43 C: Ni(s) + 4CO(g) Ni(CO)4(g) This reaction separates nickel from other solid impurities. 109. Starting with 86.4 g of Ni, calculate the pressure of Ni(CO)4 in a container of volume 4.00 L. (Assume the above reaction goes to completion.) A) 9.53 atm B) 1.30 atm C) 4.77 atm D) 2.38 atm 110. At temperatures above 43 C, the pressure of Ni(CO)4 (g) is observed to increase much more rapidly than predicted by the ideal gas equation. Explain. A) Ni(CO)4 (g) does not behave ideally above 43 C. B) Ni(CO)4 (g) is not stable above 43 C. C) More gas molecules are formed above 43 C. D) All of the above. 111. The partial pressure of carbon dioxide varies with seasons. Would you expect the partial pressure in the Northern Hemisphere to be higher in the summer or winter? Explain. A) Higher in the summer; the heat releases more carbon dioxide. B) Higher in the winter; less photosynthesis is happening.

112. A healthy adult exhales about 5.0 102 mL of a gaseous mixture with each breath. Calculate the number of molecules present in this volume at 37 C and 1.1 atm. A) 1.09 1020 molecules of gas B) 1.30 1019 molecules of gas C) 1.09 1023 molecules of gas D) 1.30 1022 molecules of gas 113. List the major components of the gaseous mixture exhaled by a healthy human adult. A) CO2, O2, B) CO2, O2, N2 C) CO2, O2, N2, H2O D) CO2, O2, N2, H2 114. Sodium bicarbonate (NaHCO3) is called baking soda because when heated, it releases carbon dioxide gas, which is responsible for the rising of cookies, doughnuts, and bread. Calculate the volume (in liters) of CO2 produced by heating 5.0 g of NaHCO3 at 180 C and 1.3 atm. (For further thought: ammonium bicarbonate (NH4HCO3) has also been used for the same purpose. Think about one advantage and one disadvantage of using NH4HCO3 instead of NaHCO3 for baking.) A) 0.68 L CO2 B) 1.72 L CO2 C) 0.34 L CO2 D) 0.86 L CO2 115. A barometer having a cross-sectional area of 1.00 cm2 at sea level measures a pressure of 76.0 cm of mercury. The pressure exerted by this column of mercury is equal to the pressure exerted by all the air on 1 cm2 of Earth's surface. Given that the density of mercury is 13.6 g/mL and the average radius of Earth is 6371 km, calculate the total mass of Earth's atmosphere in kilograms. (Hint: The surface area of a sphere is 4 r2 where r is the radius of the sphere.) A) 5.25 1018 kg B) 1.67 1024 kg C) 5.25 1024 kg D) 1.67 1018 kg 116. Some commercial drain cleaners contain a mixture of sodium hydroxide and aluminum powder. When the mixture is poured down a clogged drain, the following reaction occurs: 2NaOH(aq) + 2Al(s) + 6H2O(l) 2NaAl(OH)4(aq) + 3H2(g) The heat generated in this reaction helps melt away obstructions such as grease, and the hydrogen gas released stirs up the solids clogging the drain. Calculate the volume of H2 formed at 0 C and 1.00 atm if 3.12 g of Al are treated with an excess of NaOH. A) 1.88 L H2 B) 3.88 L H2 C) 4.24 L H2 D) 1.72 L H2

117. The volume of a sample of pure HCl gas was 189 mL at 25C and 108 mmHg. It was completely dissolved in about 60 mL of water and titrated with a NaOH solution; 15.7 mL of the NaOH solution were required to neutralize the HCl. Calculate the molarity of the NaOH solution. A) 0.0701 mol / L B) 0.836 mol / L C) 0.418 mol / L D) 0.140 mol / L Use the following to answer questions 118-119: Propane (C3H8) burns in oxygen to produce carbon dioxide gas and water vapor. 118. Write a balanced equation for this reaction. A) C3H8 (g) + 7 O2 (g) 3 CO (g) + 4 H2O (g) B) 2 C3H8 (g) + 9 O2 (g) 6 CO2 (g) + 6 H2O (g) C) C3H8 (g) + 5 O2 (g) 3 CO2 (g) + 4 H2O (g) D) C3H8 (g) + 4 O2 (g) 3 CO2 (g) + 2 H2O (g) 119. Calculate the number of liters of carbon dioxide measured at STP that could be produced from 7.45 g of propane. A) 1.90 L CO2 B) 3.80 L CO2 C) 11.4 L CO2 D) 12.5 L CO2 120. Consider the following apparatus. Calculate the partial pressures of helium and neon after the stopcock is open. The temperature remains constant at 16 C.

A) B) C) D)

Partial pressures: He = 0.24 atm; Ne = 2.3 atm Partial pressures: He = 0.18 atm; Ne = 1.4 atm Partial pressures: He = 0.22 atm; Ne = 0.61 atm Partial pressures: He = 0.16 atm; Ne = 2.1 atm

121. Nitric oxide (NO) reacts with molecular oxygen as follows: 2NO(g) + O2(g) 2NO2(g) Initially NO and O2 are separated as shown below. When the valve is opened, the reaction quickly goes to completion. Determine what gases remain at the end and calculate their partial pressures. Assume that the temperature remains constant at 25C.

A) B) C) D)

Partial pressures: O2 = 1.98 atm; NO2 = 3.97 atm Partial pressures: O2 = 0.166 atm; NO2 = 0.333 atm Partial pressures: NO = 0.332 atm; NO2 = 0.664 atm Partial pressures: NO = 0.250 atm; NO2 = 0.384 atm

122. Consider the apparatus shown below. When a small amount of water is introduced into the flask by squeezing the bulb of the medicine dropper, what will happen to the water in the long glass tubing? (Hint: Hydrogen chloride gas is soluble in water.)

A) It falls. B) It rises. C) It remains the same. 123. A certain hydrate has the formula MgSO4 xH2O. A quantity of 54.2 g of the compound is heated in an oven to drive off the water. If the steam generated exerts a pressure of 24.8 atm in a 2.00-L container at 120 C, calculate x. A) 7 B) 5 C) 4 D) 3

124. A mixture of Na2CO3 and MgCO3 of mass 7.63 g is reacted with an excess of hydrochloric acid. The CO2 gas generated occupies a volume of 1.67 L at 1.24 atm and 26 C. From these data, calculate the percent composition by mass of Na2CO3 in the mixture. A) 50.0 % B) 67.6 % C) 16.2 % D) 32.4 % Use the following to answer questions 125-129: The following apparatus can be used to measure atomic and molecular speed. Suppose that a beam of metal atoms is directed at a rotating cylinder in a vacuum. A small opening in the cylinder allows the atoms to strike a target area. Because the cylinder is rotating, atoms traveling at different speeds will strike the target at different positions. In time, a layer of the metal will deposit on the target area, and the variation in its thickness is found to correspond to Maxwell's speed distribution. In one experiment it is found that at 850 C some bismuth (Bi) atoms struck the target at a point 2.80 cm from the spot directly opposite the slit. The diameter of the cylinder is 15.0 cm and it is rotating at 130 revolutions per second.

125. Calculate the speed (m/s) at which the target is moving. (Hint: The circumference of a circle is given by 2 r, where r is the radius.) A) 12,200 m/s B) 122 m/s C) 6,120 m/s D) 61.2 m/s 126. Calculate the time (in seconds) it takes for the target to travel 2.80 cm. A) 1.71 s B) 4.58 10-4 s C) 0.171 s D) 4.58 10-5 s 127. Determine the speed of the Bi atoms. A) 61.1 m/s B) 3,280 m/s

C) 328 m/s D) 611 m/s 128. What is the urms of Bi at 850 C? A) 366 m/s B) 328 m/s C) 318 m/s D) 211 m/s 129. Compare the speed of the Bi atoms with the urms of Bi at 850 C. Comment on the difference. A) They are identical. B) They are close, but not identical. C) The urms value is an average value. D) Both b and c. E) Both a and c. 130. If 10.00 g of water are introduced into an evacuated flask of volume 2.500 L at 65 C, calculate the mass of water vaporized. (Hint: Assume that the volume of the remaining liquid water is negligible; the vapor pressure of water at 65 C is 187.5 mmHg.) A) 0.400 g B) 2.08 g C) 0.356 g D) 1.85 g Use the following to answer questions 131-132: Commercially, compressed oxygen is sold in metal cylinders. Suppose a 120-L cylinder is filled with oxygen to a pressure of 132 atm at 22 C. 131. What is the mass of O2 present? Assume ideal behavior. A) 2.09 104 g O2 B) 2.81 105 g O2 C) 1.05 104 g O2 D) 1.41 105 g O2 132. How many liters of O2 gas at 1.00 atm and 22 C could the cylinder produce? Assume ideal behavior. A) 2.12 105 L O2 B) 1.58 104 L O2 C) 1.18 103 L O2 D) 1.61 103 L O2

133. The shells of hard-boiled eggs sometimes crack due to the rapid thermal expansion of the shells at high temperatures. Suggest another reason why the shells may crack. A) The calcium lattice structure of the egg rearranges and weakens. B) The liquid inside the egg expands. C) The membrane inside the egg contracts, causing cracks. D) The air inside the egg expands. 134. Ethylene gas (C2H4) is emitted by fruits and is known to be responsible for their ripening. Based on this information, explain why a bunch of bananas ripens faster in a closed paper bag than in a bowl. A) The bag keeps the bananas warmer. B) The bag keeps oxygen away from the bananas. C) The bag traps the ethylene gas, increasing its partial pressure. D) Bananas ripen more rapidly in the dark. 135. About 8.0 106 tons of urea [(NH2)2CO] are used annually as a fertilizer. The urea is prepared at 200 C and under high-pressure conditions from carbon dioxide and ammonia (the products are urea and steam). Calculate the volume of ammonia (in liters) measured at 150 atm needed to prepare 1.0 ton of urea. A) 7.5 103 L NH3 B) 3.9 103 L NH3 C) 5.5 102 L NH3 D) 7.8 103 L NH3 136. The gas laws are vitally important to scuba divers. The pressure exerted by 33 ft of seawater is equivalent to 1 atm pressure. A diver ascends quickly to the surface of the water from a depth of 36 ft without exhaling gas from his lungs. By what factor will the volume of his lungs increase by the time he reaches the surface? Assume that the temperature is constant. A) The volume will increase by a factor of 1.1. B) The volume will increase by a factor of 1.9. C) The volume will increase by a factor of 2.1. D) The volume will increase by a factor of 1.5. 137. The partial pressure of oxygen in air is about 0.20 atm. (Air is 20 percent oxygen by volume.) In deep-sea diving, the composition of air the diver breathes must be changed to maintain this partial pressure. What must the oxygen content (in percent by volume) be when the total pressure exerted on the diver is 4.0 atm? (At constant temperature and pressure, the volume of a gas is directly proportional to the number of moles of gases.) A) 80 % oxygen by volume B) 5.0 % oxygen by volume C) 0.80 % oxygen by volume D) 48 % oxygen by volume

Use the following to answer questions 138-139: Nitrous oxide (N2O) can be obtained by the thermal decomposition of ammonium nitrate (NH4NO3). 138. Write a balanced equation for the reaction. A) NH3NO3(s) N2O(g) + 4H2O(g) B) NH4NO3(g) N2O(g) + 2H2O(l) C) NH4NO3(s) N2O(g) + 2H2O(l) D) NH3NO3(s) N2O(g) + H2(g) + O2(g) 139. In the experiment described, a student obtains 0.340 L of nitrous oxide with a partial pressure of 718 mmHg at 24 C. If the gas weighs 0.580 g, calculate the value of the gas constant. A) 0.0821 L atm / mol K B) 0.0840 L atm / mol K C) 0.0274 L atm / mol K D) 0.246 L atm / mol K 140. Two vessels are labeled A and B. Vessel A contains NH3 gas at 70 C, and vessel B contains Ne gas at the same temperature. If the average kinetic energy of NH3 is 7.1 10-21 J/molecule, calculate the mean-square speed of Ne atoms in m2/s2. A) 4.2 108 m2 / s2 B) 1.1 108 m2 / s2 C) 4.2 105 m2 / s2 D) 1.1 105 m2 / s2 141. Which of the following molecules has the largest a value: CH4, F2, C6H6, Ne? A) Ne B) CH4 C) F2 D) C6H6

142. The following procedure is a simple though somewhat crude way to measure the molar mass of a gas. A liquid of mass 0.0184 g is introduced into a syringe like the one shown below by injection through the rubber tip using a hypodermic needle. The syringe is then transferred to a temperature bath heated to 45 C, and the liquid vaporizes. The final volume of the vapor (measured by the outward movement of the plunger) is 5.58 mL and the atmospheric pressure is 760 mmHg. Given that the compound's empirical formula is CH2, determine the molar mass of the compound and the formula of the compound.

A) B) C) D)

14.0 g / mol; CH2 56.0 g / mol; C4H8 70.0 g / mol; C5H10 86.0 g / mol; C6H12

143. In 1995 a man suffocated as he walked by an abandoned mine in England. At that moment there was a sharp drop in atmospheric pressure due to a change in the weather. Suggest what might have caused the man's death. A) The oxygen concentration near the man dropped, pushed away by other gases. B) Poisonous gases expanded and flowed up out of the mine. C) It's more likely that he was poisoned, than suffocated. D) All of the above. Use the following to answer questions 144-145: Acidic oxides such as carbon dioxide react with basic oxides like calcium oxide (CaO) and barium oxide (BaO) to form salts (metal carbonates). 144. Write an equation representing the CaO reaction. A) CaO(s) + CO(g) CaCO2(s) B) CaO(s) + CO2(g) CaCO3(s) C) 2 CaO(s) + CO2(g) Ca2CO3(s) D) CaO(s) + 2 CO2(g) CaCO3(s) + CO2 (g) 145. A student placed a mixture of BaO and CaO of combined mass 4.88 g in a 1.46-L flask containing carbon dioxide gas at 35 C and 746 mmHg. After the reactions were complete, she found that the CO2 pressure had dropped to 252 mmHg. Calculate the percent composition by mass of the mixture. Assume volumes of the solids are negligible. A) 10.5% CaO; 89.5% BaO B) 89.5% CaO; 10.5% BaO C) 26.7% CaO; 73.3% BaO D) 73.3% CaO; 26.7% BaO

Use the following to answer questions 146-147: Air at 1.0 atm and 22 C is needed to fill a 0.98-L bicycle tire to a pressure of 5.0 atm at the same temperature. (Note that the 5.0 atm is the gauge pressure, which is the difference between the pressure in the tire and atmospheric pressure. Before filling, the pressure in the tire was 1.0 atm.) 146. Find the volume of air needed. A) 3.92 L B) 4.90 L C) 5.88 L D) 11.8 L 147. What is the total pressure in the tire when the gauge pressure reads 5.0 atm? A) 4 atm B) 5 atm C) 6 atm D) 7 atm 148. A bicycle tire is pumped by filling the cylinder of a hand pump with air at 1.0 atm and then, by compressing the gas in the cylinder, adding all the air in the pump to the air in the tire. If the volume of the pump is 33 percent of the tire's volume, what is the gauge pressure in the tire after three full strokes of the pump? Assume constant temperature and that the initial gauge pressure was zero. A) 0.33 atm B) 1.0 atm C) 2.0 atm D) 3.3 atm Use the following to answer questions 149-150: The running engine of an automobile produces carbon monoxide (CO), a toxic gas, at the rate of about 188 g CO per hour. A car is left idling in a poorly ventilated garage that is 6.0 m long, 4.0 m wide, and 2.2 m high at 20 C. 149. Calculate the rate of CO production in moles per minute A) 87.7 mol CO / min B) 3.13 mol CO / min C) 0.112 mol CO / min D) 0.0313 mol CO / min 150. For the situation described, how long would it take to build up a lethal concentration of CO of 1000 ppmv (parts per million by volume)? A) 2.9 102 min B) 2.0 102 min

C) 4.0 101 min D) 2.0 101 min 151. Interstellar space contains mostly hydrogen atoms at a concentration of about 1 atom/cm3. Calculate the pressure of the H atoms. The temperature is 3 K. A) 6 10-21 atm B) 5 10-22 atm C) 6 10-24 atm D) 5 10-25 atm 152. Interstellar space contains mostly hydrogen atoms at a concentration of about 1 atom/cm3. Calculate the volume (in liters) of interstellar space that contains 1.0 g of H atoms. The temperature is 3 K. A) 1 1024 L/g of H B) 5 1023 L/g of H C) 2.5 1020 L/g of H D) 5 1020 L/g of H Use the following to answer questions 153-154: Atop Mt. Everest, the atmospheric pressure is 210 mmHg and the air density is 0.426 kg/m3. The molar mass of air is 29.0 g/mol. 153. Calculate the air temperature. A) 229 K, - 44 C B) 174 K, - 99 C C) 239 K, - 34 C D) 246 K, - 27 C 154. Assuming no change in air composition, calculate the percent decrease in oxygen gas from sea level to the top of Mt. Everest. A) 72.4 % decrease B) 27.6 % decrease C) 14.5 % decrease D) 85.5 % decrease 155. Relative humidity is defined as the ratio (expressed as a percentage) of the partial pressure of water vapor in the air to the equilibrium vapor pressure (see Table 5.3) at a given temperature. On a certain summer day in North Carolina the partial pressure of water vapor in the air is 3.9 103 Pa at 30C. Calculate the relative humidity. The vapor pressure of water at 30 C is 31.82 mmHg. A) 96% B) 91 % C) 76 % D) 69 %

156. Under the same conditions of temperature and pressure, why does one liter of moist air weigh less than one liter of dry air? (Interesting fact: In weather forecasts, an oncoming low-pressure front usually means imminent rainfall.) A) One liter of moist air has less moles of gas than one liter of dry air. B) One liter of moist air has equal moles of gas as one liter of dry air. C) The molar mass of water is less than the molar mass of air (about 29 g/mol). D) Both b and c. E) Both a and c. 157. Air entering the lungs ends up in tiny sacs called alveoli. It is from the alveoli that oxygen diffuses into the blood. The average radius of the alveoli is 0.0050 cm and the air inside contains 14 percent oxygen. Assuming that the pressure in the alveoli is 1.0 atm and the temperature is 37C, calculate the number of oxygen molecules in one of the alveoli. (Hint: The volume of a sphere of radius r is (4/3) r3.) A) 1.2 1016 O2 molecules B) 1.2 1013 O2 molecules C) 1.7 1012 O2 molecules D) 1.3 1012 O2 molecules Use the following to answer questions 158-159: A student breaks a thermometer and spills most of the mercury (Hg) onto the floor of a laboratory that measures 15.2 m long, 6.6 m wide, and 2.4 m high. The temperature of the room is 20 C. The vapor pressure of mercury at 20 C is 1.7 10-6 atm. 158. Calculate the mass of mercury vapor (in grams) in the room at 20 C. A) 3.4 10-3 g Hg B) 3.4 g Hg C) 4.9 g Hg D) 49 g Hg 159. Calculate the resulting concentration of mercury vapor. Does it exceed the air quality regulation of 0.050 mg Hg/m3 of air? For further thought: one way to treat small quantities of spilled mercury is to spray sulfur powder over the metal. The sulfur powder covers the Hg surface and retards the rate of evaporation. Also, sulfur reacts slowly with Hg to form HgS, which has no measurable vapor pressure. A) 0.020 mg Hg / m3 ; no B) 0.20 mg Hg / m3 ; yes C) 0.014 mg Hg / m3 ; no D) 14 mg Hg / m3 ; yes 160. Nitrogen forms several gaseous oxides. One of them has a density of 1.33 g/L measured at 764 mmHg and 150 C. Write the formula of the compound. A) NO2 most likely, N2O possible B) N2O most likely, NO possible

C) NO most likely, N2O possible D) N2O most likely, NO2 possible 161. Nitrogen dioxide (NO2) cannot be obtained in a pure form in the gas phase because it exists as a mixture of NO2 and N2O4. At 25C and 0.98 atm, the density of this gas mixture is 2.7 g/L. What is the partial pressure of each gas? A) Partial pressures: NO2 = 0.45 atm; N2O4 = 0.53 atm B) Partial pressures: NO2 = 0.53 atm; N2O4 = 0.45 atm C) Partial pressures: NO2 = 0.33 atm; N2O4 = 0.65 atm D) Partial pressures: NO2 = 0.65 atm; N2O4 = 0.33 atm 162. Calculate the root-mean-square speed of a Rb atom at a temperature of 1.7 10-7 K. A) 2.2 10-4 m/s B) 7.0 10-4 m/s C) 7.0 10-3 m/s D) 4.0 10-3 m/s 163. Calculate the average kinetic energy of a Rb atom at a temperature of 1.7 10-7 K. A) 3.5 10-30 J B) 5.0 10-25 J C) 7.0 10-30 J D) 1.0 10-24 J 164. Lithium hydride reacts with water as follows: LiH(s) + H2O(l) LiOH(aq) + H2(g) During World War II, U.S. pilots carried LiH tablets. In the event of a crash landing at sea, the LiH would react with the seawater and fill their life belts and lifeboats with hydrogen gas. How many grams of LiH are needed to fill a 4.1-L life belt at 0.97 atm and 12 C? A) 0.7 g LiH B) 1.4 g LiH C) 2.8 g LiH D) 21 g LiH 165. The atmosphere on Mars is composed mainly of carbon dioxide. The surface temperature is 220 K and the atmospheric pressure is about 6.0 mmHg. Taking these values as Martian STP, calculate the molar volume in liters of an ideal gas on Mars. A) 5.1 104 L B) 3.0 L C) 30 L D) 2.3 103 L 166. Venus's atmosphere is composed of 96.5 percent CO2, 3.5 percent N2, and 0.015 percent SO2 by volume. Its standard atmospheric pressure is 9.0 106 Pa. Calculate the partial pressures of the gases in pascals. A) Partial pressures: CO2 = 8.7 106 Pa; N2 =3.2 105 Pa; SO2 = 1.4 103 Pa

B) Partial pressures: CO2 = 8.7 104 Pa; N2 =3.2 103 Pa; SO2 = 1.4 101 Pa C) Partial pressures: CO2 = 9.7 105 Pa; N2 =3.5 104 Pa; SO2 = 1.5 103 Pa D) Partial pressures: CO2 = 97 kPa; N2 =3.5 kPa; SO2 = 1.5 kPa 167. A student tries to determine the volume of a bulb. These are her results: Mass of the bulb filled with dry air at 23C and 744 mmHg = 91.6843 g; mass of evacuated bulb = 91.4715 g. Assume the composition of air is 78 percent N2, 21 percent O2, and 1 percent argon. What is the volume (in milliliters) of the bulb? (Hint: First calculate the average molar mass of air.) A) 1.5 105 mL B) 1.4 101 mL C) 1.4 103 mL D) 1.8 102 mL 168. Apply your knowledge of the kinetic theory of gases to the following situation. Two flasks of volumes V1 and V2 (V2 > V1) contain the same number of helium atoms (He) at the same temperature. Compare the root-mean-square (rms) speeds and average kinetic energies (KE) of the helium atoms in the flasks. A) The rms speed and average KE of He in flask 1 is greater than those of the He atoms in flask 2. B) The rms speed and average KE of He in flask 1 is less than those of the He atoms in flask 2. C) The rms speed and average KE of He in flask 1 is equal to those of the He atoms in flask 2. 169. If two flasks of volumes V1 and V2 (V2 > V1) contain the same number of helium atoms at the same temperature, compare the frequency with which the He atoms collide with the walls of their containers. A) The collision frequency of He atoms in flask 1 is greater than that of the He atoms in flask 2. B) The collision frequency of He atoms in flask 1 is equal to that of the He atoms in flask 2. C) The collision frequency of He atoms in flask 1 is less than that of the He atoms in flask 2. 170. If two flasks of volumes V1 and V2 (V2 > V1) contain the same number of helium atoms at the same temperature, then compare the force with which the He atoms collide with the walls of their containers. A) The force of the He collisions in flask 1 is greater than the force of the He collisons in flask 2. B) The force of the He collisions in flask 1 is equal to the force of the He collisons in flask 2. C) The force of the He collisions in flask 1 is less than the force of the He collisons in flask 2.

171. Apply your knowledge of the kinetic theory of gases to the following situation. Equal numbers of He atoms are placed in two flasks of the same volume at temperatures T1 and T2 (T2 > T1). Compare the rms speeds of the atoms in the two flasks. A) The rms speed of the He atomes in flask 1 is greater than that of the He atoms in flask 2. B) The rms speed of the He atomes in flask 1 is equal to that of the He atoms in flask 2. C) The rms speed of the He atomes in flask 1 is less than that of the He atoms in flask 2. 172. If equal numbers of He atoms are placed in two flasks of the same volume at temperatures T1 and T2 (T2 > T1), then compare the frequency and the force with which the He atoms collide with the walls of their containers. A) The frequency and force of He collisons in flask 1 is greater than those in flask 2. B) The frequency and force of He collisons in flask 1 is equal to those in flask 2. C) The frequency and force of He collisons in flask 1 is less than those in flask 2. 173. Apply your knowledge of the kinetic theory of gases to the following situation. Equal numbers of helium (He) and neon (Ne) atoms are placed in two flasks of the same volume, and the temperature of both gases is 74 C. Compare the rms speed of He to that of Ne. A) The rms speed of He is greater than the rms speed of Ne. B) The rms speed of He is equal to the rms speed of Ne. C) The rms speed of He is less than the rms speed of Ne. 174. If equal numbers of He and neon (Ne) atoms are placed in two flasks of the same volume, and the temperature of both gases is 74 C, then compare the average kinetic energies (KE) of the two gases. A) The average KE of He is greater than the average KE of Ne. B) The average KE of He is equal to the average KE of Ne. C) The average KE of He is less than the average KE of Ne. 175. If helium (He) atoms are placed in a flask at a temperature of 74 C, then what is the rms speed of each He atom? A) 2.14 104 m/s B) 2.14 103 m/s C) 1.47 103 m/s D) 1.47 102 m/s

Use the following to answer questions 176-180: Make these three assumptions in making your calculations: 1) There is complete mixing of air in the atmosphere. 2) No molecules of air escape to the outer atmosphere. 3) No molecules were used up during metabolism, nitrogen fixation, and so on. It has been said that every breath we take, on average, contains molecules that were once exhaled by Wolfgang Amadeus Mozart (17561791). The following calculations demonstrate the validity of this statement. 176. First, calculate the total number of molecules of air in the atmosphere. (Hint: The mass of the atmosphere is 5.25 1018 kg. Use the value of 29.0 g/mol as the molar mass of air.) A) 9.17 1046 molecules of air B) 1.09 1050 molecules of air C) 1.09 1047 molecules of air D) 1.09 1044 molecules of air 177. Assuming the volume of every breath (inhale or exhale) is 500 mL, calculate the number of molecules exhaled in each breath at 37 C, which is the body temperature. A) 1.18 1022 molecules / breath B) 1.18 1025 molecules / breath C) 9.91 1022 molecules / breath D) 9.91 1025 molecules / breath 178. If Mozart's lifespan was exactly 35 years, what is the number of molecules he exhaled in that period? (Given that an average person breathes 12 times per minute.) A) 2.60 1033 molecules breathed by Mozart B) 2.60 1030 molecules breathed by Mozart C) 2.19 1031 molecules breathed by Mozart D) 2.19 1034 molecules breathed by Mozart 179. Calculate the fraction of molecules in the atmosphere that was exhaled by Mozart. A) 2.39 10-17 B) 2.39 10-16 C) 2.39 10-14 D) 2.01 10-10 180. How many of Mozart's molecules do we breathe in with every inhale of air? Round off your answer to one significant figure. A) 2 1016 molecules that Mozart exhaled B) 2 1012 molecules that Mozart exhaled C) 3 109 molecules that Mozart exhaled D) 3 108 molecules that Mozart exhaled

181. Estimate the distance (in nanometers) between molecules of water vapor at 100 C and 1.0 atm. Assume ideal behavior. If necessary, assume a water molecule to be a sphere with a diameter of 0.3 nm. (Hint: First calculate the number density of water molecules. Next, convert the number density to linear density, that is, number of molecules in one direction.) A) 370 nm B) 37 nm C) 3.7 nm D) 0.37 nm 182. Estimate the distance (in nanometers) between molecules of liquid water at 100 C and 1 atm, given that the density of water is 0.96 g/cm3 at that temperature. Assume the water molecules to be a sphere with a diameter of 0.3 nm. (Hint: First calculate the number density of water molecules. Next, convert the number density to linear density, that is, number of molecules in one direction.) A) 0.31 nm B) 3.1 nm C) 37 nm D) 370 nm 183. Which of the noble gases would not behave ideally under any circumstance? Why? A) Radon; its mass is not stable. B) Radon; its mass is too large. C) Radon; the number of atoms is not constant. D) Both a and c. E) Both b and c. 184. A relation known as the barometric formula is useful for estimating the change in
RT atmospheric pressure with altitude. The formula is given by P = Po e , where P and Po are the pressures at height h and sea level, respectively, g the acceleration due to gravity (9.8 m/s2), M the average molar mass of air (29.0 g/mol), and R the gas constant. Calculate the atmospheric pressure in atm at a height of 4.0 km, assuming the temperature is constant at 5 degrees C and P0 = 1.0 atm. A) 0.25 atm B) 0.61 atm C) 0.94 atm D) 2.0 x 10-3 atm gM h

185. A 5.72-g sample of graphite was heated with 68.4-g of O2 in a 8.00-L flask. The reaction that took place was C(graphite) + O2(g) CO2(g) After the reaction was complete, the temperature in the flask was 182 degrees C. What was the total pressure inside the flask? A) 2.22 atm B) 9.98 atm C) 46.1 atm

D) 79.8 atm 186. A stockroom supervisor measured the contents of a partially filled 25.0-gallon acetone drum on a day when the temperature was 18.0 C and atmospheric pressure was 750 mmHg, and found that 15.4 gallons of the solvent remained. After tightly sealing the drum, an assistant dropped the drum while carrying it upstairs to the organic laboratory. The drum was dented and its internal volume was decreased to 20.4- gallons. What is the total pressure inside the drum after the accident? The vapor pressure of acetone at 18.0 C is 400 mmHg. (Hint: at the time the drum was sealed, the pressure inside the drum, which is equal to the sum of the pressures of air and acetone, was equal to the atmospheric pressure.) A) 1070 mmHg B) 1440 mmHg C) 400 mmHg D) 1230 mmHg

Answer Key
1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. C C D B A B B C A A C D D A D C D B A A C D B D A D B C C B D D B A A C B C A A D B C A B A C D D B

51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. 82. 83. 84. 85. 86. 87. 88. 89. 90. 91. 92. 93. 94. 95. 96. 97. 98. 99. 100. 101. 102.

A C C A B D C A C B B D C A C A D B C D B D C A B B C D D A C B C C D A B A C C A B B C D A B C B B D A

103. 104. 105. 106. 107. 108. 109. 110. 111. 112. 113. 114. 115. 116. 117. 118. 119. 120. 121. 122. 123. 124. 125. 126. 127. 128. 129. 130. 131. 132. 133. 134. 135. 136. 137. 138. 139. 140. 141. 142. 143. 144. 145. 146. 147. 148. 149. 150. 151. 152. 153. 154.

C A B B C B A D B D C D A B A C C D B B A D D B C A D A A B D C D C B C A C D D D B A B C B C D B D A A

155. 156. 157. 158. 159. 160. 161. 162. 163. 164. 165. 166. 167. 168. 169. 170. 171. 172. 173. 174. 175. 176. 177. 178. 179. 180. 181. 182. 183. 184. 185. 186.

B D C B D A B C A B D A D C A B C C A B C D A B C D C A D B B A