Paperclip Tutorial Handbook 4.4
Paperclip Tutorial Handbook 4.4
Handbook for Life Cycle Assessment (LCA) Using the GaBi Education Software Package
September 2010
PE INTERNATIONAL
+49 [0] 711 3418170 +49 [0] 711 34181725 [email protected] www.pe-international.com
Table of Contents
1 1.1 1.2 1.2.1 1.2.2 1.2.3 1.3 1.4 2 2.1 2.1.1 2.1.2 2.2 2.2.1 2.2.2 2.2.3 2.3 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 2.4 2.4.1 2.4.2 2.4.3 2.4.4 2.4.5 3 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 3.10
Introduction to Life Cycle Assessment ............................................................. 8 What is LCA?................................................................................................... 8 Who uses LCA?............................................................................................... 8 Industry............................................................................................................ 9 Government ..................................................................................................... 9 Universities ...................................................................................................... 9 How is an LCA created? .................................................................................. 9 GaBi overview ................................................................................................. 9 Conducting Life Cycle Assessments .............................................................. 10 Goal and Scope Definition ............................................................................. 10 Goal............................................................................................................... 10 Scope ............................................................................................................ 11 Life Cycle Inventory ....................................................................................... 16 General.......................................................................................................... 16 Data Collection - Classifications..................................................................... 17 Calculation of the LCI .................................................................................... 18 Life Cycle Impact Assessment ....................................................................... 18 Impact Assessment Methods ......................................................................... 19 Selection of Impact Categories ...................................................................... 21 Classification ................................................................................................. 21 Characterization ............................................................................................ 21 Optional elements of an LCA ......................................................................... 22 Interpretation ................................................................................................. 24 Identification of significant issues ................................................................... 24 Evaluation ...................................................................................................... 24 Conclusions, recommendations and reporting ............................................... 25 Report............................................................................................................ 25 Critical Review ............................................................................................... 26 Procedure ...................................................................................................... 27 Opening GaBi ................................................................................................ 27 Activating a database .................................................................................... 29 GaBi theory ................................................................................................... 29 Starting a project ........................................................................................... 31 Create a new plan ......................................................................................... 32 Adding a process ........................................................................................... 32 Creating a new process ................................................................................. 33 Process types ................................................................................................ 34 Specifying the flow type ................................................................................. 35 Parameters, LCC, LCW and ISO Documentation .......................................... 35
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3.11 3.12 3.13 3.14 3.15 3.16 3.17 3.18 3.19 3.20 3.21 3.22 3.23 3.24 3.25 3.26 3.27 3.28 3.29 3.30 3.31 3.32 3.33 3.34 3.35 3.36 4
Entering inputs and outputs ........................................................................... 36 Creating new flows ........................................................................................ 38 Modifying a flows properties .......................................................................... 39 Entering flow amounts ................................................................................... 39 Flow types ..................................................................................................... 40 Specifying flow types ..................................................................................... 41 Fixing and scaling processes ......................................................................... 41 Viewing the tracked inputs/outputs ................................................................ 42 Adding processes .......................................................................................... 43 Adding transportation processes.................................................................... 43 Process parameters....................................................................................... 44 Resizing process boxes ................................................................................. 44 Linking processes .......................................................................................... 45 Adding a plan to a plan .................................................................................. 48 Adding comments and modifying appearance ............................................... 50 Creating and saving a balance ...................................................................... 50 View option: IO Tables................................................................................... 51 View option: Just elementary flows ................................................................ 52 View the LCI table ......................................................................................... 52 Navigating through the balance window......................................................... 53 View option: Quantities .................................................................................. 54 View option: Quantity view ............................................................................. 55 View option: Weak point analysis ................................................................... 56 View option: Relative contribution .................................................................. 56 Creating a diagram ........................................................................................ 57 Exporting diagrams and tables ...................................................................... 58 Literature ................................................... Fehler! Textmarke nicht definiert.
Table of Figures
Figure 1: Figure 2: Figure 3: Figure 4: Figure 5: Figure 6: Figure 7: Figure 8: Figure 9: Figure 10: Figure 11: Overview of Life Cycle Assessment ....................................................... 8 Steps of a Life Cycle Assessment According to ISO 14044 ..................10 Process Flow Diagram..........................................................................13 System Boundaries. .............................................................................14 Allocation Example ...............................................................................15 Data Collection and Calculation Process ..............................................17 Example Data Collection Sheet ............................................................18 Classification and Characterization .......................................................19 Comparison of the TRACI and CML Methods .......................................20 Characterization Example.....................................................................22 Normalized impact categories for different regions ...............................23
Nomenclature
Abbreviation Explanation
AP CML
Acidification Potential Centre of Environmental Science, University of Leiden, the Netherlands Eutrophication Potential Ganzheitlichen Bilanzierung (German for holistic balancing) Global Warming Potential International Organization for Standardization Life Cycle Assessment Life Cycle Impact Assessment Ozone Depletion Potential Photochemical Ozone Creation Potential Tool for the Reduction and Assessment of Chemical and other Environmental Impacts
Figure 1:
1.1
What is LCA?
There are two LCA standards created by the International Organization for Standardization (ISO): the ISO 14040 and ISO 14044. Life Cycle Assessment, as defined by the ISO 14040 and ISO 14044 is the compiling and evaluation of the inputs and outputs and the potential environmental impacts of a product system during a products lifetime. Who uses LCA? LCAs are used by a variety of users for a range of purposes. According to the ISO standards on LCA, it can assist in: Identifying opportunities to improve the environmental aspects of products at various points in their life cycle; Decision making in industry, governmental or non-governmental organizations (e.g. strategic planning, priority setting, product and process design or redesign); Selection of relevant indicators of environmental performance, including measurement techniques; and Marketing (e.g., an environmental claim, eco-labeling scheme or environmental product declarations).
The following is just a brief list of the groups that use LCAs and of the possibilities that an LCA could be used for. 1.1.1 Industry
Large companies use LCAs as a way of identifying environmental hot spots and to develop and advertise their environmental management strategies. LCA studies are often conducted by industry associations and environmental concepts and tools research organizations including the: Canadian Wood Council; International Copper Association; International Lead and Zinc Research Organization; International Iron and Steel Institute; International Aluminum Institute and the Nickel Development Institute. 1.1.2 Government
Governmental departments around the world are active promoters of LCA. Governments use LCA for data collection and developing more effective environmental policies related to materials and products. 1.1.3 Universities
There are many universities researching and developing LCA methodology and data.
1.2
The ISO 14040 standard provides an introduction to LCA and contains applicable definitions and background information. The ISO 14044 describes the process of conducting an LCA. The detailed procedure for LCA, outlined in Chapter 2, is in accordance with the standards ISO 14040 and ISO 14044.
1.3
GaBi overview
With features refined through experience on thousands of PE consulting projects, GaBi 4 supports every stage of an LCA, from data collection and organization to presentation of results and stakeholder engagement. GaBi automatically tracks all material, energy, and emissions flows, as well as defined monetary values, working time and social issues, giving instant performance accounting in dozens of environmental impact categories. With a modular and parameterized architecture, GaBi allows rapid modeling even of complex processes and different production options. This architecture also makes it easy to add other data such as economic cost or social impact information to a model, making GaBi a holistic life cycle analysis tool. The GaBi 4 platform is complemented by the most comprehensive, up-to-date Life Cycle Inventory database available. The databases maintained by PE provide over 2,000 cradleto-gate material data sets, 8,000 intermediary chemical process models, and thousands of LCA projects from quality-controlled industry projects. The data set contained in this educational version of GaBi, GaBi Education, is a small fraction of the available data within PE. .
Figure 2:
2.1
According to the ISO 14040 standard the first phase of an LCA is the definition of the goal and scope. In this step all general decisions for setting up the LCA system are made. The goal and scope should be defined clearly and consistently with the intended application. An LCA is an iterative process and this allows redefining the goal and scope later in the study based on the interpretation of the results. 2.1.1 Goal
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The intended application of an LCA study - An LCA can be used for many different applications such as marketing, product development, product improvement, strategic planning, etc. The purpose of an LCA study The purpose of an LCA can also vary greatly and will dictate the scope of the study. If the study is intended to be published, the scope will be more comprehensive and include a greater data collection effort and a formalized review process. If the LCA will be used internally, no critical review is necessary; the scope will be dictated by the companys objective and their access to data. The intended audience of an LCA report The audience can be the shareholders, executives, engineers, consumers, etc. Depending on the clients objectives. Usage for comparative analysis If the LCA results are intended to be used for comparative reasons must be determined. If they are going to be published a critical review is obligatory. 2.1.2 Scope
During the scope definition the product or process system under study is characterized, all assumptions are detailed and the methodology used to set up the product system is defined. The following factors require definition before the LCA is done a detailed description of each factor is provided in the following sections. Function of the product Functional unit Reference flow Description of the system System boundaries Allocation procedures Impact categories and the impact assessment method Data requirements Data assumptions Limitations Data quality requirements Peer review Reporting type The most important issues are described in detail in the sections below. For further information please refer to the ISO 14040 and ISO 14044 standards. 2.1.2.1 Function of the System To describe a product the products function has to be defined. To do that the demands on the product have to be defined. In the case where different products are to be compared, the different functionalities of each of the products should be documented exactly. Sometimes products have a large variety of functions which makes it quite difficult to compare them with regard to the full range of functionalities. When, for example, the environmental impacts of mobile phones are to be compared, it should be clearly defined
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which functions they should have and how differences are taken into consideration in the case where one product has more functions than the other. 2.1.2.2 Functional Unit The functional unit is the quantified definition of the function of a product. For example, the functional unit of an aluminum beverage can might be defined as packaging 330ml of beverage, protecting it from UV radiation and oxidation and keeping in the carbonic acid for at least half a year. The ability to drink the beverages directly out of the packaging might be an additional function which should be taken into account. In order to compare two products, their functional units must be equivalent. For example, both glass bottles and cartons are used for milk packaging. Since the most common size for each packaging type might differ, the functional unit is set to be the packaging for 1000 liters of milk in order to compare the two packaging systems properly. Defining the functional unit can be difficult because the performance of products is not always easy to describe or isolate. Part of defining a functional unit is the definition of a reference flow. The reference flow is the measure of product components and materials needed to fulfill the function, as defined by the functional unit. All data collected during the inventory phase is related to the reference flow. In other words, all data used in the LCA must be calculated or scaled in accordance with this reference flow. 2.1.2.3 System Boundaries The system boundary defines which processes will be included in, or excluded from, the system; i.e. the LCA. It is helpful to describe the system using a process flow diagram showing the processes and their relationships. Figure 3 shows a generic process flow diagram with all processes included in the LCA shown inside the box marked as the System Boundary.
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Figure 3:
A systems boundaries are defined by cut-off criteria. Cut-off criteria are used to define the parts and materials included in and excluded from the product system. For example, cutoff criteria can be used to determine that any material production process that contributes less than 5% to the products overall weight can be excluded. Cut-off criteria might also be based on the number of processing steps in a process chain or the estimated contribution of a process to the overall environmental impact of the system. Often a combination of different cut-off criteria has to be used in order to define the system boundaries properly. For example, when the system boundaries are defined by cut-off criteria according to mass, an additional check should be carried out to determine whether or not small but very effective amounts of strong pollutants and toxins are cut off the system. To avoid that, additional cut-off criteria according to impact can be applied. There are four main options to define the system boundaries used (shown in Figure 4): Cradle to Grave: includes the material and energy production chain and all processes from the raw material extraction through the production, transportation and use phase up to the products end of life treatment. Cradle to Gate: includes all processes from the raw material extraction through the production phase (gate of the factory); used to determine the environmental impact of the production of a product. Gate to Grave: includes the processes from the use and end-of-life phases (everything post production); used to determine the environmental impacts of a product once it leaves the factory.
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Gate to Gate: includes the processes from the production phase only; used to determine the environmental impacts of a single production step or process. The ISO 14044 standard details the selection of a system boundary for LCA studies.
Figure 4:
System Boundaries.
2.1.2.4 Allocation and System Expansion In many processes more than one product is produced. In such a case all inputs and outputs of the process have to be allocated to the different products Allocation is the partitioning and relating of inputs and outputs of a process to the relevant products and byproducts. The allocation to different products can be done according to one of the rules defined below. Allocation by Mass: The inputs and outputs of a process are assigned to all of its products proportionally to their mass Allocation by Heating Value: The inputs and outputs of a process are assigned to all of its products according to their heating value. This allocation method is often used for production processes of fuels. Allocation by Market Value: The inputs and outputs of a process are assigned to all of its products according to their market value. Allocation by Other Rules: This can include exergy, substance content, etc.
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Figure 5:
Allocation Example
Figure 5 shows an example of a process where two products are produced. The resources used in this process and the emissions and wastes of the process have to be allocated to the two products. When the allocation is done proportionally to the products masses, product A would be assigned 90% of the resources and emissions, since the mass of product A is 90% of the overall mass of all products. If the allocation was done according to the products heating value, product A would be ascribed 99% of the resources and emissions. Since the choice of the allocation method can have a significant impact on the LCA results the ISO suggests that allocation should be avoided whenever possible. If it cannot be avoided, the allocation method should be described and the sensitivity of the results on different allocation methods should be described. The ISO also suggests that allocation according to physical relationships such as product mass or heating value rather than using non-physical relationships between the products (for example the market price). There are two ways to avoid allocation, substitution and system expansion. The topic of allocation requires much more explanation and is not covered in more detail here. 2.1.2.5 Data Quality Requirements Data quality requirements must be documented to define the required properties of the data for the study. Descriptions of data quality are important because the data quality has a significant influence on the results of the LCA study. Data quality requirements have to be determined at the beginning of the study. Mostly, data quality is a trade off between feasibility and completeness. The quality of a dataset can only be assessed if the characteristics of the data are sufficiently documented. Data quality does, therefore, correspond to the documentation quality. The following issues should be considered for the data quality: Data acquisition: Is the data measured, calculated or estimated? How much of the data required is primary data (in %) and how much data is taken from literature and databases (secondary data)?
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Time-reference: When was this data obtained and have there been any major changes since the data collection that might affect the results? Geographical reference: For what country or region is this data relevant? Technology (Best Available Technology) Is the secondary data from literature or databases representative for state-of-the-art-technology or for older technology? Precision: Is the data a precise representation of the system? Completeness: Are any data missing? How are data gaps filled? Representivity, consistency, reproducibility: Is the data representative, consistent and can it be reproduced?
2.2
2.2.1
The Inventory Analysis is the LCA phase that involves the compilation and quantification of inputs and outputs for a given product system throughout its life cycle or for single processes. The inventory analysis includes data collection and the compilation of the data in an Life Cycle Inventory (LCI) table.
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Figure 6:
Figure 6 shows the process of setting up an LCI. The process of conducting an LCI is iterative. As data is collected and more is learned about the system, data requirements or limitations may be redefined or a change in the data collection procedures in order to meet the goal of the study may be required. Sometimes issues may be identified that require revisions of the goal or scope definition of the study. After all process data is collected, an LCI table for the whole product system is created. The LCI is often presented as a table listing of all the material and energy inputs and outputs for the system. Detailed information on data collection and calculation can be found in the ISO 14044. 2.2.2 Data Collection - Classifications
This phase is the most work intensive and time consuming of all the phases in an LCA. It includes collecting quantitative and qualitative data for every unit process in the system. The data for each unit process can be classified as follows: energy inputs raw material inputs ancillary inputs other physical inputs products
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co-products wastes emissions to air, water and soil other environmental aspects
Practical constraints on data collection should be documented in the scope definition. Figure 7 shows a simple diagram that can be used to support data collection. It allows the user to enter the various quantified input and output flows.
Figure 7:
2.2.3
Before calculating the life cycle inventory, the following three steps should be completed: Data Validation - Validating the collected data is a continuous process. This can be done with mass or energy balances as well as with a comparison to similar data. Also, methods have to be in place to handle data gaps. Relating Data to Unit Processes - The data has to be related to unit processes Relating Data to Functional Unit - The data has to be related to the functional unit. These steps are necessary to generate the LCI for each unit process and for the overall product system. The LCI of the whole product system is the sum of all LCIs of all involved processes. The LCI can be calculated using the GaBi software. In GaBi, the LCI of the whole system is generated automatically once a system of processes is set up. In addition, the LCIs for a huge variety of processes are already stored in the database and only have to be connected to model a system. This process of modeling is described in detail in Chapter 3 of this handbook.
2.3
The Life Cycle Impact Assessment (LCIA) identifies and evaluates the amount and significance of the potential environmental impacts arising from the LCI. The inputs and
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outputs are first assigned to impact categories and their potential impacts quantified according to characterization factors. Figure 8 shows the conversion from emissions to impact potentials via classification and characterization.
Figure 8:
The Life Cycle Impact Assessment involves several steps according to the ISO standard. These can be found in more detail in the ISO 14044 standard. Within the scope of a study certain elements are defined for the LCIA. Mandatory elements include the selection of relevant impact categories, classification and characterization. The optional elements of the study are normalization, grouping and weighting. 2.3.1 Impact Assessment Methods
There are different methods that can be used to perform a Life Cycle Impact Assessment. These methods are continuously researched and developed by different scientific groups based on different methodologies. This handbook does not explain the development of the different methods, but it does describe them. In life cycle impact assessment methods, such as TRACI or CML, two main approaches are used to classify and characterize environmental impacts: the problem-oriented approach (mid point) and the damage-oriented approach (end point).
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In the problem-oriented approach flows are classified as belonging to environmental impact categories to which they contribute. With the help of the CML and TRACI methods more than a thousand substances are classified and characterized according to the extent to which they contribute to a list of environmental impact categories. Figure 9 shows the different impact categories used in the CML and TRACI methods.
Figure 9:
The so-called CML method is the methodology of the Centre for Environmental Studies (CML) of the University of Leiden and focuses on a series of environmental impact categories expressed in terms of emissions to the environment. The CML method includes classification, characterization, and normalization. The impact categories for the global warming potential and ozone layer depletion are based on IPCC factors. Further information is available at the Centre for Environmental Studies (CML), University of Leiden: For the tutorial example the CML method is used. Another method is the Tool for the Reduction and Assessment of Chemical and other Environmental Impacts, called TRACI. This problem-oriented method is developed by the U.S. Environmental Protection Agency (EPA) and is primarily used in the US. The damage-oriented methods also start with classifying a system's flows into various impact categories, but the impact categories are also grouped to belong to end-point categories as damage to human health, damage to ecosystem quality or damage to resources. EcoIndicator 99 is an example of a damage-oriented method. The used end points are easier to interpret and to communicate.
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2.3.2
A number of impact categories are typically chosen as the focus of an LCA study. This choice of impact categories depends on the goal of the study. The selected impact categories should cover the environmental effects of the analyzed product system. The choice of impact categories and the choice of the impact assessment method should be documented in the goal and scope definition. 2.3.3 Classification
The results of the Life Cycle Inventory phase include many different emissions. After the relevant impact categories are selected, the LCI results are assigned to one or more impact categories. If substances contribute to more than one impact category, they must be classified as contributors to all relevant categories. For example, CO2 and CH4 are both assigned to the impact category global warming potential. NOx emissions can be classified to contribute to both eutrophication and acidification and so the total flow will be fully assigned to both of these two categories. On the other hand, SO2 is apportioned between the impact categories of human health and acidification. Human health and acidification are parallel mechanisms and so the flow is allocated between the two impact categories. 2.3.4 Characterization
Characterization describes and quantifies the environmental impact of the analyzed product system. After assigning the LCI results to the impact categories, characterization factors have to be applied to the relevant quantities. The characterization factors are included in the selected impact category methods like CML or TRACI. Results of the LCI are converted into reference units using characterization factors. For example, the reference substance for the impact category global warming potential is CO2 and the reference unit is defined as kg CO2-equivalent. All emissions that contribute to global warming are converted to kg CO2-equivalents according to the relevant characterization factor. Each emission has its own characterization factor.
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Figure 10:
Characterization Example
Figure 10 shows the classification and characterization of methane according to CML 2001 with the characterization factor from December 2007. Methane contributes to the global warming potential (GWP). Therefore, during the classification step, methane is classified as a contributor to the global warming potential impact category. According to the CML method, methane has a characterization factor of 25. This means that CML has determined that methane contributes 25 times more than carbon dioxide to the global warming potential when a time frame of a hundred years is taken into account. The 6 kg of CH4-emissions in this example contribute 150 kg CO2-equivalents to the total GWP.
2.3.5
Normalization, evaluation, grouping and weighting are all optional elements that are performed to facilitate the interpretation of the LCIA results. It is essential that these actions are transparently documented since other individuals, organizations and societies may have different preferences for displaying the results and might want to normalize, evaluate, group or weight them differently. 2.3.5.1 Normalization Normalization involves displaying the magnitude of impact indicator results relative to a reference amount. For example this can be done for comparison with a reference system. The impact potentials quantify the potential for specific ecological impacts. In the normalization step the impact category results are compared to references in order to distinguish what is normal or not. For the normalization, reference quantities for a reference region or country (e.g. Germany) during a time period (e.g. 1 year) are used. This could be, for example, the overall emission of CO2-equivalents in Germany within
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one year, or, the CO2-equivalents of one person in Western Europe per year. When the results of all impact categories are compared to their references, they can be compared to each other more easily, since it is possible to say which impact indicator result contributes more or less to the overall entity of this impact category. Figure 11 shows impact categories normalized for different regions.
3.0E-11 2.5E-11 2.0E-11
USA
1.5E-11 1.0E-11 5.0E-12 0.0E+00
North America
World
GWP 100
ODP [-]
AP [-]
EP [-]
POCP [-]
Year [-]
Figure 11: Normalized impact categories for different regions
Normalized impact indicator results are non-dimensional quantities that allow for comparison between different impact categories; which impact category has a normal amount and which one is relatively larger? The normalized results of all chosen impact categories can also be displayed in a single graph, since they do not have different physical units anymore. 2.3.5.2 Grouping Grouping involves the sorting and ranking of the impact categories. It is an optional element with two possible approaches. The impact categories could be sorted on a nominal basis by characteristics such as inputs and outputs or global, regional or local spatial scales. The impact categories could also be ranked in a given hierarchy, for example in high, medium, and low priority. Ranking is based on value-choices. Different individuals, organizations, and societies may have different preferences. It is therefore possible that different parties will reach different ranking results based on the same indicator results or normalized indicator results. 2.3.5.3 Weighting Weighting is an optional element of the LCA and is based on value-choices and not on scientific principles. Weighting is used to compare different impact indicator results according to their significance. This weighting of the significance of an impact category is expressed with weighting factors. Those weighting factors are appraised through surveys among different groups (for example experts with hierarchical, egalitarian or individual approach, population).Weighting can also be used to aggregate weighted impact indicator results to a single score result.
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2.4
Interpretation
In the interpretation phase the results are checked and evaluated to see that they are consistent with the goal and scope definition and that the study is complete. This phase includes two primary steps: 1. identification of significant issues; 2. evaluation (described below). The life cycle interpretation is an iterative procedure both within the interpretation phase itself and with the other phases of the LCA. The roles and responsibilities of the various interested parties should be described and taken into account. If a critical review has been conducted, these results should also be described.
The goal of the evaluation is to enhance the reliability of the study. The following three methods should be used for the evaluation: Completeness check: In the completeness check, any missing or incomplete information will be analyzed to see if the information is necessary to satisfy the goal and scope of the study. Missing data have to be added or recalculated to fill the gap or alternatively the goal and scope definition can be adjusted. If the decision is made that the information is not necessary, the reasons for this should be recorded. Sensitivity check: The sensitivity check determines how the results are affected by uncertainties in the data, assumptions, allocation methods, calculation
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procedures, etc. This element is especially important when different alternatives are compared so that significant differences or the lack of them can be understood and reliable. Consistency check: The consistency of the used methods and the goal and scope of the study is checked. Some relevant issues to check could be: data quality, system boundaries, data symmetry of time period and region, allocation rules and impact assessment. 2.4.3 Conclusions, recommendations and reporting
The goal of the life cycle interpretation phase is to draw conclusions, identify limitations and make recommendations for the intended audience of the LCA. The conclusions are drawn from an iterative loop with the other elements of the interpretation phase in the sequence that follows: Identify the significant issues; Evaluate the methodology and results for completeness, sensitivity and consistency; and Draw preliminary conclusions and check that these are consistent with the requirements of the goal and scope of the study. If the conclusions are consistent, they are reported as final conclusions. Otherwise one might return to the previous steps until consistent conclusions are obtained. A thorough analysis of the data quality requirements, the assumptions, and the predefined values needs to be done. When the final conclusions of the study are drawn, recommendations to decision-makers are made to reflect a logical and reasonable consequence of the conclusions. 2.4.4 Report
The results of the Life Cycle Assessment should be assembled in a comprehensive report to present the results in a clear, transparent and structured manner. The report should present the results of the LCI and LCIA and also all data, methods, assumptions and limitations in sufficient detail. The reporting of the results should be consistent with the goal and scope definition. The type and format of the report is defined in the scope definition and will vary depending on the intended audience. The ISO 14044 requires full transparency in terms of value choices, rationales, and expert judgments. If the results will be reported to someone who is not involved in the LCA study, i.e. third-party or stakeholders, any misrepresentation of the results should be prevented. The reference document should consist of the following elements (ISO 14044): 1. Administrative Information a. Name and Address of LCA Practitioner (who conducted the LCA study) b. Date of Report c. Other Contact Information or Release Information 2. Definition of Goal and Scope
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3. Life Cycle Inventory Analysis (data collection, calculation procedures, LCI table) 4. Life Cycle Impact Assessment (methodology, results) 5. Life Cycle Interpretation a. Results b. Assumptions and Limitations c. Data Quality Assessment 6. Critical Review (internal and external) a. Name and Affiliation of Reviewers b. Critical Review Reports c. Responses to Recommendations If the study extends to the LCIA phase and is reported to a third-party, the following information should be reported: a description of the data quality; the relationship between LCI and LCIA results; the selection of impact categories; the impact assessment method; the indicator results profile normalization references weighting procedure 2.4.5 Critical Review
The ISO standards require critical reviews to be performed on all Life Cycle Assessments supporting a comparative assertion. The type and scope (purpose, level of detail, persons to be involved in the process etc.) of the critical review is described in the LCA report. The review should ensure the quality of the study as follows: LCA methods are consistent with the ISO standards; Data are appropriate and reasonable in relation to the goal of the study; Limitations are set and explained; Assumptions are explained; and Report is transparent and consistent and the type and style are oriented to the intended audience. The critical review can be done by an external or internal expert, or by a panel of interested parties.
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Procedure
3 Procedure
This chapter outlines a step by step procedure for conducting an LCA in GaBi. The example used in this manual and in the online video tutorial involves the modelling of the life cycle of 1000 steel paper clips based on German and European datasets. The procedure outlined below contains two types of text: 1. Numbered text indicates that a step should be completed. Text in italics provides explanatory comments about why you might do something or how something works. You will also notice that there are headings scattered throughout the procedure. These correspond (mostly; there are a couple of extra headings here) with the contents found in the video tutorial. The idea is that it is as easy as possible to work together with a friend, or in a group as well as to stop and continue whenever at any point. Viel Spa! (Thats German for have fun)
3.1
Opening GaBi
1. Open GaBi now.
The first thing you need to do is connect a database to the software. It could be the case that there is already a database connected. In the GaBi DB Manager you can see if there is already a database connected. Do you see something listed here?
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Procedure
If so, you already have a database connected. Please make sure that it is the Education database. If so, you can skip this step. 2. Otherwise, click on Database (Step 1) and then on Connect database (Step 2).
A new window will open. There you can locate the database that you want to connect. A GaBi database is normally contained in a folder in the My Documents folder. 3. Locate the Education database, select the folder and click OK.
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Procedure
3.2
Activating a database
4. Click on Activate, next to the connected database, or right click on the database in the object hierarchy on the left side of the GaBi window and select Activate. 5. A new window will open asking for a password just click OK.
The database is now connected to GaBi. Now you need to activate the database.
3.3
GaBi theory
GaBi calculates the potential environmental impacts as well as other important quantities of a product system based on plans. Within a plan, the system being studied is made up of processes and flows. In LCA terms, a plan represents the system with its boundaries, processes represent the actual processes taking place, and flows represent all the inputs and outputs related to the system. They connect plans or processes within the system or they define the input/output flows of the system. This list of input output flows is referred to as the Life Cycle Inventory (in short: LCI). The flows that enter the product system coming from the natural system (our environment, e.g. resources as hard coal) or that leave the system (e.g. CO2 emissions) are called elementary flows. The LCI is the input/output list of all elementary flows associated with the system. Perhaps the most important information of GaBi is the flow information. Flows are characterized by mass, energy and costs with their respective values. For example, GaBi contains flow information for different raw materials, plastics, metals, emissions to air and water and many, many more. It is important to understand that flows contain information that tells GaBi to what extent one unit of this flow contributes to different environmental impact categories: these are called classification and characterisation factors. Lets look at an example. In the object hierarchy, click on the plus next to flows and expand the flow group. You will notice that flows are grouped in folders according to whether or not they are resources, emissions or other types of flows. 6. Click to expand the Resources flow category and again to expand Energy resources and Non renewable energy resources. 7. Now click on the Natural gas folder.
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Procedure
You can now see all the natural gas flows available in your database. There are several country specific flows for natural gas since the gas mixture and its properties vary from region to region.
8. Open a flow by double clicking on it. You will now see the flow dialog box. In this window you can see, that the flow is automatically defined to be an input or output flow, or the flow type is undefined, when it can be both. This categorisation is done automatically based on the location of the flow within the GaBi database. The reference quantity of a flow is mostly the mass, this means that the reference unit of the flow is kg and that all other quantities refer to this reference quantity. Quantities can be thought of as the properties of a flow. Another quantity could be e.g. number of pieces, length, volume and so on. In the quantity list you can see which quantities are associated to this flow. Any additional quantities can be defined.
GaBi databases are completely open but predefined objects are also protected.
30
Procedure
In most cases there are several quantities associated with a flow. New quantities can be created in order to describe a special property of a flow. You will also notice the LCC tab. LCC stands for Life Cycle Costing and refers to a methodology that allows you to calculate the costs related to the life cycle of the system being studied. On the LCC tab economical quantities, such as the price can be defined for the flow. At this stage we do not need to go deeper into quantities. It is enough to understand that GaBi uses this information to calculate the potential environmental impact of the analyzed system. 9. You can close the Natural gas flow window.
3.4
Starting a project
You are going to construct a model of a steel paperclip. We already did some research on the paper clip, defined the goal and scope definition and qualitatively described the paper clip life cycle. Lets convert all this information into a new GaBi project. 10. Click on Projects in the object hierarchy and start a new project by right clicking in the display area on the right. 11. Name this project Life Cycle Steel Paper Clip. 12. Click Activate project.
Once the project is activated, all newly created processes, plans and flows will be saved under this project. This makes it much easier to find all the relevant information when you open the project in the future. It is a good idea to work with projects to keep your LCAs organised. 13. Close the project window.
31
Procedure
3.5
The first thing you need to do then is to create a plan. On this plan you will model the life cycle of the paperclip. 14. To create a new plan you can click on Plans in the object hierarchy and then right click in the display area and select New. A new plan will open in a new window. 15. Enter the name of the plan Life Cycle Steel Paper Clip and press enter. It is a great idea to save your plan regularly. 16. Save your plan now by clicking on the save icon in the plan window or by clicking Object and Save.
3.6
Adding a process
You will now add process and flow information to the plan. GaBi databases contain predefined processes and flows and these can be easily added to the model. In order to manufacture the paperclip you need steel wire. So, this will be the first process that you add to the plan. Adding processes to a plan is as easy as dragging and dropping. But first, you need to locate the processes. There are 2 ways to do this in GaBi: The first is by manually expanding and collapsing the object hierarchy in the DB manager to search for the process you require. The second and quicker way is to use the GaBi search function. 17. Make sure you have the Processes object selected in the object hierarchy. This is important because it tells GaBi to search only for processes. 18. Click the Search icon and enter the name of the process you are looking for. You are looking for Steel wire so you enter this now and click New search.
32
Procedure
GaBi now searches for all matches. Steel wire is exactly the process you are looking for. 19. Click on Steel wire and drag and drop it onto the plan.
3.7
Youll notice that there are no matches. This means you need to create a new process. In GaBi this is really easy. 21. Right click in the plan and select New process. A new window will open where you can define the new process. 22. Enter the name Paper Clip Bending, click Save and close it. You have now added a new process. However, you need to define this in some more detail. 23. Right click on the process and open it by selecting Details.
33
Procedure
24. Begin by selecting the country that your process refers to. You dont have to do this, but it is helpful, if you have the information. 25. Name the process simply by clicking in the Name field and typing Paperclip Bending. 26. In the source field you can select where this process data comes from. Leave this blank for now. You can also select the type of process. This requires a bit more explanation.
3.8
Process types
There are 5 types of processes in GaBi in accordance with the European Unions ILCD system. Processes are categorised in order to better understand their roles within a product system. If youd like to find out more about the ILCD system you can visit the ILCD website (http://lct.jrc.ec.europa.eu/index_jrc) or watch the Welcome to GaBi 4.4 video. A unit process single operation, represented by u-so, is often referred to as a unit process or gate to gate process. This process type contains only the data for one specific process step and no LCI (or Life cycle inventory) data. A unit process black box, represented by u-bb, refers to a multifunctional process or process chain at a plant level. This type of process may represent a group of processes rather than a single process step. For example, the entire production chain of a computer keyboard key (excluding acquisition of raw materials) rather than the individual manufacturing and transport processes for the keyboard key. In contrast, an LCI Result contains the entire life cycle data for part of or for the complete life cycle of a product system. This kind of dataset is often referred to as a cradle to gate or system process. A partly terminated system, represented by p-agg, contains all LCI data for the process except for one or more product flows that require additional modelling. For example, the steel wire process is a partly terminated system because all of the inputs and emissions for the process are accounted for except for the type of steel being used to make the steel wire. This process type is sometimes referred to as a partly linked process. The last process type is called an avoided product system and is represented by aps. This can be a confusing process type because all input and output flows are set to negative values or all inputs are converted to outputs or vice versa. This kind of dataset is typically used when modelling allocation and shows the way that the use of certain materials and energies is avoided by the product system under study. We wont go any deeper into this process type. Take a guess what kind of process paperclip bending might be. Is it a unit process single operation, unit process black box, LCI result, partly terminated system or avoided product system? If you guessed unit process single operation you are correct. But why?
34
Procedure
Well, because this process represents only the process of bending the paperclip. It does not contain multiple process steps, does not contain life cycle data for a complete life cycle of a product system, LCI data and does not include negative flows.
3.9
In GaBi you can specify the process type by selecting the appropriate type from the type drop down menu. 27. Since the Paper Clip Bending process is a unit process single operation, you can go ahead and select u-so.
Here you see the parameters area. By entering parameters, you can create what if scenarios as well as determining certain aspects of this processs relationship to other processes. The parameter area is closed for now and for now we will not go deeper into this. You now see a series of tabs. Since GaBi is designed to carry out a large variety of evaluations, it is possible to enter additional information relating to costs and working time. You can also add ILCD documentation. However, this is too detailed for this tutorial. For the time being we will focus on the current LCA tab. You have the possibility to enter additional information relating to this process such as its year, region, completeness and additional comments. Adding this information improves the quality of your process information but does not affect the results calculated by GaBi. You can enter some information here if you like or carry on.
35
Procedure
GaBi searches for potential flow matches in the active database. If an exact match is found, the flow is entered automatically. If a number of possible matches are found, the search window will appear and all the flows that contain the word you entered will be displayed. Lets take a look at that. 29. Click in the field where steel wire is written, type the word Steel and press enter.
36
Procedure
You will notice the search box appears listing all the flows containing the word steel. When you look at the Object Group column, you see that a variety of types of flows are listed, metal parts, waste for recovery, metals and consumer waste. 30. Sort the search results according to their object group by clicking on the Object group header. When you select a flow from the search window, always take note that the flow is chosen from the correct object group. 31. Select Steel wire by clicking on it and on Accept. This process also requires power to run the bending machine. 32. Click in the Flow field and enter the word Power. 33. You require electric power so you can select and accept this flow from the search box. Make sure you check the object group column to ensure that you have selected the correct object type.
The output of this process is, of course, paperclips. Just like for inputs, you can click in the flow field and enter the name of the flow you want to enter.
37
Procedure
You have to specify where you would like to locate the new object. Since this object is the product that you are producing, it makes sense to place it in the valuable substances folder, under systems, parts and metal parts. This categorisation is relevant for balance calculations in GaBi so make sure you select the appropriate location for your new flow. 36. Go ahead and select Valuable substances>Systems>Parts>Metal parts and click OK.
You can now edit the name of the flow and add any additional information.
38
Procedure
The reference quantity of a new flow is automatically set to mass. This means that the standard unit of this flow is measured in kg. If you add new quantities to this flow, you also need to enter the quantity related to 1kg of this flow. You do this by entering a number and unit. We will do this now.
Procedure
We determined that our paperclip has a weight of approximately 0.35 g. By clicking in the Quantity column of the Paperclip output you can choose if you either want to specify the amount of mass or number of pieces. 42. Choose the quantity Number of pieces and enter the amount 1. We do this to specify the functional unit: 1 paperclip. All data for the process will now refer to the production of 1 paperclip. If you change the quantity back to mass, the amount will be converted to 0.00035 kg.
We need the same amount of steel wire on the input side. 43. Enter the input mass 0.00035 now.
40
Procedure
Waste flows are, not surprisingly, waste flows that require additional processing within or outside of the current system but that remain within the technosphere.
We have now fully defined the paperclip bending process. 48. Click Save to save the process and close the process window.
41
Procedure
If no process or more than one process on a plan is fixed, there will be an error message. This means you need to go back and check that exactly one process is fixed.
We now have a plan for the paperclip life cycle that contains the paperclip bending process and steel wire process.
Red dot Tracked Flow, not yet connected Black dot Tracked Flow, connected
These dots indicate the tracked input and output flows and whether or not they have been linked. In this case you have not yet linked any of the processes and so all the tracked flows are displayed as red dots.
42
Procedure
43
Procedure
44
Procedure
In fact the power flow is automatically entered based on the fact that the single output from the power grid mix process is power and one of the input flows to the paperclip bending process is power. When linking processes GaBi checks for input/output matches. You can see now that the output dot from the power grid mix process is black, as is one of the input dots of the paperclip bending process. We can now connect the steel billet, steel wire, truck and paperclip bending processes. You will notice, when connecting the steel wire with the truck process the connect flows window opens. This window allows you to specify which output flow should be connected to which input flow. This occurs because there are no matching flows. In this case, GaBi is not sure whether the steel output should be connected to the cargo or diesel input. 62. Connect the steel wire process to the cargo flow of the truck process now by selecting Steel wire as the source and Cargo as the sink.
45
Procedure
You might have noticed that the truck process has another open input flow called diesel. This now means, that you have to add another process called diesel to our plan and to connect it with our truck process. 63. Search for a process called Diesel at refinery by clicking on the Search button. 64. Choose the one that is representative for Germany by selecting DE and drag and drop it from the search window onto the plan. 65. Place the process on your plan somewhere near your truck and connect the two together.
66. Connect the truck Cargo (which is actually steel wire) with the Paper Clip Bending process. Now the production process chain is complete. To complete the whole life cycle, you should add a process for the use phase and another plan for the End of life scenario. 67. Right click on the plan and select New process. and when you are asked where to save it, just choose the Processes folder.
Procedure
Lets assume that the usage of the paperclip does not contribute to any environmental impact, consume any power or release any emissions. 69. We can now enter the input flow Steel Paper Clip. 70. Enter the amount 0.00035kg. 71. Mark it with an X as a tracked flow. Then we assume that after the use phase, which has no environmental impact, the paper clip will be thrown away. To model this you integrate a waste flow on the output side of our use phase process. 72. Type in the output line Steel scrap and choose the flow Steel scrap (St) from the object group Waste for recovery. 73. Enter the amount 0.00035kg. 74. Mark this output flow with a * as a waste flow.
75. Save and close the process window. 76. On our life cycle plan connect the Paper Clip Bending process with the Use Phase Steel Paper Clip process.
47
Procedure
You can see different steel processes; 80. Choose a process that belongs to the Object group Material recovery. Choose steel billet (electric furnace) and put it on the plan by dragging and dropping.
48
Procedure
Since each plan requires one fixed process, this process must also be fixed. 81. Double click on the process and set the scaling factor to 1 and select Fixed just like before. 82. Save and close this plan. We will now add this newly created plan to the Life Cycle Steel Paperclip Plan. 83. Drag and drop the End of Life Paper Clip plan from the DB manager onto the already open Life Cycle Steel Paper Clip plan. 84. Connect the Use Phase Steel Paper Clip process with this plan.
Since the recycling of our End of life plan produces steel and has the output flow steel billet, you can model a circular material flow within the paper clip life cycle by connecting the output flow of our end of life plan with the steel wire production process. 85. Connect the End of Life Paper Clip plan to the Steel wire process now.
You can see that the amount of steel that is provided by the primary steel billet production decreases by the amount of steel that is provided by the recycling plan.
Congratulations, you have now completed modelling the life cycle of a paperclip!
49
Procedure
87. Write the comment: This model contains some non representative assumptions. 88. Click OK. 89. You can now resize and move this box as if it were a process.
You can now play around with your model and resize, relocate and redirect your processes and flow arrows to make it look the way you prefer. Remember that your model should reflect the real life situation. 90. Save and close your plan. You have now completed modelling.
Procedure
91.
The Balance window will open. This window allows you to choose how you would like to view the LCI and LCIA results. You can also view the results of the Life Cycle Costing and Life Cycle Working Time analysis here. Since you did not enter any information in these tabs earlier in the tutorial, there are no results generated here. We can skip these tabs. You can save the balance separately by clicking on the save button. The balance will be saved in the balances folder of your database. You find your balances in the object hierarchy of your GaBi DB Manager right above your plans. 92. Save your balance, but remember if you change anything on your plan, you have to calculate and save a new balance.
93. Deactivate the option Separate IO tables. The input and output tables will be merged. If there are matching flows on both the input and the output side of the LCI, the input and output amounts will be aggregated.
51
Procedure
If you leave this option activated, only elementary flows will be shown in the balance window.
Procedure
96. Select the separate IO tables option. Now, you see every substance that enters our system and every substance that leaves our system. 97. Activate the separate IO tables view and 98. Activate the Just elementary flows option. In the table you see the total values for each flow category. At the moment you see the flow grouping Resources on the input side and Resources, Emissions to air, fresh water, sea water and industrial soil on the output side. These are the flows that enter our system from nature and exit our system back to nature.
101. Collapse the list of the crude oil consumption again to view the total results. At the moment you are only seeing the total results for the whole paperclip product system. To get a better understanding of exactly where particular materials are used and emissions released you can look at the results for each and every process and sub plan. 102. Double click on the Life Cycle Steel Paper Clip column header to see these contributions to the overall result. This expands the view so that you can see the contributions of each process and sub plan.
53
Procedure
103. Click in the Quantity box, scroll up and choose the quantity CML 2001- Dec07 Global Warming Potential (GWP 100 years) [kg CO2-Equiv].
The balance window now displays all kg CO2-Equivalents for our plan. 104. Expand all the rows to see every substance and quantity of each substance that contributes to the global warming potential result for this system. As you see, only the flow categories Resources, on the input side, and Emissions to air, on the output side, contribute to the global warming potential. This makes sense since it is only these types of flows that contribute to global warming potential.
54
Procedure
All quantities that could be selected in the Quantity Box now appear in the table rows. For example you can now find information regarding how much mass enters and leaves the paperclip product system by looking at the mass values listed under the Technical quantities category in both the input and Output tables. Alternatively, you could deselect the separate IO tables option to view the aggregated results. 106. Look through the Environmental quantities by double clicking on it until you find the Global Warming potential quantity. 107. Make sure the separate IO table option is deselected.
108. Deselect the Quantity view. You should now see all the flows that contribute to GWP again. Here you can see that the flow contributing to global warming potential include flows in the resources category and emissions to air category. You will also notice that the resources total is a negative value. In this view, negative values indicate that there was an input of CO2 on the input side.
55
Procedure
You will notice that some values are highlighted in red. These are the weak points of the life cycle that correspond to more than 10% of the total sum of the life cycles kg CO2Equiv. Others values are grey. This means that they contribute minimally to the total result. You will also notice that some rows completely disappear. This indicates that they have no contribution at all. In the options of the balance window the thresholds for this view option can be set. 110. Fully expand your table so that you can see every column and every row. 111. Search for the most contributing flows in the categories resources and emissions to air by double clicking on the categories. You will notice that carbon dioxide contributes the most to the total result.
56
Procedure
By right clicking on a column and selecting define as 100% column, you could choose which process should be considered the 100% mark. This option is more interesting when comparing different products or processes which we are not doing here.
57
Procedure
You can now adjust the colours, gradients as well as numerous other visual aspects of the diagram. If you would like to use this diagram in a text document, you can click the copy icon and then paste it into its new location.
Alternatively you can right click in the input or output table and select Select all and then right click and select copy. The cells can now be pasted into Excel.
58
Literature
4 Literature
GABI 2003
GaBi 4: Software und Datenbank zur Ganzheitlichen Bilanzierung. IKP, Universitt Stuttgart und PE Europe GmbH, LeinfeldenEchterdingen, April 2003. LCA impact assessment of toxic releases; Generic modelling of fate, exposure and effect for ecosystems and human beings. (no. 1996/21) Centre of Environmental Science (CML) Leiden and National Institute of Public Health and Environmental Protection (RIVM), Bilthoven, May 1996.
Guine, J. et. al. Handbook on Life Cycle Assessment - Operational Guide to the ISO Standards. Centre of Environmental Science, Leiden University (CML); The Netherlands, 2001. Handbook on Life Cycle Assessment: An operational Guide to the ISO Standards; Dordrecht: Kluvver Academic Publsihers, 2002. Institut fr Kunststoffprfung und Kunststoffkunde der Universitt Stuttgart, Abteilung Ganzheitliche Bilanzierung, 2003 ISO 14040 Environmental Management Life Cycle Assessment Principles and Framework, 1997 ISO 14044 Environmental Management Life Cycle Assessment Requirements and Guidelines:2006 Kreiig, J. und J. Kmmel (1999): Baustoff-kobilanzen. Wirkungsabschtzung und Auswertung in der Steine-Erden-Industrie. Hrsg. Bundesverband Baustoffe Steine + Erden e.V.
GUINE ET AL. 2002 IKP 2003 ISO 14040 : 1997 ISO 14044:2006 KREISSIG & KMMEL 1999
59
Appendix A
Primary energy demand is often difficult to determine due to the various types of energy source. Primary energy demand is the quantity of energy directly withdrawn from the hydrosphere, atmosphere or geosphere or energy source without any anthropogenic change. For fossil fuels and uranium, this would be the amount of resource withdrawn expressed in its energy equivalent (i.e. the energy content of the raw material). For renewable resources, the energy-characterised amount of biomass consumed would be described. For hydropower, it would be based on the amount of energy that is gained from the change in the potential energy of the water (i.e. from the height difference). As aggregated values, the following primary energies are designated: The total Primary energy consumption non renewable, given in MJ, essentially characterises the gain from the energy sources natural gas, crude oil, lignite, coal and uranium. Natural gas and crude oil will be used both for energy production and as material constituents e.g. in plastics. Coal will primarily be used for energy production. Uranium will only be used for electricity production in nuclear power stations. The total Primary energy consumption renewable, given in MJ, is generally accounted separately and comprises hydropower, wind power, solar energy and biomass. It is important that the end energy (e.g. 1 kWh of electricity) and the primary energy used are not miscalculated with each other; otherwise the efficiency for production or supply of the end energy will not be accounted for. The energy content of the manufactured products will be considered as feedstock energy content. It will be characterised by the net calorific value of the product. It represents the still usable energy content. Appendix A 2 Waste categories
There are various different qualities of waste. Waste is according to e.g. German and European waste directives. From the balancing point of view, it makes sense to divide waste into three categories. The categories overburden/tailings, industrial waste for municipal disposal and hazardous waste will be used. Overburden / tailings in kg: This category is made up of the layer which has to be removed in order to get access to raw material extraction, ash and other raw material extraction conditional materials for disposal. Also included in this category are tailings such as inert rock, slag, red mud etc. Industrial waste for municipal disposal in kg: This term contains the aggregated values of industrial waste for municipal waste according to 3. AbfVwV TA SiedlABf. Hazardous waste in kg: In this category, materials that will be treated in a hazardous waste incinerator or hazardous waste landfill, such as painting sludges, galvanic sludges, filter dusts or other solid or liquid hazardous waste and radioactive waste from the operation of nuclear power plants and fuel rod production.
60
Appendix A
Appendix A 3
The mechanism of the greenhouse effect can be observed on a small scale, as the name suggests, in a greenhouse. These effects are also occurring on a global scale. The occurring short-wave radiation from the sun comes into contact with the earths surface and is partly absorbed (leading to direct warming) and partly reflected as infrared radiation. The reflected part is absorbed by so-called greenhouse gases in the troposphere and is reradiated in all directions, including back to earth. This results in a warming effect at the earths surface. In addition to the natural mechanism, the greenhouse effect is enhanced by human activates. Greenhouse gases that are considered to be caused, or increased, anthropogenically are, for example, carbon dioxide, methane and CFCs. Figure A 1 shows the main processes of the anthropogenic greenhouse effect. An analysis of the greenhouse effect should consider the possible long term global effects. The global warming potential is calcuAbsorption lated in carbon dioxide equivalents Reflection UV - radiation (CO2-Eq.). This means that the greenhouse potential of an emission is given Infrared radiation in relation to CO2 Since the residence CFCs CO CH time of the gases in the atmosphere is incorporated into the calculation, a time range for the assessment must also be specified. A period of 100 Figure A 1: Greenhouse effect years is customary.
T
ra
ce
s ga
i es
a he nt
sph tmo
ere
(ISO 14044:2006)
Appendix A 4
The acidification of soils and waters occurs predominantly through the transformation of air pollutants into acids. This leads to a decrease in the pH-value of rainwater and fog from 5.6 to 4 and below. Sulphur dioxide and nitrogen oxide and their respective acids (H2SO4 und HNO3) produce relevant contributions. This damages ecosystems, whereby forest dieback is the most well-known impact. Acidification has direct and indirect damaging effects (such as nutrients being washed out of soils or an increased solubility of metals into soils). But even buildings and building materials can be damaged. Examples include metals and natural stones which are corroded or disintegrated at an increased rate. When analysing acidification, it should be considered that although it is a global problem, the regional effects of acidification can vary. Figure A 2 displays the primary impact pathways of acidification.
61
Appendix A
The acidification potential is given in sulphur dioxide equivalents (SO2-Eq.). The acidification potential is described as the ability of certain substances to build and release H+ - ions. Certain emissions can also be considered to have an acidification potential, if the given S-, N- and halogen atoms are set in proportion to the molecular mass of the emission. The reference substance is sulphur dioxide.
Appendix A 5
Eutrophication is the enrichment of nutrients in a certain place. Eutrophication can be aquatic or terrestrial. Air pollutants, waste water and fertilization in agriculture all contribute to eutrophication. The result in water is an accelerated algae growth, which in turn, prevents sunlight from reaching the lower depths. This leads to a decrease in photosynthesis and less oxygen production. In addition, oxygen is needed for the decomposition of dead algae. Both effects cause a decreased oxygen concentration in the water, which can eventually lead to fish dying and to anaerobic decomposition (decomposition without the presence of oxygen). Hydrogen sulphide and methane are thereby produced. This can lead, among others, to the destruction of the eco-system. On eutrophicated soils, an increased susceptibility of plants to diseases and pests is often observed, as is a degradation of plant stability. If the nutrification level exceeds the amounts of nitrogen necessary for a maximum harvest, it can lead to an enrichment of nitrate. This can cause, by means of leaching, increased nitrate content in groundwater. Nitrate also ends up in drinking water. Nitrate at low levels is harmless from a toxicological point of view. However, nitrite, a reaction product of nitrate, is toxic to humans. The causes of eutrophication are displayed in Figure A 3. The eutrophication potential is calculated in phosphate equivalents (PO4-Eq). As with acidification potential, its important to remember that the effects of eutrophication potential differ regionally.
Air pollution
NOX N2O NH3
Fertilisation
NO3 -
Waste water
NH4+
PO4-3
62
Appendix A
Appendix A 6
Despite playing a protective role in the stratosphere, at ground-level ozone is classified as a damaging trace gas. Photochemical ozone production in the troposphere, also known as summer smog, is suspected to damage vegetation and material. High concentrations of ozone are toxic to humans. Radiation from the sun and the presence of nitrogen oxides and hydrocarbons incur complex chemical reactions, producing aggressive reaction products, one of which is ozone. Nitrogen oxides alone do not cause high ozone concentration levels. Hydrocarbon emissions occur from incomplete combustion, in conjunction with petrol (storage, turnover, refuelling etc.) or from solvents. High concentrations of ozone arise when the temperature is high, humidity is low, when air is relatively static and when there are high concentrations of hydrocarbons. Today it is assumed that the existence of NO and CO reduces the accumulated ozone to NO2, CO2 and O2. This means, that high concentrations of ozone do not often occur near hydrocarbon emission sources. Higher ozone concentrations more commonly arise in areas of clean air, such as forests, where there is less NO and CO (Figure A 4). In Life Cycle Assessments, photochemical ozone creation potential (POCP) is referred to in ethyleneequivalents (C2H4-q.). When analyzing, its important to remember that the actual ozone concentration is strongly influenced by the weather and by the characteristics of the local conditions.
Hydrocarbons Nitrogen oxides Dry and warm climate Hydrocarbons
Ozone
Nitrogen oxides
Appendix A 7
Ozone is created in the stratosphere by the disassociation of oxygen atoms that are exposed to short-wave UV-light. This leads to the formation of the so-called ozone layer in the stratosphere (15 - 50 km high). About 10 % of this ozone reaches the troposphere through mixing processes. In spite of its minimal concentration, the ozone layer is essential for life on earth. Ozone absorbs the short-wave UV-radiation and releases it in longer wavelengths. As a result, only a small part of the UV-radiation reaches the earth. Anthropogenic emissions deplete ozone. This is well-known from reports on the hole in the ozone layer. The hole is currently confined to the region above Antarctica, however another ozone depletion can be identified, albeit not to the same extent, over the midlatitudes (e.g. Europe). The substances which have a depleting effect on the ozone can essentially be divided into two groups; the fluorine-chlorine-hydrocarbons (CFCs) and the nitrogen oxides (NOX). Figure A 5 depicts the procedure of ozone depletion. One effect of ozone depletion is the warming of the earth's surface. The sensitivity of humans, animals and plants to UV-B and UV-A radiation is of particular importance. Possible
63
Appendix A
effects are changes in growth or a decrease in harvest crops (disruption of photosynthesis), indications of tumors (skin cancer and eye diseases) and decrease of sea plankton, which would strongly affect the food chain. In calculating the ozone depletion potential, the anthropogenically released halogenated hydrocarbons, which can destroy many ozone molecules, are recorded first. The so-called Ozone Depletion Potential (ODP) results from the calculation of the potential of different ozone relevant substances. This is done by calculating, first of all, a scenario for a fixed quantity of emissions of a CFC reference (CFC 11). This results in an equilibrium state of total ozone reduction. The same scenario is considered for each substance under study whereby CFC 11 is replaced by the quantity of the substance. This leads to the ozone depletion potential for each respective substance, which is given in CFC 11 equivalents. An evaluation of the ozone depletion potential should take into consideration the long term, global and partly irreversible effects.
UV - radiation
Stratosphere 15 - 50 km
Absorption
Absorption
Appendix A 8
The method for the impact assessment of toxicity potential is still, in part, in the development stage. The Human Toxicity Potential (HTP) assessment aims to estimate the negative impact of, for example, a process on humans (Figure A 6). The Eco-Toxicity potential aims to outline the damaging effects on an ecosystem. This is differentiated into Terrestrial Eco-Toxicity Potential (TETP, Figure A 7) and Aquatic Eco-Toxicity Potential (AETP, Figure A 8) In general, one distinguishes acute, sub-acute/sub-chronic and chronic toxicity, defined by the duration and frequency of the impact. The toxicity of a substance is based on several parameters. Within the scope of life cycle analysis, these effects will not be mapped out to such a detailed level. Therefore, the potential toxicity of a substance based on its chemical composition, physical properties, point source of emission and its behaviour and whereabouts, is characterised according to its release to the environment. Harmful substances can spread to the atmosphere, into water bodies or into the soil. Therefore, potential contributors to important toxic loads are ascertained. Characterisation factors are calculated through the Centre of Environmental Science (CML), Leiden University, and the National Institute of Public Health and Environmental Protection (RIVM), Bilthoven, based on the software USES 1.0 (GUINE ET AL. 1996). The model, LCA-World, which underlies the calculation, is based on the assumptions of a slight exchange of rainwater and air (western Europe), long residence times of substances, moderate wind and slight transposition over the system boundaries.
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Appendix A
The surface of the model is divided into 3% surface water, 60% natural soil, 27% agricultural soil and 10% industrial soil. 25% of the rainwater is infiltrated into the soil. The potential toxicities (human, aquatic and terrestrial ecosystems) are generated from a proportion based on the reference substance 1,4Dichlorbenzol (C6H4Cl2) in the air reference section. The unit is kg 1,4Dichlorbenzol-Equiv. (kg DCB-q.) per kg emission (GUINE ET AL. 2002). The identification of the toxicity potential is afflicted with uncertainties because the impacts of the individual substances are extremely dependent on exposure times and various potential effects are aggregated. The model is therefore based on a comparison of effect and exposure assessment. It calculates the concentration in the environment via the amount of emission, a distribution model and the risk characterisation via an input sensitive module. Degradation and transport in other environmental compartments are not represented. Toxicity potential can be calculated with toxicological threshold values, based on a continuous exposure to the substance. This leads to a division of the toxicity into the groups mentioned above (HTP, AETP, TETP) for which, based on the location of the emission source (air, water, soil), three values are calculated. Consequently, there is a matrix for toxic substances with rows of the various toxicities that have impacts on both humans and aquatic and terrestrial ecosystems, and columns of the extent of the toxic potential, considering the different emission locations.
Products
Biosphere
(Terrestrial ecosystem)
Biosphere
(Aquatic ecosystem)
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Appendix A
Appendix A 9
The abiotic depletion potential covers all natural resources (incl. fossil energy carriers) as metal containing ores, crude oil and mineral raw materials. Abiotic resources include all raw materials from non-living resources that are non-renewable. This impact category describes the reduction of the global amount of non-renewable raw materials. Nonrenewable means a time frame of at least 500 years. This impact category covers an evaluation of the availability of natural elements in general, as well as the availability of fossil energy carriers. The reference substance for the characterisation factors is antimony.
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