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Statistical Physics Phy632-Tutorial: Sharifah Hafizah Binti Syed Ab Aziz

The document discusses several topics in statistical physics: 1. It derives the energy levels of a 1-D infinite square well based on quantum mechanics, showing the energy is proportional to n^2 where n is the quantum number. 2. It calculates the total number of microstates and average occupational numbers for the Maxwell-Boltzmann, Bose-Einstein, and Fermi-Dirac statistics. 3. It shows that for Bose-Einstein statistics, the number of different distributions for the jth energy level is proportional to (N+j-1)!, where N is the total number of particles. For Fermi-Dirac statistics, the number of distributions is proportional

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360 views26 pages

Statistical Physics Phy632-Tutorial: Sharifah Hafizah Binti Syed Ab Aziz

The document discusses several topics in statistical physics: 1. It derives the energy levels of a 1-D infinite square well based on quantum mechanics, showing the energy is proportional to n^2 where n is the quantum number. 2. It calculates the total number of microstates and average occupational numbers for the Maxwell-Boltzmann, Bose-Einstein, and Fermi-Dirac statistics. 3. It shows that for Bose-Einstein statistics, the number of different distributions for the jth energy level is proportional to (N+j-1)!, where N is the total number of particles. For Fermi-Dirac statistics, the number of distributions is proportional

Uploaded by

SharifahHafizahAl-juf
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PPT, PDF, TXT or read online on Scribd
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STATISTICAL PHYSICS

PHY632- TUTORIAL
SHARIFAH HAFIZAH BINTI SYED AB AZIZ
Question 1)define
Question 2
Question 3
3.Derive the energy levels of a 1-D infinite square well of width L based on quantum mechanic concept.
λ1 = 2 L λ2 =½ 2 L λ3 = ⅓ 2 L

P =h/λ

λj = 1/nj 2 L
 
P= momentum, h= planck’s constant, 6.626 x 10 -34 J.s
λ = de Broglie wavelength
substitute λ= 2L

P= h/2L

Pj = nj h/2L

 
 
 If Pj is the resultant momentum corresponding to some set of quantum
numbers nx,ny,nz
 So,
Pj2= nj2 h2/4L2
 
Ej = ½ mv2 , P= mv
=½ m ( P2/m2 ) , v2 = ( P/m )2
= ½ P2 /m
Ej = ½ m ( n2 )(h2/4L2)

 Ej = n2 ( h2/8mL2)
 
MAXWELL BOLTZMAN
QUESTION 4 fig: 11-8
a)thermodynamic probability M-B
b) Total no of microstates

Ω = ∑ k Шk

Ω = 4374 + 21870 + 21870 + 43740 + 10935 +


87480 + 43740 + 14580 + 65610 + 21870 +
729 = 336798
c) Average occupational number
BOSE EINSTEIN
QUESTION 4 fig 11-4
a)thermodynamic probability B-E
b) total number of microstates

Ω =∑ Wk

Ω =W1 + W2 + W3 +...............+W12

Ω =63+135+135+180+90+270+180+100+216
+135+28=1532.
c) average occupation number, Ñ
Ñ = 1(∑ N .W )/ Ω
j jk k

Ñ =1[5(63) + 4(135) + 4(135) + 3(180)


0

+4(90)+3(270)+2(180) + 3(100) +2(216)


+1(135) ] /1532
=2.83
Ñ =1[ 1(135) + 2(180) + 1(270) +3(180) + 2(216)
1

+4(135) +6(28)] /1532


=1.60
Ñ = 1[1(135) +1(270) +3(100) +2(216) +1(135)]
2

/1532
=0.83
Ñ = 1[2(90) + 1(270) +1(180)] / 1532= 0.41
3

Ñ = 1[1(135) + 1(180)]/1532=0.21
4

Ñ = 1[1(135)/1532=0.088
5

Ñ = 1[1(63)/1532= 0.041
6
FERMI-DIRAC
QUESTION 4 fig 11-6
a)thermodynamic probability F-D
b) total number of microstate

Ω =∑ Wk

Ω =W1 + W2 + W3 + W4 + W5

Ω =9+27+9+1+27

Ω =73
c) average occupational number

Ň0 = [3(9) + 3(27) + 2(9) + 3(180) +3(1) +2(27)]


= 2.51

Ň1 = [2(9) + 1(27) + 3(9) +2(27)]


= 1.73

Ň2 = [1(27) +3(1) +2(27)]


=1.15

Ň3 = [1(27) + 1(9)]
= 0.493

Ň4 = [1(9)]
=0.123
Question 5) Show that the equation
•Bose-Einstien statistics
•The number of different distribution for jᵗʰ level is

or

since
therefore,
• Fermi-Direct statistics
• The total number of ways in which a given
sequence of letter can be assigned to the states is:

since
•The number of different distributions for the jᵗʰ level is

therefore,
Question 6

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