CAMBRIDGE INTERNATIONAL EXAMINATIONS JUNE 2002 INTERNATIONAL GCSE MARK SCHEME SYLLABUS/COMPONENT : 0620/3 CHEMISTRY (EXTENDED) GER Unvensiry ef Cammnose ©) Local Examinations SyndicatePaget Mark Scheme ‘Syllabus ISGSE Examinations - Jurve 2002 0620. © When the name of a chemical is demanded by the question, a correct formula © When a word equation is req. If.an equation is request ‘© An incorrectly written symbol, e.g.NA or CL, should be penalised once ina ‘* Unusual responses which include correct Chemistry that answers the question 1 is usually acceptable, When the formula is asked for, the name is not acceptable. question. luired a correct symbol equation is usually acceptable. ed then a word equation is not usualy acceptable. "e Jn the mark scheme if a word or phrase is underlined it(or an equivalent) is required for the award of the mark. question. or indicates different ways of gaining the same mark. COND indicates that the award of this mark is conditional upon previous mark being gained. (.....) is used to denote material that is not specifically required. OR designates ahternative and independent ways of gaining the marks for the should always be rewarded-even if they are not mentioned in the marking scheme. + All the candidate's work must show evidence of being marked by the examiner. @® @ (b) © @ Gi) @ @ Gi) wy) @ @ Any metal above aluminium Na, K, Ca, Mg etc IF() is correct then word equation conseq to (i) symbol equation If not balanced ONLY [1] AI + 3e => Al For AP* ONLY [1] anywhere in equation baunite molten or liquid or fused or bomogencous exyolite oxygen from oxide or formed at anode or implied it is formed carbon (anode) to form carhon dioxide packaging of food or window frames or roofs accept “cans” NOT aircraft cars etc low density light alloys for aircraft or electrical cables good conductor or foil malleable or cooling utensils fu) a) a) 2) (2) Q t] oy ii] oy 2) t)Pago? Wark Scheme ‘Syllabus | Papar IGCSE Examinations - June 2002 0620 3 good conductor of heat Ifuse repeated with different properties then 2/3 @) @ protected by oxide layer or temperature/energy heat low tu (i) removal of oxide layer y temperature/energy/heat increases (il NB comments must relate to this reaction TOTAL=17 2 (a) (@__ limestone ar quicklime or calcium oxide a or marble or chalk or calcium carbonate NOT just lime Gi) Ca** and SOZ [2] Gi) blue precipitate accept light blue precipitate then blue solution m dissolves or solution fy deep bloc 0 (b) Tight chlorophyll ‘water and carbon dioxide react to form (glucose) and oxygen 4] or equation [2] (© @ provides enzymes or named enzyme or catalyst or anaerobic respiration of yeast cells m (i) onidises alcohot ra to ethanoic acid or acetic acid or vinegar a) accept anaerobic [1] and respiration {1} if not eredited in (i) (ii) above “kills” or denatures yeast lower slows reaction most efficient/besUsvitable temperature for enzymes any TWO NOT repeat optimum (@)—_butanoie acid propanol names only (21 O} (1Pages Mark Scheme ‘Syllabus | Paper 1GCSE Examinations - June 2002 0620 a TOTAL = 17 3 @ (amide amino acids RI) or peptide ester carboxylic acid or salts or glycerol 2 or soap or fatty acids sugat or glucose or named sugar ft] @_nylon(s} or polyamide uy polyesters or terylene or dacron 0) (Gii) bromine (water or in organic solvent) tu remains brownvorange red/orange/yellow TW NOT stays the same goes colourless ri} ‘OR potassium manganate(VI1) (6) (catalytic converter a (i combustion (i incomplete ar insufficient oxygen wy (no carbon compounds or carbon monoxide formed or reduced oxides of nitrogen or no unburnt hydrocarbons ‘or only forms water or water is not a pollutant ANY ONE. a © (steam) and alkane a heat or catalyst or details of chemistry ~ forms carbon monoxide/dioxide and (hydrogen) ay OR electrolysis wW brine or acidified water or hydrogen forms at cathode a] OR carbon/coke m1 heat or details of chemistry - forms carbon monoxide/dioxide and (hydrogen) mMark Schi raat TGCSE Examinations - June 2002 an ne TOTAL = 16 4 (a) @ fluorine 0) Gi) iodine and astatine m1 ) @ Ch + 2Br => 2Cr + Br Q] © @ &) TOTAL not balanced ONLY [1] Gi) because it has lost electron(s )(Must be electron transfer) [1] Not couseq because it took electrons from the bromide [1] or chlorine gained electrons or bécause chlorine was reduced (i) Iodide or metals or iron(lI) ete not iodine accept iodine ions or alkene Pand 3Br COND upon first mark being swarded 3bp and Inbp sround phosphorus 8c around each bromine if charges then first mark only @ balanced @ pH phosphorous acid has higher pH OR electrical conductivity phosphorous acid poorer OR reaction with named metal or carbonate hydrobromic faster OR pH indicator correct colours proton or hydrogen ion (ii). base o proton acceptor or electron pair donor = 15 m0 it] 1] ay a tu a u] 0] B) 0) a fy io) om