Trial 1

V pH Ave mL titrant ΔpH ΔV ΔpH/ΔV Ave mL titrant Δ^2pH

0.00 3.70 1.00 0.53 2.00 0.265 2 -0.24

2.00 4.23 3.00 0.29 2.00 0.145 4 -0.11
4.00 4.52 5.00 0.18 2.00 0.09 6 0.00
6.00 4.70 7.00 0.18 2.00 0.09 8 0.01
8.00 4.88 9.00 0.19 2.00 0.095 10 -0.05
10.00 5.07 11.00 0.14 2.00 0.07 12 0.10
12.00 5.21 13.00 0.24 2.00 0.12 14 0.00
14.00 5.45 15.00 0.24 2.00 0.12 16 0.14
16.00 5.69 17.00 0.38 2.00 0.19 18 3.26
18.00 6.07 19.00 3.64 2.00 1.82 19.625 -2.94
20.00 9.71 20.25 0.70 0.50 1.4 20.5 -0.45
20.50 10.41 20.75 0.25 0.50 0.5 21 -0.14
21.00 10.66 21.25 0.11 0.50 0.22 21.5 0.02
21.50 10.77 21.75 0.13 0.50 0.26 22 -0.03
22.00 10.90 22.25 0.10 0.50 0.2 22.5 -0.08
22.50 11.00 22.75 0.02 0.50 0.04 23 0.03
23.00 11.02 23.25 0.05 0.50 0.1 23.5 0.01
23.50 11.07 23.75 0.06 0.50 0.12 24.125 0.04
24.00 11.13 24.50 0.10 1.00 0.1 25.25 -0.03
25.00 11.23 26.00 0.07 2.00 0.035 27 -0.01
27.00 11.30 28.00 0.06 2.00 0.03 29 0.07
29.00 11.36 30.00 0.13 2.00 0.065 31 -0.09
31.00 11.49 32.00 0.04 2.00 0.02 33 0.01
33.00 11.53 34.00 0.05 2.00 0.025 35 0.02
35.00 11.58 36.00 0.07 2.00 0.035 37 -0.06
37.00 11.65 38.00 0.01 2.00 0.005 39 0.05
39.00 11.66 40.00 0.06 2.00 0.03 41 -0.06
41.00 11.72 42.00 0.00 2.00 0 43 0.04
43.00 11.72 44.00 0.04 2.00 0.02 45 0.04
45.00 11.76 46.00 0.08 2.00 0.04 47 -0.06
47.00 11.84 48.00 0.02 2.00 0.01 48.75 -0.02
49.00 11.86 49.50 0.00 1.00 0 50.25 0.00
50.00 11.86 51.00 0.00 2.00 0 52.25 0.02
52.00 11.86 53.50 0.02 3.00 0.006667 55.5 0.00
55.00 11.88 57.50 0.02 5.00 0.004 60 0.02
60.00 11.90 62.50 0.04 5.00 0.008 65 0.02
65.00 11.94 67.50 0.06 5.00 0.012 70 -0.04
70.00 12.00 72.50 0.02 5.00 0.004
75.00 12.02
NOTE!
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
For 2nd derivative plot, first 2 pa
 Δ^2V Δ^2pH/Δ^2V

4 -0.06 Titration Curve

16 -0.006875
36 -2.467162E-17 14.00
64 0.00015625 12.00

pH
10.00
100 -0.0005
8.00
144 0.0006944444
6.00
196 0
4.00
256 0.000546875
2.00
324 0.0100617284
0.00
385.1406 -0.007633575 0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00
420.25 -0.001070791 Titrant volume (mL)
441 -0.00031746
462.25 4.326663E-05
484 -6.198347E-05 First Derivative Plot
ΔpH/ΔV

506.25 -0.000158025 2
529 5.671078E-05
552.25 1.810774E-05 1.5
582.0156 6.872668E-05
1
637.5625 -4.705421E-05
729 -1.371742E-05 0.5
841 8.323424E-05
961 -9.365245E-05 0
0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00
1089 9.182736E-06 Titrant volume (mL)
1225 1.632653E-05
1369 -4.382761E-05
Second Derivative Plot
Δ^2pH/Δ^2V

1521 3.287311E-05
1681 -3.569304E-05
0.015
1849 2.163332E-05
2025 1.975309E-05 0.01
2209 -2.716161E-05
0.005
2376.563 -8.415516E-06
2525.063 0 0
0 10 20 30 40 50 60 70 80
2730.063 7.32584E-06 -0.005
3080.25 -5.766924E-19
3600 5.555556E-06 -0.01
Titrant volume (mL)
4225 4.733728E-06
4900 -8.163265E-06

vative plot, first 2 pairs of values were omitted

vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
vative plot, first 2 pairs of values were omitted
0.00 80.00

0.00 80.00

70 80
 Second trial

mL pH Ave mL titrant ΔpH ΔV ΔpH/ΔV Ave mL titrant Δ^2pH

0.00 3.60 1 0.46 2.00 0.23 2 -0.14

2.00 4.06 3 0.32 2.00 0.16 4 -0.12
4.00 4.38 5 0.20 2.00 0.1 6 0.02
6.00 4.58 7 0.22 2.00 0.11 8 -0.05
8.00 4.80 9 0.17 2.00 0.085 10 -0.03
10.00 4.97 11 0.14 2.00 0.07 12 0.04
12.00 5.11 13 0.18 2.00 0.09 14 0.05
14.00 5.29 15 0.23 2.00 0.115 16 0.09
16.00 5.52 17 0.32 2.00 0.16 18 0.65
18.00 5.84 19 0.97 2.00 0.485 19.625 2.04
20.00 6.81 20.25 3.01 0.50 6.02 20.5 -2.47
20.50 9.82 20.75 0.54 0.50 1.08 21 -0.25
21.00 10.36 21.25 0.29 0.50 0.58 21.5 -0.17
21.50 10.65 21.75 0.12 0.50 0.24 22 0.00
22.00 10.77 22.25 0.12 0.50 0.24 22.5 -0.03
22.50 10.89 22.75 0.09 0.50 0.18 23 -0.01
23.00 10.98 23.25 0.08 0.50 0.16 23.5 -0.04
23.50 11.06 23.75 0.04 0.50 0.08 24.125 0.05
24.00 11.10 24.5 0.09 1.00 0.09 25.25 0.11
25.00 11.19 26 0.20 2.00 0.1 27 -0.14
27.00 11.39 28 0.06 2.00 0.03 29 0.09
29.00 11.45 30 0.15 2.00 0.075 31 -0.09
31.00 11.60 32 0.06 2.00 0.03 33 -0.06
33.00 11.66 34 0.00 2.00 0
35.00 11.66

NOTE!
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
For 2nd derivative plot, first 3 pairs of values were o
 Δ^2V Δ^2pH/Δ^2V Titration Curve
14.00
4 -0.035
16 -0.0075 12.00
36 0.00055555555556 10.00

pH
64 -0.00078125
8.00
100 -0.0003
6.00
144 0.00027777777778
196 0.00025510204082 4.00
256 0.0003515625 2.00
324 0.00200617283951
0.00
385.1406 0.00529676660311 0.00 5.00 10.00 15.00 20.00 25.00 30.0
420.25 -0.0058774538965 Titrant volume (mL)
441 -0.000566893424
462.25 -0.0003677663602
484 3.6701587591E-18 First Derivative Plot
506.25 -5.925925926E-05
7
529 -1.890359168E-05
ΔpH/ΔV

552.25 -7.243096424E-05 6
582.0156 8.5908346533E-05 5
637.5625 0.0001725321047 4
729 -0.0001920438957
3
841 0.00010701545779
961 -9.365244537E-05 2
1089 -5.509641873E-05 1
0
0 5 10 15 20 25 3
Titrant volume (mL)

airs of values were omitted Second Derivative Plot

airs of values were omitted
0.006
airs of values were omitted
Δ^2pH/Δ^2V

airs of values were omitted 0.004

airs of values were omitted 0.002

airs of values were omitted
0
airs of values were omitted 0 5 10 15 20 25
airs of values were omitted -0.002

airs of values were omitted -0.004

airs of values were omitted
-0.006

-0.008
Volume titrant (mL)
-0.004

-0.006

-0.008
Volume titrant (mL)
n Curve

20.00 25.00 30.00 35.00 40.00

volume (mL)

ative Plot

20 25 30 35 40
volume (mL)

ivative Plot

20 25 30 35

me titrant (mL)
me titrant (mL)