Electron Affinity

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21/09/2010 Electron Affinity

Electron Affinities of the Main-


Group Elements*
The electron affinity is a measure of the energy change when an electron is added
to a neutral atom to form a negative ion. For example, when a neutral chlorine
atom in the gaseous form picks up an electron to form a Cl- ion, it releases an
energy of 349 kJ/mol or 3.6 eV/atom. It is said to have an electron affinity of -349
kJ/mol and this large number indicates that it forms a stable negative ion. Small
numbers indicate that a less stable negative ion is formed. Groups VIA and VIIA
in the periodic table have the largest electron affinities.

* Alkali earth elements (Group IIA) and noble gases (Group VIIIA) do not form
stable negative ions.

Electron Affinities in kJ/mole


Period IA IIIA IVA VA VIA VIIA
H ... ... ... ... ...
Period 1
-73 ... ... ... ... ...
Li B C N O F
Period 2
-60 -27 -122 0 -141 -328
Na Al Si P S Cl
Period 3
-53 -44 -134 -72 -200 -349 Index
K Ga Ge As Se Br
Period 4 Tables
-48 -30 -120 -77 -195 -325
Rb In Sn Sb Te I Reference
Period 5 Ebbing
-47 -30 -121 -101 -190 -295
Sec 8.5
Cs Tl Pb Bi Po At
Period 6
-45 -30 -110 -110 -180 -270

Electron Affinities in Electron Volts


1 kJ/mol = .010364 eV/atom
Period IA IIIA IVA VA VIA VIIA
H ... ... ... ... ...
Period 1
-0.76 ... ... ... ... ...
Li B C N O F
Period 2
-0.62 -0.28 -1.27 0 -1.43 -3.41

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21/09/2010 Electron Affinity
Na Al Si P S Cl
Period 3
-0.55 -0.46 -1.39 -0.75 -2.08 -3.62
K Ga Ge As Se Br
Period 4
-0.50 -0.31 -1.25 -0.80 -2.02 -3.37
Rb In Sn Sb Te I
Period 5
-0.49 -0.31 -1.26 -1.05 -1.97 -3.06
Cs Tl Pb Bi Po At
Period 6
-0.47 -0.31 -1.14 -1.14 -1.87 -2.80

Periodic Table Chemical bonds

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