Scribd
Upload
40K views1 page

Antoine Constants

This table provides vapor pressure and boiling point properties for various pure chemical species. It lists the Antoine equation parameters to calculate vapor pressure over specific temperature ranges, as well as the normal boiling point and latent heat of vaporization for each species. A total of 46 common organic and inorganic compounds are included, with their respective chemical formulas and parameter values.

Uploaded by

radwaelhadad
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
40K views1 page

Antoine Constants

This table provides vapor pressure and boiling point properties for various pure chemical species. It lists the Antoine equation parameters to calculate vapor pressure over specific temperature ranges, as well as the normal boiling point and latent heat of vaporization for each species. A total of 46 common organic and inorganic compounds are included, with their respective chemical formulas and parameter values.

Uploaded by

radwaelhadad
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 1

Supplemental Table: Properties of Pure Species

B
Vapor pressure (P sat ) by the Antoine Equation: ln P sat /kPa = A −
t/◦ C + C
Latent heat of vaporization at the normal boiling point (Hn ), and normal boiling point (tn )

Parameters for Antoine Eqn. Temp. Range Hn tn


Name Formula A† B C ◦C kJ/mol ◦C

Acetone C3 H6 O 14.3145 2756.22 228.060 −26 — 77 29.10 56.2


Acetic acid C2 H4 O2 15.0717 3580.80 224.650 24 — 142 23.70 117.9
Acetonitrile* C2 H3 N 14.8950 3413.10 250.523 −27 — 81 30.19 81.6
Benzene C6 H6 13.7819 2726.81 217.572 6 — 104 30.72 80.0
iso-Butane C4 H10 13.8254 2181.79 248.870 −83 — 7 21.30 −11.9
n-Butane C4 H10 13.6608 2154.70 238.789 −73 — 19 22.44 −0.5
1-Butanol C4 H10 O 15.3144 3212.43 182.739 37 — 138 43.29 117.6
2-Butanol* C4 H10 O 15.1989 3026.03 186.500 25 — 120 40.75 99.5
iso-Butanol C4 H10 O 14.6047 2740.95 166.670 30 — 128 41.82 107.8
tert-Butanol C4 H10 O 14.8445 2658.29 177.650 10 — 101 39.07 82.3
Carbon tetrachloride CCl4 14.0572 2914.23 232.148 −14 — 101 29.82 76.6
Chlorobenzene C6 H5 Cl 13.8635 3174.78 211.700 29 — 159 35.19 131.7
1-Chlorobutane C4 H9 Cl 13.7965 2723.73 218.265 −17 — 79 30.39 78.5
Chloroform CHCl3 13.7324 2548.74 218.552 −23 — 84 29.24 61.1
Cyclohexane C6 H12 13.6568 2723.44 220.618 9 — 105 29.97 80.7
Cyclopentane C5 H10 13.9727 2653.90 234.510 −35 — 71 27.30 49.2
n-Decane C10 H22 13.9748 3442.76 193.858 65 — 203 38.75 174.1
Dichloromethane CH2 Cl2 13.9891 2463.93 223.240 −38 — 60 28.06 39.7
Diethyl ether C4 H10 O 14.0735 2511.29 231.200 −43 — 55 26.52 34.4
1,4-Dioxane C4 H8 O2 15.0967 3579.78 240.337 20 — 105 34.16 101.3
n-Eicosane C20 H42 14.4575 4680.46 132.100 208 — 379 57.49 343.6
Ethanol C2 H6 O 16.8958 3795.17 230.918 3 — 96 38.56 78.2
Ethylbenzene C8 H10 13.9726 3259.93 212.300 33 — 163 35.57 136.2
Ethylene glycol* C2 H6 O2 15.7567 4187.46 178.650 100 — 222 50.73 197.3
n-Heptane C7 H16 13.8622 2910.26 216.432 4 — 123 31.77 98.4
n-Hexane C6 H14 13.8193 2696.04 224.317 −19 — 92 28.85 68.7
Methanol CH4 O 16.5785 3638.27 239.500 −11 — 83 35.21 64.7
Methyl acetate C3 H6 O2 14.2456 2662.78 219.690 −23 — 78 30.32 56.9
Methyl ethyl ketone C4 H8 O 14.1334 2838.24 218.690 −8 — 103 31.30 79.6
Nitromethane* CH3 NO2 14.7513 3331.70 227.600 56 — 146 33.99 101.2
n-Nonane C9 H20 13.9854 3311.19 202.694 46 — 178 36.91 150.8
iso-Octane C8 H18 13.6703 2896.31 220.767 2 — 125 30.79 99.2
n-Octane C8 H18 13.9346 3123.13 209.635 26 — 152 34.41 125.6
n-Pentane C5 H12 13.7667 2451.88 232.014 −45 — 58 25.79 36.0
Phenol C6 H6 O 14.4387 3507.80 175.400 80 — 208 46.18 181.8
1-Propanol C3 H8 O 16.1154 3483.67 205.807 20 — 116 41.44 97.2
2-Propanol C3 H8 O 16.6796 3640.20 219.610 8 — 100 39.85 82.2
Toluene C7 H8 13.9320 3056.96 217.625 13 — 136 33.18 110.6
Water H2 O 16.3872 3885.70 230.170 0 — 200 40.66 100.0
o-Xylene C8 H10 14.0415 3358.79 212.041 40 — 172 36.24 144.4
m-Xylene C8 H10 14.1387 3381.81 216.120 35 — 166 35.66 139.1
p-Xylene C8 H10 14.0579 3331.45 214.627 35 — 166 35.67 138.3
Based primarily on data presented by B. E. Poling, J. M. Prausnitz, and J. P. O’Connell,
The Properties of Gases and Liquids, 5th ed., App. A, McGraw-Hill, New York, 2001.
*Antoine parameters adapted from Gmehling et al. See footnote 2, p. 764.
† Antoine parameters A are adjusted to reproduce the listed values of t .
n

You might also like