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window.docManager = docManager;
docManager.setEmbeddedDoc('False');
docManager.fontAggregatorHosts = ["https://html1-f.scribdassets.com", "https:/
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docManager.assetPrefix = "82yvztl0zk1xq4ev";
docManager.addFont(214, "b", "ff214", "Arial, Arial, Helvetica, sans-serif", "
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docManager.addFont(215, "", "ff215", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(212, "", "ff212", "Verdana, Verdana, Geneva, sans-serif", "
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docManager.addFont(213, "", "ff213", "Times New Roman, Times, serif", "normal"
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docManager.addFont(210, "", "ff210", "Times New Roman, Times, serif", "normal"
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docManager.addFont(211, "b", "ff211", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(165, "", "ff165", "Times New Roman, Times, serif", "normal"
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docManager.addFont(133, "", "ff133", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(132, "", "ff132", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(131, "b", "ff131", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(130, "i", "ff130", "Times New Roman, Times, serif", "normal
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docManager.addFont(137, "", "ff137", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(136, "", "ff136", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(135, "i", "ff135", "Arial, Arial, Helvetica, sans-serif", "
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docManager.addFont(134, "b", "ff134", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(139, "", "ff139", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(138, "", "ff138", "Verdana, Verdana, Geneva, sans-serif", "
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docManager.addFont(166, "", "ff166", "Verdana, Verdana, Geneva, sans-serif", "
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docManager.addFont(24, "", "ff24", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(25, "", "ff25", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(26, "b", "ff26", "Georgia1, Georgia, serif", "bold", "norma
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docManager.addFont(27, "", "ff27", "Times New Roman, Times, serif", "normal",

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docManager.addFont(20, "", "ff20", "Times New Roman, Times, serif", "normal",
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docManager.addFont(21, "b", "ff21", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(22, "", "ff22", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(23, "", "ff23", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(160, "b", "ff160", "Comic Sans MS, Comic Sans MS5, cursive"
, "bold", "normal");
docManager.addFont(28, "", "ff28", "Arial, Arial, Helvetica, sans-serif", "nor
mal", "normal");
docManager.addFont(29, "i", "ff29", "Times New Roman, Times, serif", "normal",
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docManager.addFont(161, "i", "ff161", "Times New Roman, Times, serif", "normal
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docManager.addFont(0, "b", "ff0", "Arial, Arial, Helvetica, sans-serif", "bold
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docManager.addFont(4, "", "ff4", "Times New Roman, Times, serif", "normal", "n
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docManager.addFont(8, "", "ff8", "Arial, Arial, Helvetica, sans-serif", "norma
l", "normal");
docManager.addFont(163, "", "ff163", "Georgia1, Georgia, serif", "normal", "no
rmal");
docManager.addFont(119, "b", "ff119", "Arial, Arial, Helvetica, sans-serif", "
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docManager.addFont(120, "", "ff120", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(121, "", "ff121", "Times New Roman, Times, serif", "normal"
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docManager.addFont(122, "b", "ff122", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(123, "", "ff123", "Georgia1, Georgia, serif", "normal", "no
rmal");
docManager.addFont(124, "", "ff124", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(125, "", "ff125", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(126, "", "ff126", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(127, "", "ff127", "Times New Roman, Times, serif", "normal"
, "normal");
docManager.addFont(128, "b", "ff128", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(129, "b", "ff129", "Georgia1, Georgia, serif", "bold", "nor
mal");
docManager.addFont(167, "", "ff167", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(118, "", "ff118", "Times New Roman, Times, serif", "normal"
, "normal");
docManager.addFont(59, "b", "ff59", "Times New Roman, Times, serif", "bold", "
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docManager.addFont(58, "", "ff58", "Times New Roman, Times, serif", "normal",
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docManager.addFont(55, "b", "ff55", "Times New Roman, Times, serif", "bold", "
normal");
docManager.addFont(54, "", "ff54", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(57, "b", "ff57", "Times New Roman, Times, serif", "bold", "

normal");
docManager.addFont(56, "i", "ff56", "Times New Roman, Times, serif", "normal",
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docManager.addFont(51, "", "ff51", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(50, "", "ff50", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(53, "b", "ff53", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(52, "", "ff52", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(164, "", "ff164", "Georgia1, Georgia, serif", "normal", "no
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docManager.addFont(201, "", "ff201", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(199, "i", "ff199", "Arial, Arial, Helvetica, sans-serif", "
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docManager.addFont(179, "", "ff179", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(200, "", "ff200", "Times New Roman, Times, serif", "normal"
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docManager.addFont(195, "", "ff195", "Times New Roman, Times, serif", "normal"
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docManager.addFont(194, "", "ff194", "Arial, Arial, Helvetica, sans-serif", "n
ormal", "normal");
docManager.addFont(197, "", "ff197", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(178, "", "ff178", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(191, "", "ff191", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(190, "b", "ff190", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(193, "", "ff193", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(192, "", "ff192", "Times New Roman, Times, serif", "normal"
, "normal");
docManager.addFont(115, "i", "ff115", "Times New Roman, Times, serif", "normal
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docManager.addFont(114, "b", "ff114", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(88, "i", "ff88", "Times New Roman, Times, serif", "normal",
"italic");
docManager.addFont(89, "", "ff89", "Georgia1, Georgia, serif", "normal", "norm
al");
docManager.addFont(111, "", "ff111", "Arial, Arial, Helvetica, sans-serif", "n
ormal", "normal");
docManager.addFont(110, "", "ff110", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(113, "", "ff113", "Georgia1, Georgia, serif", "normal", "no
rmal");
docManager.addFont(112, "", "ff112", "Times New Roman, Times, serif", "normal"
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docManager.addFont(82, "b", "ff82", "Arial, Arial, Helvetica, sans-serif", "bo
ld", "normal");
docManager.addFont(83, "", "ff83", "Georgia1, Georgia, serif", "normal", "norm
al");
docManager.addFont(80, "", "ff80", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(81, "", "ff81", "Georgia1, Georgia, serif", "normal", "norm

al");
docManager.addFont(86, "i", "ff86", "Times New Roman, Times, serif", "normal",
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docManager.addFont(87, "", "ff87", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(84, "", "ff84", "Times New Roman, Times, serif", "normal",
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docManager.addFont(85, "b", "ff85", "Arial, Arial, Helvetica, sans-serif", "bo
ld", "normal");
docManager.addFont(198, "", "ff198", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(206, "b", "ff206", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(3, "i", "ff3", "Times New Roman, Times, serif", "normal", "
italic");
docManager.addFont(177, "", "ff177", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(7, "", "ff7", "Comic Sans MS, Comic Sans MS5, cursive", "no
rmal", "normal");
docManager.addFont(108, "", "ff108", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(109, "", "ff109", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(102, "", "ff102", "Georgia1, Georgia, serif", "normal", "no
rmal");
docManager.addFont(103, "", "ff103", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(100, "b", "ff100", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(101, "", "ff101", "Times New Roman, Times, serif", "normal"
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docManager.addFont(106, "", "ff106", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(107, "", "ff107", "Times New Roman, Times, serif", "normal"
, "normal");
docManager.addFont(104, "i", "ff104", "Times New Roman, Times, serif", "normal
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docManager.addFont(105, "", "ff105", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(39, "", "ff39", "Times New Roman, Times, serif", "normal",
"normal");
docManager.addFont(38, "", "ff38", "Times New Roman, Times, serif", "normal",
"normal");
docManager.addFont(33, "i", "ff33", "Times New Roman, Times, serif", "normal",
"italic");
docManager.addFont(32, "b", "ff32", "Comic Sans MS, Comic Sans MS5, cursive",
"bold", "normal");
docManager.addFont(31, "b", "ff31", "Times New Roman, Times, serif", "bold", "
normal");
docManager.addFont(30, "", "ff30", "Arial, Arial, Helvetica, sans-serif", "nor
mal", "normal");
docManager.addFont(37, "", "ff37", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(36, "b", "ff36", "Arial, Arial, Helvetica, sans-serif", "bo
ld", "normal");
docManager.addFont(35, "", "ff35", "Times New Roman, Times, serif", "normal",
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docManager.addFont(34, "", "ff34", "Arial, Arial, Helvetica, sans-serif", "nor
mal", "normal");
docManager.addFont(205, "i", "ff205", "Times New Roman, Times, serif", "normal

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docManager.addFont(176, "", "ff176", "Times New Roman, Times, serif", "normal"
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docManager.addFont(60, "", "ff60", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(61, "", "ff61", "Times New Roman, Times, serif", "normal",
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docManager.addFont(62, "", "ff62", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(63, "", "ff63", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(64, "i", "ff64", "Times New Roman, Times, serif", "normal",
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docManager.addFont(65, "", "ff65", "Arial, Arial, Helvetica, sans-serif", "nor
mal", "normal");
docManager.addFont(66, "b", "ff66", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(67, "b", "ff67", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(68, "", "ff68", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(69, "", "ff69", "Times New Roman, Times, serif", "normal",
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docManager.addFont(175, "", "ff175", "Georgia1, Georgia, serif", "normal", "no
rmal");
docManager.addFont(174, "b", "ff174", "Times New Roman, Times, serif", "bold",
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docManager.addFont(173, "", "ff173", "Times New Roman, Times, serif", "normal"
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docManager.addFont(172, "", "ff172", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(171, "b", "ff171", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(170, "", "ff170", "Times New Roman, Times, serif", "normal"
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docManager.addFont(203, "", "ff203", "Times New Roman, Times, serif", "normal"
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docManager.addFont(181, "b", "ff181", "Times New Roman, Times, serif", "bold",
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docManager.addFont(182, "", "ff182", "Verdana, Verdana, Geneva, sans-serif", "
normal", "normal");
docManager.addFont(183, "", "ff183", "Georgia1, Georgia, serif", "normal", "no
rmal");
docManager.addFont(180, "", "ff180", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(2, "", "ff2", "Times New Roman, Times, serif", "normal", "n
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docManager.addFont(162, "", "ff162", "Times New Roman, Times, serif", "normal"
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docManager.addFont(187, "", "ff187", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(184, "b", "ff184", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(6, "", "ff6", "Times New Roman, Times, serif", "normal", "n
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docManager.addFont(186, "", "ff186", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(188, "", "ff188", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(189, "", "ff189", "Arial, Arial, Helvetica, sans-serif", "n

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docManager.addFont(196, "", "ff196", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(185, "", "ff185", "Times New Roman, Times, serif", "normal"
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docManager.addFont(99, "i", "ff99", "Arial, Arial, Helvetica, sans-serif", "no
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docManager.addFont(98, "", "ff98", "Times New Roman, Times, serif", "normal",
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docManager.addFont(168, "b", "ff168", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(169, "", "ff169", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(91, "b", "ff91", "Arial, Arial, Helvetica, sans-serif", "bo
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docManager.addFont(90, "", "ff90", "Times New Roman, Times, serif", "normal",
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docManager.addFont(93, "b", "ff93", "Comic Sans MS, Comic Sans MS5, cursive",
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docManager.addFont(92, "", "ff92", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(95, "", "ff95", "Times New Roman, Times, serif", "normal",
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docManager.addFont(94, "", "ff94", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(97, "", "ff97", "Times New Roman, Times, serif", "normal",
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docManager.addFont(96, "", "ff96", "Times New Roman, Times, serif", "normal",
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docManager.addFont(11, "", "ff11", "Times New Roman, Times, serif", "normal",
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docManager.addFont(10, "i", "ff10", "Verdana, Verdana, Geneva, sans-serif", "n
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docManager.addFont(13, "", "ff13", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(12, "i", "ff12", "Times New Roman, Times, serif", "normal",
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docManager.addFont(15, "", "ff15", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(14, "b", "ff14", "Times New Roman, Times, serif", "bold", "
normal");
docManager.addFont(17, "", "ff17", "Times New Roman, Times, serif", "normal",
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docManager.addFont(16, "", "ff16", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(19, "", "ff19", "Times New Roman, Times, serif", "normal",
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docManager.addFont(18, "", "ff18", "Times New Roman, Times, serif", "normal",
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docManager.addFont(117, "", "ff117", "Times New Roman, Times, serif", "normal"
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docManager.addFont(116, "", "ff116", "Times New Roman, Times, serif", "normal"
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docManager.addFont(204, "", "ff204", "Times New Roman, Times, serif", "normal"
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docManager.addFont(150, "", "ff150", "Times New Roman, Times, serif", "normal"

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docManager.addFont(153, "b", "ff153", "Arial, Arial, Helvetica, sans-serif", "
bold", "normal");
docManager.addFont(152, "b", "ff152", "Times New Roman, Times, serif", "bold",
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docManager.addFont(155, "", "ff155", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(154, "b", "ff154", "Times New Roman, Times, serif", "bold",
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docManager.addFont(157, "i", "ff157", "Times New Roman, Times, serif", "normal
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docManager.addFont(156, "", "ff156", "Times New Roman, Times, serif", "normal"
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docManager.addFont(159, "", "ff159", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(158, "", "ff158", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(207, "", "ff207", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(48, "", "ff48", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(49, "b", "ff49", "Arial, Arial, Helvetica, sans-serif", "bo
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docManager.addFont(46, "", "ff46", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(47, "", "ff47", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(44, "", "ff44", "Times New Roman, Times, serif", "normal",
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docManager.addFont(45, "i", "ff45", "Times New Roman, Times, serif", "normal",
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docManager.addFont(42, "", "ff42", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(43, "i", "ff43", "Arial, Arial, Helvetica, sans-serif", "no
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docManager.addFont(40, "", "ff40", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(41, "b", "ff41", "Times New Roman, Times, serif", "bold", "
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docManager.addFont(1, "", "ff1", "Times New Roman, Times, serif", "normal", "n
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docManager.addFont(5, "", "ff5", "Times New Roman, Times, serif", "normal", "n
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docManager.addFont(9, "", "ff9", "Arial, Arial, Helvetica, sans-serif", "norma
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docManager.addFont(146, "", "ff146", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(147, "", "ff147", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(144, "b", "ff144", "Times New Roman, Times, serif", "bold",
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docManager.addFont(145, "", "ff145", "Times New Roman, Times, serif", "normal"
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docManager.addFont(142, "b", "ff142", "Times New Roman, Times, serif", "bold",
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docManager.addFont(143, "", "ff143", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(140, "", "ff140", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(141, "", "ff141", "Times New Roman, Times, serif", "normal"

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docManager.addFont(208, "", "ff208", "Times New Roman, Times, serif", "normal"
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docManager.addFont(148, "", "ff148", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(149, "", "ff149", "Arial, Arial, Helvetica, sans-serif", "n
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docManager.addFont(77, "", "ff77", "Times New Roman, Times, serif", "normal",
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docManager.addFont(76, "", "ff76", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(75, "", "ff75", "Times New Roman, Times, serif", "normal",
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docManager.addFont(74, "i", "ff74", "Arial, Arial, Helvetica, sans-serif", "no
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docManager.addFont(73, "", "ff73", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(72, "", "ff72", "Times New Roman, Times, serif", "normal",
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docManager.addFont(71, "", "ff71", "Arial, Arial, Helvetica, sans-serif", "nor
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docManager.addFont(70, "i", "ff70", "Times New Roman, Times, serif", "normal",
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docManager.addFont(79, "", "ff79", "Times New Roman, Times, serif", "normal",
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docManager.addFont(78, "", "ff78", "Times New Roman, Times, serif", "normal",
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docManager.displayType = "vector";
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<span class=a style="left:3854px;top:342px;word-spacing:-2px">Chem 206 </span><s
pan class=a style="left:313px;top:326px;word-spacing:-1px">D. A. Evans </span></
div>
<div class="ff185" style="font-size:53px">
<span class=a style="left:440px;top:2983px;letter-spacing:2px">Matthew D. Shair<
/span><span class=a style="left:1622px;top:2942px;letter-spacing:3px">Wednesday,
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<div class="ff178" style="font-size:76px">
<span class=a style="left:450px;top:2201px;word-spacing:-4px;color:#ff0000">Read
ing Assignment for week:</span></div>
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<span class=a style="left:630px;top:2313px;word-spacing:4px">A. <span class=w9><
/span>Carey &amp; <span class=l9>Sundberg:</span></span></div>
<div class="ff49" style="font-size:50px">
<span class=a style="left:1182px;top:2324px;word-spacing:-2px">Part A</span></di
v>
<div class="ff178" style="font-size:61px">
<span class=a style="left:1336px;top:2313px;word-spacing:-2px">; Chapter 1</span
><span class=a style="left:630px;top:2426px;word-spacing:1px">B. <span class=w12
></span>Fleming, Chapter 1 <span class=l7>&amp; 2</span></span><span class=a sty
le="left:630px;top:2483px"> </span><span class=a style="left:630px;top:2540px;wo
rd-spacing:-1px">C. Fukui,</span></div>
<div class="ff89" style="font-size:50px">
<span class=a style="left:840px;top:2550px;word-spacing:-1px">Acc. Chem. Res.</s
pan></div>
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<span class=a style="left:1232px;top:2540px"> </span></div>
<div class="ff49" style="font-size:50px">
<span class=a style="left:1247px;top:2550px">1971</span></div>
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<span class=a style="left:1363px;top:2540px">,</span></div>
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<span class=a style="left:1392px;top:2550px">4 </span></div>
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<span class=a style="left:1420px;top:2540px">, 57.</span><span class=a style="le
ft:630px;top:2652px;word-spacing:-2px">D. O. J. Curnow,</span></div>
<div class="ff89" style="font-size:50px">
<span class=a style="left:1031px;top:2663px;word-spacing:-1px">J. Chem. Ed.</spa
n></div>
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<span class=a style="left:1333px;top:2652px"> </span></div>
<div class="ff49" style="font-size:50px">
<span class=a style="left:1348px;top:2663px">1998</span></div>
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<span class=a style="left:1493px;top:2663px">75 </span></div>
<div class="ff178" style="font-size:61px">
<span class=a style="left:1550px;top:2652px">, 910.</span><span class=a style="l
eft:630px;top:2766px;word-spacing:-2px">E. J. I. Brauman,</span></div>

<div class="ff89" style="font-size:50px">


<span class=a style="left:1034px;top:2777px">Science </span></div>
<div class="ff178" style="font-size:61px">
<span class=a style="left:1220px;top:2766px">,</span></div>
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<span class=a style="left:1249px;top:2777px">2002</span></div>
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<span class=a style="left:1365px;top:2766px">,</span></div>
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<span class=a style="left:1394px;top:2777px">295 </span></div>
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iv>
<div class="ff185" style="font-size:70px">
<span class=a style="left:996px;top:779px;word-spacing:1px;letter-spacing:3px">C
hemistry 206</span><span class=a style="left:725px;top:963px;word-spacing:-1px;l
etter-spacing:4px">Advanced Organic Chemistry</span></div>
<div class="ff112" style="font-size:41px">
<span class=a style="left:1005px;top:1160px;word-spacing:-1px;letter-spacing:3px
">Lecture Number 1</span></div>
<div class="ff97" style="font-size:69px">
<span class=a style="left:723px;top:1330px"> In<span class=w9></span>t<span clas
s=w9></span>rod<span class=w9></span>uct<span class=w style="width:13px"></span>
io<span class=w8></span>n t<span class=w style="width:13px"></span>o FM<span cla
ss=w9></span>O <span class=w7></span>Th<span class=w9></span>eory</span></div>
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<span class=a style="left:379px;top:1547px">s</span></div>
<div class="ff185" style="font-size:53px">
<span class=a style="left:467px;top:1548px;word-spacing:4px;letter-spacing:2px">
General Bonding Considerations</span></div>
<div class="ff93" style="font-size:42px">
<span class=a style="left:379px;top:1685px">s</span></div>
<div class="ff185" style="font-size:53px">
<span class=a style="left:467px;top:1686px;word-spacing:-1px;letter-spacing:2px"
>The H</span></div>
<div class="ff185" style="font-size:44px">
<span class=a style="left:630px;top:1709px">2</span></div>
<div class="ff185" style="font-size:53px">
<span class=a style="left:669px;top:1686px;word-spacing:-5px;letter-spacing:2px"
>Molecule Revisited (Again<span class=w6></span>!<span class=l6>)</span></span><
/div>
<div class="ff93" style="font-size:42px">
<span class=a style="left:379px;top:1823px">s</span></div>
<div class="ff185" style="font-size:53px">
<span class=a style="left:467px;top:1824px;word-spacing:-1px;letter-spacing:2px"
>Donor &amp; Acceptor Properties of Bonding &amp; Antibonding States</span></div
>
<div class="ff93" style="font-size:42px">
<span class=a style="left:379px;top:1961px">s</span></div>
<div class="ff185" style="font-size:53px">
<span class=a style="left:467px;top:1962px;word-spacing:-9px;letter-spacing:3px"
>Hyp<span class=w6></span>erconj<span class=l10>ugation <span class=w6></span>an
d <span class=w11></span>"<span class=l6>Negative" Hyperconjugatio<span class=l6
>n</span></span></span></span></div>
<div class="ff93" style="font-size:42px">
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<div class="ff185" style="font-size:53px">
<span class=a style="left:467px;top:2100px;letter-spacing:2px">Anomeric and Rela
ted Effects</span></div>
<div class="ff178" style="font-size:91px">

<span class=a style="left:1328px;top:304px;word-spacing:-2px;color:#ff0000">An I


ntroduction to Frontier Molecular Orbital Theory-1</span></div>
<div class="ff93" style="font-size:47px">
<span class=a style="left:2311px;top:540px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:2396px;top:524px;word-spacing:-2px;color:#ff0000">Prob
lem of the Day</span></div>
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e<span class=w style="width:17px"></span>mo<span class=l9>le<span class=l8>cu<sp
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></span></span></span></span></span></span></span></span></span></span></span></
span></span></span></span></span></span><span class=a style="left:2329px;top:679
px;letter-spacing:2px">for<span class=l7>m<span class=w style="width:16px"></spa
n>sal<span class=l6>t</span></span></span></div>
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<span class=a style="left:2572px;top:690px">1</span></div>
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<span class=a style="left:2854px;top:679px;letter-spacing:4px">.<span class=w st
yle="width:33px"></span>In<span class=w11></span>bo<span class=l8>th<span class=
w10></span>in<span class=l8>st<span class=l8>an<span class=l8>ce<span class=l8>s
<span class=w style="width:15px"></span>th<span class=l8>e<span class=w style="w
idth:15px"></span>ca<span class=l8>rb<span class=l8>on<span class=l8>yl<span cla
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e="width:16px"></span>as<span class=w11></span>th<span class=l9>e</span></span><
/span></span></span></span></span></span></span></span></span></span></span></sp
an></span></span></span><span class=a style="left:2329px;top:735px;word-spacing:
-1px">nucleophile in an intramolecular alkylation. <span class=w11></span>What i
s the preferred reaction path</span><span class=a style="left:2329px;top:790px;w
ord-spacing:-2px">for the transformation in question?</span></div>
<div class="ff185" style="font-size:41px">
<span class=a style="left:3730px;top:935px">+</span><span class=a style="left:35
79px;top:1223px">+</span><span class=a style="left:3648px;top:1322px">Br</span><
/div>
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<span class=a style="left:3854px;top:1016px"> </span></div>
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<span class=a style="left:3418px;top:958px">1</span><span class=a style="left:34
11px;top:1200px">2</span></div>
<div class="ff185" style="font-size:41px">
<span class=a style="left:3145px;top:922px;word-spacing:-5px;letter-spacing:3px"

>Path A</span><span class=a style="left:3142px;top:1172px;word-spacing:-5px;lett


er-spacing:3px">Path B</span></div>
<div class="ff178" style="font-size:61px">
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<div class="ff178" style="font-size:76px">
<span class=a style="left:2415px;top:1330px;word-spacing:-4px;color:#ff0000">You
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<div class="ff196" style="font-size:71px">
<span class=a style="left:3435px;top:1918px">(+)</span></div>
<div class="ff178" style="font-size:91px">
<span class=a style="left:3428px;top:1652px">B</span></div>
<div class="ff196" style="font-size:71px">
<span class=a style="left:3481px;top:1673px"> </span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:3437px;top:2656px;word-spacing:-1px">2 LiH</span><span
class=a style="left:3412px;top:2889px">CH</span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:3506px;top:2918px">3</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:3516px;top:2889px"> MgBr</span></div>
<div class="ff178" style="font-size:91px">
<span class=a style="left:3857px;top:1654px">A<span class=w style="width:116px">
</span>B</span><span class=a style="left:3857px;top:1903px">A<span class=w style
="width:116px"></span>B</span></div>
<div class="ff89" style="font-size:75px">
<span class=a style="left:3846px;top:318px;word-spacing:-2px">Chem 206 </span><s
pan class=a style="left:323px;top:319px;word-spacing:-2px">D. A. Evans </span></
div>
<div class="ff178" style="font-size:91px">
<span class=a style="left:1470px;top:293px;word-spacing:-2px;color:#ff0000">An I
ntroduction to Frontier Molecular Orbital Theory-1</span></div>
<div class="ff178" style="font-size:69px">
<span class=a style="left:1707px;top:2055px;word-spacing:35px;letter-spacing:-1p

x">+ Br:</span></div>
<div class="ff178" style="font-size:57px">
<span class=a style="left:1852px;top:2040px"> </span></div>
<div class="ff178" style="font-size:69px">
<span class=a style="left:1925px;top:1615px">minor</span><span class=a style="le
ft:1919px;top:1338px">major</span><span class=a style="left:1873px;top:1008px">B
r:</span></div>
<div class="ff178" style="font-size:57px">
<span class=a style="left:1951px;top:992px"> </span></div>
<div class="ff178" style="font-size:69px">
<span class=a style="left:531px;top:1017px">Nu:</span><span class=a style="left:
444px;top:733px;word-spacing:-3px">Nonbonding interactions (Van der Waals repuls
ion) between</span><span class=a style="left:444px;top:795px;word-spacing:-3px">
substituents within a molecule or between reacting molecules</span></div>
<div class="ff93" style="font-size:47px">
<span class=a style="left:334px;top:651px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:432px;top:635px;word-spacing:-2px;color:#ff0000">Steri
c Effects</span></div>
<div class="ff49" style="font-size:63px">
<span class=a style="left:516px;top:487px;word-spacing:-5px;color:#ff0000">Unive
rsal Effects Governing Chemical Reactions</span><span class=a style="left:1029px
;top:556px;word-spacing:3px;letter-spacing:-1px;color:#ff0000">There are three:<
/span></div>
<div class="ff93" style="font-size:47px">
<span class=a style="left:375px;top:1849px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:473px;top:1833px;word-spacing:-3px;color:#ff0000">Elec
tronic Effects (Inductive Effects):</span></div>
<div class="ff178" style="font-size:69px">
<span class=a style="left:1478px;top:1958px">+</span></div>
<div class="ff178" style="font-size:61px">
<span class=a style="left:1061px;top:2006px">S</span></div>
<div class="ff178" style="font-size:49px">
<span class=a style="left:1096px;top:2027px">N</span></div>
<div class="ff178" style="font-size:61px">
<span class=a style="left:1126px;top:2006px">1</span></div>
<div class="ff178" style="font-size:69px">
<span class=a style="left:506px;top:2216px;word-spacing:-3px">rate decreases as
R becomes more electronegative</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:478px;top:2340px;word-spacing:1px">Inductive Effects:
<span class=w style="width:14px"></span>Through-bon<span class=l6>d polarizatio<
span class=l6>n</span></span></span><span class=a style="left:478px;top:2408px;w
ord-spacing:32px">Field <span class=l style="margin-left:-34px">Effects: <span c
lass=w style="width:77px"></span>Through-space <span class=l style="margin-left:
-37px">polarization</span></span></span></div>
<div class="ff178" style="font-size:54px">
<span class=a style="left:393px;top:3039px">Danishefsky</span></div>
<div class="ff89" style="font-size:44px">
<span class=a style="left:642px;top:3048px;word-spacing:-1px">, JOC </span></div
>
<div class="ff178" style="font-size:54px">
<span class=a style="left:759px;top:3039px"> </span></div>
<div class="ff49" style="font-size:44px">
<span class=a style="left:772px;top:3048px;letter-spacing:-1px">1991</span></div
>
<div class="ff178" style="font-size:54px">
<span class=a style="left:874px;top:3039px">,</span></div>
<div class="ff89" style="font-size:44px">

<span class=a style="left:899px;top:3048px">56 </span></div>


<div class="ff178" style="font-size:54px">
<span class=a style="left:950px;top:3039px;word-spacing:2px;letter-spacing:-1px"
>, 387</span><span class=a style="left:1086px;top:2765px;word-spacing:-2px">Lewi
s acid</span></div>
<div class="ff89" style="font-size:50px">
<span class=a style="left:1432px;top:3030px;word-spacing:-2px;color:#ff0000">dia
stereoselection &gt;94 : 6 </span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:683px;top:2535px;word-spacing:-3px;color:#ff0000">Your
thoughts on this <span class=w6></span>transformation</span></div>
<div class="ff178" style="font-size:69px">
<span class=a style="left:2468px;top:959px;word-spacing:-3px">"During the course
of chemical reactions, the interaction of</span><span class=a style="left:2467p
x;top:1053px;word-spacing:-3px">the highest filled (HOMO) and lowest unfilled <s
pan class=w6></span>(antibonding)</span><span class=a style="left:2416px;top:114
5px;word-spacing:-3px">molecular orbital (LUMO) in reacting species is very i<sp
an class=w6></span>mportant</span><span class=a style="left:2644px;top:1238px;wo
rd-spacing:-3px">to the stabilization of the transition structure."</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:2314px;top:607px;word-spacing:-1px">Geometrical constr
ai<span class=l6>nts placed upon ground <span class=w style="width:15px"></span>
and transition states</span></span><span class=a style="left:2790px;top:677px;wo
rd-spacing:-4px">by orbital overlap <span class=w6></span>considerations<span cl
ass=l6>.</span></span></div>
<div class="ff93" style="font-size:47px">
<span class=a style="left:2351px;top:516px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:2416px;top:500px;word-spacing:-6px;color:#ff0000">Ster
eoelectronic Effects</span></div>
<div class="ff49" style="font-size:57px">
<span class=a style="left:2830px;top:840px;word-spacing:4px;letter-spacing:-1px;
color:#ff0000">Fukui Postulate for reactions:</span></div>
<div class="ff93" style="font-size:47px">
<span class=a style="left:2364px;top:1474px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:2430px;top:1458px;word-spacing:-4px;color:#ff0000">Gen
eral Reaction Types</span><span class=a style="left:2366px;top:1655px;word-spaci
ng:-5px">Radical Reactions (~10%):</span></div>
<div class="ff178" style="font-size:91px">
<span class=a style="left:3349px;top:1647px">+</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:2366px;top:1904px;word-spacing:-4px">Polar Reactions (
~90%):</span></div>
<div class="ff178" style="font-size:91px">
<span class=a style="left:3317px;top:1900px">+</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:3046px;top:2183px;word-spacing:-3px">Lewis Base</span>
<span class=a style="left:3423px;top:2147px;word-spacing:5px;letter-spacing:-1px
">Lewis Acid</span><span class=a style="left:2481px;top:2305px;word-spacing:-3px
;color:#ff0000">FMO concepts extend the <span class=w7></span>donor-accepto<span
class=l6>r paradigm to</span></span><span class=a style="left:2791px;top:2375px
;word-spacing:-4px;color:#ff0000">non-obvious families of reactions</span></div>
<div class="ff93" style="font-size:47px">
<span class=a style="left:2369px;top:2519px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:76px">
<span class=a style="left:2435px;top:2503px;word-spacing:-4px;color:#ff0000">Exa
mples to consider</span><span class=a style="left:2968px;top:2656px;word-spacing
:4px;letter-spacing:-1px">2 Li(0)</span><span class=a style="left:2835px;top:265
6px">+</span><span class=a style="left:2959px;top:2865px">Mg(0)</span><span clas

s=a style="left:2826px;top:2865px">+</span></div>
<div class="ff178" style="font-size:54px">
<span class=a style="left:414px;top:1181px;word-spacing:3px;letter-spacing:-1px"
>J. I. Brauman,</span></div>
<div class="ff89" style="font-size:44px">
<span class=a style="left:711px;top:1190px">Science </span></div>
<div class="ff178" style="font-size:54px">
<span class=a style="left:874px;top:1181px">,</span></div>
<div class="ff49" style="font-size:44px">
<span class=a style="left:899px;top:1190px;letter-spacing:-1px">2002</span></div
>
<div class="ff178" style="font-size:54px">
<span class=a style="left:1000px;top:1181px">,</span></div>
<div class="ff89" style="font-size:44px">
<span class=a style="left:1026px;top:1190px">295 </span></div>
<div class="ff178" style="font-size:54px">
<span class=a style="left:1102px;top:1181px;word-spacing:-2px">, 2245.</span></d
iv>
</div>
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&nbsp;
<div class="ff89" style="font-size:69px">
<span class=a style="left:3876px;top:295px">Chem 206 </span><span class=a style=
"left:320px;top:301px;word-spacing:-1px">D. A. Evans </span></div>
<div class="ff178" style="font-size:84px">
<span class=a style="left:813px;top:437px;word-spacing:1px;color:#ff0000">The H<
/span></div>
<div class="ff178" style="font-size:66px">
<span class=a style="left:1010px;top:468px;color:#ff0000">2</span></div>
<div class="ff178" style="font-size:84px">
<span class=a style="left:1061px;top:437px;word-spacing:1px;color:#ff0000">Molec
ule (again!!)</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:382px;top:575px;word-spacing:-3px">Let's combine two h
ydrogen atoms to form <span class=w6></span>the hydrogen molecule.</span><span c
lass=a style="left:382px;top:639px;word-spacing:-2px">Mathematically, linear com
bination<span class=l6>s of the 2 atomic 1s <span class=w7></span>states create<
/span></span><span class=a style="left:382px;top:703px;word-spacing:-3px">two ne
w orbitals, one is <span class=w8></span>bonding, and one antibonding:</span></d
iv>
<div class="ff161" style="font-size:41px">
<span class=a style="left:375px;top:1369px"> E</span><span class=a style="left
:390px;top:1334px"> n</span><span class=a style="left:390px;top:1304px"> e</sp
an><span class=a style="left:390px;top:1274px"> r</span><span class=a style="le
ft:390px;top:1257px"> g</span><span class=a style="left:390px;top:1227px"> y</
span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:685px;top:1326px">1</span></div>
<div class="ff89" style="font-size:52px">
<span class=a style="left:715px;top:1337px">s </span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:1534px;top:1326px">1</span></div>
<div class="ff89" style="font-size:52px">
<span class=a style="left:1564px;top:1337px">s </span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:1568px;top:985px">s* (</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:1659px;top:971px">antibonding)</span></div>
<div class="ff93" style="font-size:39px">
<span class=a style="left:356px;top:883px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:397px;top:870px;color:#ff0000"> </span></div>
<div class="ff49" style="font-size:52px">
<span class=a style="left:427px;top:881px;word-spacing:-1px;color:#ff0000">Rule
one</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:656px;top:870px;word-spacing:1px;color:#ff0000">: <spa
n class=w style="width:13px"></span>A linear combination of n atomic states will
create n <span class=l6>MOs.</span></span></div>

<div class="ff196" style="font-size:49px">


<span class=a style="left:794px;top:1169px">?</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:826px;top:1155px">E</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:790px;top:1523px">?</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:824px;top:1509px">E</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:330px;top:1885px;word-spacing:-2px;color:#ff0000">Let'
s now add the two electrons to the new MO, one from each H <span class=w6></span
>atom:</span><span class=a style="left:725px;top:2864px;word-spacing:-4px;color:
#ff0000">Note that</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:986px;top:2880px;color:#ff0000">?</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:1023px;top:2864px;color:#ff0000">E</span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:1063px;top:2888px;color:#ff0000">1</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:1107px;top:2864px;word-spacing:-2px;color:#ff0000">is
greater than</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:1509px;top:2880px;color:#ff0000">?</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:1546px;top:2864px;color:#ff0000">E</span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:1586px;top:2888px;color:#ff0000">2</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:1614px;top:2864px;word-spacing:16px;color:#ff0000">. W
hy?</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:1576px;top:1687px">s (</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:1641px;top:1673px">bonding)</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:1572px;top:2675px">s (</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:1637px;top:2661px">bonding)</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:789px;top:2553px">?</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:822px;top:2539px">E</span></div>
<div class="ff178" style="font-size:50px">
<span class=a style="left:859px;top:2560px">2</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:786px;top:2228px">?</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:819px;top:2214px">E</span></div>
<div class="ff178" style="font-size:50px">
<span class=a style="left:855px;top:2235px">1</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:1560px;top:2044px">s* (</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:1652px;top:2030px">antibonding)</span><span class=a st
yle="left:1527px;top:2385px">1</span></div>
<div class="ff89" style="font-size:52px">
<span class=a style="left:1557px;top:2396px">s </span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:678px;top:2385px">1</span></div>

<div class="ff89" style="font-size:52px">


<span class=a style="left:708px;top:2396px">s </span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:1655px;top:1425px">? </span></div>
<div class="ff178" style="font-size:50px">
<span class=a style="left:1692px;top:1432px">2</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:1654px;top:2487px">? </span></div>
<div class="ff178" style="font-size:50px">
<span class=a style="left:1691px;top:2494px">2</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:583px;top:1425px">? </span></div>
<div class="ff178" style="font-size:50px">
<span class=a style="left:620px;top:1432px">1</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:576px;top:2487px">? </span></div>
<div class="ff178" style="font-size:50px">
<span class=a style="left:613px;top:2494px">1</span></div>
<div class="ff161" style="font-size:41px">
<span class=a style="left:368px;top:2412px"> E</span><span class=a style="left
:383px;top:2376px"> n</span><span class=a style="left:383px;top:2346px"> e</sp
an><span class=a style="left:383px;top:2317px"> r</span><span class=a style="le
ft:383px;top:2299px"> g</span><span class=a style="left:383px;top:2269px"> y</
span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3454px;top:837px;color:#ff0000">+</span><span class=a
style="left:3297px;top:835px;color:#ff0000">C</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3340px;top:871px;color:#ff0000">1</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3365px;top:851px;color:#ff0000">? </span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:3407px;top:858px;color:#ff0000">1</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3182px;top:851px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3235px;top:835px;color:#ff0000">= <span class=w style=
"width:248px"></span>C</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3579px;top:871px;color:#ff0000">2</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3604px;top:851px;color:#ff0000">? </span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:3646px;top:858px;color:#ff0000">2</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2370px;top:481px;word-spacing:-3px;color:#ff0000">Line
ar Combination of Atomic Orbitals (LCAO): <span class=w7></span>Orbital Coeffici
ents</span><span class=a style="left:2470px;top:670px;word-spacing:-2px">Each MO
is constructed by taking a <span class=w6></span>linear combination of the</spa
n><span class=a style="left:2470px;top:734px;word-spacing:-2px">individual atomi
c orbitals (AO):</span><span class=a style="left:2734px;top:834px;word-spacing:3px;color:#ff0000">Bonding MO</span><span class=a style="left:2646px;top:969px;w
ord-spacing:-4px;color:#ff0000">Antibonding MO</span><span class=a style="left:3
541px;top:962px;color:#ff0000">C*</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3608px;top:998px;color:#ff0000">2</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3633px;top:978px;color:#ff0000">? </span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:3674px;top:985px;color:#ff0000">2</span></div>

<div class="ff196" style="font-size:55px">


<span class=a style="left:3187px;top:978px;color:#ff0000">s*</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3270px;top:962px;color:#ff0000">=C*</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3369px;top:998px;color:#ff0000">1</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3394px;top:978px;color:#ff0000">? </span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:3435px;top:985px;color:#ff0000">1</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3442px;top:964px;color:#ff0000"> </span><span class=a s
tyle="left:2419px;top:1093px;word-spacing:-2px">The coefficients, C</span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:2917px;top:1116px">1</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2962px;top:1093px;word-spacing:2px;letter-spacing:-1px
">and C</span></div>
<div class="ff178" style="font-size:58px">
<span class=a style="left:3123px;top:1116px">2</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3150px;top:1093px;word-spacing:-2px">, represent the c
ontribution of each AO.</span></div>
<div class="ff93" style="font-size:43px">
<span class=a style="left:2386px;top:1330px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2430px;top:1315px;color:#ff0000"> </span></div>
<div class="ff49" style="font-size:58px">
<span class=a style="left:2464px;top:1328px;word-spacing:5px;letter-spacing:-1px
;color:#ff0000">Rule Three</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2775px;top:1315px;color:#ff0000">:</span><span class=a
style="left:2885px;top:1309px">(C</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:2948px;top:1345px">1</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:2973px;top:1325px">)</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:2994px;top:1308px">2</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3042px;top:1311px">+</span><span class=a style="left:3
118px;top:1309px">(C</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3181px;top:1345px">2</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3206px;top:1325px">)</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3226px;top:1308px">2</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:3281px;top:1315px">= <span class=w style="width:17px">
</span>1</span><span class=a style="left:3685px;top:1647px">= <span class=w styl
e="width:16px"></span>1</span><span class=a style="left:3231px;top:1641px">antib
onding(C*</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3628px;top:1677px">1</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3653px;top:1657px">)</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3674px;top:1640px">2</span></div>
<div class="ff178" style="font-size:70px">

<span class=a style="left:3155px;top:1636px">+</span><span class=a style="left:2


808px;top:1641px">bonding(C</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3086px;top:1677px">1</span></div>
<div class="ff196" style="font-size:55px">
<span class=a style="left:3110px;top:1657px">)</span></div>
<div class="ff196" style="font-size:45px">
<span class=a style="left:3130px;top:1640px">2</span></div>
<div class="ff93" style="font-size:43px">
<span class=a style="left:2382px;top:1657px;color:#ff0000">s</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2427px;top:1643px;color:#ff0000"> </span></div>
<div class="ff49" style="font-size:58px">
<span class=a style="left:2461px;top:1655px;word-spacing:-3px;color:#ff0000">Rul
e Four</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2741px;top:1643px;color:#ff0000">:</span></div>
<div class="ff161" style="font-size:41px">
<span class=a style="left:2490px;top:2696px"> E</span><span class=a style="lef
t:2505px;top:2661px"> n</span><span class=a style="left:2505px;top:2631px"> e<
/span><span class=a style="left:2505px;top:2601px"> r</span><span class=a style
="left:2505px;top:2584px"> g</span><span class=a style="left:2505px;top:2554px"
> y</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:3399px;top:2328px">p* (</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:3487px;top:2314px">antibonding)</span></div>
<div class="ff196" style="font-size:49px">
<span class=a style="left:3535px;top:2983px">p (</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:3596px;top:2968px">bonding)</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2341px;top:1946px;word-spacing:-1px">Consider the pi bond of a C=O function: <span class=w12></span>In the ground state pi-C O</span><s
pan class=a style="left:2341px;top:2011px;word-spacing:-1px">is polarized toward
Oxygen. <span class=w style="width:14px"></span>Note (Rule 4) that the antibond
<span class=l6>ing MO</span></span><span class=a style="left:2341px;top:2074px;w
ord-spacing:-2px">is polarized in the opposite direction.</span></div>
<div class="ff178" style="font-size:60px">
<span class=a style="left:2956px;top:2296px">C</span><span class=a style="left:2
769px;top:2663px">C</span><span class=a style="left:3067px;top:2296px">O</span><
span class=a style="left:2956px;top:3010px">C<span class=w style="width:73px"></
span>O</span></div>
<div class="ff178" style="font-size:84px">
<span class=a style="left:1582px;top:281px;color:#ff0000">The H</span></div>
<div class="ff178" style="font-size:66px">
<span class=a style="left:1778px;top:311px;color:#ff0000">2</span></div>
<div class="ff178" style="font-size:84px">
<span class=a style="left:1830px;top:281px;word-spacing:-1px;color:#ff0000">Mole
cular Orbitals &amp; Antibonds</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2337px;top:1409px;word-spacing:-2px">The squares of th
e C-values are a measure of the electron population</span><span class=a style="l
eft:2771px;top:1473px;word-spacing:-3px">in neighborhood of atoms in question</s
pan><span class=a style="left:2465px;top:1771px;word-spacing:-1px">In LCAO metho
d, both wave fu<span class=l6>nctions <span class=w style="width:17px"></span>mu
st each contribute</span></span><span class=a style="left:3087px;top:1831px;word
-spacing:-3px">one net orbital</span></div>
<div class="ff93" style="font-size:43px">
<span class=a style="left:2339px;top:601px;color:#ff0000">s</span></div>

<div class="ff178" style="font-size:70px">


<span class=a style="left:2384px;top:586px;color:#ff0000"> </span></div>
<div class="ff49" style="font-size:58px">
<span class=a style="left:2418px;top:599px;word-spacing:3px;letter-spacing:-1px;
color:#ff0000">Rule Two</span></div>
<div class="ff178" style="font-size:70px">
<span class=a style="left:2685px;top:586px;color:#ff0000">:</span></div>
<div class="ff178" style="font-size:63px">
<span class=a style="left:585px;top:1319px">H<span class=w style="width:1027px">
</span>H</span><span class=a style="left:1644px;top:2378px">H</span><span class=
a style="left:578px;top:2378px">H</span><span class=a style="left:3643px;top:274
5px">O</span></div>
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ALL PERSONS MORE THAN A MILE HIGH HAVE TO LEAVE WONDERLAND. This is an unfortunate
example of inaccurate scriptwriting, because in Lewis Carroll s book, the land in
which Alice s adventures take place is never referred to as Wonderland by any of
the characters. In fact, the word is not found anywhere in the book other than o
n the title page and in the final two paragraphs. The original manuscript was ti
tled Alice s Adventures Underground, and never used the word Wonderland at all.
The title was not changed to include Wonderland until after the manuscript for t
he published version
was completed.
The Queen's Tears
When Prince Albert died of typhoid fever on 14 December 1861, his death devastat
ed Queen Victoria, who was still affected by the death of her mother earlier tha
t year. Not long afterwards, while she was still grieving deeply, the Queen happ

ened to see a little girl sitting on a footstool by a fireplace, looking at pict


ures in a book. When the Queen asked what she was reading, the child got up and
carried a copy of Alice s Adventures in Wonderland over to Her Majesty. The little
girl showed the Queen the drawing of Alice swimming in a pool of her own tears.
Looking into Queen Victoria s face, with the devastating innocence of a child, th
e little girl asked: Do you think please, that you could cry as much as that?
A profound hush fell over the room as the Queen spoke quietly with the child abo
ut Wonderland. The next day, Her Majesty sent the little girl a locket by specia
l messenger from Windsor Castle. The necklace design was of intertwined horsesho
es in coral and pearls, with a miniature portrait of the Queen inside.
Carroll s Buffalo Pun
Lewis Carroll published Sylvie and Bruno in 1889, the year of the Bicentennial o
f the signing of the Bill of Rights by William and Mary in 1689. This event was
to the British what the Bicentennial of the Signing
of the Declaration of Independence is to Americans. Sylvie and Bruno includes th
e poem The Mad Gardener s Song, which contains the stanza:
He thought he saw a Buffalo
Upon the chimney-piece:
He looked again, and found it was
His Sister s Husband s Niece.
Unless you leave this house, he said,
I ll send for the Police!
Carroll insisted that Sir John Tenniel illustrate the
ece as an American bison instead of a water buffalo
iel.

Buffalo upon the chimney pi


thereby making it a Bison Tenn

The Dormouse is not a mouse at all but a furry-tailed rodent more like a squirre
l. An edible species of Dormouse was considered a delicacy in ancient Rome as a
savoury appetizer or as a dessert (dipped in honey and poppy seeds).
During the turned-on era of the 1960s, recording artist Grace Slick produced a h
it song entitled
White Rabbit, which connected Alice s size-changing episodes to then-popular drug us
age. One pill makes you larger and one pill makes you small. Other parts of the so
ng made reference to Wonderland characters, including men on the chessboard, the
caterpillar s mushroom, and the Dormouse.
A Radge Tea-Party
Foreign translations of Alice s Adventures in Wonderland were the rage by the 1870
s, including such languages as French, German, Italian, and Danish. In 1892, the
re was even a translation published with the book translated into Scottish. Here
is an excerpt from that book of the Mad Tea Party scene:
"Thaur was a table sit it under a cabre in front ay th hoose, an th March Haur an th
Hatter waur havin tea at it: a Dormoose was sittin atween them, fest asleep, an th o
ther tois waur usin it as a cushion, restin their elbows oan it, an talkin o wer its
heed.

" Very uncomfortable fur th


it doesnae min .

Dormoose, thooght Alice;

only, as it s asleep, ah suppose

"The table was a large a body, but th thee waur aw crowded together at a body co
rner ay it: No room! Nae room! they cried it when they saw Alice comin . There s plenty
ay room! said Alice indignantly, an she sat doon in a large arm-chair at a body e
nd ay th table.
" Hae some bucky,

th

March Haur said in an encooragin

"Alice looked aw roon th table, but thaur was naethin


nie bucky, she remarked.
" Thaur isnae onie,

said th

tain.
oan it but tea.

I dornt see o

March Haur.

" Then it wasnae huir uv a civil ay ye tae offer it,

said Alice angrily.

" It wasnae huir uv a civil ay ye tae sit doon withit bein


r."

invited,

said th March Hau

The Dean s Daily Sneeze


Alice s father, Henry George Liddell, was at various times in his life vice-chance
llor of Oxford University; Dean of Christ Church, Oxford; Headmaster of Westmins
ter School; author of A History of Rome; and co-author of the monumental work A
Greek-English Lexicon, which is still used by students of Greek to this day. Dea
n Liddell was so busy with his duties at Oxford that he had to schedule times to
see Alice in his appointment book. He was so meticulous about doing everything
on time that every day, at exactly noon, he would sneeze.
Generations of adults and children who loved Alice s Adventures in Wonderland and
Through the Looking Glass always assumed that they had read all of Lewis Carroll s
Alice stories.
This was not the case. In 1997, a suppressed Wonderland episode came to light wh
en the London auction house of Sotheby Parke Bernet and Company listed, inconspi
cuously, the following item in their June 3 catalogue:
Dodgeson (C.L.) Lewis Carroll. Handwritten manuscript for suppressed portion of Ali
ce s Adventures in Wonderland with a note on the final page in the author s purple in
k that the chapter was to be omitted. Four pages on note paper.
The fragment relates an incident in which Alice encounters a featherless eagle t
hat recites a poem of six stanzas, beginning: When I am old, I ll cut my hair. It wa
s to appear after an encounter with a group of impoverished children that Alice
was not allowed to play with after the Caucus Race. The manuscript, found betwee
n the pages of a book on higher mathematics,
was bought at a sale of the author s desk, personal effects, and books, and is app
arently unrecorded and unpublished.
The word apparently in the above paragraph is a significant understatement. Not on
ly had the suppressed episode not been published, but Lewis Carroll scholars wer
e unaware of its existence until the Sotheby auction. The discovery of the manus
cript in Carroll s own handwriting represents a literary event of major significan
ce to Carrollians indeed to all students of British literature.

Beneath a Sunny Sky?


In her description of the boat excursion the day that Lewis Carroll made up the
story of the nonsensical adventures underground, Alice later wrote that it was a
blazing summer afternoon with a heat haze shimmering over the meadows. The sun w
as so burning that we landed in the meadows down the river, deserting the boat t
o take refuge in the only bit of shade to be found, which was under a new-made h
aystack.
A check of the meteorological records, the weather near Oxford
July in 1862 was cool and rather wet and that it rained that
g party had made numerous other boating trips on days when the
r, and were possibly confusing the weather that day with other
sunnier.

on the Fourth of
afternoon. The boatin
weather was bette
days when it was

The Stuttering Dodo


The creatures in the Pool of Tears at the bottom of the rabbit hole include a mo
use, a duck, a lorrie, an eaglet, and a dodo. Each of these represented one of t
he queer-looking party in the boat on the Thames where the story of Alice s adventur
es were first told. The duck represented Reverend Duckworth, the lorrie represen
ted Lorina, the Eaglet represented Edith. Charles Dodgson was caricatured as the
dodo because he stammered thus when he spoke his last name it would come out DoDo-Dodgson.
He sent an autographed facsimile of Alice s Adventures Underground to Duckworth in
1886 inscribed The Duck from the Dodo.
The Hunting of the Snark was the first book in publishing history with a printed
dust jacket instead of plain paper. In correspondence with his publishers, Lewi
s Carroll suggested that they print the title of the book on the paper wrapper. T
he advantage will be that it can stand in bookstalls without being taken out of
paper, and so can be kept in cleaner and more saleable condition.
Daddy s on the Wall
You ve heard of the Shroud of Turin, on which there is an image supposed to be tha
t of Jesus Christ?
Well, a wall in Christ Church, Oxford was observed to have a faithful and unmista
keable likeness of Alice s father, Dean Liddell, in the damp stains on the stonewor
k. Cassell s Weekly reported the image to be: straight upon the wall as it might ha
ve been drawn by the hand of a master artist. Yet it is not etched, neither is i
t sketched nor sculptured.
She Haunts Me Phantomwise
Lewis Carroll s poems and correspondences often contained hidden messages. He wrot
e letters to child friends where the words were backwards, a mirror image, a spi
ral, or a rebus. The dedication in The Hunting of the Snark was to Gertrude Chat
away; the poem was a double acrostic
the first letters of each line spelled out
her name, while the first words in each stanza are Girt ... Rude ... Chat ... Aw
ay. The final poem in Through the Looking Glass is an acrostic of Alice Pleasanc
e Liddell.
On August 1st, 1881 a story appeared in Aunt Judy s Magazine entitled

The Land of I

dleness supposedly written by Lewis Carroll. This story was actually written by a
lady named Fraulein Ida Lackowitz. She had sent the manuscript to Lewis Carroll
, who forwarded it to his Editor, which then led to the mistake of naming him as
its author.
According to historian John Kennedy Melling, Ida Lackowitz was an eastern Europe
an emigre woman (c. 1852 - 1976) who published a number of verses in English and
in her native Rhaabish (an obscure dialect of Romanian) ... How she encountered
Lewis Carroll is not clear, but there exists a letter from her to him, dated Jul
y 1876, in badly spelled English, apparently requesting acknowledgement in print
for her assistance regarding some words and phrases of Rhaabish she supplied for
him at that time. The result of this correspondence remains unknown, but Lackowi
tz ended her days soon afterwards. On July 20, she was found floating in the Tha
mes River at Oxford, having apparently jumped from Folly Bridge late one night.
Eyewitnesses stated she had been seen standing there in the company of a tall gen
tleman who had mild blue eyes, an umbrella, some grey and black gloves, a tall hat,
and small toy bat but he was never successfully traced ...
It is a little-known fact that Lewis Carroll s stories about Alice were inspired b
y English humorist
Tom Hood s From Nowhere to the North Pole, a droll children s fantasy about the whim
sical inhabitants of a wonderland in the Arctic. An article in The Nineteenth Ce
ntury stated:
... in 1864, Tom Hood was delighting the world with such works as
From Nowhere to the North Pole. Between Tom HOOD and Mr. LEWIS CARROLL there is
more than a suspicion of resemblance in some particulars ...
The opening stanza of the poem Jabberwocky was originally written in 1855 with p
seudo-arcane spelling and purported to be a stanza of Anglo-Saxon Poetry. It appea
red in a self-published periodical that Lewis Carroll made for the amusement of
his brothers and sisters. He wrote the rest of the poem later while visiting his
cousins near Sunderland, when the family was having a game of verse-making.
Bats in the Belfry
Lewis Carroll apparently had a predilection for bats. He constructed a flying to
y bat for the amusement
of Alice. The Mad Hatter recites a parody of Twinkle Twinkle Little Star featuri
ng a bat instead of a star:
Twinkle, twinkle, little bat!
How I wonder what you re at!
Up above the world you fly,
Like a tea-tray in the sky ...
He gave his good friend Bartholomew Price the nickname
lectures soared far above his students heads.

Bat

because his mathematics

Many readers of GAMES are familiar with Douglas Adams whimsical masterpiece, The
Hitchhiker s Guide to the Galaxy, which began life as a radio drama series and the
n went on into various incarnations as books, a television show, and a motion pi
cture adaptation. The characters in the story were always pondering the answer t
o Life, the Universe, and Everything ... A race of highly-intelligent alien mice c
reated a massive super computer named Deep Thought to calculate this answer, whi
ch turned out to be ... 42.

What you may not know is that Lewis Carroll and the real Alice discussed the imp
ortance of the number forty-two well over one hundred years before The Hitchhike
r s Guide was written. Lewis Carroll told Alice that the diameter of the Mercury P
ond in the middle of Tom Quad at Christ Church was exactly forty-two feet. Whene
ver he took Alice s photograph, he always told her to sit still for forty-two seco
nds. He also told Alice that if she fell down a rabbit hole, it would take exact
ly forty-two minutes before she reached the other side of the earth. (Lewis Carr
oll had calculated that mathematically by using the speed at which she would be
falling and the diameter of the earth.) They played a number of math games with
the square and cube of their favorite number ... forty-two.
And at the Jack of Hearts trial, the King says to Alice:
NS MORE THAN A MILE HIGH TO LEAVE THE COURT.

Rule Forty-two. ALL PERSO

In 1843, when Lewis Carroll was eleven years old, his family lived at the rector
y in the village of Croft-on-Tees, a resort area in Yorkshire where his father h
ad been appointed rector. Lewis Carroll played in the nursery of this building a
s a child.
In 1950, while the Croft rectory house was being renovated, workmen pulled up th
e wooden floorboards in the nursery. Underneath the old boards, they found the l
id of a doll s teapot, a letter from a child s alphabet, a dilapidated shoe (for the
left foot), a child s white glove, a pocket knife, a crochet hook, three pieces o
f wood, and a thimble. On one of the pieces of wood was written the date June 18
th, 1843 along with the words in Lewis Carroll s childish handwriting.
Some of the items that Lewis Carroll had secreted in his childish hiding place w
ould eventually feature in his writings.
The white glove would appear in Alice s Adventures in Wonderland on the person of
the White Rabbit, who was always worrying about his white kid gloves. The buffal
o showed up in The Mad Gardener s Song from Sylvie and Bruno (see above), as well as
in The White Knight s Song from Alice s Adventures Underground
Who rocked his body to and fro,
And muttered mumblingly and low,
As if his mouth were full of dough,
Who snorted like a buffalo
That summer evening long ago ...
The left-hand shoe would also appear in that same poem:
And now, if e er by chance I put
My fingers into glue
Or madly squeeze a right-hand foot
Into a left-hand shoe ...
And as to the thimble
When Alice found herself with all the animals around the Pool of Tears, the Dodo
asked her what she had in her pocket.
Only a thimble,

said Alice sadly.

Hand it over here,

said the Dodo.

Then they all crowded round her once more, while the Dodo solemnly presented the
thimble, saying We beg your acceptance of this elegant thimble; and, when it had
finished this short speech, they all cheered.
The thimble would also play a prominent role in Lewis Carroll s epic poem The Hunt
ing of the Snark:
They sought it
They pursued it
They threatened
They charmed it

with
with
it s
with

thimbles, they sought it with care;


forks and hope;
life with a railway-share;
smiles and soap.

Some Day My Prince Will Come


When Alice grew up, she met Prince Leopold, the youngest son of Queen Victoria.
They fell in love, and the two of them were frequently seen together. Alice s moth
er encouraged the romance. Lewis Carroll was extremely jealous; there were rumor
s that he had asked for Alice s hand himself. The prince wanted to marry Alice, bu
t his mother the Queen forbade it. She wanted the prince to marry royalty
and so
he did. Prince Leopold married Princess Helen Frederica Augusta of Germany. Ali
ce eventually married a man named Reginald Gervis Hargreaves who ironically was
one of Lewis Carroll s mathematics students ...

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