4lecture Wastewater Treatment.
4lecture Wastewater Treatment.
Learning Outcomes
On completion of this unit you should be able to:
Content
Wastewater characteristics
Wastewater composition
Wastewater characterization studies
Primary and secondary treatment of wastewater
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Wastewater Treatment
General principles:
Biological treatment as main purification
process.
Replicate what nature does
Predominantly aerobic processes
Anaerobic processes for specific
treatment e.g. sludge
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Basic information:
Flow to the treatment plant
Individual constituent loads e.g. TSS, COD,
BOD5, ammonia, TKN, Total Phosphorus,
Orthophosphorus.
Minor constituents e.g. heavy metals,
pesticides residues.
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Forecasting average flow rate Average flow rates need to be developed both for
the initial period of operation and for the future
(design) period.
Elements to be considered are:
The current base flows ( e.g. 40 L/capita .d for
commercial and small industrial flows, 40 L/capita . d
for infiltration)
Estimated future flows for residential, commercial,
institutional and industrial sources
Non-excessive infiltration/inflow.
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Reactors- Vessels
Note: P-
Physical Process
C-
Chemical Process
B-
Biological Process
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Batch Reactor
Influent
(ex; Raw
Water)
REACTORVESSEL
Effluent
(ex; finished
drinking
water)
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Fluid particles pass through the tank and are discharged in the
same sequence in which they enter.
The particles remain in the tank for a time equal to the
theoretical detention time.
The reactors are long with a high length-width ratio in which
longitudinal dispersion is minimum or absent.
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Packed-bed reactor
Q, C0
Q, C
Container
V, C
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The volumetric flow rate into and out of the reactor is constant
The liquid within reactor is not subject to evaporate
The liquid within the container is mixed completely
A chemical reaction involving the reactant C is occurring within
the reactor
The reaction rate constant is first-order.
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Symbolic representation:
Mass Balance equation
Rate of flow of
reactant out of the
system boundary
Rate of
generation/utilization
of reactant within the
system boundary
Rate of
accumulation of
reactant within
the system
boundary
= + ()
= , 3
= , 3 1
OR
In Simply
InflowOutflow + Generation/utilization = Accumulation
= , 3 1
0 = , 3
= , 3
= , 1
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ANAEROBIC
ANAEROBIC TREATMENT TAKES
PLACE IN ABSENCE OF AIR.
THE ORGANIC POLLUTANTS ARE
CONVERTED BY ANAEROBIC
MICROORGANISMS TO A GAS
CONTAINING METHANE AND
CARBON DIOXIDE.
THERE IS SMELL ALL AROUND THE
PLANT
THE ENERGY CONSUMPTION IS
LOW
THE SLUDGE PRODUCTION IS LOW
Secondary
Treatment
Raw
wastewater
Screening
Primary
Sedimentation
Trickling
Filter
Secondary
Aeration
Sedimentatio
n
Anaerobic
Digestion
Disinfection
Treated
effluent
Land Disposal
Incineration
Composting
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Municipal
wastewater
Pre-Treatment
for
urban
wastewater is normally include
only physical processes, i.e. Flow
balancing, screening, grit removal
or oil scum removal.
Screens
Grit
facilities
Preliminary
treatment
FOG
flotation
Balancing
pH, organic,
Nutrients,
flow
To
Primary treatment
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Industrial process
wastewater
Heavy
metals
Organic
chemicals
Ammonia
organics
Oxidation
reduction
Oxidation
Air
stripping
Precipitation
Adsorption
Filtration
Primary treatment
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Screens Contd:
Classification of screens:
Coarse Screens
Coarse screens are classified as either bar racks(trash
racks) or bar screens depending on the spacing between
the bars. Composed of vertical arrangement of equally
spaced parallel bars or rods designed to trap coarse debris.
Bar racks have clear spacing of 5.08 cm to 10. 16 cm and
bar screens have clear spacing of 0.64 cm to 5.08 cm.
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Head Loss
Design of Screens
Velocity
Optimum velocity = 0.6 m/s (through the
screen opening)
Maximum velocity = 0.75-1.0 m/s (to prevent
entrapped materials being forced through the
bars.
Minimum velocity = 0.4 m/s to prevent
deposition of solids
Typical range
= 0.6 -1.0 m/s
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Note:
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Cleaning
Parameter
Angle of inclination
Maximum head loss cm)
Manual
Mechanical
45 - 60
75 - 85
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80
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flow
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Comminutors
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GRIT REMOVAL
Grit is the heavy inorganic (mineral) matter in wastewater
such as sand, silt, gravel, cigarette filter tips, metal
fragments etc:
Sources of Grit;
Street washing
Domestic sewage (ashes and clinker, egg shells, bone
chips etc.)
Beach sand
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Grit is;
Usually abrasive
Causes accelerated wear on pumps, pipes and valves
and other equipment if not removed
Builds up in low velocity areas of channels
The density of grit is much greater than that of the
wastewater so there is always a tendency for grit to
settle
The inorganic content of grit is generally in the range 70
85%.
Moisture in the grit can range from 10 70%.
The quantity of grit removed can vary from 0.004 0.1
m3/ML wastewater depending on the nature of the grit
and type of removal device used. The condition of the
sewer system also contributes leaky sewers tend to
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carry higher levels of grit.
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Objective
Protect moving mechanical equipment from abrasion
and accompanying abnormal wear.
Reduce formation of heavy deposits in pipelines,
channels.
Reduce frequency of digester cleaning.
Theory
Based on free settling of particles.
Using Stokes formula (laminar flow)
Here as the concentration of the grit particles are
relatively low, they behave as discrete particles (type 1
settling, no flocculation).
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Weir Sections
( )
= ( /)
= (/ )
= (/ )
= (/ )
= ()
= (//)
=
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=
=
( ) 2
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H
Q
Resultant velocity, Vn
W
L
3
) (
, =
( )
,
max
=
( 0.3 )
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Required length:
Considering discrete particle settling theory at maximum flow,
, =
At maximum flow,
=
) (
) (
3
,
max
=
( 0.021 )
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Item
Value
Range
Typical
Dimensions:
Depth, m
2:5
Length, m
7.5:20
Width, m
2.5:7.0
1:1 5:1
2:1
2-5
Air supply,
m3/min .m of length
0.15-0.45
0.3
0.004-0.200
0.015
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are:
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FLOTATION
FLOW BALANCING
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Primary treatment
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The flotable
substances are
removed by a surface
skimmer device
The settled sludge is
removed by
mechanical scrapers or
pumped.
Effluent from
preliminary processes
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The above may vary from hour to hour or from day to day. The flow rates may have
peaks several times the daily average and waste strength may vary accordingly.
Recycle streams can come from several sources and in hugely varying waste
strengths.
Septage for instance may have a BOD5 value 30 times greater than the municipal
raw wastewater.
Supernatants from anaerobic digestion processes or filtrate backwashings may also
be very high in waste strength.
As such, the performance of a primary clarification is not solely dependent on
influent flow variations. For instance, plants that may have been overdesigned for
flow may find that the retention time in the tank is not the 2 hours of the original
design but several times that.
Excessive retention time leads to septicity as there is no mixing in primary
sedimentation. It is also possible that where the operation and maintenance of
primary tanks is poor (i.e. Long retention times and infrequent sludge removals)
the quality of clarified water is no improvement on the influent wastewater.
However, with good performance management , removal rates of 50 to 70 percent
for suspended solids and 25 to 40 percent for BOD can be achieved. Figure shows
the
percentage
removal
rates
versus
surface
overflow
rates.
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Value
Range
Typical
1.5-2.5
2.0
30-50
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Peak flow
80-120
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Dimensions, m
Rectangular
Depth
3-4.9
4.3
Length
15-90
24-40
Width
3-24
4.9-9.8
Circular
Depth
3-4.9
4.3
Diameter
3.0-60
12-45
1/16-1/6
1/12
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Secondary treatment
Processes
Screens
Grit Settling
Scum Flotation
Primary Settling
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Stages (continued)
Secondary
Contaminants
BOD 90% Removed
TSS 90% Removed
Processes
Trickling Filter rotating disk
Activated Sludge Suspended and mixed
Oxidation ponds lagoons
(promote contact between microbes and contaminants)
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Secondary process
air
diffuser
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To tertiary
process
From primary
process
Aeration
and rapid
mixing
Settling
collects sludge
on bottom
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Introduction
The effluent from the primary treatment is rich on highly
biodegradable organic portion of solids. i.e. BOD, COD ratio is very
high.
To meet the minimum effluent standards for discharge, the organic
fraction of both suspended and dissolved, must be significantly
reduced.
This organic matter removal is referred to as secondary treatment.
It may consist of physico-chemical processes or biological processes.
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Quick Look
Based
On
Requirement
Micro organisms
Microorganisms
Secondary
Treatment
Biological
Processes
Important to
Know
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Microorganisms Contd:
Microorganisms Contd:
Heterotrophic organisms obtain energy for growth and
maintenance by breaking down an organic food supply
Autotrophic organisms are able to obtain energy
requirements either by:
Oxidising inorganic ions, or
By utilising sunlight
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Microorganisms Contd:
A source of energy
Carbon for synthesis of new cellular materials
Inorganic elements (nutrients) such as N, P, K, Mg and Ca.
Organic nutrients
O2 addition/exclusion
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Role of Microorganisms
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Bacterial Biochemistry
Metabolism
Catabolism
Anabolism
All the biochemical processes by which
the bacterium synthesizes new cells.
The synthesize process is driven by the
energy that was stored in the energy
carrier
Organic matter + O2
Stationary phase
Biomass
WW sewage
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Endogeneous phase
Lag phase
Concentration mg/L
Lag Phase
Log growth phase
Stationary phase
Endogenous phase
Bacteria
Batch
Reactor
Bacterial cells reproduce by binary fission; that is, cells divide into
segments that separate to become two new independent cells.
The regeneration time, or the time required for a cell to mature
and separate, depends on environmental factors and food supply.
Food
Time
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Stationary phase
Maximum growth cannot continue indefinitely. The food supply
may become limiting, environmental conditions may change.
Segment 3 of the curve, the stationery phase represents the time
during which the production of new cellular material is roughly
offset by death and endogenous respiration.
Endogenous phase
Although some reproduction continues beyond the stationary
phase, endogenous respiration and death predominate in segment 4
of the curve.
In this final phase, biomass slowly decreases, approaching
zero asymptotically after a very long time.
Now we are trying to put some equations for this growth curve.
There are several mathematical models to describe growth rate.
Based on Monods model
To describe the
behaviour of microbes
Logistic growth model
Lets go to the reactor.
t=0 , X=Xo , S=So
mg/l
mg/l
Micro organisms
present at that
time
Rate of
growth of
microbes
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.
+
Specific max
growth
rate
is independent on sub:
conn
Substrate concentration
= )(
When = max /2
S= 0
ks
S Substrate con:
Actually this is (BOD)
When
S=0
=0 No change in growth rate.
As sub
also
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Growth rate
of microbes
very high
S is >>>> compared to ks
constant
Microbial
concentration
Substrate
Constant (saturation concentration
substrate conn)
.
=
= .
In this X is changing
and also - specific growth rate
is also changing.
This Equation governs the growth of microbes & growth rate curve.
=0
=0
= 0 max
+ve
+ve
Case 2
With the food decreasing, i.e. when the food is
limited S is limited.
+ve
S <<< ks
Saturation constant
of substrate
Seg 2
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S&X
As S
.
+
.
.
+
kS
then X
so called dependant.
Varies
dependant variables
microbe utilize substrate and increase X & S
()
Varies
Constant
()
decreasing
Conn of microbes at t = t
Concentration of
microbes at t = t
0
=
0
Concentration of
substrate at t = 0
Concentration of
microbes at t = 0
Concentration of
substrate at t = t
Yobs The term yield (Y) when considering endogenous decay is called Yobs
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Anaerobic
Anoxic
Facultative
Biological treatment
occurs in the
presence of bound
O2
Suspended
Growth Process
Attached
Growth Process
Activated
sludge
processes
Trickling
filter
Aerated
Lagoon
Rotating
biological
contactors
M/O responsible for conversion of the M/O are attached to some inert
organic matter or other constituents in medium such as rocks, specially
WW to gasses and cell tissues are designed ceramics or plastic materials
maintained in suspension within the
liquid
Bio tower
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Clarifier
Influent
Clarifier
Effluent
Influent
Sludge
Effluent
Sludge
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Aeration Basin
Aeration system
Final sedimentation tank
Return activated sludge system
Waste activated sludge withdrawal system
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Qw, X
Qe, Xe, S
Q, X0, S0
Qr, Xr, S
(a)
Qe, Xe, S
Q, X0, S0
Qr, Xr, S
(b)
Qw, Xr
Figure : Schematic diagram of ASP (a) with wasting from the aeration tank and
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(b) with wasting from the sludge return line (recycle line)
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Endogenous respiration:
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Assumptions:
Contents of the reactor are completely mixed
Negligible M/Os present in the influent
Waste stabilization occurs only in the reactor by M/O
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= )(
units of time
) (
0 ) (
=
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Qe, Xe, S
Q, So, Xo
Qr, Xr , S
Qw, Xr, S
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) (
3
/=
3 ( 3 )
Qe
Note
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kg BOD / day
kg MLVSS
MLSS is simpler to measure than MLVSS and because the ratio of MLVSS
to MLSS tends to be relatively constant for a given system (75 80%) F/M is
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often expressed in terms of MLSS concentration
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Food-to-Microorganism Ratio
3
) (
3
/=
3 ( 3 )
/=
/ =
0 0
0 = (
3
0 = (
)
= . . ,
= ) (
3
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)
3
(
)
3
= )(
166
0 0
=
(/)
/=
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aeration basin
air or
oxygen
RAS
WAS
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Primary
Settling Tank
Activated Sludge
Aeration Basin
Diffusers
Screenings
Grit
Secondary
Settling Tank
Return Activated
Sludge (RAS)
Primary
Sludge
Air or Oxygen
Waste Activated Sludge (WAS)
Cl2
Tertiary
Filtration
(Optional)
wastewater flow
residuals flow
to
receiving
stream
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Primary effl.
RAS
plan view
to secondary clarifier
Example1
Example1 :Design a complete-mix ASP and secondary settling
facilities to treat 0.25 m3/s of settled WW with 250 mg/L of
BOD5. The effluent is to have 20 mg/L of BOD5 or less. Assume
that the temperature is 20 C and that the following conditions
are applicable:
Influent VSS to reactor are negligible.
Ratio of MLVSS to MLSS = 0.8.
Return sludge concentration = 10000 mg/L of SS.
MLVSS = = 3500 mg/L.
Design
= 10 d.
Hydraulic regime of reactor = complete mix.
Kinetic coefficients, Y = 0.65 lb cells/lb BOD5 utilized; kd = 0.06 d-1
It is estimated that the effluent will contain about 22 mg/L of biological
solids, of which 65 % is biodegradable.
BOD5 = 0.68 X BODL.
WW contains adequate nitrogen, phosphorus and other trace nutrients
for biological growth.
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= 10 d.
Hydraulic regime of reactor = complete mix.
Kinetic coefficients, Y = 0.65 lb cells/lb BOD5 utilized; kd = 0.06 d-1
It is estimated that the effluent will contain about 20 mg/L of biological
solids, of which 80 % is volatile and 65 % is biodegradable. Assume that
the biodegradable biological solids can be converted from ultimate BOD
demand to a BOD5 demand using the factor 0.68 ( e.g. BOD k value = 0.1
d-1, base 10).
Waste contains adequate nitrogen, phosphorus and other trace nutrients
for biological growth.
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Clarifier
Influent
Trickling filter
with rock
packing
Effluent
Recycle (optional)
Influent
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Clarifier
Effluent
Recycle (optional)
Sludge
Recycle
Sludge
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Operation:
Wastewater distributed
evenly over surface of
media.
Media acts surface on
which microorganisms
grow.
Organisms aerobically
decompose solids
producing more organisms
and stable wastes
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Settling tank
TF
Recirculation
of effluent
Anaerobic or endogenous
phase
Air space
CO2
Dissolved
organics
O2
Air
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Sloughing
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Design Guide
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Single pass
High rate
filtration
(plastic
media)
Up to 0.6
Up to 20
Sludge Yield
(kg/kg BOD)
0.4 0.6
0.8 1.0
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Bio Towers
Deep trickling filters.
Lightweight, modular media formed by welding corrugated and
flat polyvinyl chloride sheets together in alternating patterns
provide structural rigidity for vertical stacking without the
excessive weight that would result from stone or slag media.
Additionally, the porosity and regular shapes provided by this
medium overcome the head loss problem encountered in
randomly packed reactors.
Design of bio-towers is usually based on formulas developed for
trickling filters, with allowances made for medium
characteristics.
Formula proposed by Eckenfelder;
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Where:
Se = Effluent substrate concentration (mg/L)
Si = Influent substrate concentration (mg/L)
k = Treatability constant relating to the wastewater
and the medium characteristics, (min-1 )
D = Filter depth (m)
Q = Hydraulic loading rate (m3/m2.min)
n = Coefficient relating to the medium
characteristics(m)
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So far.............
Bio-tower
Primary clarifier
Pump
Influent
Secondary
clarifier
Effluent
Dosing tank
Alternate
Pump
recycle
Secondary
sludge
Effluent
recycle
Sludge
disposal
We know;
Organic matter Utilized by Microbes and
convert to CO2, H2O and remaining biomass.
So, in the aeration tank we get more biomass
or else solids getting convert to colloidal form
(i.e. Microbial cells).
Now we have to separate the solids.
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