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Observations:: Lab Report For Experiment #2: Purification of Acetanilide by Recrystallization

This lab report summarizes an experiment to purify acetanilide through recrystallization. Water was determined to be the best solvent. Impure acetanilide was dissolved in hot water and filtered to remove impurities. Upon cooling, white crystals formed which were collected via vacuum filtration. The recrystallized product had a narrower melting point range of 112-114°C compared to 105-111°C for the impure sample, indicating improved purity. Some acetanilide was lost during filtration steps. The maximum recoverable pure acetanilide was calculated to be 1.4073g but only 0.8575g was collected, with losses of 0.5498g likely occurring during

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113 views2 pages

Observations:: Lab Report For Experiment #2: Purification of Acetanilide by Recrystallization

This lab report summarizes an experiment to purify acetanilide through recrystallization. Water was determined to be the best solvent. Impure acetanilide was dissolved in hot water and filtered to remove impurities. Upon cooling, white crystals formed which were collected via vacuum filtration. The recrystallized product had a narrower melting point range of 112-114°C compared to 105-111°C for the impure sample, indicating improved purity. Some acetanilide was lost during filtration steps. The maximum recoverable pure acetanilide was calculated to be 1.4073g but only 0.8575g was collected, with losses of 0.5498g likely occurring during

Uploaded by

JV Gamo
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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LAB REPORT FOR EXPERIMENT #2: PURIFICATION OF

ACETANILIDE BY RECRYSTALLIZATION
Your name
Your Partners name

TAs name
Lab Section

OBSERVATIONS:
A. SELECTING A RECRYSTALLIZATION SOLVENT
Solubility Test (cold)
Solubility Test (hot)
Water
insoluble
soluble
pet ether insoluble
insoluble
ethanol
fairly soluble
readily soluble
acetone
very soluble
readily soluble
After looking at the solubility of impure acetanilide in
the four solvents, water seems to be the best choice as a
recrystallizing solvent.
B. DECOLORIZING A SOLUTION OF IMPURE ACETANILIDE AND HOT
FILTRATION
2. 1.5637 grams of impure acetanilide
5. 38 ml total solvent volume
7. Added tip of carbon black to mixture and mixture almost
boiled over!
8. 28 ml total solvent volume
C. ISOLATING THE RECRYSTALLIZED PRODUCT WITH VACUUM
FILTRATION
2. Chilled crystals in ice bath for 19 minutes.
collected flaky white crystals
Mass of watch glass and acetanilide = 22.5478
Mass of watch glass = 21.6903
Mass of recovered acetanilide = 0.8575 g
Mass of impure acetanilide = 1.5637 g
Percent recovered = 54.8 %
D. DETERMINING THE MELTING RANGE
Melting range of recrystallized acetanilide = 112 114 oC
Melting range of impure acetanilide = 105 111 oC

CONCLUSION:
In this experiment a technique was used that will be used
frequently throughout the semester: Purification by
recrystallization. This technique allows for the
purification of a crude material. The small loss in yield

is made up by the high gain in purity. The purity of the


material obtained can be correlated to the sharpness and
veracity of the melting point data and this was observed.

QUESTIONS:
1. Did recrystallization improve the purity of your
acetanilide? How can you tell?
Yes, the melting point range of the recrystallized
material was very narrow and was close to the literature
value.
2. Assume that your original sample of acetanilide was 90%
pure. What was the maximum amount of pure acetanilide
that you could recover after your recrystallization?
Mass of impure acetanilide = 1.5637 g
Mass of maximum amount of pure acetanilide = 1.5637 X 90%
= 1.4073 g
3. How much acetanilide did you lose during the entire
recrystallization process? Where did the losses probably
occur?
Mass of recovered acetanilide = 0.8575 g
Mass of lost acetanilide = 1.4073 - 0.8575 = 0.5498 g
1) In the hot filtration step, material crystallized in
filter paper.
2) In the second filtration step, material was lost on
filter paper
3) Material did not completely crystallize from solution

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