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NAN

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P LA S TIC S

ng{'n' FRaIE-l
C OR P G' R A TION

EpoxidizedSoybeanOil ESO- 132,ESO - 132D

Introduction
Physical& ChemicalProperties
Characters
Applications & Description in PVC Processing
Packing& Operation
MaterialSafetyData Sheet(MSDS)
Appendix l. JHPA CertihcateFor ESO - 132,ESO-I32D

Oil
Epoxidized
Soybean

ESO-132,aproductafter
oxidation
of soybean
oil ,
is widelyusedasnon-toxic
in
stabilizer
andplasticizer
PVCprocessing.
Theproductiontechnology
is basedonthecooperation
betweenNanYaandNippon
Sanwa
Gosei.

ESO-132D(Deodorized
Epoxidized
Oil),
Soybean
m a d e oE
f SO-132bya
seriesof deodorization
purifications
is produced
to
meetthespecial
requests
in
someapplications.

ChemicalName

EooxidizedSovbean
Oil

I{,C - O - C - C -(CHr)x - CH - CH - R
|
\//

Hl - o - c - c -(cH,)x- cH- cH- R'

IlC- O- C- C- ( CH,) x- CH

_CH

o
MolecularWeisht
MeltedPoint
Boiling Point

> 150i5mmHg

3r5.6
t
SpecificGravity

( 25'C)
0.982- 1.002

400a 50 cps( 25t )

Weight Loss after Heating

RefractiveIndex
Color Number

OxiraneOxygen
Iodine Value

+ 0.002
( 2st )
t.470
200(APHA)I

6.4-6.8o/o

l. Non-toxic
Besides
theapprovalfromJHPA,PL specification
B.7,item I (ApprovalNo. J-7885),alsomeetstrict
FDArequirement,
( 181.27and175.300).
according
to thestipulations
onFoodAdditives
with stabilizers.
ESO- 132andESO- 132D canbeusedin association
For example,
thecombination
with ESO,is in non-toxicapplications.
betweenBa-ZnandCa-Znseriesstabilizers
Thisnon-toxic
combination
will bethemainstream
in PVCprocessing.

2. Heat stability and Weather - resistance

Thesynergistic
effectcanbeexpected
in caseofthe combination
with metalseriesstabilizers.
Thanks
to thecapabilityofthe activeepoxyringto catchHCI andits antioxidation
effectagainstdegradation.
After heatingandlight exposure,
thecross-linking
amongPVCmolecules
canbeminimized.
Namely,thebig-scale
enhancement
in bothheatstabilityandweatherresistance
for PVCproducts
can
beexoected.

3. Low volatility and High molecule plasticizer

Muchlowerin volatilitythanDOP(about20%of DOP),it providesbetterstabilityin PVCflexibility.
With aboutM.W. 1000,ESO- 132canberegarded
asa goodplasticizerin PVCprocessing.

4. Low I.V., Good in non-migrationresistanceand extractionresistance

Low I.V., goodcompatibilitywith PVCPlasticizers,
it thereforeprovidesgoodperformance
in nonmigrationandextractionresistance.

5. Water - resistance,Oil - resistanceand Low loss in transparency.

Applications
/ Formulas

Description

PVCLeather'.
fllm.

. Betterhcat-r'csislancc
in conrbinrtiourr ith nletrl stiibilizcrs.

Coating
and

a Irrpro\ ing transfatcnc)'.

Ertmsion

e Suguestcd
dosagc0.5 - 1.0 PHR.

o I'rrpcrlr tblrrLrlatirgrr ith DO.\ or DINA. uscdas anti-

Filnrsfbl packing

l l r' .zi r ,' l rl .r' ti z, ' i r P \ ( |, ' | | |I tIIi || i\ ' | .

rl osaucl (1.(l- 10.0 P H R .
o S rrggestctl

\\ i l h B l -Zn. Ca- Zn slabilizcr s.

r A ppl i crbl ci n combi nati on

\on-toric

closage
o Suggesteci
o P V C Lel ther.tl l nr: l .(l l .(l P H R .
oToys ancll nj ecti onproducts:.1.(l- 5.0 PHR.
sLrchls to]-s.
r Good to bc lpplicd in non toric PfodLlct\gl o\ c etc.
\\ith
r (irxxlrrc(ingto colorpurrtlcr.
1ocnhance
conrl)alibilil!

Toncr&
\'iastcrbatch

I' \' ( poi rtl crl l i cr bl cndi ngu i th D OP .D I \ P andDI DP.

r i scosi tvati cr mir ing $ it h
o R cduci ngconrpouncl i n{
i nol guni cpi gnrcnts.
dosl gc:-i .0 6.0 I' l l R .
r S uggcstccl
o A ppl i crbl eto i i orki ng l i th B r Zn sel i esst abilizels.

Anti-weathel'

&

dosrge:1.0 1.0 P I IR .
r S Lrggcsl ed
o Widclv uscdas cor clrgc lilnr in ugricullureand cxterior
hydrolvsis-rcsisliinc.
clolh.

ri i th stabi l i zcls.
t o r nakeLr p
o ,\ppl i cabl ei n corrbi nati on

Fire-retuldation

thc stabilitvin illc leturilrtiontirr Sb,O,anclAlrO,.

. S uggcsl cd
dosagc:1.0 - -s.0P l l R .

non nrigntiol.
r In pairt ith poli"estef-tllephsticizeNto enhance

Non-nrisration

o Suggcstcd
tlosagexccordingto diftcfentprodrrcts:
o N on-ni grati oncabl eanclri i re : 5.0 - I0. 0 PHR.
eGasketofl ei i i gel ator:aboutl 0 P H R .

r ,\pplicablcin pair tr ith TOT1\'1

so ils 1ocnhrncciinli-

.,\nti- fbgging

firi.rrintpr.oducts.
rl ,r.:r:t-.:
i tt. 0 { l P H R
o \Lr' -r.:c.tcJ
o \V i l dl l ' appl i cdi n crr prncl products.

r Couplingu'ith polyesterk) \\'orkrs a plasticizcrtbr

Low cxtractior'l
tbrrnLrlas

solr.entand oil resistanttbrmLrlas.

dosage:3.0 5.0 P H R .
. S uggested
o W i l dl v uscdi n l l exi bl etubcs.

Packing and Notices

In use
l. Fol I'\'( lcrth!'r.lllnr...clc.
rhcsLLtgcstcd
dosage
no nr()fclllrn 1.0 pHR. if
crceedcd.beinulpr ro blcedin-r:.
L Iior I'\ ( packinrlilrl. lhc rnarinrunr
doslgcshouldbc belorr20.0pHR . Il.
erccctlecl
. bc culclirlrvithbleeding.

,F
a

. lhe nlrxintunr
-1.\\'hcnprintinuis rcclrrcstcd
dosaqe
shouldbc belos j.0
Pllll . ii'crcccdcd.thc\cak cohc'sion
bclrlccnprintinuink andpVC
pr odlr c ls l' nt \ e n t e f g c .

-1.Withconsicleration
ol thc poorinitialcolor.top\rC.in tcr.nts
ol'those
rupplicalions
tbalinitialcolor.arc
esscntill. theESOtlosauc
is totall1,.
depcndcnt
on thedosllcol'stabilizer..
Thesugsested
dosasc
is 1.0_j.0 pHR.
5. 1.0PIIRdosasc'
\\ ill brinsrh!'soii pointof'I,\rCclorvn
aboLrt
2 'C
l:spcciullv.
fbl rigidP\it applications
. thc closage
shoultlbc Lrncler
propcr.
controL

Storage and Transportation

l. ESOshouldbepropcrlvsloredat th!'lcrnpcrrture
bclou.-15
C. Ifcxceeded.
polvmcrization
u ill rakeplace
L Contilnlinrtion
flom lLrstandsand...elc
will leadto thc polvnrerization.
It
is suggcsted
to pu1nrctillscreen
(28 mcshmin.)in therentsof arrsroragc
tanks.Thelegularclcaninrr
of thentctalscreen
shouldbc clonc.
.C.
,C.
theriscositlof EsO sour.s
up. IflorierthanI5
it is in thc
paslclirm (likelarul).
Il is eas),togct hardin pipetranspoftation.
Heatinsit

i. Bclorr10
up to.l5 t

nta\.cancaseoffthe problcm.

Safety
L Sk i n c o n ta c tr ral carrsei rri tati on.cspcci al l yto thosc skj n-l l l crgi c peopl c.
l l c o n l i tc te dr. rashol l ' contuni nati on\\' i th soupand \\,rter.scck ntedi cal
l l l c n ti o n i f i tr i tati rrnpcrsi srs.

L l l ' c v c c o n ti rcteciri.nsc l i rl l 5 nti nutcsrni ni nruntsi th a gcntl c w ater strei l nt .

o b l l i n n rc d i c alattenl i oni fthe syntptonl spcrsi st.

,/

Packing
L Loldcdin 53-gallon
iror dr.um.
200ku ncrpcrdrum.
2. ISOtankavailable.
llMT persetor according
contnct.

L lvlanufacturer/
Manufacturer
/ SupplierName: HP Plant, Plastics4th Division, NanYa PlasticsCorporation

Taiwan,
Manufacturer
/ SupplierAddress
: 20l,TungHwaN. Rd.,Taipei,
R.O.C.
Consultants
NameandPhoneNo. :

(02) 2712221|
ext.

Emergency
Contact
Phone
No.: (02) 27122211
ext.

FaxNo.:(02) 27178530

ProductName: EooxidizedSovbeanOil

Short-term
Exposure
Limit
(STEL)

Appearance
: Clearliquid

VaporPressure
: NA
-Er--

Specific
Cnvity(tlo:

Evaporation
Rate(Ethyl
Acetate:l) :NA

l) :0.982
- 1.002

Solubility
in Water
: 0.01% ( 20t )

FlashPoint: 600" F

LowerExplosion
Limit( LEL) : No data

(v) Opencup( ) Closedcup

TestMethod:

UpperExplosionLimit ( UEL) : No data

Fire FightingAgent: Dry chemical. alcoholfoamor carbondioxide.

Special
FireFightingProcedures
: None

Conditionsto Avoid :
Hazardous
Decomposition
:

Materialsto Avoid : Stroneacidanddust.

( v ) Inhalation( v) Skincontact ( v) Ingestion (v ) Eyescontact

Skin contactmay causeirritation of the skin.

Eyescontactwill causeirritation of eyes.

Emergency
Response
&
FirstAid Measures

Inhalation: l. Removeto freshair.

2. Ifbreathingis difficult , ensureairwayis clearandgiveoxygen.
(CPR).
Ifnot breathing, instituteCardiopulmonary
Resuscitation
personwarmandatrest.Getimmediate
3. Keepaffected
medicalattention.
washwithplentyof soapandwaterwhileremoving
Skincontact
: Irnmediately
contaminated
clothing.
Eyescontact: l. Flushimmediately
withplenfyofwaterfor atleast15minutes.
Eyelidsshouldbeheldawayfromtheeyeballto ensure
thorough
rinsing.
2. Getimmediate
medical
attention.
Ingestion: I . If afiectedpenonawake,rinsehis(her)mouth.
2. Letdrinkplentyofwarmwateror milk,andtheninducevomiting.
3. Getimmediate
medicalattention.

7. Measures
to PreventExposure
E1-r"'s
: \\iearchenticllsulctvgogglcs.

Pcrssnlrl
Pfotcclivc
['-cluipntcnt

(i]or es : Use rLrtrbcr

slor cs ol chenriculplolcclirc lloves.

V c nt illt ion

E q u i pr,e n ti l a ticr c c l L l i l n' rcnl

or l rci l i tr. K ccp l i r l i csh.

lllndlinq &
Slorasc
Prccattlions

Shouldbe stotedundcr-{5C.

in closccicontaincrlirr slolagcrLntillaunder.cd
ll clL,thrr.-:
I . Placccontaninilted
clothin_l
oI dirclrrrlcLl.
tir '
is to be laundcrad
. inlirlrnpclsonpcllil rninuopcralionof contaminanl
s hrz;rrdorrs
l'rr,rper
P c r s onal
||y - ! r c nc

l . D o n o t c rt . d l i n k . s n ro ke.l nclcurl r' l rshteli n rol ki ng arcas.

J. After handling. washhandsthoroughl\.
,1.Kccp the rl'orkingatcrtsclcan.

8. Respone
to Spill andWasteDisposal
I--nrc'rgcncl
I lc s lt onct o Sl ti l l s

urcusi i i th ti n sund. cafi hor cl outto bui l d tenrpol ul vt likc:

I . Is o l a tcth c c o n ti l rl i nuted
cnlirlgc.
in cast'ol'lc'akruc
l . L .s c ' c l o Ll rt
o i rb sol bspi l l or rrsc.i nri l urnrcl hrxll o l fei rt N n(lthcni rrci nc| l tcthecLr Lr lr
-1.C lcan ii itlt sorp and \ llcf.

\ \ ' ir s t cDi: pu .l l
ML-thods

l n c i n e rr rr.'

Information
9. Transportation
Hazard
('lassillcltion

Llnilc d Nati o n
NLr nr bc r ' ( l.l N .N o )

Il azard l abcl s

I:l .tl t t t lr t ble

l .i q uid

10.Informationof MSDSheparation
\anre : \ul Yu Plltstics( orporation
( ) r ' ganiz r t i o n
t hat f r c lar e d

Il drrstl i i rll ' i rl k \o. I . \l ai l i ro. \i Ln]i nC ountr.Tl i rran . Il .O.( .

.\d d re s s: F o rn ro sn

I hC \ { S D S
5
T e l e p h o n :c(0 5) 68l l -.1-+c\1.
Pclsnnr hu
pr.p,u.ri,f',. niSOS
Dalc t hc M S D S
\\ls prcpaleo

lob Titlc : Safiy anclSanit tior Munrgcr

D a v :0 .1

l \l o n th:.l unc

Y cur' : 1999

Nanrc: Su Yu-lVling

l l r!:l

(FOI{!I

3,

lNtr".
1l -- 2)l

' Fr[ l 1

l 5R

)irv t'.Liititr', 2.\42

'+

fi 6 e*E*+ (; Ff 6 E +*Ei*
EIt c = )v#lEE#A

=aB
=r

EE
E

HtrSryI
HfltiiE,,EilFl
{t i"}fsiftlit
t-, .J< rF

trt.ru
tr:v

HCCffi
=L

LS O- 132

Fq

tfiffia
(ffifi8)

+*tl
q ,([H i l

ilSO-1:J2D

HiTt r E

7 BB5

Aftn'r+li | | + 2 ,Hr o El{,tJif l'Ll:l:;ld,F;=iil:t't')c7"+t;EE

fi + rFIt * 6i;* + a rr"1Y.u = )vijl B?H f: iAE7":r
E f,.1:|: iHi u fr i*Et6
,=il
(Jllp+n
tf ) i: i-iit L -aL'.7r; u-:a(ft.if.l-:: I: il:rlEi4.

al

t't
P rint e d o n N a n Y a P P S yn th e tic Pa p e r .
Pleasedo not mix wilh other 9ene6l paperrecycle.
(1999 . 0 9 . 1 0 0 0 )

ffi H lE flgr # Hlfi

NAN

YA

P LA S TIC S

[Rr*=l

C OR P OR ATI O N

R.OC.
TAIPEI,
TAIWAN,
201,TUNHWAN. ROAD.
TEL:(O2\2712-2211