IMPORTANT INSTRUCTIONS:

There are three parts in the question paper A, B, C consisting of Physics,

Maths and Chemistry having 30 questions in each part of equal weightage.
Each question is allotted 4 (four) marks for each correct response.

Candidates will be awarded marks as stated above in instruction for correct

response of each question. 1/4 (one fourth) marks will be deducted for

indicating incorrect response of each question. No deduction from the total

score will be made if no response is indicated for an item in the answer
sheet.

There is only one correct response for each question. Filling up more than
one response in each question will be treated as wrong response and marks

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.i

for wrong response will be deducted accordingly as per instruction

In a cylindrical region of radius R, a time varying magnetic field B kt exists as

shown in the figure k 0 . A charged particle having charge q located at a distance d
from centre of cylinder is situated at P. This charged particle is taken slowly form P to
via the path shown in the figure, with the help of an external agent. The work done
by this force (external agent) during the process, is

ww
w

.s
t

ud

1.

ys

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PHYSICS

q R2k
a)
4

2.

q R d k
b)
2

P
q

q R3k
c)
2d

d) zero

For a process on a system (gas enclosed in a vessel), the p V graph is shown in the
figure. For this process three statements are given as:

pV constant

3.

I. During the process, work done by the system is continuously increasing.

II. During the process, work done by the system is zero.
III. During the process, internal energy of the gas is continuously increasing.
IV. During the process, heat supplied to the system is continuously increasing.
a) all the four statements are correct
b) only I and IV are correct
c) only II and IV are correct
d) no statement is correct
The displacement x of a particle as a function of time t is shown in the figure. The
figure indicates:

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ps

.i

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a) the particle starts with a certain velocity, but the motion is retarded, and finally the

.s
t

particle stops

b) the velocity of the particle is constant throughout

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w

c) the acceleration of the particle is constant throughout

d) the particle starts with certain velocity and then its motion is uniformly accelerated
4.

From a conducting ring of radius R which carries a charge Q (uniformly distributed)

along it periphery a small length dl is cut-off. The electric field at the centre due to the
remaining wire is
a)

5.

Q dl
8 2 0 R 3

b)

Q
4 0 R 2

c) zero

d) cannot be determined

The charge on two plates of a parallel plate capacitor of capacitance C are 3Q and Q,
respectively. The potential of the capacitor is [None of the plates of capacitor is
grounded].
a)

Q
C

b)

3Q
C

c)

4Q
C

d)

2Q
C

6.

In the circuit shown in the figure, the charges on capacitors C1 and C2 are respectively
[In steady state].
R

C2

C1

E1

7.

E2

a) C1 E1 and C2 E1 E2

b) C1 E1 and C2 E2

c) C1 E1 and C2 E1 E2

d) C1 E1 and C2 E1

C2 E12
E2

A battery of emf E and negligible internal resistance is connected to a resistor R.

Taking the heating effect of current and its further effects on circuit into the

.i

considerations, indicate which of the plots shown in figure best represents the rate of

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production of thermal energy in the resistor.

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P
A

ys

8.

b) B

c) C

d) D

ww
w

a) A

.s
t

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A transparent sphere has its right half of the curved surface polished so that it acts as a
mirror. A paraxial light ray is incident from the left and emerges as shown in the
figure. The refractive index of the material of cylinder is:

9.

a) 1.5
b) 1.7
c) 2.0
d) 2.3
A solid cylinder is performing pure rolling motion on a moving platform as shown.
Which of the relation between, v0 , , R and v is correct?

v0

a) v0 R
10.

b) v v0 R

c) v v0 R

d) v v0

In steady state find the current through branch containing inductor and voltage across
capacitor.
R

2R

a)
11.

E
E
amp, volt
2R
2

b)

2R

E
E
amp, volt
9R
2

c)

E
E
amp, volt
3R
4

d)

E
E
amp, volt
9R
4

A doubly ionized Li 2 ion in ground state absorbs 91.8 eV of energy. The increase in
b) 0.53 1033 J s

c) 1.05 1034 J s

d) cannot be computed

ps

.i

a) 2.111034 J s

A sound source of frequency f sends waves of wavelength with speed v in some

te

12.

angular momentum of electron is [h 6.63 1034 J s] .

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medium. If the frequency is changed from f to 2 f , then the new wavelength and the

13.

b)

and 2v
2

c)

and v
2

d)

v
and
4
2

.s
t

a) and v

ud

wave speed are respectively,

A stationary source generates 5.0 Hz water waves whose speed is 2 m/s. A boat is

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approaching the source at 10 m/s. The frequency of these waves as observed by a

person on the boat, is (assume Doppler Effect is valid)
a) 5 Hz
14.

b) 10 Hz

c) 20 Hz

d) 30 Hz

A stationary body of mass m is slowly lowered onto a massive platform of mass

M m moving at a speed 4 m/s as shown in the figure. How far the body slides

along the platform? [Take 0.2 and g 10m / s 2 ].

0.2
m
Smooth

a) 8 m

b) 12 m

v0 4 m / s
M

c) 6 m

d) 4 m

15.

The potential energy of a particle of mass 5 kg moving in the x-y plane is given by
U 7 x 24 y J ; x and y being measured in metre. If the particle starts from origin

from rest, the magnitude of the conservative force acting on the particle is:
a) 25 units
16.

b) 24 units

c) 7 units

d) 84 units

A solid sphere of radius R is resting on a smooth horizontal surface. A constant force

F is applied at a height h from the bottom. Choose the correct alternative.

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c) sphere will roll without slipping if h 1.4 R .

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d) sphere never be set into pure rolling

Two particles of masses m and M are initially at rest and infinitely separated from each

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17.

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b) sphere will roll without slipping if h 0.4 R .

a) sphere will always slide whatever be the value of h.

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other. Due to mutual interaction (gravitational) they approach each other. Their
relative velocity of approach when they are at a distance d, is:

18.

b)

2G M m
d

.s
t

2Gd
M m

c)

2GMm
M m d

d)

2Gm
d

ww
w

a)

A point of mass m 20 kg is suspended by a massless spring of spring constant

k 2000 N / m . The point mass is released from rest at t 0 when elongation in the

spring is 15 cm. The equation of displacement of particle from its mean position as a
function of time is given by: [Take g 10 m / s 2 and downward direction as + ve].
(Assume Hookes law to be valid).


a) y 10 cm sin 10t

b) y 5 cm sin 10t

c) y 5 cm sin 10t

d) y 5 cm sin 10t

19.

The length of an elastic string is a metre when the tension in it is 4 N and b metres
when the tension in it is 5 N. The length of string in metres when the tension in the
string is 9 N, is
a) a b

20.

b) 5b 4a

c) 4a 5b

d) 9b 5a

Two particles A and B are moving uniformly around concentric circular paths of radii
rA and rB . If both the particles complete one rotation in the same time, then:

a) the ratio of their angular velocity is 1

rA
rB

.i

b) the ratio of linear velocity is

rA
rB

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c) the ratio of the force required for their motion may not be
d) all of the above
For CE configuration of a transistor,

22.

a) input resistance is very small while output resistance is very high

b) input resistance is very large while output resistance is very small
c) both input and output resistances are very small
d) both input and output resistances are very large
A small mirror of area A and mass m is suspended by means of light thread, in vertical

ww
w

.s
t

ud

ys

21.

plane. On the mirror, a beam of light of intensity I, is made to be incident

perpendicular to mirror, due to which mirror is displaced and thread makes a small
angle with the vertical. Assuming mirror to be totally reflecting, the value of is
[ c speed of light, a is in radians].
a)
23.

2IA
cmg

b)

IA
cmg

c)

3IA
cmg

d)

IA
2cmg

A piece of ice is floating in water. The fraction of volume of the piece of ice outside
the water is [ ice 900 kg / m3 and water 1000 kg / m3 ].
a) 0.21

24.

b) 0.01

c) 0.1

d) 0.9

a 3b 2
Some physical quantities, a, b, c, x are related as x
if the % error in a, b, c are
c
2% , 1% and 4% respectively, then % age error in x is

a) 8%
25.

b) 12%

c) 4%

d) 10%

Density of a liquid varies with depth as h . A small ball of density 0 is released

from the surface of the liquid. Then( a is A positive constant)
a) the ball will execute simple harmonic motion of amplitude

0
from the free surface
2

b) the mean position of the ball will be at a depth

c) the ball will sink to a maximum depth of

d) all of the above

26.

The time taken by a transverse pulse to travel full length of a uniform rope of mass 0.1

c) 2 s

d) 1.5 s

Two point white dots are 1 mm apart on a black paper. They are viewed by eye of

ps

27.

b) 0.5 s

.i

a) 1 s

kg and length 2.45 m hanging from the ceiling, is

pupil diameter 3mm. Approximately, what is the maximum distance at which these

c) 7 m

d) 3 m

Which of the following statement leads us to identify the p-side of p-n junction

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28.

b) 1 m

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a) 5 m

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dots can be resolved by the eye? [Wavelength of light = 500 nm].

.s
t

diode?(Beep is indication of flow of current)

a) when positive lead of multimeter is connected to one leg of diode and negative lead

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of multimeter to other leg, then a beep is obtained

b) when p-side of diode is connected to negative lead of multimeter and n-side to
positive lead, then a beep is obtained
c) when one leg of diode is connected to ve lead of multimeter and other leg to +ve
lead, then no beep is obtained
d) both (a) and (c)
29.

To identify whether a p-n-p transistor is working or not, using multimeter, which

statement serves the purpose?
a) the common lead of multimeter is connected to base and other lead to first emitter
and then to collector, only 1st connection shows the continuity
b) the common lead of multimeter is connected to base and other lead to first emitter
and then to collector, both the connections shows the continuity

c) the common lead of multimeter is connected to base and other lead to first emitter
and then to collector, none of the connection shows the continuity
d) all of the above
30.

In measurement of mass of a given object by the principle of moments, the meter scale
is hung from its mid-point. A known weight of mass 2 kg is hung at one end of metre
scale and unknown weight of mass m kg is hung and 20 cm from the centre on other
side. The value of m is
a) 2 kg
b) 5 kg
c) 2.5 kg
d) 0.8 kg

MATHEMATICS
31.

If p1 , p2 , p3 denote the distance of the plane 2 x 3 y 4 z 2 0 from the planes

2 x 3 y 4 z 6 0 , 4 x 6 y 8 z 3 0 and 2 x 3 y 4 z 6 0 respectively, then

a) p1 8 p2 p3 0 b) p32 16 p22

A ray of light incident at the point 2, 1 gets reflected from the tangent at 0, 1 to

.i

32.

d) p1 2 p2 3 p3 29

c) 8 p22 p12

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the circle x 2 y 2 1 . The reflected ray touches the circle. The equation of the line

33.

b) 4 x 3 y 11 0

c) 3x 4 y 11 0

d) 3x 4 y 11 0

ys

a) 4 x 3 y 11 0

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along which the incident ray moved is

In a shop there are five types of ice-creams (each type is available unlimited).A child

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buys six ice-creams.

.s
t

Statement-1: The number of different ways the child can buy the six ice-creams is 10 C5 .
Statement-2: The number of different ways the child can buy the six ice-creams is

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equal to the number of different ways of arranging 6 As and 4 Bs in a row.

a) Statement 1 is true, Statement 2 is true; Statement 2 is not a correct explanation for
Statement1.
b) Statement 1 is true, Staement2 is false.
c) Statement 1 is false, Statement 2 is true.
d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for
Statement 1.
34.

The mean deviation of items x, x y, x 2 y.................., x 2ny from mean (y > 0) is

a)

n n 1 y
2n 1

b)

n 1 y
2n 1

c)

ny
2n 1

d)

2n 1 y
n n 1

35.

If PQ is a double ordinate of the hyperbola

x2 y 2

1 such that OPQ is an equilateral

a 2 b2

triangle, O being the center of hyperbola. Then the eccentricity e of the hyperbola
satisfies.
a) 1 e 2 3
36.

b) e

3
3

c) e

3
2

d) e

2
3

Let a i j k ; b i j k and c be a unit vector perpendicular to a and coplanar with

a and b , then c is

a)
37.

1
j k

b)

1
j k

c)

1
i 2 j k

d)

1
2 i j k

Out of 3n consecutive natural numbers, 3 natural numbers are chosen at random with

3x 4

3n 2

2 3n 1 3n 2

f x dx is

3x 4
c
3x 4

8
3

3n

3n 2

3n 1 3n 2

d)

n 3n 1 3n 2
3 n 1

8
3

4
3

8
3

2
3

b) log 1 x x c

2
3

.s
t

c) log 1 x x c

d) log 1 x x c

Let A be a 2 2 matrix with real entries. Let I be the 2 2 identity matrix. Denote by

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39.

c)

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If f
x 2 , then
3x 4

a) e x 2 log

.i

3n

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b)

ud

38.

n 3n 2 3n 2

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a)

replacement. The probability that the sum of the chosen numbers is divisible by 3 is

tr A , the sum of principal diagonal entries of A . Assume that A2 I .

Statement-1: If A I and A I , then det A 1 .

Statement-2: If A I and A I , then tr A 0 .
a) Statement 1 is true, Statement 2 is true; Statement 2 is not a correct explanation for
Statement1.
b) Statement 1 is true, Staement2 is false.
c) Statement 1 is false, Statement 2 is true.
d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for
Statement 1.
40.

2
Statement -1: If A 5
0

0
1
1

1
0 then adj adjA A
3

Statement-2: If A is a non-singular matrix of order n then adj adjA A

n 1

a) Statement 1 is true, Statement 2 is true; Statement 2 is not a correct explanation for

Statement1.
b) Statement 1 is true, Staement2 is false.
c) Statement 1 is false, Statement 2 is true.
d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for
Statement 1.
41.

Statement-1: An equation of a common tangent to the parabola y 2 16 3x and the ellipse

2 x 2 y 2 4 is y 2 x 2 3
4 3
, m 0 is a common tangent to the parabola
m

Statement-2: If the line y mx

.i

y 2 16 3 x and the ellipse 2 x 2 y 2 4 , then m satisfies m 4 2m 2 24 .

ps

a) Statement 1 is true, Statement 2 is true; Statement 2 is not a correct explanation for

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Statement1.
b) Statement 1 is true, Staement2 is false.

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c) Statement 1 is false, Statement 2 is true.

Statement-1:

r 1

Cr n 2 2n 1 .

Cr x r 1 x nx 1 x

r 0

r 1
r 0

n 1

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w

Statement-2:

.s
t

42.

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d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for Statement 1.

a) Statement 1 is true, Statement 2 is true; Statement 2 is not a correct explanation for

Statement1.
b) Statement 1 is true, Staement2 is false.
c) Statement 1 is false, Statement 2 is true.
d) Statement 1 is true, Statement 2 is true, Statement 2 is a correct explanation for
Statement 1
43.

The equation sin x 1 0 has one root in interval

a) 0,
2

44.

b) , 0
2

3
c) ,

One of the solution of differential equation

dy
y
is

dx y sin y x

d) ,

45.

a) y x cos y 2008 sin y

b) y x cos y 2008 sin y

c) x 2 sin 2 y 420

d) y ( x 2 cos y ) 20 sin y

The sums of first n terms of two A.P.s are in the ratio 3n 8 : 7n 15 .The ratio of
their 12th terms is
4
9

a)
46.

b)

7
16

c)

3
7

d)

16
7

A person is permitted to select at least one and at most n coins from a collection of
2n 1 (distinct) coins. If the total number of ways in which he can select coins is 255,

then n equals
a) 4

In a ABC , if 1

a 0 , then sin 2 A Sin 2 B sin 2 C is equal to

c

b)

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9
4

ps

4
9

c) 1

d) 3 3

.s
t

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Let f x x 1 x 2 x 3 .... x 100 and g x f x . f x f x , then g x 0 ,

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a) no solution
c) exactly two solutions
f x be

If
x

b) exactly one solution

d) minimum three solutions

a continuous function for all real values of x and satisfies

8

x2
f t dt t 2 f t dt , then
2 x

5
a) ln

b)

51.

d) p q

has

50.

.i

c) p q

b) p q
1

a)
49.

d) 32

q is
The statement p q

a) p q
48.

c) 16

ys

47.

b) 8

f x dx is equal to

1/ 2

1 8
ln
2 5

8
c) 2 ln
5

d)

1 5
ln
2 8

i 2 sin j k are coplanar is

a) 0
52.

The number of distinct real values of for which the vectors 3 i k , i 3 j and

b) 1

c) 2

The maximum value of z satisfying the equation

a) 2

b) 3

c) 4

d) 3
1
1 2
2
z z 1 z is:
12
3

d) 6

The shortest distance between the lines

a) 1/ 6

55.

d) 1/ 3

, then domain and range of f x are respectively given by:

a) 2,1 , 1,1

b) , 2 1, , 0,1

c) 0,1 , 1,1

d) , 2 1, , 0,1

1 sin x cos x log 1 x

equals:
x 0
x3

lim

b) -1/2

c) 0

d) 1

All the points on the curve y x sin x at which the tangent is parallel to x-axis lie on a/an:

a) straight line

b) circle

c) parabola

d) ellipse

Two fair dice are rolled simultaneously. It is found that one of them shows odd prime

ps

57.

4 x2
1 x

If f x sin log e

a) 1/2
56.

c) 1/ 3

b) 1/ 6

54.

x 1 y 2 z 3
x2 y 4 z 5
and
is:

2
3
4
3
4
5

.i

53

a) 1/5

b) 2/5

c) 3/5

d) 4/5

An investigator interviewed 100 students to determine their preferences for the three drinks,

ys

58.

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number. The probability that remaining die also shows an odd prime number, is equal to:

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Milk (M), Coffee (C) and Tea (T). He reported the following:

.s
t

n M C T 10 , n M C 20 , n C T 30, n M T 25, n (only C) = 5,

n (only T) = 8.Assuming that every student consumes atleast one of the above mentioned

59.

1) n M 47

2) n C 45

3) n T 53

4) n M C T 20

a) 1

b) 2

c) 3

d) 4

Area of the region bounded by the curves y x log x and y 2 x x 2 is:

a) 1/2

60.

ww
w

drinks the number of correct statements from the following is:

b) 7/12

c) 5/12

d) 13/12

If y 2 x tan 1 x log x 1 x 2 ,then:

a) y increases in [0, )

b) y decreases in [0, )

c) y increases in , 0

d) y increases in ,

CHEMISTRY

61.

Lemon juice normally has a pH of 2. If all the acid in the lemon juice is citric acid and
there are no citrate salts present, then what will be the citric acid(H.cit) concentration
in the lemon juice? (Assume that only the first hydrogen of citric acid is important).

H .Cit H

Cit .K a1 8.4 104 mol lit 1

a) 8.4 104 M
62.

b) 4.2 104 M

c) 16.8 104 M

d) 12.0 102 M

One mole of an anhydrous salt AB dissolves in excess of water with the evolution of
21.0 J mol-1 of heat. If the heat of hydration of AB is -29.4 J mol-1, then the heat of
dissolution of the hydrated salt AB is
a) 50.4 J mol-1

63.

b) 8.4 J mol-1

c) -50.4 J mol-1

d) -8.4 J mol-1

The number of isomers of [Co (NH3)3 Cl3] complex and secondary valency of the
c) 2 & 6

CO2 H

CH 2OH

ys

II

d) 3 & 6

OH

III

SO3 H

IV

b) IV < I < II < III

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a) I < III < II < IV

d) II < IV < III < I

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t

c) III < I < II < IV

65.

ps

The order of acidity of compounds I-IV, is-

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64.

b) 2 & 3

.i

a) 3 & 3

metal ion in the complex respectively are.

A concentrated solution of copper sulphate, which is dark blue in colour, is mixed at

this process-

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w

room temperature with a dilute solution of copper sulphate, which is light blue. For

a) Entropy change is positive, but enthalpy change is negative

b) Entropy and enthalpy changes are both positive
c) Entropy change is positive and enthalpy does not change
d) Entropy change is negative and enthalpy change is positive
66.

67.

Increasing the temperature increases the rate of reaction but does not increase thea) number of collisions

b) activation energy

c) number of fruitful collisions

d) average velocity of the reactant molecules

From equations 1 and 2,

1
2

1). CO2( g ) CO( g ) O2( g ) K1 9.11012 at 10000 C ;

1
2

2). H 2O(l ) H 2( g ) O2( g ) K 2 7.11012 at 10000 C

The equilibrium constant for the reaction CO2( g ) H 2( g ) CO( g ) H 2O(l ) at the same
temperature, is
a) 0.78
68.

b) 2.0

c) 16.2

d) 1.28

Consider the reaction: 2 NO2 g 2 NO g O2 g , In the figure below, identify the

curves X, Y and Z associated with the three species in the reaction

.i

ps

te

Time

ys

a) X = NO, Y = O2, Z = NO2

b) X = O2, Y = NO, Z = NO2

d) X = O2, Y = NO2, Z = NO

ud

c) X = NO2, Y = NO, Z = O2

Two isomeric compounds I and II are heated with HBr

.s
t

69.

Concentration

OH

CH 2OH

ww
w

OH

II

OCH 3

The products obtained are

OH

Br

OH

a)

Br

b)
OH

CH 2 Br

CH 2OH

OCH 3

OH

Br

OH

Br

Br

c)

d)
CH 2 Br

CH 2OH

Br

OCH 3

Br

70.

The number of possible enantiomeric pair(s) produced from the bromination

(Br2/CCl4) of I and II, respectively, are

H 3C
H 3C

CH 3

CH 2

H 3C

a) 0,1
71.

H 3C

CH 3

II

b) 1, 0

c) 0, 2

d) 1, 1

For the reaction A B, H 0 7.5 KJ mol 1 and S 0 25 JK 1 mol 1 . The value of G 0 and
the temperature at which the reaction reaches equilibrium are, respectively,
b) 2.5 KJ mol 1 and 400 K

c) 2.5 KJ mol and 200 K

d) 0 KJ mol 1 and 300 K

The solubility product of Mg OH 2 is 1.0 1012 at 250C. Aqueous NaOH solution is

.i

72.

a) 0 KJ mol 1 and 400 K

ps

added to a 0.01 M aqueous solution of MgCl2 . The minimum pH at which precipitation

c) 8.0

d) 9.0

Diborane is formed from the elements as shown in equation (1)

.s
t

2 B s 3H 2 g B2 H 6 g ............ 1

ud

73.

b) 7.8

ys

a) 7.2

te

occurs at 250C is

Given that

ww
w

H 2O l H 2O g

H10 44 kJ

2 B s 3 / 2O2 g B2O3 s

H 20 1273 kJ

B2 H 6 g 3O2 g B2O3 s 3H 2O g

H 30 2035 kJ

H 2 g 1/ 2O2 g H 2O l

H 40 286 kJ

the H 0 for the reaction (1) isa) 36 kJ

74.

b) 509 kJ

c) 520 kJ

d) 3550 kJ

The Crystal Field Stabilization Energy CFSE and the spin-only magnetic moment in
Bohr Magneton (BM) for the complex K3 Fe CN 6 are, respectivelya) 0.0 0 and 35 BM

b) 2.0 0 3 BM

c) 0.4 0 and 24 BM

d) 2.4 0 and 0 BM

75.

Conversion of Isopropyl chloride into Isopropyl alcohol can take place by both SN1 &
SN2 mechanism based on the conditions, from the following table
Mechanism

No.of Intermediates

No.of Transition states

SN1

SN2

What is the value of (P + Q) - (R + S) is

a) 1
76.

b) 2

c) 3

d) 4

0
When 2 Moles of Zn(s) is oxidized at 298 K, in Daniel cell Ecell
1.1V , the standard

Gibbs free energy change G 0 in kJ mol 1 , is closed to

a) -212.3

d) -53.1

b) 8

Number of P-O bonds in P4O6 molecule is

a) 6

c) 12

d) 16

The adsorption isotherm for a gas is given by the relation x = ap/ (l + bp) where x is

ps

78.

c) -424.6

.i

77.

b) -106.2

ys

are constants. Then correct statement is

te

moles of gas adsorbed per gram of the adsorbent, p is the pressure of the gas, a and b

b) x remains unchanged with p

ud

a) x increases with p

.s
t

c) x decreases with p

d) x increases with p at low pressures and then remains the same at high pressure
XeF6 on hydrolyses to give an oxide. The structures of XeF6 and the oxide,

respectively, are-

80.

ww
w

79.

a) octahedral and tetrahedral

b) distorted octahedral and pyramidal

c) octahedral and pyramidal

d) distorted octahedral and tetrahedral

When MnO4 oxidizes separately (i) oxalate ion in acidic medium (ii) HCl. The ratios of
MnO4 : C2O42 in (i) and MnO4 : HCl in (ii), in the respective balanced chemical

equations are respectively

a) 1:5 and 2:5
81.

b) 2:5 and 1:8

c) 2:5 and 1:5

d) 5:2 and 1:8

The electron in hydrogen atom is in the first Bohrs orbit (n=1). The ratio of electronic
transition energies,
E n 1 n 3 to E n 1 n 2 , is

a) 32/27

b) 16/27

c) 32/9

d) 8/9

82.

What is the major product of the following reaction sequence?

HO CH 2

1 SOCl2 (excess)

OH 2CH3ONa1 eq

O
a)

c)

CH 3 O CH 2

ClCH 2

Cl
O

O CH 3

O
d)

CH 3

CH3 O CH2

Cl

29.5 mg. of an organic compound containing nitrogen was digested according to

83.

Cl CH 2

b)

.i

Kjeldahls method and the evolved NH 3 gas was absorbed in 20 mL of 0.1 M HCl

ps

solution. The excess of acid required 15 mL of 0.1 M NaOH solution for complete

84.

b) 59.0

c) 47.4

d) 23.7

ud

a) 29.5

ys

te

neutralization. The percentage of nitrogen in the compound is:

Which of the following statement(s) are correct.

.s
t

(i) More number of oxidation states are exhibited by the actinoids than those by the

ww
w

lanthanoids due to lesser energy difference between 5f and 6d in actinoids than 4f

and 5d orbitals in lanthanoids.
(ii) There is a gradual decrease in the radii of the trivalent ions with the increasing
atomic number in the lanthanoids series.
(iii) The 5f-orbitals are deeply seated than the 4f-orbitals in the atom.
(iv) Zr and Hf have about the same raidus due to lanthanoid contraction

85.

a) (i), (ii), (iv)

b) (i), (ii), (iii)

c) (i), (ii)

d) (i), (ii), (iii), (iv)

With reference the scheme given, which of the given statement(s) about T ,U ,V and
W is (are) correct?

H 3C
L iA lH

C rO 3 / H

E xcess of
C
H 3C O 2 O

(i) T is soluble in hot aqueous NaOH

(ii) U is optically active
(iii) Molecular formula of W is C10 H18O4
(iv) V gives effervescence with aqueous NaHCO3
a) (i), (ii), (iii)
86.

b) (i), (iii), (iv)

c) (i), (ii), (iv)

d) (i), (iii)

Choose the correct reason(s) for the stability of the lyophobic colloids.

.i

i) Preferential adsorption of ions on their surface from the solution

ii) Perferential adsorption of solvent on their surface from the solution

ps

iii) Attraction between different particles having opposite charges on their surface

c) (i), (ii), (iv)

d) (i), (iv)

Which of the following statement(s) are correct.

.s
t

87.

b) (i), (iii), (iv)

ud

a) (i), (ii), (iii)

ys

charges around the colloidal particles.

te

iv) Potential difference between the fixed layer and the diffused layer of opposite

(i) D glucopyranose and D glucopyranose are anomers.

known as mutaroation

ww
w

(ii) The change in optical rotaion of freshly prepared solution of fructose with time is

(iii) Sugars can be detected by Molishs test.

(iv)Synthesis of each molecule of glucose in photosynthesis involves 10 molecules of
ATP.
(v) Biuret test is given by proteins.

88.

a) (i), (ii), (iv), (v)

b) (ii), (iii), (v)

c) (i), (ii), (iii), (v)

d) (i), (ii), (iii), (iv), (v)

In which of the following arrangements, the sequence is not strictly according to the
property written against it?
a) HF HCl HBr HI : increasing acid strength
b) NH 3 PH 3 AsH 3 SbH 3 : increasing basic strength

c) B C O N : increasing 1st ionization enthalpy

d) GeO2 SnO2 PbO2 : increasing oxidizing power
89.

Four coins of the same size are placed on the corners of a square in such a way that
their centres coincide with the corners of the square. Radius of coins is R and edge of
square is 2R . What is maximum radius of a coin that can be placed in the gap of the
above square?
a) 0.155 R

c) 0.414 R

d) 0.732 R

During the extraction of iron in the blast furnace,

a) Coke acts as reducing agent in the lower zone and CO acts as reducing agent in the upper
zone
b) CO acts as reducing agent in the lower zone and Coke acts as reducing agent in the upper

.i

zone

c) Coke acts as reducing agent in the lower zone and CO acts as reducing agent in the lower

ps

zone

te

d) CO acts as reducing agent in the upper zone and Coke acts as reducing agent in the

.s
t

ud

ys

upper zone

ww
w

90.

b) 0.225 R