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Redox Titration Problems

This document describes several redox titration problems involving the titration of various analytes like tin(II), iron(II), bromide, and manganese(VII) ions with standardized solutions of potassium manganate(VII), potassium dichromate(VI), hydrogen peroxide, and determining their concentrations. The problems involve writing balanced redox reactions, calculating volumes of titrants needed, and molar concentrations based on moles and volumes.

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Xyrell Claude Monta
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3K views1 page

Redox Titration Problems

This document describes several redox titration problems involving the titration of various analytes like tin(II), iron(II), bromide, and manganese(VII) ions with standardized solutions of potassium manganate(VII), potassium dichromate(VI), hydrogen peroxide, and determining their concentrations. The problems involve writing balanced redox reactions, calculating volumes of titrants needed, and molar concentrations based on moles and volumes.

Uploaded by

Xyrell Claude Monta
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOC, PDF, TXT or read online on Scribd
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Redox Titration Problems

1. A solution of Sn(NO3)2 of unknown concentration can be titrated with a solution of


acidified KMnO4 of known concentration and the concentration of the Sn(NO3)2 can be
calculated. The unbalanced reaction is
Sn2+ + MnO4- + H+ Sn4+ + Mn2+ + H2O
purple
colourless
If 42.0 mL of Sn(NO3)2 are titrated by 18.0 mL of 0.15 M KMnO4 then find the
[Sn(NO3)2].
2. A solution of Fe(NO3)2 of unknown concentration can be titrated with a solution of
acidified KMnO4 of known concentration and the concentration of the Fe(NO3)2 can be
calculated. The unbalanced reaction is
Fe2+ + MnO4- + H+ Fe3+ + Mn2+ + H2O
Purple
colourless
If 18.0 mL of Fe(NO3)2 are titrated by 32.0 mL of 0.250 M KMnO4 then find the
[Fe(NO3)2].
3. Given the following unbalanced redox equation:
Br- + Cr2O72-

Cr+3 + Br2 (in acid)

In a redox titration 12.38 mL of 0.225 M Cr2O72- was needed to completely oxidize the
Br- in a 20.00 mL sample of NaBr. Calculate the original [Br-].
4. Acidified hydrogen peroxide (H2O2) is used to titrate a solution of MnO4- ions
of unknown concentration. Two products are O2 gas and Mn2+.
a) Write the balanced redox equation:
b) It takes 6.50 mL of 0.200 M H2O2 to titrate a 25.0 mL sample of MnO4solution. Calculate the original [MnO4-].
5. What volume of 0.010 mol/L iron (II) sulphate solution will be oxidized by 25.0mL of
0.020 mol/L of acidified potassium manganate (VII) solution?
Fe 2 MnO4 Fe 3 Mn 2

6. What volume of 0.0125 mol/L sodium oxalate solution will be oxidized by 20.0mL of
0.0150 mol/L of acidified potassium dichromate (VI) solution?
C 2 O42 Cr2 O72 CO2 Cr 3

7. 0.2640 g of sodium oxalate is dissolved in a flask and requires 30.74 mL of potassium


permanganate (from a buret) to titrate it and cause it to turn pink (the end point).
The equation for this reaction is:
5Na2C2O4(aq) + 2KMnO4(aq) + 8H2SO4(aq) 2MnSO4(aq) + K2SO4(aq) + 5Na2SO4(aq)
+ 10 CO2(g) + 8 H2O(l)
(a) How many moles of sodium oxalate are present in the flask?
(b) How many moles of potassium permanganate have been titrated into the flask to reach
the end point?
(c) What is the molarity of the potassium permanganate?

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