Sodium Hydrosulphite Manufacturing Process, Raw Material Requirement, Specifications and Properties and Many More.................

SODIUM HYDROSULPHITE
By:
Imran
Anwar
[email protected]
NATIONAL TEXTILE UNIVERSITY
FAISALABAD
PAKISTAN
Sodium Hydrosulfite
Sodium hydrosulfite is a very effective reducing

agent,comes in solid white crystalline powder
form.Designed for flexible volume usage, solid sodium
hydrosulfite can be transported easily and stored for an
extended period of time. It has wide applications in
various industries, including textile, pulp and paper,
Kaolin clay, and water treatment. These are known for
accurate compositions, eco friendliness and safe to use
features.[1]
Manufacturing process
From Zinc ,Sulphur Dioxide and Soda Ash
Sodium hydrosulphite is manufactured by reacting
zinc dust with sulphur dioxide and treting the
resultant zinc hydrosulphite with soda ash to convert it
into sodium hydrosulphite.[2]
Raw material requirement
Basis 1 ton sodium hydrosulphite
Zinc dust 425 kg
Soda ash 725 kg
Sulphur dioxide 770 kg
Sodium chloride 1050 kg

Manufacturing process
Process is divided in two steps :manufacture of zinc hydrosulphite and
conversion into sodium hydrosulite.
Charge high purity zinc dust into a lead lined vessel provided with stirring
and cooling arrangement. Add water to make suspension of zinc in
water.bubble sulphur dioxide through the bottom of the vessel initially at
rapid rate and slowly the rate near saturation at 25 to 30 c.
 In Japan it is manufactured from sodium sulphate.In this process the
manufacture of sodium hydrosulphite is carried out by the reaction of
sulphur dioxide with alkialine sodium formate under controlled conditions.

Reaction :
Zn +so2 +h2o =zns2o4
Zns2o4+na2co3=znco3+na2s2o4
Flexible yet safe
Sodium hydrosulfite is highly stable if stored and kept

carefully. Our solid hydrosulfite has a shelf life of over
12 months. We provide a wide variety of packaging,
50KG drums, 100KG, 200KG to 1,800MT Intermediate
Bulk Containers (IBC). We give you the option to
choose the most appropriate packaging to minimize
package handling and air exposure. All our solid
hydrosulfite comes with inner liners as an extra
precaution against moisture and water
Innovative bulk packaging
Designed for volume users
Safety - Unique inner liners prevent moisture and water
Convenience - Designed for easy mechanical operation
by forklift
Dust free and odorless - The liners trap all powder and
odor when the bag is emptied
No packaging material handling - All packaging
materials, include drums and liners, can be returned to
us.

Specifications and properties
Chemical formula: Na2S2O4
Appearance: white granular powder
Bulk density: 0.9 to 1.1
Melting point: decomposed at 52 c
Solubility: decompose in water (hot) slightly soluble in

cold water insoluble in acids.

Common Applications
Sodium hydrosulfite is commonly used in the pulp
and paper industry for bleaching brightening and de-
colorization of virgin and recycled fiber. It is also
applied extensively to brighten Kaolin clay. In textiles,
the primary usage is in processing vat dyes and indigo
dyes. Other applications include water treatment,
leather processing and food bleaching (sugar, honey
and gelatin). As a reducing agent ,it is used in organic
synthesizing .
Hazards
Solid sodium hydrosulfite is highly stable when stored in
dry closed containers. However, solid sodium
hydrosulfite is a very reactive chemical which can
decompose when exposed to air and moisture or in
contact with small amount of water. Decomposition
will result in spontaneous ignition and liberation of
toxic SO2. The chemical reacts violently with oxidants
and will explode or combust.
Potential Health Effects
Inhalation:
Inhalation can cause severe irritation of mucous membranes and upper
respiratory tract. Symptoms may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting. High concentrations may cause lung damage. Higher exposures
can cause a build-up of fluid in the lungs (pulmonary edema), a medical
emergency.
Ingestion:
May cause abdominal pain, nausea, vomiting, colic and diarrhea,
circulatory disturbances, central nervous system depression, irritability,
restlessness, convulsions, cyanosis, respiratory and cardiovascular
collapse, and death. Estimated lethal dose 30 grams.
Potential Health Effects
Skin Contact:
Can irritate the skin causing a rash or burning feeling on
contact. High concentrations could cause burns.
Eye Contact:
Causes irritation, redness, and pain. May cause burns and
possible damage to vision.
Chronic Exposure:
Exposure may induce allergic reaction.
Aggravation of Pre-existing Conditions:
Persons allergic to "sulfiting" agents, used to preserve some
foods, may be more susceptible to the effects of this substance.
First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person.
Get medical attention.
Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove
contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before
reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get
medical attention immediately.
Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified
in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and
equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal
and place in a closed container.
Stability and Reactivity
Stability:
Stable when stored in closed containers at room
temperature. Heats spontaneously in contact with
moisture and air. Loses all of its water of crystallization at
110C. Decomposes in hot water and acid.
Hazardous Decomposition Products:

Burning may produce sulfur oxides.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Water, combustible materials, strong oxidizing agents, strong acids and sodium
chlorite. An explosion occurred after mixing sodium hydrosulfite, aluminum
powder, potassium carbonate and benzaldehyde.
Conditions to Avoid:
Moisture, humidity, heat, flame, ignition sources and incompatibles.
Storage and handling

Sodium hydrosulphite must be always handled and stored in sealed clean iron
drums or bulk containers. Avoid contacts with moisture, acids, oxidizing
chemicals and combustible organic substances. Protect it from heat, direct
sunlight, sparks and naked flames. Avoid damaging the packaging.
In the event of fire, use large quantities of water to extinguish the product. Other
extinguishing media may not stop decomposition thoroughly
Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as
hazardous waste and sent to a RCRA approved waste facility. Processing, use or
contamination of this product may change the waste management options. State
and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and
local requirements.
Spillage
Sweep up immediately all spillage of sodium hydrosulfite around the application
and storage areas.Deposit it in a dry and clean container where it can be dissolved
in water.Wash the area invovlved with water .If the product is suspected to already
absorbed moisture.use it as soon as possible (if it is impossible to use it
immediately,you need to dispose it.) 　

Thanks to Almighty
ALLAH

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SODIUM HYDROSULPHITE

Sodium hydrosulfite is a very effective reducing

Zinc dust 425 kg

Soda ash 725 kg

Sulphur dioxide 770 kg

Sodium chloride 1050 kg

Sodium hydrosulfite is highly stable if stored and kept

Appearance: white granular powder

Bulk density: 0.9 to 1.1

Melting point: decomposed at 52 c

Solubility: decompose in water (hot) slightly soluble in

Accidental Release Measures

Hazardous Decomposition Products:

Storage and handling

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