Homework 6 - Solution
Homework 6 - Solution
Homework 6 Solution
6.1.
(i) Calculate the density of states of the electron gas in 2 and 1 dimensions.
(ii) Derive expressions for the Fermi energy in atomic units, where the energy is expressed in Hartree
and the length is expressed in Bohr radius.
(iii) Consider a 2D electron gas with the density of 1.51011 cm2 . Express this density in atomic units.
What is the Fermi energy for this 2D electron gas?
Solution:
(i) In 2 dimensions (2D),
2k dk
D(E)dE = 2 2 .
2
L
With
E = E~k =
m
2 k2
h
k dk = 2 dE
2m
we get
A
D(E) =
2
2m
h2
independent of E.
In 1 dimension (1D),
2 dk
D(E)dE = 2
2
L
with one factor of 2 for spin and the other factor of 2 for k and k. With
s
k=
2m 1/2
1
dk =
2 E
2
h
2m 1/2
E
dE
h2
we get
2m
h2
1/2
and A =
A
.
a2B
D(E) =
(ii) In 2D, EF = N A1 , where EF =
In 1D, EF =
2
8
N
L
2
, where EF =
EF
Hartree
EF
Hartree
and L =
E 1/2 .
L
aB .
(iii)
N
A
N
A
= 1.51011 cm2 ,
=
N
N
= a2B = 1.51011 cm2 (0.529108 cm)2 = 0.42105 ,
A
A/a2B
1
EF
EF
N
= 0.42105 ,
A
= 0.42105 Hartree = 0.42105 27.2 eV = 35.9105 eV .
=
6.2. The 3 He atom is a fermion with spin 1/2 (why?). The density of liquid 3 He is 0.081 g/cm3 near
T = 0. Calculate the Fermi energy EF and the Fermi temperature TF .
Solution:
Particles with a half-integer spin (here: nuclear spin) are fermions. The mass density of the liquid is
=
N
M (3 He) = 0.081 g/cm3 .
V
0.081 g/cm3
N
=
=
= 1.6171022 cm3 = 1.6171028 m3 .
V
M (3 He)
31.671024 g
2/3
h2
2N
=
3
= 6.781023 J = 4.24104 eV ,
2M (3 He)
V
= 4.24104 1.16104 K = 4.91 K .
EF
TF
6.3. Assuming a free electron gas model for the valence electrons of the metals Li, Na, Cs, Cu, Mg, Al,
In, Pb, calculate the Fermi energy (in eV) and the zero point pressure (in atmospheric pressure). Use
Table 4 (Density and atomic concentration) in Chapter 1 of Kittel (p. 24 in 7th edition, p. 21 in 8th
edition).
Solution:
The expression for the zero point pressure derived in Class is
2
P =
3
3
EF n ,
5
where n is the electron density and EF the Fermi level that can be expressed in terms of n. Make sure
you get a result for a couple of elements (e.g. Na, Mg, In).