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Hydrodynamic Radius (A)

The document contains graphs and tables showing how the hydrodynamic radius and mean-square radius of gyration of polymer chains increase with the number of monomers in the chain. The data shows a power law relationship between chain size and number of monomers. Additional data tables provide values for the mean-square radius of gyration and root-mean-square radius calculated from exact equations and approximated formulas across a range of chain lengths.

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42 views5 pages

Hydrodynamic Radius (A)

The document contains graphs and tables showing how the hydrodynamic radius and mean-square radius of gyration of polymer chains increase with the number of monomers in the chain. The data shows a power law relationship between chain size and number of monomers. Additional data tables provide values for the mean-square radius of gyration and root-mean-square radius calculated from exact equations and approximated formulas across a range of chain lengths.

Uploaded by

Anonymous ZP5SDj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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1600

1400
1200
1000
Hydrodynamic Radius (A)

800
600
400
200
0
0

100000

200000

300000

Number of Monomers in the Chain (N)

10000

1000

<R^2>/b^2

100

10

1
1

10

100

1000

Number of Monomers in the Chain (N)

10000

Exact
<R2>/b2

Formula
<R2>/b2

Exact Rrms/b

Formula Rrms/b

3.6

18

1.90

4.24

12.384

36

3.52

6.00

38.711

72

6.22

8.49

16

105.13

144

10.25

12.00

32

248.03

288

15.75

16.97

64

536

576

23.15

24.00

128

1112

1152

33.35

33.94

256

2264

2304

47.58

48.00

512

4568

4608

67.59

67.88

1024

9176

9216

95.79

96.00

Exact <R2> Formula <R2> Exact Rrms


Formula Rrms
(nm2)
(nm2)
(nm)
(nm)
2
0.73
3.65
0.85
1.91
4

2.51

7.29

1.58

2.70

7.84

14.58

2.80

3.82

16

21.29

29.16

4.61

5.40

32

50.23

58.32

7.09

7.64

64

108.54

116.64

10.42

10.80

128

225.18

233.28

15.01

15.27

256

458.46

466.56

21.41

21.60

512

925.02

933.12

30.41

30.55

1024

1858.14

1866.24

43.11

43.20

0.15

0.1

0.05
dG/MkT
0
0

0.1

0.2

0.3

0.4

0.5

0.6

-0.05

-0.1
Polymer Volume Fraction

0.7

0.8

0.9

0.15

0.1

0.05
dG/MkT
0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

-0.05

-0.1
Polymer Volume Fraction

0.8

0.9

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