Determining Molecular Geometries

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Molecular Lewis Domain Type of Molecular Ideal

Formula Structure Geometry Structure Geometry Bond


Angle
NH3 tetrahedral MX3E trigonal 109.5°
5+3(1)= 8e- pyramidal
(# valence e-)
H2O
CH2Cl2
*OPCl3
(violate octet rule
CO32-
*AlCl6 3-

(violate octet rule)


*SO2
(violate octet rule)
*BrF3
(violate octet
rule)

*SeF4
(violate octet
rule)

*BrF5
(violate octet
rule)
*PCl5
(violate octet rule)

CH2O C C C C
C C C C
C2H6O
O O O O
(CH3OCH3)
C C C C
C C C C
C2H6O
C C C C
(C2H5OH)
O O O O
C6H6 Only
(C's form a around one
ring) C

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