Developments in Flame Retardant Finish
Developments in Flame Retardant Finish
SUBMITTED TO
DR. DEEPTI GUPTA
SUBMITTED BY
ABHISHEK SRIVASTAVA
CONTENT
1-Introduction
2-Non halogen based flame retardants
2.1 Phosphorous containing flame retardants
2.1.1Simple reactive
i. Epoxy resin
ii. Poly(ester)s
iii. Poly(amide)s
2.1.2 linear poly(phosphazene)s
2.1.3 aromatic cyclic phosphazenes
2.2 silicon containing flame retardants
2.2.1 linear silanes/ siloxanes
2.2.2 silsequioxanes
3- formaldehyde free flame retardants
4-intumescent
5- plasma technology and its potential
6-Incorporation of expandable graphite
INTRODUCTION
Many flame retardant chemistries researched and developed during the 1950-1980 period for
improving the fibre performance of both natural and chemical fibres have not been significantly
added to last 25 years or so. this is a consequence of increasing commercial demands in term of
cost effectiveness and general toxilogical character of these materials and treatments.
Recent developmemts includes increasing efficiency of known chemisry to enhance char formation by
intumescents
Replace to Antimony bromine formulation in textile back-coating by phosphorous based compounds
Contnd.
Replacements for established durable
formaldehyde based flame retardants such as
those based on tetrakis(hydroxymethyl0phosphonium salt and alkyl- substituted,
N-methylol phosphonopropionamide chemistries
for cellulose textile(ref.-flame retardant challenges
for textile and fibres : new chemistry versus
innovatory solutions A.Richard Horrocks-2010)
Use of plasma technology that offers a means of
achieving the means of developing novel
nanocoating having desired thermal shielding
effects.
Contnd
by using low pressure , radio frequency
discharge plasma treatmentof a number
of polymer surface including PET in
presence of gaseous (CF4/CH4) leads to
flame retardant(ref.Shi L S investigation
of surface modification and reaction
kinetics of PET in CH4-CH4 plasma 1999)
Incorporation of expandable graphite as
flame retardant in various polymers