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KEY WORDS: Liquid-liquid extraction, Mass transfer coefficients, Continuous phase, Packed
column.

.
.

() Back mixing

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:
d Vslip r c

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mc

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)(

Vd
Vc
+
) ef e( - f

= Vslip

) ( ) [] (
:
)(

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.

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.

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() Laddah

() Fair

() Slater

() Seibert

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)Vslip(m/s

)D32(m

)Vc(ml/min

)Vd(ml/min

Exp No.

/ /.
Shc

Scc

NRe

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)Vslip(m/s

)D32(m

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Exp No.

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yE

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)(

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m n k p
) (
:

 .
%ARE for Seibert

for correlation ARE%

Shc,Seibert

Shc,correlation

Shc,exp

Exp No.

.
%ARE for Seibert

for correlation ARE%

Shc,Seibert

Shc,correlation

Shc,exp

Exp No.

( - f )

)(

/ Re Sc
/

= Sh c

) ()(AARE

]:[
)(

R redicted value - Experimeta lvalue

NDP

i =

NDP

= AARE

NDP .
) ()(ARE ) (
) ( ) (
.
)(

R redicted value - Experiment al value

= ARE

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/ / /
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% AARE

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% AARE

/ /

% AARE for correlation

% AARE for correlation

% AARE for Seibert

% AARE for Seibert

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% AARE

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a

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a
A


y*


yin

yout

rav = w i ri
(Kg/m )
f

e

y

D
H
K Ea
mE
Re
Scc
Shc
Vslip
Vc

/ / : / / :

Vd

(m)
(/s)
(Kg/s)
( c VSlip d32 / c )
( c / c Dc )
(k c d32 / Dc )
(m/s)

(m /s)

(m /s)
(m)

[1] Stevens, G.W., Packed columns, In: J. C. Godfrey, M. J. Slater. Liquid-Liquid Extraction

Equipment, pp.227-246 (1994).

Laddha, G.S., Smith, J.M., Transport Phenomena in Liquid Extraction, Tata McGraw-Hill,
New Dehli, (1976).

[4]

Slater, M.J., Rate Coefficients in Liquid-Liquid Extraction Systems, In: J. C. Godfrey, M. J.

[5]

Kumar, A., Hartland, S., Correlations for Prediction of Mass Transfer Coefficients in Single
Drop Systems and Liquid-Liquid Extraction Columns, Trans. Inst. Chem. Eng., 77, p. 372
(1999).

[6]

Steiner, L., Mass Transfer Rates from Single Drops and Drop Swarms, Che. Eng. Sci., 41(8),
p. 1979 (1986).

[7] Seibert, A.F., Fair, J.R., Hydrodynamic and Mass Transfer in Spray and Packed Liquid-Liquid
Extraction Columns, Ind. Eng. Chem. Res., 27, p. 470 (1988).
[8]

Wilke, C.R, Chang, P., Correlation of Diffusion Coefficients in Dilute Solutions, AIChE J.,
1, p. 264 (1955).

[9] Arsalani, V., Rostemi, Kh., Lipoxygenase-1 Mass Transfer Coefficient in Aqueous Two Phase
System Using Spary Extraction Column, Ind. Eng. Chem. Res., 44, p. 7469 (2005).
[10] Yu Jie, Fei Weiyang, Huai Z. Li., Effect of Packing on Drop Swarms Extraction of High
Viscosity Solvents, Hydrometallurgy, 78, p. 30 (2005).
[11] Laraci, F., A Unified Approach to the Hydraulics and Mass Transfer in Randomly Packed
Towers, Che. Eng. Sci., 56, p. 6003 (2001).
[12] Kays, W. M., Convective Heat Mass Transfer, McGraw-Hill: New York, (1966).

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