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Peroxide Value PDF

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151 views

Peroxide Value PDF

penentuan bilangan peroksida

Uploaded by

sutareja
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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LUBRIZOL STANDARD TEST PROCEDURE

TEST PROCEDURE AATM 516-01


Edition: October 13, 2006
Previous Edition: November 30, 1999

PEROXIDE VALUE - AOCS METHOD


APPARATUS
1.
2.
3.
4.
5.
6.

Balance capable of weighing to the nearest 0.1 mg.


250 ml. glass stoppered Erlenmeyer flasks.
10 ml Class B Burette, graduated in 0.05 divisions, with a tolerance of 0.04 ml.
Mohr pipette capable of containing 1 ml with a tolerance of 0.04 ml.
2-graduated cylinders capable of containing 50 ml.
Dispensing device, capable of dispensing 1 ml.

REAGENTS AND SOLUTIONS


1.
2.
3.
4.
5.

Acetic Acid - chloroform solution (480ml Acetic Acid and 320ml Chloroform).
Saturated Potassium Iodide solution. Store in the dark.
Sodium thiosulfate solution, 0.1N. Commercially available.
1% Starch solution. Commercially available.
Distilled or deionized water.

PROCEDURE
Conduct a blank determination of the reagents daily.
1.

Weigh 5.00 (0.05)g of sample into a 250 ml glass stoppered Erlenmeyer flask. Record
weight to the nearest 0.01g.

2.

By graduated cylinder, add 30 ml of the acetic acid - chloroform solution.

3.

Swirl the flask until the sample is completely dissolved (careful warming on a hot plate
may be necessary).

Lubrizol Advanced Materials, Inc. / 9911 Brecksville Road, Cleveland, Ohio 44141-3247 / TEL: 800.379.5389 or 216.447.5000
The information contained herein is believed to be
reliable, but no representations, guarantees or
warranties of any kind are made as to its accuracy,
suitability for particular applications or the results to be
obtained therefrom.
The information is based on
laboratory work with small-scale equipment and does
not necessarily indicate end product performance.
Because of the variations in methods, conditions and

equipment used commercially in processing these


materials, no warranties or guarantees are made as to
the suitability of the products for the application
disclosed.
Full-scale testing and end product
performance are the responsibility of the user. Lubrizol
Advanced Materials, Inc. shall not be liable for and the
customer assumes all risk and liability of any use or
handling of any material beyond Lubrizol Advanced

Materials, Inc.s direct control. THE SELLER MAKES NO


WARRANTIES, EXPRESS OR IMPLIED, INCLUDING,
BUT NOT LIMITED TO, THE IMPLIED WARRANTIES
OF MERCHANTABILITY AND FITNESS FOR A
PARTICULAR PURPOSE. Nothing contained herein is
to be considered as permission, recommendation, nor
as an inducement to practice any patented invention
without permission of the patent owner.

For further information, please visit www.personalcare.noveon.com


Lubrizol Advanced Materials, Inc. is a wholly owned subsidiary of The Lubrizol Corporation
* Trademark owned by The Lubrizol Corporation
Copyright 2007 / The Lubrizol Corporation

2
PROCEDURE cont.
4.

Using 1 ml Mohr pipette, add 0.5 ml of saturated potassium iodide solution.

5.

Stopper the flask and swirl the contents of the flask for exactly one minute.

6.

Immediately add by graduated cylinder, 30 ml of either distilled or deionized water,


stopper and shake vigorously to liberate the iodine from the chloroform layer.

7.

Fill the burette with 0.1N sodium thiosulfate.

8.

If the starting color of the solution is deep red orange, titrate slowly with mixing until the
color lightens. If the solution is initially a light amber color, go to step 9.

9.

Using a dispensing device, add 1 ml of starch solution as indicator.

10. Titrate until the blue gray color disappears in the aqueous (upper layer).
Note: for Doe-120, titrate until the lower layer has a "milky" appearance.
11. Accurately record the mls of titrant used to two decimal places.

CALCULATIONS
S = titration of sample
B= titration of blank
Peroxide value =

(S - B)

X N thiosulfate X
weight of sample

1000

or
(S - B) X

N thiosulfate X 200

PRECISION*
Product
DOE-120

Average
4.12

Std. Dev.
1.04

*Data from Institute WV Project Report 7-24-98

Coeff. of Var.
25.11

Df
10

Cm
**

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