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Reaction Orders

This document contains data from 4 trials of a first-order chemical reaction. The data includes time points and concentration measurements. Linear regression analysis was performed on plots of the natural log of concentration versus time for each trial. This yielded straight lines with negative slopes, allowing calculation of the pseudo-first-order rate constant for each reaction from the slope.

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Mario V Lopez
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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48 views27 pages

Reaction Orders

This document contains data from 4 trials of a first-order chemical reaction. The data includes time points and concentration measurements. Linear regression analysis was performed on plots of the natural log of concentration versus time for each trial. This yielded straight lines with negative slopes, allowing calculation of the pseudo-first-order rate constant for each reaction from the slope.

Uploaded by

Mario V Lopez
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Time

Trial 1
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

Time

Trial 3
2.5
2.43
2.24
2.05
1.85
1.67
1.51
1.39
1.24
1.14
1.04
0.95
0.85
0.78
0.7
0.64
0.59
0.53
0.49
0.45
0.42
0.38

trial 1 ln
0 0.91629073
30 0.88789126
60 0.80647587
90 0.71783979
120 0.61518564
150 0.51282363
180 0.41210965
210 0.32930375
240 0.21511138
270 0.13102826
300 0.03922071
330 -0.05129329
360 -0.16251893
390 -0.24846136
420 -0.35667494
450 -0.4462871

Trial 1
3
2.5

f(x) = - 0.0034161491x + 2.2506324


R = 0.9401489112

Axis Title

1.5
1
0.5
0
0

100

200

300

Axi

trial 1
1.5

f(x) = - 0.003108953x + 0.97061


R = 0.9990184797
0.5

Axis Title

0
0

100

200

-0.5

-1

-1.5

100

200

-0.5

-1

480
510
540
570
600
630

Time

-0.52763274
-0.63487827
-0.71334989
-0.7985077
-0.86750057
-0.96758403

-1.5

trial 1

trial 1 1/A
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

0.4
0.41152263
0.44642857
0.48780488
0.54054054
0.5988024
0.66225166
0.71942446
0.80645161
0.87719298
0.96153846
1.05263158
1.17647059
1.28205128
1.42857143
1.5625
1.69491525
1.88679245
2.04081633
2.22222222
2.38095238
2.63157895

2.5

f(x) = 0.0034586428x + 0.10468


R = 0.9444790985

Axis Title

1.5

0.5

0
0

100

200

30

First order reaction

slope of line (most linear line) is the pse

Time
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

Trial 1

.0034161491x + 2.2506324111
01489112

00

200

300

400

500

600

700

Axis Title

Time

trial 1 ln

- 0.003108953x + 0.97061982
.9990184797

100

200

300

Axis Title

400

500

600

700

0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450

100

200

300

400

500

600

700

480
510
540
570
600
630

Axis Title

Time

trial 1 1/A

0.0034586428x + 0.1046848241
0.9444790985

100

200

300

400

500

600

700

Axis Title

st linear line) is the pseudo rate constant

0.9902

0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

Trial 2
2.5
2.36
2.23
2.1
1.97
1.84
1.72
1.62
1.51
1.42
1.33
1.25
1.17
1.1
1.03
0.97
0.9
0.86
0.81
0.75
0.71
0.68

Trial 2 ln
0.91629073
0.85866162
0.80200159
0.74193734
0.67803354
0.60976557
0.54232429
0.48242615
0.41210965
0.35065687
0.28517894
0.22314355
0.15700375
0.09531018
0.0295588
-0.03045921

Trial 2
3
2.5
f(x) = - 0.0028723885x + 2.3061660079
R = 0.9682330846

Axis Title

1.5
1
0.5
0
0

100

200

300

400

500

600

700

500

600

700

Axis Title

Chart Title
1
f(x) = - 0.0021112561x + 0.9228276805
R = 0.9996630758

0.8
0.6
0.4
Axis Title

0.2
0
0

100

200

300

400

-0.2
-0.4
-0.6
Axis Title

0
0

100

200

300

400

500

600

700

500

600

700

-0.2
-0.4

-0.10536052
-0.15082289
-0.21072103
-0.28768207
-0.34249031
-0.38566248

-0.6
Axis Title

trial 2 1/a
0.4
0.42372881
0.44843049
0.47619048
0.50761421
0.54347826
0.58139535
0.61728395
0.66225166
0.70422535
0.7518797
0.8
0.85470085
0.90909091
0.97087379
1.03092784
1.11111111
1.1627907
1.2345679
1.33333333
1.4084507
1.47058824

Chart Title
1.6
1.4
f(x) = 0.0017057594x + 0.299181854
R = 0.9731974407

1.2
1
Axis Title

0.8
0.6
0.4
0.2
0
0

100

200

300

400

Axis Title

Time

500

600

700

Trial 3
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630
660
690

2.5
2.5
2.5
2.49
2.43
2.36
2.29
2.2
2.13
2.05
1.97
1.92
1.85
1.78
1.71
1.65
1.61
1.54
1.49
1.43
1.38
1.33
1.28
1.24

0
30
60
90
120
150
180
210
240
270
300
330
360
390
420

Trial 3 ln
0.91629073
0.91629073
0.91629073
0.91228271
0.88789126
0.85866162
0.82855182
0.78845736
0.75612198
0.71783979
0.67803354
0.65232519
0.61518564
0.57661336
0.53649337

Time

500

600

700

Chart Title
3
2.5

f(x) = - 0.0020473913x + 2.6076


R = 0.9912407674

Axis Title

1.5
1
0.5
0
0

100

200

300

400

50

Axis Title

Chart Title
1

f(x) = - 0.0011065431x + 0.9980826286


R = 0.98810308

0.9
0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

400

Axis Title

50

0.4
500

600

700

0.3
0.2

450
480
510
540
570
600
630
660
690
Time

500

600

700

0.50077529
0.47623418
0.43178242
0.39877612
0.35767444
0.3220835
0.28517894
0.24686008
0.21511138

0.1
0
0

100

200

300

400

50

Axis Title

Trial 3 1/a
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630
660
690

0.4
0.4
0.4
0.40160643
0.41152263
0.42372881
0.43668122
0.45454545
0.46948357
0.48780488
0.50761421
0.52083333
0.54054054
0.56179775
0.58479532
0.60606061
0.62111801
0.64935065
0.67114094
0.6993007
0.72463768
0.7518797
0.78125
0.80645161

Chart Title
0.9
0.8

f(x) = 0.0006163287x + 0.3420392822


R = 0.9682643138

0.7
0.6
0.5
Axis Title

0.4
0.3
0.2
0.1
0
0

100

200

300

400

Axis Title

Time
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630
660
690
720
750

Chart Title

0473913x + 2.6076
07674

200

300

400

500

600

700

800

Axis Title

Chart Title
Time

1065431x + 0.9980826286
308

200

300

400

Axis Title

500

600

700

800

Trial 4
2.5
2.5
2.5
2.5
2.5
2.5
2.49
2.45
2.43
2.37
2.36
2.34
2.3
2.25
2.23
2.18
2.16
2.13
2.11
2.05
2.01
1.98
1.93
1.89
1.86
1.84

Trial 4 ln
0 0.91629073
30 0.91629073
60 0.91629073
90 0.91629073
120 0.91629073
150 0.91629073
180 0.91228271
210 0.89608802
240 0.88789126
270 0.86288996
300 0.85866162
330 0.85015093
360 0.83290912

3
2.5

f(x) =
R = 0

Axis Title

1.5
1
0.5
0
0

1
0.9
0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0

f(x
R

0.6
Axis Title

0.5
0.4

200

300

400

500

600

700

390
420
450
480
510
540
570
600
630
660
690
720
750

800

Axis Title

Chart Title
Time

6163287x + 0.3420392822
643138

200

300

400

Axis Title

500

600

700

800

0.3

0.81093022
0.80200159
0.77932488
0.77010822
0.75612198
0.74668795
0.71783979
0.69813472
0.68309684
0.65752
0.63657683
0.62057649
0.60976557

0.2
0.1
0
0

Trial 3 1/a
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630
660
690
720
750

0.4
0.4
0.4
0.4
0.4
0.4
0.40160643
0.40816327
0.41152263
0.42194093
0.42372881
0.42735043
0.43478261
0.44444444
0.44843049
0.4587156
0.46296296
0.46948357
0.47393365
0.48780488
0.49751244
0.50505051
0.51813472
0.52910053
0.53763441
0.54347826

0.6

f(x
R

0.5

0.4

Axis Title

0.3

0.2

0.1

0
0

Chart Title
3
2.5

f(x) = - 0.0009796011x + 2.611965812


R = 0.9631334887

Axis Title

1.5
1
0.5
0
0

100

200

300

400

500

Axis Title

Chart Title
1
0.9
0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0

f(x) = - 0.0004451452x + 0.9702872714


R = 0.952586786

600

700

800

0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

400

500

600

700

800

500

600

700

800

Axis Title

Chart Title
0.6

f(x) = 0.0002035038x + 0.3739084508


R = 0.9389091002

0.5

0.4

Axis Title

0.3

0.2

0.1

0
0

100

200

300

400
Axis Title

Time

Trial 1
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

Time

Trial 3
2.5
2.43
2.24
2.05
1.85
1.67
1.51
1.39
1.24
1.14
1.04
0.95
0.85
0.78
0.7
0.64
0.59
0.53
0.49
0.45
0.42
0.38

trial 1 ln
0 0.91629073
30 0.88789126
60 0.80647587
90 0.71783979
120 0.61518564
150 0.51282363
180 0.41210965
210 0.32930375
240 0.21511138
270 0.13102826
300 0.03922071
330 -0.05129329
360 -0.16251893
390 -0.24846136
420 -0.35667494
450 -0.4462871

2.5

f(x) = - 0.0034161491x + 2.2506324


R = 0.9401489112

Axis Title

1.5

0.5

0
0

100

200

300

Axi

1.5

f(x) = - 0.003108953x + 0.97061


R = 0.9990184797
0.5

Axis Title

0
0

100

200

-0.5

-1

-1.5

-0.5

-1

480
510
540
570
600
630

Time

-0.52763274
-0.63487827
-0.71334989
-0.7985077
-0.86750057
-0.96758403

-1.5

trial 1 1/A
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

0.4
0.41152263
0.44642857
0.48780488
0.54054054
0.5988024
0.66225166
0.71942446
0.80645161
0.87719298
0.96153846
1.05263158
1.17647059
1.28205128
1.42857143
1.5625
1.69491525
1.88679245
2.04081633
2.22222222
2.38095238
2.63157895

2.5

f(x) = 0.0034586428x + 0.10468


R = 0.9444790985

Axis Title

1.5

0.5

0
0

100

200

30

First order reaction

slope of line (most linear line) is the pse

Time
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

.0034161491x + 2.2506324111
01489112

00

200

300

400

500

600

700

Axis Title

Time

- 0.003108953x + 0.97061982
.9990184797

100

200

300

Axis Title

400

500

600

700

0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450

480
510
540
570
600
630

Axis Title

Time

0.0034586428x + 0.1046848241
0.9444790985

100

200

300

400

500

600

700

Axis Title

k'

st linear line) is the pseudo rate constant

0.0031
0.9902
second graph

0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

Trial 2
2.5
2.36
2.23
2.1
1.97
1.84
1.72
1.62
1.51
1.42
1.33
1.25
1.17
1.1
1.03
0.97
0.9
0.86
0.81
0.75
0.71
0.68

Trial 2 ln
0.91629073
0.85866162
0.80200159
0.74193734
0.67803354
0.60976557
0.54232429
0.48242615
0.41210965
0.35065687
0.28517894
0.22314355
0.15700375
0.09531018
0.0295588
-0.03045921

2.5
f(x) = - 0.0028723885x + 2.3061660079
R = 0.9682330846

Axis Title

1.5

0.5

0
0

100

200

300

400

500

600

700

500

600

700

Axis Title

1
f(x) = - 0.0021112561x + 0.9228276805
R = 0.9996630758

0.8
0.6
0.4
Axis Title

0.2
0
0

100

200

300

400

-0.2
-0.4
-0.6
Axis Title

100

200

300

400

500

600

700

500

600

700

-0.2
-0.4

-0.10536052
-0.15082289
-0.21072103
-0.28768207
-0.34249031
-0.38566248

-0.6
Axis Title

trial 2 1/a
0.4
0.42372881
0.44843049
0.47619048
0.50761421
0.54347826
0.58139535
0.61728395
0.66225166
0.70422535
0.7518797
0.8
0.85470085
0.90909091
0.97087379
1.03092784
1.11111111
1.1627907
1.2345679
1.33333333
1.4084507
1.47058824

1.6
1.4
f(x) = 0.0017057594x + 0.299181854
R = 0.9731974407

1.2
1
Axis Title

0.8
0.6
0.4
0.2
0
0

100

200

300

400

Axis Title

k'
slope of line (most linear line) is the pseudo rate constant

Time

500

600

Trial 3
0
2.5
30
2.49
60
2.43
90
2.36
120
2.29
150
2.2
180
2.13
210
2.05
240
1.97
270
1.92
300
1.85
330
1.78
360
1.71
390
1.65
420
1.61
450
1.54
480
1.49
510
1.43
540
1.38
570
1.33
600
1.28
630
1.24
660
690 Trial 3 ln

700

2.5

f(x) = - 0.0021180124x + 2.5139920949


R = 0.9945535571

Axis Title

1.5

0.5

0
0

100

200

300

400

Axis Title

Time

500

600

700

0
30
60
90
120
150
180
210
240
270
300
330
360
390
420

0.91629073
0.91228271
0.88789126
0.85866162
0.82855182
0.78845736
0.75612198
0.71783979
0.67803354
0.65232519
0.61518564
0.57661336
0.53649337
0.50077529
0.47623418

1
f(x) = - 0.0011660668x + 0.956366725
R = 0.9975967018

0.9
0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

400

Axis Title

500

600

0.4

700

0.3
0.2

450
480
510
540
570
600
630

Time

500

600

700

0.0021
0.99966
2nd graph

0.1

0.43178242
0.39877612
0.35767444
0.3220835
0.28517894
0.24686008
0.21511138

0
0

0.4
0.40160643
0.41152263
0.42372881
0.43668122
0.45454545
0.46948357
0.48780488
0.50761421
0.52083333
0.54054054
0.56179775
0.58479532
0.60606061
0.62111801
0.64935065
0.67114094
0.6993007
0.72463768
0.7518797
0.78125
0.80645161

200

300

400

Axis Title

Trial 3 1/a
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600
630

100

0.9
0.8
f(x) = 0.0006606887x + 0.3606168885
R = 0.9831313485

0.7
0.6
0.5
Axis Title

0.4
0.3
0.2
0.1
0
0

100

200

300

400

Axis Title

slope of line (most linear line) is the pseudo rate con

Time
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600

1180124x + 2.5139920949
35571

200

300

400

500

600

700

Axis Title

Time

11660668x + 0.956366725
67018

Trial 4
2.5
2.49
2.45
2.43
2.37
2.36
2.34
2.3
2.25
2.23
2.18
2.16
2.13
2.11
2.05
2.01
1.98
1.93
1.89
1.86
1.84

trial 4 ln a
0 0.91629073
30 0.91228271
60 0.89608802
90 0.88789126
120 0.86288996
150 0.85866162
180 0.85015093
210 0.83290912
240 0.81093022
270 0.80200159
300 0.77932488
330 0.77010822
360 0.75612198

2.5

f(x) =
R = 0

Axis Title

1.5

0.5

0
0

1
0.9

f(x) = R = 0.9

0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1

200

300

400

Axis Title

500

600

700

0
0

0.4
0.3
0.2

200

300

400

500

600

390
420
450
480
510
540
570
600

700

Axis Title

300

400

0.1
0
0

0.6

606887x + 0.3606168885
13485

200

0.74668795
0.71783979
0.69813472
0.68309684
0.65752
0.63657683
0.62057649
0.60976557

Time

500

600

700

Axis Title

k'

is the pseudo rate constant

0.0012

0.9976
2nd graph

Trial 3 1/a
0
30
60
90
120
150
180
210
240
270
300
330
360
390
420
450
480
510
540
570
600

0.4
0.40160643
0.40816327
0.41152263
0.42194093
0.42372881
0.42735043
0.43478261
0.44444444
0.44843049
0.4587156
0.46296296
0.46948357
0.47393365
0.48780488
0.49751244
0.50505051
0.51813472
0.52910053
0.53763441
0.54347826

f(x) =
R =

0.5

0.4

Axis Title

0.3

0.2

0.1

0
0

slope of line (most linear l

2.5

f(x) = - 0.0011419913x + 2.5264069264


R = 0.9956777453

Axis Title

1.5

0.5

0
0

100

200

300

400

500

600

700

Axis Title

1
0.9

f(x) = - 0.0005277103x + 0.9347820985


R = 0.9904300374

0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

400

Axis Title

500

600

700

0.4
0.3
0.2
0.1
0
0

100

200

300

400

500

600

700

Axis Title

0.6
f(x) = 0.0002452067x + 0.3886180692
R = 0.9817167876

0.5

0.4

Axis Title

0.3

0.2

0.1

0
0

100

200

300

400

500

600

700

Axis Title

k'

e of line (most linear line) is the pseudo rate constant

0.0011

0.99568
1st graph

trial

concentration
2
1.5
1
0.5

slope
0.0031
0.0021
0.0012
0.0005

0.0035
0.003
0.0025

f(x) = 0.00174x - 0.00045


R = 0.9939592909

0.002
k' (1/s)

0.0015
0.001
0.0005
0
0.4

0.6

0.8

1.2

Concnetration

concentration slope
0.6931471806 -5.77635317
0.4054651081 -6.16581793
0 -6.72543372
-0.6931471806 -7.60090246

-0.8

-0.6

-0.4

-0.2

ln (k')

f(x) = 1.3165357716x - 6.700579


R = 0.9995189257

0035

.003

0025

f(x) = 0.00174x - 0.00045


R = 0.9939592909

.002

0015

.001

0005
0
0.4

0.6

0.8

1.2

1.4

Concnetration OH (M)

1.6

1.8

2.2

0
-0.4

-0.2

0
-1
-2
-3
-4
-5

3165357716x - 6.7005791506-6
995189257
-7
-8
ln [OH-]

0.2

0.4

0.6

0.8

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