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Abstract NaSAEAST 2014

The document summarizes a study of the optical characteristics and effective Schottky barrier of polyaniline (PANI) films doped with dodecylbenzene sulphonic acid (DBSA). PANI films were synthesized using ammonium persulfate as the oxidizing agent and three concentrations of DBSA as the dopant. The optical band gap of the PANI films was found to be between 2.1-2.4eV based on UV-visible absorption spectra. A Schottky junction of Ag/PANI-DBSA/ITO was fabricated and showed rectifying behavior in current density-voltage characteristics. Increasing the DBSA concentration decreased the barrier height and increased the ideality factor of

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Sanjib Baglari
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66 views1 page

Abstract NaSAEAST 2014

The document summarizes a study of the optical characteristics and effective Schottky barrier of polyaniline (PANI) films doped with dodecylbenzene sulphonic acid (DBSA). PANI films were synthesized using ammonium persulfate as the oxidizing agent and three concentrations of DBSA as the dopant. The optical band gap of the PANI films was found to be between 2.1-2.4eV based on UV-visible absorption spectra. A Schottky junction of Ag/PANI-DBSA/ITO was fabricated and showed rectifying behavior in current density-voltage characteristics. Increasing the DBSA concentration decreased the barrier height and increased the ideality factor of

Uploaded by

Sanjib Baglari
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Optical characteristics and effective Schottky barrier of polyaniline

(PANI) film doped with dodecylbenzene sulphonic acid (DBSA)


Sanjib Kumar Baglari and D. Sarkar*
Department of Physics, Gauhati University, Guwahati, Assam 781014
Email: [email protected]
*Email: [email protected]
Abstract: Conducting polymers show large range of modulation of electrical
conductivity on doping(oxidation) and dedoping(reduction) cycle due to contribution
of protonic conduction. This has been used in various fields for this astonishing
property. In this communication, we report studies on optical characteristics of
polyaniline film and metal-polyaniline (PANI) Schottky barrier junction and the effect
of junction property on DBSA doping. PANI has been synthesized by the most
conventional chemical polymerization methods using ammonium persulphate (APS)
as oxidizing agent. Three different concentrations of DBSA, viz, 0.1, 0.3, 0.5 M/M,
are used during polymerization process. DBSA is known as a dopant as well as
surfactant. The optical band gap of PANI film as estimated from UV-visible spectra
absorption data has been found within the range 2.1-2.4eV. A Schottky junction with
configuration Ag/PANI-DBSA/ITO has been fabricated by coating of PANI-DBSA
on ITO and then taking Ag contact on to it. Current density-voltage (J-V)
characteristics of this junction show rectifying behavior. Junction parameter such as
barrier height, ideality factor has been calculated from J-V curves shows decrease of
barrier height and increase of ideality factor with increasing concentration of DBSA.

Keywords:

Polyaniline, optical properties, schottky barrier, ideal factor

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