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Chapter 16 - Section A - Mathcad Solutions

This document contains calculations to determine the standard molar entropy (Sig) of argon, krypton, and xenon gases at 1 bar pressure and 298.15K temperature. It provides the relevant physical constants and molar masses used. The calculated Sig values for each gas are within 0.05 J/mol∙K of the reported NIST reference values.

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Hafiidz Malek
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62 views1 page

Chapter 16 - Section A - Mathcad Solutions

This document contains calculations to determine the standard molar entropy (Sig) of argon, krypton, and xenon gases at 1 bar pressure and 298.15K temperature. It provides the relevant physical constants and molar masses used. The calculated Sig values for each gas are within 0.05 J/mol∙K of the reported NIST reference values.

Uploaded by

Hafiidz Malek
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Chapter 16 - Section A - Mathcad Solutions

16.10(Planck's constant)
 34

h  6.626 10

J s

P  1bar

(Boltzmann's constant)
 23 J
k  1.381 10

T  298.15K
39.948

a) For Argon:

M

23

NA  6.023 10 mol
3

R T
P

mol

mol

gm
mol

Sig

154.84

J
mol K

NIST value: 154.84

J
mol K

Sig

J
mol K

Ans.

NA

3
5

2
2
2 S M k T V e

Sig  R ln

NA
h

164.08

NIST value: 164.05


131.30
M

0.025

NA

83.800

c) For Xenon

1

gm

3
5

2
2
2

T
V

Sig  R ln
2

NA
h

b) For Krypton: M 

V

(Avagodro's number)

Ans.

J
mol K

gm
mol

NA

3
5

2
2
2 S M k T V e

Sig  R ln

NA
h

164.08

J
mol K

NIST value: 169.68

J
mol K

Sig

Ans.

620
______________________________________________________________________________________________
PROPRIETARY MATERIAL. 2005 The McGraw-Hill Companies, Inc. Limited distribution permitted
only to teachers and educators for course preparation. If you are a student using this Manual, you are using
it without permission.

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