Chemical Unit Operations: Lecture - 4
Chemical Unit Operations: Lecture - 4
Operations
Lecture -4
Dewi Tristantini
Course Content
What is unit operation
Description of unit process
Chemical State
Rates
Phase (L,S,G, G-L, G-S, L-S, L-L, G-L-S)
T&P
Reactors
Separators
Compressors, Pumps, Turbine, Expander, Valves
Heat Exchangers, Process Heaters
Mixers, Splitters
Separations
Distillation
- Relative volatility a greater than 1.2
- Product thermally stable
- Rate greater than 5,000-10,000 lbs/day
- No corrosion, precipitation or explosion problems
Azeotropic/Extractive Distillation
-Systems normally contain azeotropes
in solvent greater than for distillation
-Solvent thermally stable and easily regenerable
-Solvent commercially available (at a
reasonable cost)
Adsorption
- Adsorbent selectivity greater than 2 for
bulk separations and greater than 10-100
for purifications
- High percentage solute removal
- Acceptable delta loadings
- Adsorbent not susceptible to rapid fouling
- Bed(s) easily regenerable
- Clean air/water projects
Extraction
- Solvent selectivity greater than for
distillation and greater than 1.5-2.0
- Solvent selective for low-concentration
component
- Energy costs high
- Easy solvent recovery
Membranes
- Membrane selectivity greater than 10 (except for
air separation)
- Bulk separation, clean air/water projects
and some trace removal
- Acceptable fluxes
- Membrane chemically stable
- Membrane not susceptible to rapid fouling
- Low to moderate feed rates
Assignment IV
Short
presentation - unit
operation/student group
Content: what is?, brief description and
photo
Thank You