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AIITS-PT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/15

JEE(Advanced)-2015
ANSWERS, HINTS & SOLUTIONS
PART TEST IV
(Paper-1)

Q. No.

PHYSICS

CHEMISTRY

MATHEMATICS

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

A, D

A, B

A, B

12.

A, B, C

B, C, D

A, B

13.

A, B

B, C

A, B, D

14.

A, B, C, D

A, B, C

A, C

15.

A, B

B, D

A, B, C

1.

2.

3.

4.

5.

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AIITS-PT-IV-(Ppaer-1)-PCM(S)-IITJEE(Advance)/15

Physics

PART I

2.

Use Lenzs Rule

3.

Speed of image = speed of object in all the mirrors

4.

A m
sin

2
Use =
A
sin
2

6.

7.

For CBF P = 0 = tA(A 1) tB(B 1) +

9.

VA iR + 15 + (5 103) 103 = VB

2
d
and P =
dt
R
dy
D

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Chemistry

AIITS-PT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/15

PART II
SECTION A

1.

PF

2r 2

2 2r

2r 2

2
4
8r

So packing efficiency =
2.

100 78.54%
4

Tf Tf for glucos e Tf for KCl Tf for urea

100 80
74.5 100
100 60
Tf = 3.069
F. Pt = 273 3.069 = 269.93 K
Tf

3.

Zn 4HNO 3
ZnNO3 2 2NO2 2H2 O

NO3 ion is reduced to NO2 in preference to H3O+ ion.

H2O is a weak field ligand and CN is strong, field ligand.

5.

2HClO4 P2 O5
Cl2O7 2HPO3

7.

SnCl2 /HCl
HNO2
Cu dil HNO3
NO
NH2 OH.HCl
N2O

9.

F 103 F
Cl 110 Cl H 105 H
Because of larger size of Cl atm.
OCl2 have largest bond angle.
2

10.

is sp3 hybridized, because Cl is weak field ligand. Hence there is two unpaired
electrons.

15.

Number of particles from K4[Fe(CN)6] = 5

NiCl4

SECTION C
1.
H

2.

O
H

P O

OH

OH

OH

H
H

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AIITS-PT-IV-(Ppaer-1)-PCM(S)-IITJEE(Advance)/15

3.
F

F
Xe

4.

5.

1
AgNO3
Ag NO2 O2
2
HgNO3 2
Hg 2NO2 O 2

In Fe CO 5 , there is no unpaired electron.

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Mathematics
2

AIITS-PT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/15

PART III
4

3 1

2 3
y +c
3

1.

(3 yx ) dx + (x 2y ) dy = 0, x y =

2.

2
1 x
2
2
f(x)
[x] 1 ({x} 1) ([x] {x})
2

3.

4.

x dy ydx
x2 y2

dx Solution is y = x tan (C x)

cos 7 9

cos 7 10

cos 7 11

Given determinant = cos 8 9

cos 8 10

cos 8 11

cos 9 9

cos 9 10

cos 7

sin 8

0 cos 9

sin 9

cos

sin

cos

sin

cos 9

5.

sin A
cos A

Let

sin 9

sinB
cosB

cos3 A

10

0 cos 11

cos 9 11
0

10

sin 11

0 0
0

sinC
tan A
cos C cos A cosB cos C
1

cos3 B

cos3 C

cos A

tanB
1
cos B

tanC
1
cos C

sin(B C)sin(C A).sin(A B) 0

6.

7.

ydx xdy 1 x 2
2 dx sin ydy 0
x2
x
1

d y x d x d( cos y) 0
x

1
y x x cos y c 0
x
sin
cosn

cos
sinn

1
Let 3 2
3
2

8.

cos
We know
sin

1
2

15

sinn

cosn

0
I
1

15

215 I

X is a skew symmetric matrix of odd order.

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9.

1 dy 2 y x
dy

now let
4y x 2 y
x
2
dx
2 y dx

y t

1 dy dt

2 y dx dx

dt 2
x
t this is linear differential equation so
dx x
2
2
dx
x

y 1
1
1 x
2 . dx 2 nx c
2
2
2
x
x
x 2
x
Given curve passes through (1,(n2)2 )
I.F. e

e2nx

solution t

x2
nx x 2 .n2 now
2
1 4 1 1
(1 2)
2
4 5 7 7

Required probability
49
1 4 1 1
2(19) 11
4 5 7 7
( n2)2 c c n2

10.

11.

n!

1
n1
n 1n 2

1
n 1 n 2 1
1

n!

n 1
n

1n 2
n 1 n 2 n 3

x2
nx x 2c
2

y(2) 6n2 y(2) (6n2)2

n 1n 2
n

1n 2 n 3
n 4 n 3 n 2 n 1

n 1 n 2 n 1
n 2 n 2 n 3
n 3 n 3 n 4

1
n 1 n 2 0
0
2

n 1 n 2 n 1
1
2 n 2
1
2 n 3

n 1 n 2 .2 n 3 n 2

2n n2 4n 5 4

12.

0 1 2 0 1 2 2 1 2
A 0 3 0 0 3 0 0 9 0
1 1 1 1 1 1 1 1 3
3 1 6
adjA 1
1
A
0 2 0
A
6
3
1 0
Comparing L.H.S and R.H.S., we get a = 1, b = 4, c = 1, d = 12
Alternate method
By Cayley Hamilton theorem, A must satisfy A I 0
2

3 2 2 5 6 0
A must satisfy the above equation
A 3 2A 2 5A 6I 0
Multiplying by A1
A 2 2A 5I 6A 1

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13.

P(E F) P(E).P(F) xy

AIITS-PT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/15

k
3

.. (1)

Let P(E) = x and P(F) = y

k
6

k
.. (2)
6
Solving equation 1 and 2, we get 6x 2 x (k + 6) + 2k = 0
As x Q; then D should be perfect square, which is possible for k = 1
1
1
2
2
Therefore we get x or
and y =
or
3
2
2
3
But given (P(E) P(F)) (1P(F)) > 0 P(E) > P(F)
1
1
2
2
Hence x and y P(E) =
and P(F) =
3
2
3
2
(1 x)(1 y)

14.

15.

bc
a c b a b c
2
1 1
ba c c a b 0

2
1

1
a c and a b
2
2

1 is
and 2 = 120
3
a.a a.b a.c
3 1 1
a b c b.a b.b b.c 1 3 1 3 9 1 1 3 1 11 3 24 2 2 20
c.a c.b c.c
1 1 3
2

1
5
a b c

6
3
a b b c c a a b b c . c a a b a c b b b c c a

Volume of tetrahedron =

= a b .c a c .c b c .c a b .a a c .a b c .a
a b b c
Let d a b

2 a b

c a

d.c .b d.b .c . c a a b c b 0 c a

a b c b c a a b c

1.

SECTION C
n(S) = 5 5 5 = 125
n(A) = 514, 541, 523, 532, 413, 431, 422, 312, 321, 211
10
2
Required probability =

125 25

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6c 2 4c 2 2c 2 3c13c1 4c 2 2c 2 3c 2 3c 2 2 3 90 54 18 6 8

.
6c 2 4c 2 2c 2
90
15

2.

3.

2
d a d d c

4.

a.(b c) is maximum then cos = 1.

(S.D.)2 = 2
5.

y x 2 y 2 dx x x 2 y 2 dy xdx ydy

ydx xdy

xdx ydy
x2 y2

Integrating both sides, xy x 2 y 2 c , c 2

3
4

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