Scribd
Upload
138 views19 pages

Phase Equilibria

This document discusses various phase equilibria in multi-component systems. It describes two-component systems with vapor-liquid equilibria and partially miscible liquids that have upper and lower critical temperatures. Solid-liquid equilibria are also covered. The document concludes by discussing liquid-liquid extraction and the Nernst distribution law that relates solute concentrations in immiscible solvents.

Uploaded by

Alexis Pulhin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
138 views19 pages

Phase Equilibria

This document discusses various phase equilibria in multi-component systems. It describes two-component systems with vapor-liquid equilibria and partially miscible liquids that have upper and lower critical temperatures. Solid-liquid equilibria are also covered. The document concludes by discussing liquid-liquid extraction and the Nernst distribution law that relates solute concentrations in immiscible solvents.

Uploaded by

Alexis Pulhin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 19

PHASE EQUILIBRIA

One-Component System

Two-Component System

! "
%
"
##
! " ## %

## #

$
!

&

Two-Component System
vap o r
p ress ure

L IQU ID

P A+P B

P 0A

PB

VAPO R

1 .0
0

P0 B

PA

A
B
M ole fraction

0
1 .0

Two-Component System

Partially Miscible Liquids


Upper Critical Temperature

" #

$%

&

Partially Miscible Liquids


Lower Critical Temperature

'

$(

Partially Miscible Liquids


Upper and Lower Critical Temperature

$(

Partially Miscible Liquids

Partially Miscible Liquids

Solid-Liquid Equilibrium

Solid-Liquid Equilibrium

$(

$(

Liquid-Liquid Extraction
)
)
+

Nernst Distribution Law


%
)

(
)
)
,
'
#
#

&

)
,
)

You might also like