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NH H N: T (Min) C

The document provides details for two assignment problems related to kinetics and reactor design. The first problem involves the gas-phase reaction of nitrogen and hydrogen to produce ammonia. It asks the student to (1) construct a stoichiometric table, (2) calculate concentrations given a 60% conversion of hydrogen, and (3) write rate expressions for flow and batch systems. The second problem provides concentration data over time for a reaction in a constant volume batch reactor and asks the student to determine the reaction order and specific reaction rate.

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0% found this document useful (0 votes)
32 views

NH H N: T (Min) C

The document provides details for two assignment problems related to kinetics and reactor design. The first problem involves the gas-phase reaction of nitrogen and hydrogen to produce ammonia. It asks the student to (1) construct a stoichiometric table, (2) calculate concentrations given a 60% conversion of hydrogen, and (3) write rate expressions for flow and batch systems. The second problem provides concentration data over time for a reaction in a constant volume batch reactor and asks the student to determine the reaction order and specific reaction rate.

Uploaded by

PIratȅ Ilı
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Kinetics and Reactor Design (CHPE303)

Fall 2014-15
Assignment 2
Due 1/12/2014 (each day late, 10% is deducted)
1- The gas-phase reaction

1
3
N 2 H 2 NH 3
2
2
is to be carried out isothermally. The molar feed is 50% N2, at a pressure of 16.4 atm
and 227C.
(a)
(b)
(c)

Construct a complete stoichiometric table.


What are CA0, , and ? Calculate the concentration of ammonia and
hydrogen when the conversion of H2 is 60%.
Suppose by chance the reaction is elementary with kN2= 40 dm3/mol/s.
Write the rate of reaction solely as a function of conversion for (1) a flow
system and (2) a constant volume batch system.

2- The reaction

A BC
Was carried out in a constant volume batch reactor where the following
concentration measurements were recorded as a function of time.

t (min)
CA (mol/dm3)

0
2

5
1.6

9
1.35

15
1.1

22
0.87

30
0.70

40
0.53

50
0.35

Using differential and integral methods determine the reaction order and the
specific reaction rate, k.

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