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Virial Equation: P P R T DT C S S

1. The document discusses various equations of state that can be used to model the thermodynamic properties of fluids, including the van der Waals, Redlich-Kwong, Soave-Redlich-Kwong, and Peng-Robinson equations. 2. It presents the general form of cubic equations of state and defines parameters commonly used such as alpha, sigma, epsilon, and omega. 3. Correlations are shown for calculating the second virial coefficient and compressibility factor based on the Pitzer method.

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JassimMohamed
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30 views1 page

Virial Equation: P P R T DT C S S

1. The document discusses various equations of state that can be used to model the thermodynamic properties of fluids, including the van der Waals, Redlich-Kwong, Soave-Redlich-Kwong, and Peng-Robinson equations. 2. It presents the general form of cubic equations of state and defines parameters commonly used such as alpha, sigma, epsilon, and omega. 3. Correlations are shown for calculating the second virial coefficient and compressibility factor based on the Pitzer method.

Uploaded by

JassimMohamed
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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c

c r
P
T R T
T a
2 2
) (
) (
o
+ =
c
c
P
RT
b O =
2857 . 0
r
) T 1 (
c c
sat
Z V V

=
Virial equation


Generic cubic equation of state


Vaper vaper like srk
Pr


Liquid- liquid like


Pitzer Correlations for the compressibility factor

Pitzer correlations for the second Virial coefficient





Generalized correlations for liquid


EOS (T
r
) Z
c

VdW 1 0 0 1 / 8 27 / 64 3/ 8
RK

1 0 0.08664 0.42748 1 / 3
SRK
SRK
(T
r
:)* 1 0 0.08664 0.42748 1 / 3
PR
PR
(T
r
:)**

0.07779 0.45724 0.3074
2
V
C
V
B
1
T R
V P
Z + + = =
|
|
.
|

\
|
+ + =
2
m
m
m
V
C
V
B
1
P
T R
V
( )
( ) ( ) b V b V
T a
b V
T R
P
o c + +

=
( )
( ) ( ) | o | c
|
| |
+ +

+ =
Z Z
Z
q Z 1
( )
r
r
r
r
T
T
T R b
T a
q
T T R
P b
O
+
= = O = =
o
|
) (
,
P
( )( )
(

+
+ + + =
) (T a
P V P b T R
b V b V b V o c
( )( )
(

+
+ + + =
|
|
| o | c |
q
Z
Z Z Z
1
2
1

r
T
2 1+ 2 1
1 0
Z Z Z e + =
r
r
c
c
T
P
RT
BP
RT
BP
Z
|
|
.
|

\
|
+ = + = 1 1
r
r
r
r
T
P
B
T
P
B Z
1 0
1 e + + =
6 . 1
0
422 . 0
083 . 0
r
T
B =
2 . 4
1
172 . 0
139 . 0
r
T
B =
V
V
c
c
r
=

2
1
1 2
r
r
V V

=
}
+ =
T
T
i g
p
i g
o
i g
o
dT c H H
o
T
T
i g
p
i g
o
i g
P
P
R
T
dT
c S S
o
ln + =
}
}
+ + =
T
T
R i g
p
i g
o
o
H dT c H H
R
o
T
T
i g
p
i g
o
S
P
P
R
T
dT
c S S
o
+ + =
}
ln
( ) ( )
c
R
c
R
c
R
RT
H
RT
H
RT
H
1 0
e + =
( ) ( )
R
S
R
S
R
S
R R R 1 0
e + =
(

|
|
.
|

\
|
+ =
r
r
r
r r
c
R
dT
dB
T B
dT
dB
T B P
RT
H
1
1
0
0
e
|
|
.
|

\
|
+ =
r r
r
R
dT
dB
dT
dB
P
R
S
1 0
e
6 . 2
0
675 . 0
r r
T dT
dB
=
2 . 5
1
722 . 0
r r
T dT
dB
=
( ) ( ) ( )
o
o
o o
ig
P
T T
T
D
T
C
T
B
A dT
R
C

+ + + + + + =
} 2 2
2
15 . 913
15 . 308
1
3
1
2 t
t t t
I q
T d
T d
Z
RT
H
r
r
R
(

+ = 1
ln
) ( ln
1
o
I q
T d
T d
Z
R
S
r
r
R
ln
) ( ln
) ( ln
o
| + =
For
(

+
+

=
| c
| o
c o Z
Z
I ln
1
For =
Z
I
|
=

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