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    Aldehydes & Ketones

    Uploaded by

    Rahul Shivroop
    The document is a quiz on aldehydes and ketones containing multiple choice questions testing knowledge of reactions and properties. Some key points: 1) PCC cannot oxidize aldehydes to carboxylic acids because it decomposes upon formation of the aldehyde, losing its oxidizing power. 2) In a reaction involving bromination of a ketone, the organic product is the bromoketone. 3) In an aldol condensation reaction involving a ketone and base, the product is the β-hydroxy aldehyde.

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    © All Rights Reserved
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    Aldehydes & Ketones

    Uploaded by

    Rahul Shivroop
    35 views2 pages
    The document is a quiz on aldehydes and ketones containing multiple choice questions testing knowledge of reactions and properties. Some key points: 1) PCC cannot oxidize aldehydes to carboxylic acids because it decomposes upon formation of the aldehyde, losing its oxidizing power. 2) In a reaction involving bromination of a ketone, the organic product is the bromoketone. 3) In an aldol condensation reaction involving a ketone and base, the product is the β-hydroxy aldehyde.

    Original Description:

    worksheet for kvpy ak

    Original Title

    KVPY AK

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    The document is a quiz on aldehydes and ketones containing multiple choice questions testing knowledge of reactions and properties. Some key points: 1) PCC cannot oxidize aldehydes to carboxylic acids because it decomposes upon formation of the aldehyde, losing its oxidizing power. 2) In a reaction involving bromination of a ketone, the organic product is the bromoketone. 3) In an aldol condensation reaction involving a ketone and base, the product is the β-hydroxy aldehyde.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    35 views2 pages

    Aldehydes & Ketones

    Uploaded by

    Rahul Shivroop
    The document is a quiz on aldehydes and ketones containing multiple choice questions testing knowledge of reactions and properties. Some key points: 1) PCC cannot oxidize aldehydes to carboxylic acids because it decomposes upon formation of the aldehyde, losing its oxidizing power. 2) In a reaction involving bromination of a ketone, the organic product is the bromoketone. 3) In an aldol condensation reaction involving a ketone and base, the product is the β-hydroxy aldehyde.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    of 2

    Quiz

    Aldehydes & Ketones


    Name of the Student :_____________________ Maximum Marks : 40
    Bath Num!er :_____________________ Maximum "ime : #0 minutes
    1. PCC cant oxidise aldehyde into carboxylic acid because
    (A) it is a weak oxidant
    (B) Oxidation by PCC is carried out in nonaqueous solvent (C!Cl!) in which aldehyde cant exist as
    "e#diol.
    (C) PCC does not dissolve in solvent (C!Cl!) in the $resence o% aldehyde
    (&) PCC deco#$oses u$on %or#ation o% aldehyde and thus loses its oxidisin" $ower.
    !.
    P
    '"Br C
    (

    C
    (
    Br
    O
    )here the or"anic $roduct P is*
    (A)
    C
    (
    Br
    C
    (
    O'"Br
    (B)
    C
    (
    C
    (
    O
    (C)
    O
    C
    (
    C
    (
    (&)
    O
    C
    (
    C
    (
    (.
    + , O
    .) conc (
    + +

    &
    O
    &
    ( ! #oles)
    )here , and + are*
    (A) &
    O
    -
    O
    and
    O&
    &

    &
    (B)
    O
    -
    O
    and
    O
    &
    &
    &
    (C)
    O
    -
    O
    and
    O
    &

    &
    (&) &
    O
    -
    O
    and
    O
    &
    &
    &
    ..
    / P
    O


    C
    (
    CO
    O
    )here the $roduct P is*
    (A)
    O
    C
    (
    O
    (B)
    O
    C
    (
    O
    (C)
    O
    CO
    (&)
    O
    0.
    ) ulti#ate ( ,
    . !
    O . 1



    O
    C
    !
    C
    (
    O
    +
    1he $roduct , is*
    (A)
    O
    (B) C
    (
    O
    (C)
    O
    (&)
    O
    2.
    3 + ,
    .) conc ( O 4eO " 5 O
    !
    !
    (

    + +

    )here 3 is*
    (A)
    COO
    O
    (B)
    O
    (C)
    COO
    -
    O
    (&)
    O
    O
    6. 7n the Canni88aro reaction "iven below *
    Ph CO Ph C
    !
    O
    PhCOO
    the slowest ste$ is
    O


    (A) 1he attack o% O

    at the carbonyl "rou$.


    (B) 1he trans%er o% hydride to the carbonyl "rou$.
    (C) 1he abstraction o% $roton %ro# carboxylic acid.
    (&) 1he de$rotonation o% Ph 9 COO.
    :. )hich one o% the %ollowin" reactions can not be used %or the reduction o%
    C
    ;
    ;
    O
    C
    !
    ;
    ;
    (A) Cle##ensen reaction (B) )ol% 9 <ishner reaction
    (C) )urt8 reaction (&) 7 and red $hos$horous at !==
    =
    C.
    >. 1he canni88aro reaction o% PhCOCO %or#s the $roduct(s)
    (A) PhCOC!O ? PhCOCO!
    9
    (B)
    PhC@CO
    !
    9
    O
    (C)
    O PhCOC PhCO
    ! !
    +

    (&) both (A) and (C)


    1=. )hich o% the %ollowin" co#$ounds will under"o sel% aldol condensation in $resence o% a base.
    (A) !CAC@CO (B) C C@CO
    (C) PhCO (&) C(C!CO
    11. 7denti%y ,/ + B 3 in the %ollowin" sequence o% reactions and show the #echanis# %or %or#ation o% 3 %ro#
    +

    .
    <'nO . dil
    (,)
    .
    7O
    (+)

    O
    (3)
    1!. )rite the $roducts
    (A)
    conc. CaO
    ( !
    (C ) C CO
    (B)
    ! !
    C
    !
    C C CO =
    (C)
    ( !
    A"(C )
    (
    C C C CO
    +
    =
    (&)
    C C CO
    !
    5 Ci

    (D)
    O
    C
    !
    O
    C
    !
    C
    !
    O

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