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Acid Dew Point

The document calculates the acid dew point of SO3 at 1000°C given the partial pressures of SO3 and H2O. It determines the partial pressure of SO3 based on the partial pressures of O2 and SO2. It then lists the flue gas composition and calculates the SO3 concentration and acid dew point as 118.5°C, which is checked against the estimated 120°C.

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170 views3 pages

Acid Dew Point

The document calculates the acid dew point of SO3 at 1000°C given the partial pressures of SO3 and H2O. It determines the partial pressure of SO3 based on the partial pressures of O2 and SO2. It then lists the flue gas composition and calculates the SO3 concentration and acid dew point as 118.5°C, which is checked against the estimated 120°C.

Uploaded by

apminshull
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as XLS, PDF, TXT or read online on Scribd
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Calculates acid dew point of SO3 as function of partial pressures of SO3 and H2O

for temperature of 1000C (Max SO3 production). The partial pressure of SO3 is
caculated as function of partial pressures of O2 and SO2.

Flue Gas Composition


Component

Mol frac

CO2
H2O
N2
O2
SO2

0.1506524
0.0895448
0.7588626
0.0004179
5.22E-04

Calculated SO3
Input SO3

2.541E-05
1.815E-06

Acid dew point [C]

118.5

Check [C]

120.0

T
T*
ln Kp
Kp
pp SO3

705
0.978
0.86714
2.38009
2.5E-05

T dew

118.464

pp H20
68.054 mmHG
pp SO3 0.0014 mmHG
1000/Tdew2.5447
Tdew
392.98 K

T dew

120.0 C

Acid Dew Point Estimates. TEC/32/01 (31/07/03)

V4808

3%v O2
10%v O2

V4809

3%v O2
10%v O2

RLFS

3%v O2
10%v O2

max H2S [ppm]

92

Based on average composition Jan - June 2003

2645

Based on average composition Jan - June 2003

Acid dew point [C]


115
108

max H2S [ppm]


Acid dew point [C]
131
124

wt% Sulphur
Acid dew point [C]
134
127

1.00

wt% Sulphur
Acid dew point [C]
140
133

2.00

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