Cladding Technology
Cladding Technology
Cladding Technology
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CASTI HANDBOOK OF
CLADDING TECHNOLOGY
2nd Edition
Executive Editor
John E. Bringas, P.Eng.
ISBN 1-894038-30-4
Printed in Canada
iii
CASTI PUBLICATIONS
CASTI HANDBOOK SERIES
Volume 1 - CASTI Handbook of Cladding Technology
Volume 2 - CASTI Handbook of Stainless Steels and Nickel Alloys
Volume 3 - CASTI Handbook of Corrosion in Soils (to be released)
iv
IMPORTANT NOTICE
The material presented herein has been prepared for the general
information of the reader and should not be used or relied upon for
specific applications without first securing competent technical
advice. Nor should it be used as a replacement for current complete
engineering codes and standards. In fact, it is highly recommended
that the appropriate current engineering codes and standards be
reviewed in detail prior to any decision making.
While the material in this book was compiled with great effort and is
believed to be technically correct, the authors, CASTI Publishing Inc.
and its staff do not represent or warrant its suitability for any general
or specific use and assume no liability or responsibility of any kind in
connection with the information herein.
Nothing in this book shall be construed as a defense against any
alleged infringement of letters of patents, copyright, or trademark, or
as defense against liability for such infringement.
ix
PREFACE
Cladding technology refers to the application of a relatively thin layer
of an alloy (as the cladding) onto a substrate or backing material.
In many cases the cladding is selected for its resistance to corrosion.
A wide range of alloys can be clad, including stainless steels and
nickel base alloys to rare metals such as zirconium and tantalum.
The backing material is normally selected to meet the necessary
mechanical requirements (strength and toughness). The backing
material is often a grade of carbon or low alloy steel, other metals
may be used.
A key feature of clad products is that the backing material is often
significantly cheaper than the cladding alloy, so that clad products
can offer substantial cost savings over the use of solid alloy products.
The authors have been personally involved in the use of corrosionresistant alloy cladding of carbon steel for various applications in the
oil and gas industry for more than 10 years. This experience
prompted them to write this book covering wider aspects of clad
products including the different means of manufacturing them, their
properties, and their applications in various industries. The
substantial use of clad pipe in the oil and gas sector merits particular
mention, and so Chapter 9 of the book is devoted entirely to project
experience in that industry.
The principal units of measurements used are metric with imperial
conversions. Where appropriate, figures are expressed in nominal
imperial units with actual size metric conversion.
Alloys are identified principally by UNS numbers and abbreviated
terms are listed in the Appendix 1.
Liane Smith
Mario Celant
June1998
xi
TABLE OF CONTENTS
1. Introduction to Cladding Technology
Materials Selection Options for Corrosive Service
Dimensions of Clad Products
Economics of Clad Technology
Optimising the Corrosion Properties
Using Cladding Technology to Best Advantage
1
3
4
6
7
2. Clad Plate
Production Methods
Hot Roll Bonding
Backing Steel Types
Manufacturing Sequence
Optimizing Bonding
Heat Treatment
Inspection Requirements
Explosive Bonding
Weld Overlaying
9
9
10
12
16
19
22
23
29
3. Clad Pipes
Definitions
Longitudinally Welded Clad Pipe
Centricast Clad Pipe
Seamless Pipe Mill Clad Pipe
Explosively Bonded Clad Pipe
Lined Pipe
Thermo-Hydraulically Lined Pipe
Hydraulically Lined Pipe
Explosively Lined Pipe
33
34
38
43
48
50
51
53
55
4. Clad Bends
Manufacturing of Bends from Clad Pipe
Manufacturing of Bends from Lined Pipe
57
61
5. Clad Fittings
Clad Fittings Made by Weld Overlaying
Clad Fittings Made by Hot Isostatic Pressing
Clad Fittings Made from Clad Plate or Pipe
Clad Elbows
Clad Tees
Clad Manifolds
Clad Reducers and Caps
Clad Flanges and Valves
65
66
69
70
73
76
77
78
xii
6. Specification Requirements of Clad Products
Maximum Allowable Stress Values
Cladding Alloy
Backing Steel
Backing Steel Requirements for Application in
H2S Containing Environments
Mechanical Tests
Corrosion Tests
Demagnetising
Dimensions and Tolerances of Clad Pipe
Cladding and Wall Thickness
Diameter and Out of Roundness
Ultrasonic Inspection
81
82
83
84
85
87
90
90
90
92
93
95
95
96
100
101
101
102
105
106
107
109
111
112
112
113
117
121
123
124
127
129
134
134
135
143
143
146
xiii
8. Clad Product Applications
Cladding Technology in the Petrochemical Industry (Continued)
Cladding Alloy
147
Disbonding in Hot Hydrogen
148
Cladding Technology in the Chemical Industry
149
Backing Steel
150
Cladding Alloy
150
Cladding Technology in Chemical Tankers
153
Cladding Technology in Metal Purification
154
Cladding Technology in the Power Industry
154
Cladding Technology in Air Pollution Systems
158
Cladding Technology in Shipping Applications
163
Cladding Technology in the Pulp and Paper Industry
165
9. Clad Pipe Projects
ADMA OPCO - Um-Shaif - 1993
Agip UK - Thelma and South East Thelma - 1995
ARCO Alaska Inc. - Prudhoe Bay - 1991
ARCO - Thames Bacton - 1987
Asamera Oil - Corridor - 1996
BP International Ltd. - Ravenspurn to Cleeton - 1987
BP International Ltd. - Forties - 1987
BP International Ltd. - Miller - 1989
BP International Ltd. - Cyrus - 1995
Chevron - Ninian - 1992
Clyde Petroleum - P2/P6 - 1997
Louisiana Land and Exploration - Lost Cabin - 1991
Mobil - Arun Booster Gas Compression - 1993
Mobil - South Lho Sukon - 1996
Mobil - Mobil 823 - 1995
Mobil - Yellowhammer - 1994
Mobil - 869 Field - 1995
Mobil - Ras Laffan LNG Co. Ltd. - North Field - 1998
Nederlandse Aardolie Maatschappij, NAM
- Early Field Trails - 1974-1975
Nederlandse Aardolie Maatschappij, NAM
- Roswinkel, Zuidlaren - 1978
Nederlandse Aardolie Maatschappij, NAM
- Emmen - 1987-1989
Nederlandse Aardolie Maatschappij, NAM
- Twente, Schoonebeek - 1988
Nederlandse Aardolie Maatschappij, NAM
- Dalen 6 And Dalen 9 - 1988
Nederlandse Aardolie Maatschappij, NAM
- Grijpskerk - 1996
167
168
170
171
172
173
174
174
176
180
180
182
182
188
188
189
190
192
192
193
194
196
196
197
xiv
9. Clad Pipe Projects (Continued)
ONGC - South Bassein - (1988 and 1993)
Shell Offshore - Fairway - 1991
Shell Todd Oil Services - Maui 'B' to 'A' - 1991
Pipe Production
Laying the Line
Welding
Inspection
Statoil - sgaard - 1997
Texaco - Erskine - 1997
Total Oil Marine - Bruce - 1991
198
204
208
209
210
211
214
214
215
216
217
219
229
237
Appendix 5 Bibliography
243
253
Index
257
Chapter
1
INTRODUCTION TO
CLADDING TECHNOLOGY
Materials Selection Options for Corrosive Service
For many applications where a metallic material is needed, it is
normal to consider initially whether carbon or low alloy steels (total
alloying element content typically below 1% to 2%) would be suitable.
Such steels are cheap, have a wide range of mechanical properties to
suit various demands, and are readily available from many sources in
a wide range of product forms.
In aggressive environments, because of certain corrosive conditions, a
more highly alloyed material may be necessary or justified for
improved reliability and extended service life compared to basic steels.
Such alternative materials may include various grades of stainless
steels, nickel alloys, copper alloys, or titanium alloys depending upon
the environment. Since such materials would be selected to be
resistant to the environment in question, they may be referred to
generically as corrosion-resistant alloys or CRAs.
Any of these options would represent quite an increase in initial
installed cost per tonne compared to basic steels. Whilst such a shift in
materials selection may often be justified on a case-by-case basis
(particularly when the cumulative life cycle cost over the full service
life is considered), under many circumstances there is another option
to considerusing the selected CRA as a cladding or lining. The term
cladding technology is widely used generically to refer to both
cladding and lining options.
Chapter 1
Alloy UNS
410S S41008
C
max
0.08
S
max
1.00
Mn
max
1.00
304L
S30400
0.030
1.00
2.00
316L
S31603
0.030
1.00
2.00
321
S32100
0.08
1.00
2.00
317L
S31700
0.030
1.00
2.00
22Cr
S31803
0.030
2.00
904L N08904
0.020
0.70
2.00
926
N08926
0.020
1.00
2.00
825
N08825
0.025
0.50
1.00
625*
N06625
0.025
0.50
0.50
400
N04400
0.150
0.50
1.25
Cr
12.0
14.0
18.0
20.0
16.5
18.5
17.0
19.0
17.5
19.5
21.0
23.0
19.0
21.0
19.0
21.0
19.5
23.5
2.0
23.0
-
Ni
Mo
10.0
12.5
11.0
14.0
9.0
12.0
14.0
17.0
4.50
6.50
24.0
26.0
24.0
26.0
38.0
46.0
61.0
65.0
> 63.0
* 3,15 - 4,15 Nb
CASTI Handbook of Cladding Technology 2nd Edition
Cu
Fe
Ti
2.0
2.5
5x%C
0.70
3.0
4.0
2.50
4.50
4.0
5.0
6.0
7.0
2.5
3.5
8.0
10.0
-
1.0
2.0
0.5
1.5
1.5
3.0
28.0
34.0
bal.
<
3.0
1.0
2.5
0.6
1.2
< 0.4
Chapter 1
Chapter
2
CLAD PLATE
Production Methods
The total production of metallurgically bonded clad plate by various
methods is about 80,000 tonnes/year. There are three principal
methods of manufacturing clad plate:
hot roll bonding
explosive bonding
weld overlaying
The production approach varies within each of these methods
depending upon the selected grade of backing steel, the selected
corrosion-resistant alloy (CRA), and the specification requirements.
Different manufacturers also vary somewhat in the approach they
take. Selecting the most appropriate route for clad plate manufacture
depends upon quantity, thickness, and alloy type.
26
Clad Plate
Chapter 2
detonation front
explosive
frame
cladding metal
jet
backing metal
collision point
Chapter
3
CLAD PIPES
Definitions
The American Petroleum Institute API defines clad and lined steel
pipe in Section 2.1.a of API Specification 5LD as follows:
1. CLAD. Clad steel pipe is a bimetallic pipe composed of
an internal CRA layer metallurgically bonded to the base
metal.
2. LINED. Lined pipe is pipe in which a CRA layer is
affixed inside the carbon steel pipe, full length, by
expanding the liner and/or shrinking the pipe or by other
applicable processes. The CRA layer and the carbon steel
pipe shall be manufactured in accordance with Spec. 5LC
and Spec. 5L, respectively, except as may be otherwise
specified herein.
Normally, the word clad is used generally to mean both products
except where a specific distinction is made.
Generally speaking, the CRA layer is inside the pipe as defined above
but externally clad pipe is occasionally made for specific applications
(e.g., nickel-copper UNS N04400 clad pipe for riser splash zone
protection as discussed further under Line Pipe and Manifolds
(Chapter 8).
34
Clad Pipes
Chapter 3
Chapter
4
CLAD BENDS
Manufacturing of Bends from Clad Pipe
Manufacturing of clad bends is usually carried out using induction
heating of metallurgically bonded clad pipe. The clad pipe is put into
the bending machine: one end of the pipe is held with the clamp at the
top of the arm while the other end is fixed in a position with the tail
stock. An induction heating coil heats a limited narrow portion of the
pipe as it is pushed forward through this region. The pipe is
continuously heated and bent around the centre of gyration of the arm
until the given angle of bend is reached (Figure 4.1). Some bending
equipment is capable of producing multiple bends in pipe which may
help reduce the number of welds in piping systems (Figure 4.2).
It is preferable if the bending machines can induction heat the
tangent portions of the bend to avoid heat affected zones after
bending. Some machines have such continuous heat treat facilities
over the bent portion and also the tangents with facilities for internal
and external water quenching if required. Otherwise, bends may be
furnace heat treated. Figure 4.3 shows a number of clad bends coming
out of a furnace after heat treatment. If bends come from TMCP steel,
tempering should be avoided as this may cause a loss of strength.
Careful qualification of the bending and heat treatment process is
necessary in all cases.
Chapter 4
Clad Bends
61
Bends and elbows (down to 1.5 DR) can also be made using the
mandrel bending process (pushing the pipe over a bend former called
a mandrel) from 12.5-1219 mm (0.5-48 inch), and even larger
diameters up to 2540 mm (100 inch), with good dimensional tolerances
(see Clad Elbows in Chapter 5).
Bends have been made using the cold forming method (flexible
mandrel process), from seamless or welded metallurgically bonded
clad pipes. Although work hardening will occur, the forming
equipment is high powered and strong enough to compensate for the
increase in yield strength with plastic deformation. After bending,
final heat treatment (usually QT), if required by the specifications,
can be carried out.
Chapter
5
CLAD FITTINGS
Whilst there are many manufacturers of solid alloy fittings, there are
relatively few with wide experience producing clad fittings. This may
explain why solid alloy fittings have sometimes been used to complete
a clad system. In other cases availability or cost factors may lead to
the selection of solid alloy fittings. Furthermore, certain design codes
may favour solid alloys over clad steel because of higher allowable
stresses. Essentially each project has to be considered separately to
decide whether clad or solid fittings will be the most appropriate.
In spite of the relatively limited use of clad fittings to date, several
manufacturers are now capable of producing all the items necessary to
fulfill the needs of typical processing systems.
All types of fittings are available with internal cladding including
elbows, bends, tees, manifolds, reducers, eccentrics, and caps.
Manufacturing methods include:
weld overlaying
hot isostatic pressing (HIP)
manufacturing from clad plate or pipe.
Chapter
6
SPECIFICATION REQUIREMENTS
OF CLAD PRODUCTS
This chapter is not intended to give a rigorous breakdown of clad
product specifications but simply to comment on a few aspects.
Typical roll bonded clad plate production specifications are ASTM
A 264 (Stainless chromium-nickel steel clad plate, sheet and strip),
ASTM A 265 (Nickel and nickel-base alloy clad steel plate), and
JIS G 3602 (Nickel and nickel alloy clad steels).
There is an API specification, API 5LD, for CRA Clad or Lined Steel
Pipe.
82
Chapter 6
Cladding Alloy
The specifications for clad plate and clad pipe are limited to a small
selection of cladding alloys but with the option for purchaser and
manufacturer to agree on other grades or modified compositions
between. Thus, in principal, any cladding alloy may be selected whilst
in practice there are technical and economic limitations. Purchasers
may therefore find that what appears to be a cheaper alloy selection
may result in a more costly clad pipe because of the production
difficulties in heat treating certain alloys and optimising backing steel
toughness while achieving good corrosion resistance of the cladding.
90
Chapter 6
Demagnetising
Using magnetic grips to hold clad plates or pipes at various stages of
manufacturing and transportation can result in residual magnetism
which can interfere with welding by causing arc blow. Residual
magnetism may also arise form electromagnetic inspection in the mill.
Demagnetising of products at the mill is often requested in purchase
specifications but this can be a waste of time since they may remagnetise in transit. In the case of clad pipes, re-magnetising arises
because of pipe being knocked in transit or even by being stored in a
North-South orientation. In many cases pipes have had to be demagnetised on site immediately before welding to avoid arc blow
problems during welding.
Chapter
7
WELDING CLAD PRODUCTS
The key factor which has to be considered in welding clad products is
maintaining the corrosion resistance of the inner cladding layer in
and around the weld zone. This has an impact on all aspects of the
welding procedure including the type of weld preparation, the choice
of welding process, the filler material, the shielding gas, and the heat
input.
Chapter 7
97
Thickness (mm)
up to 15
(")
65 o 5 o
1.5
65o 5o
1.5
over 15 up to 22
(" ~ ")
90o 5 o
0~1
a
2.0
65 o 5 o
over 22 up to 38
(" ~ 1")
b'
2~3
2.0
60 o 5 o
0~1
15o 5 o
over 38
(1")
a:b = 1:3
2.0
82R
82R
2.0
15 o 5 o
0~1
Cladding ratio of
over 20%
In case of
difficulty at edge
preparation
min. 5
min. 5
min. 5
min. 5
Chapter
8
CLAD PRODUCT APPLICATIONS
Cladding Technology in the Oil & Gas Industry
Clad products have been used extensively in the oil and gas industry
to counteract corrosive conditions. Major applications have been in the
form of clad pipes, vessels, and heat exchangers but there are also
other components that are routinely supplied in clad form such as
wellheads and other valves.
Clad products have to compete against carbon steel and solid CRAs.
Where the duration of a project is short, the amount of corrosion
arising on carbon steel may be tolerated by allowing extra wall
thickness, or corrosion allowance, which is consumed during the
project. Chemicals (corrosion inhibitors) may be injected into the
environment to reduce the corrosion rate.
In some cases, however, the anticipated rate of corrosion may be too
high or the life of the project too long to simply allow the corrosion to
take place. In such cases, CRAs may be selected which will suffer
negligible corrosion over the duration of the project. The choice of solid
or clad is then a matter of which is more economical, but clad steel
may offer some specific advantages in this industry in some cases.
One example is offshore projects developed by means of a fixed or
floating structure. In such cases it is beneficial to save weight in the
topside facilities to reduce the cost of the support structure. The use
of backing steels with higher strength than solid CRAs then allows a
reduction in wall thickness of the topside facilities (vessels and piping,
etc.) which reduces the weight of those items with corresponding
economic benefits for the structure.
CASTI Handbook of Cladding Technology 2nd Edition
Chapter 8
153
154
Chapter 8
Chapter
9
CLAD PIPE PROJECTS
The oil and gas industry has made the most extensive use of clad pipe
of any industrial sector. The clad pipe is most often selected for the
flowlines, i.e. the pipe carrying the untreated produced fluids from the
wellhead to the treatment facilities.
An overview of the types of clad pipe products and the materials
selected was given in Chapter 8 (Line Pipe and Manifolds). The
present chapter describes some individual projects or experiences of
particular operators with clad pipe installations. The aim is to
highlight key issues for selecting a particular pipe material, e.g., the
nature of the cladding, the way in which the pipe was welded or laid,
and any operating experience to guide future potential users.
The projects are described in alphabetical order of the operating
company with the year of installation.
168
Chapter 9
Chapter 9
183
The original piping in the plant was centricast 13% Cr but the gradual
drop in pressure of the field necessitated an increase in the pipe
diameter and 13% Cr piping was not available in 762 mm (30 inch)
diameter required. Hence clad pipe was selected. The installation of
762 mm (30 inch) OD clad piping was cost effective since it meant that
there was no need to install compressor stations in the manifold to
carry the gas to the treatment units (Akabane, 1994).
This field development consists of 4 well clusters each with two
headers requiring a total of 10.2 km (6.3 miles) of 762 mm (30 inch)
diameter, 12.7 mm (0.5 inch) wall thickness (API 5L X60) with 2 mm
(0.08 inch) UNS N08825 cladding pipe and some 219 mm (8 inch)
diameter clad pipe (Figure 9.6). The pipes were supplied by JSW as
were 64 tees (762 x 219 mm, 30 x 8 inch). The clad lines collect gas
and condensate which are then dehydrated.
The gas is compressed to an LNG plant 20 miles away through a
1066.8 mm (42 inch) pipeline and the condensates are transported in a
406 mm (16 inch) line (Figure 9.7).
The backing steel for the clad pipe was not specified to be SWC
resistant, but the welds were limited to 250 HV maximum hardness
since the conditions are judged to be slightly sour. All the pipe ends
were bevelled by the manufacturer (JSW) and supplied with end
protectors. Considerable planning went into the design of the cluster
layout to suit joint lengths so that only 44 field cuts and bevels were
required out of about 1,000 joint lengths supplied. The average time
per cut and bevel was 6.5 hours.
Some solid UNS N08825 flanges and 114.3 mm (4 inch) and
60.3 mm (2 inch) weld-o-lets were also used in the project.
Appendix
1
ABBREVIATED TERMS
AAI
AISI
ANSI
API
ASME
ASTM
BS
CII
CITHP
CLI
CPT
CRA
CRC
CTOD
DHF
DIN
DR
DWTT
EFC
ENP
ESW
FAC
FCAW
FGD
GMAW
GTAW
HAZ
HIP
218
Abbreviated Terms
HSLA
ID
JSW
LIDB
LNG
NACE
NAM
NDE
NKK
NSC
OCTG
OD
OOR
PASSO
PGMAW
PGTAW
PQR
PTA
PWHT
PWR
QT
RT
SAW
SCC
SDH
SMAW
SMYS
SSC
SSCV
SWC
TDS
TMCP
UNS
UO
UOE
UT
V-A
Appendix 1
Appendix
2
HARDNESS CONVERSION NUMBERS
Appendix 2
220
Vickers
HV
940
900
865
832
64
800
63
772
62
Brinell
3000 kgf
10 mm ball
HB
------739d
Knoop
500 gf
HK
920
895
870
846
Rockwell A
60 kgf
Diamond
HRA
85.6
85.0
84.5
83.9
Approximate
Tensile
Strength
ksi (MPa)
---------
722d
822
83.4
91.8
81.1
71.0
---
706d
799
82.8
91.4
80.1
69.9
---
746
688d
776
82.3
91.1
79.3
68.8
---
61
720
670d
754
81.8
90.7
78.4
67.7
---
60
697
654d
732
81.2
90.2
77.5
66.6
---
59
674
634d
710
80.7
89.8
76.6
65.5
351 (2420)
58
57
56
55
54
53
52
51
50
49
48
47
653
633
613
595
577
560
544
528
513
498
484
471
615
595
577
560
543
525
512
496
482
468
455
442
690
670
650
630
612
594
576
558
542
526
510
495
80.1
79.6
79.0
78.5
78.0
77.4
76.8
76.3
75.9
75.2
74.7
74.1
89.3
88.9
88.3
87.9
87.4
86.9
86.4
85.9
85.5
85.0
84.5
83.9
75.7
74.8
73.9
73.0
72.0
71.2
70.2
69.4
68.5
67.6
66.7
65.8
64.3
63.2
62.0
60.9
59.8
58.6
57.4
56.1
55.0
53.8
52.5
51.4
338 (2330)
325 (2240)
313 (2160)
301 (2070)
292 (2010)
283 (1950)
273 (1880)
264 (1820)
255 (1760)
246 (1700)
238 (1640)
229 (1580)
Appendix 2
221
Vickers
HV
458
446
434
423
412
402
392
382
372
363
354
345
336
327
318
310
302
294
286
279
272
266
260
Brinell
3000 kgf
10 mm ball
HB
432
421
409
400
390
381
371
362
353
344
336
327
319
311
301
294
286
279
271
264
258
253
247
Knoop
500 gf
HK
480
466
452
438
426
414
402
391
380
370
360
351
342
334
326
318
311
304
297
290
284
278
272
Rockwell A
60 kgf
Diamond
HRA
73.6
73.1
72.5
72.0
71.5
70.9
70.4
69.9
69.4
68.9
68.4
67.9
67.4
66.8
66.3
65.8
65.3
64.6
64.3
63.8
63.3
62.8
62.4
Approximate
Tensile
Strength
ksi (MPa)
221 (1520)
215 (1480)
208 (1430)
201 (1390)
194 (1340)
188 (1300)
182 (1250)
177 (1220)
171 (1180)
166 (1140)
161 (1110)
156 (1080)
152 (1050)
149 (1030)
146 (1010)
141 (970)
138 (950)
135 (930)
131 (900)
128 (880)
125 (860)
123 (850)
119 (820)
Appendix
3
UNIT CONVERSIONS
Appendix 3
METRIC CONVERSION FACTORS
To Convert From
To
Angle
degree
rad
Area
in.2
mm2
in.2
cm2
in.2
m2
2
ft
m2
Bending moment or torque
lbf - in.
N-m
lbf - ft
N-m
kgf - m
N-m
ozf - in.
N-m
Bending moment or torque per unit length
lbf - in./in.
N - m/m
lbf - ft/in.
N - m/m
Corrosion rate
mils/yr
mm/yr
mils/yr
/yr
Current density
A/in.2
A/cm2
2
A/in.
A/mm2
A/ft2
A/m2
Multiply By
1.745 329 E -02
6.451 600
6.451 600
6.451 600
9.290 304
E + 02
E + 00
E - 04
E - 02
1.129 848
1.355 818
9.806 650
7.061 552
E - 01
E + 00
E + 00
E - 03
4.448 222 E + 00
5.337 866 E + 01
2.540 000 E - 02
2.540 000 E + 01
1.550 003 E - 01
1.550 003 E - 03
1.076 400 E + 01
To Convert From
To
Mass per unit time
lb/h
kg/s
lb/min
kg/s
lb/s
kg/s
Mass per unit volume (includes density)
g/cm3
kg/m3
3
lb/ft
g/cm3
3
lb/ft
kg/m3
lb/in.3
g/cm3
3
lb/in.
kg/m3
Power
Btu/s
kW
Btu/min
kW
Btu/h
W
erg/s
W
ft - lbf/s
W
ft - lbf/min
W
ft - lbf/h
W
hp (550 ft - lbf/s)
kW
hp (electric)
kW
Power density
W/in.2
W/m2
Unit Conversions
230
Multiply By
1.259 979 E - 04
7.559 873 E - 03
4.535 924 E - 01
1.000 000
1.601 846
1.601 846
2.767 990
2.767 990
E + 03
E - 02
E + 01
E + 01
E + 04
1.055 056
1.758 426
2.928 751
1.000 000
1.355 818
2.259 697
3.766 161
7.456 999
7.460 000
E + 00
E - 02
E - 01
E - 07
E + 00
E - 02
E - 04
E - 01
E - 01
1.550 003 E + 03
Appendix 3
THE GREEK ALPHABET
, - Alpha
, - Beta
, - Gamma
, - Delta
, - Epsilon
, - Zeta
, - Eta
, - Theta
, - Iota
, - Kappa
, - Lambda
, - Mu
, - Nu
, - Xi
, - Omicron
, - Pi
Unit Conversions
235
, - Rho
, - Sigma
, - Tau
, - Upsilon
, - Phi
, - Chi
, - Psi
, - Omega
Appendix
4
PIPE DIMENSIONS
Appendix 4
DIMENSIONS OF WELDED AND SEAMLESS PIPEa
Nominal
Outside
Pipe Size
Diameter
Schedule
Schedule
(in.)
(in.)
5S
10S
1/8
0.405
--0.049
1/4
0.540
--0.065
3/8
0.675
--0.065
1/2
0.840
0.065
0.083
3/4
1.050
0.065
0.083
1
1.315
0.065
0.109
1 1/4
1.660
0.065
0.109
1 1/2
1.900
0.065
0.109
2
2.375
0.065
0.109
2 1/2
2.875
0.083
0.120
3
3.5
0.083
0.120
3 1/2
4.0
0.083
0.120
4
4.5
0.083
0.120
5
5.563
0.109
0.134
6
6.625
0.109
0.134
8
8.625
0.109
0.148
10
10.75
0.134
0.165
12
12.75
0.156
0.180
14 O.D.
14.0
0.156
0.188
16 O.D.
16.0
0.165
0.188
18 O.D.
18.0
0.165
0.188
20 O.D.
20.0
0.188
0.218
22 O.D.
22.0
0.188
0.218
Pipe Dimensions
Schedule
Standard
0.068
0.088
0.091
0.109
0.113
0.133
0.140
0.145
0.154
0.203
0.216
0.226
0.237
0.258
0.280
0.322
0.365
0.375
0.375
0.375
0,375
0.375
0.375
238
Schedule
40
0.068
0.088
0.091
0.109
0.113
0.133
0.140
0.145
0.154
0.203
0.216
0.226
0.237
0.258
0.280
0.322
0.365
0.406
0.438
0.500
0.562
0.594
---
Appendix 4
DIMENSIONS OF WELDED AND SEAMLESS PIPEa (Continued)
Nominal
Outside
Pipe Size
Diameter
Schedule
Schedule
(in.)
(in.)
5S
10S
24 O.D.
24.0
0.218
0.250
26 O.D.
26.0
----28 O.D.
28.0
----30 O.D.
30.0
0.250
0.312
32 O.D.
32.0
----34 O.D.
34.0
----36 O.D.
36.0
----42 O.D.
42.0
----a. See next page for heavier wall thicknesses
Pipe Dimensions
Schedule
Standard
0.375
0.375
0.375
0.375
0.375
0.375
0.375
0.375
239
Schedule
40
0.688
------0.688
0.688
0.750
---
Appendix
5
BIBLIOGRAPHY
The following is an alphabetical list of sources consulted in preparing
this book.
Akabane, H. Mobil Arun Field Debottlenecking, 2nd International
Seminar on Clad Engineering, Houston, May 6th, 1994.
ANSI/ASME B16.9 Factory Made Wrought Steel Buttwelding Fittings.
ANSI/ASME B31.3 Process Piping.
API Specification for Corrosion Resistant Alloy Line Pipe (Spec. 5LC).
API Specification for CRA Clad or Lined Steel Pipe (Spec. 5LD).
API Specification for Line Pipe (Spec. 5L).
API 1104 Welding of Pipelines and Related Facilities.
ASME B31.3 Chemical Plant and Petroleum Refinery Piping.
ASME Section VIII Pressure Vessels.
ASTM A204 Specification for Pressure Vessel Plates, Alloy Steel,
Molybdenum.
ASTM A262Practices for Detecting Susceptibility to Intergranular
Attack in Austenitic Stainless Steels.
244
Bibliography
Appendix 5
ASTM A263 Specification for Corrosion-Resisting Chromium SteelClad Plate, Sheet, and Strip.
ASTM A264 Specification for Stainless Chromium-Nickel Steel Clad
Plate, Sheet, and Strip.
ASTM A265 Standard Specification for Nickel and Nickel-Base Alloy
Clad Steel Plate.
ASTM A387 Specification for Pressure Vessel Plates, Alloy Steel,
Chromium-Molybdenum.
ASTM A516 Standard Specification for Pressure Vessel Plates,
Carbon Steel, for Moderate and Lower-Temperature Service.
ASTM A533 Standard Specification for Pressure Vessel Plates, Alloy
Steel, Quenched and Tempered, Manganese-Molybdenum and
Manganese-Molybdenum-Nickel.
ASTM A578 Standard Specification for Straight-Beam Ultrasonic
Examination of Plain and Clad Steel Plates for Special Applications.
ASTM G28 Test Methods of Detecting Susceptibility to Intergranular
Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys.
ASTM G39 Practice for Preparation and Use of Bent-Beam StressCorrosion Test Specimens.
ASTM G48 Test Method for Pitting and Crevice Corrosion Resistance
of Stainless Steels and Related Alloys by Use of Ferric Chloride
Solution.
ASTM G146 Practice for Evaluation of Disbonding of Bimetalic
Stainless Alloy/Steel Plate for use in High-Pressure, HighTemperature Refinery Hydrogen Service.
Avery, R.E. and Schillmoller, C.M. Development of Mechanized Field
Girth Welding of High Alloy Corrosion Resistant Pipeline Materials,
NiDI Technical series N 10061, 1991.
CASTI Handbook of Cladding Technology 2nd Edition
Appendix 5
Bibliography
245
246
Bibliography
Appendix 5
Breinan, E.M., Kear, B.H. and Banas, C.M. Physics Today, November
1976, Vol. 44, Issue 23.
BS 1501, Steels for Fired and Unfired Pressure Vessels: Plates,
British Standards Institute.
BS 4515, Process of Welding of Steel Pipelines on Land and Offshore,
British Standards Institute.
BS 5500, Specification for Unfired Pressure Vessels, British
Standards Institute.
Butler, P. et al., Welding the Maui A-B Pipeline, Welding Journal,
Nov. 1993, pp. 31-38.
Calvarano, M., Fassina, P. and Ghielmetti, A. A Review of Cost
Effective Alternatives for Sealines in Marginal Field with Corrosive
Fluids, OMC - Offshore Mediterranean Conference, 1995.
Chakravarti, B. and Dobis, J. Plant Maintenance Repairs Utilizing
Clad Piping Spools to Improve Reliability, Stainless Steel World,
Jan./Feb. 1997, Vol. 9, Issue 1, p.39.
Clay, K. Use of Cladding Materials in the Power Generation
Industry, Stainless Steel World, Oct. 1996, Vol. 8, Issue 8, p. 32-35.
Colwell, J.A., Martin, C.J. and Mack, R.D. Evaluation of Full Scale
Sections of Bimetallic Tubing in Simulated Production
Environments, Corrosion, 45 (5) 1989, p. 429.
Craig, B.D. Field Experience with Alloy Clad API Grade L-80
Tubing, Materials Performance, 25 (6) 1986 p.48.
Craig, B.D., Corrosion Testing of Clad and Lined Bends, 2nd
International Seminar on Clad Engineering, Houston, May 6th, 1994.
Currie, D.M. Yellowhammer Project, 2nd International Seminar on
Clad Engineering, Houston, May 6th, 1994.
Appendix
6
LIST OF FIGURES
AND CONTRIBUTORS
Figure No.
Contributor(s)
Front cover
Figure 1.2
Figure 2.1
Figure 2.2
Figure 2.3
Figure 2.4
Figure 2.5
Figure 2.6
Figure 2.7
Figure 2.8
Figure 2.9
Figure 2.10
Figure 2.11
Figure 2.12
Figure 2.13
Figure 2.15
Figure 3.1
Figure 3.2
Figure 3.3
Figure 3.4
Figure 3.5
Figure 3.6
Figure 3.7
Figure 3.8
254
Figure 3.9
Figure 3.10
Figure 3.11
Figure 3.12
Figure 3.13
Figure 4.1
Figure 4.2
Figure 4.3
Figure 5.1
Figure 5.2
Figure 5.3
Figure 5.4
Figure 5.5
Figure 5.6
Figure 5.7
Figure 5.8
Figure 5.9
Figure 5.10
Figure 5.11
Figure 5.12
Figure 5.13
Figure 5.14
Figure 5.15
Figure 5.16
Figure 5.17
Figure 6.2
Figure 7.1
Figure 7.2
Figure 7.3
Figure 7.5
Figure 7.6
Figure 7.7
Figure 7.8
Figure 7.9
Figure 8.1
Figure 8.2
Figure 8.3
Figure 8.4
Figure 8.5
Appendix 6
Wyman-Gordon Ltd.
Wyman-Gordon Ltd.
Tubacex
Nippon Steel Corporation
H. Butting GmbH & Co. and UPL
Dai-Ichi High Frequency Co. Ltd.
Dai-Ichi High Frequency Co. Ltd.
Kubota Corporation
Not required
Tecphy
Tecphy
Kubota Corporation
Coprosider S.p.A
Coprosider S.p.A
Coprosider S.p.A
Coprosider S.p.A
Coprosider S.p.A
Coprosider S.p.A
Coprosider S.p.A
Kubota Corporation
Scomark Engineering Ltd.
Dynamic Materials Corporation
Scomark Engineering Ltd.
ABB Vetco Grey UK Ltd.
Scomark Engineering Ltd.
NKK Corporation
The Japan Steel Works Ltd.
The Japan Steel Works Ltd.
Nobelclad
Kubota Corporation
Saipem
Allseas Engineering B.V.
Coflexip Stena Offshore Ltd.
Rockwater Ltd.
Nippon Steel Corporation
Forth Tool and Valve Ltd.
Strachan and Henshaw Ltd. & Borsig Valves of Berlin
Creusot-Loire Industrie
Soudometal and NEI International Combustion Ltd.
Appendix 6
Figure 8.6
Figure 8.7
Figure 8.8
Figure 8.15
Figure 8.16
Figure 8.17
Figure 8.18
Figure 8.19
Figure 8.20
Figure 8.21
Figure 8.22
Figure 8.23
Figure 8.24
Figure 8.25
Figure 8.26
Figure 8.27
Figure 8.28
Figure 9.1
Figure 9.2
Figure 9.3
Figure 9.4
Figure 9.5
Figure 9.6
Figure 9.7
Figure 9.8
255
Verbundmetalle GmbH
Head Robinson Engineering Ltd.
NEI International Combustion Ltd.
Scomark Engineering Ltd.
Kubota Corporation and Highland Fabricators
Kubota Corporation and Highland Fabricators
Klad Inc.
Creusot-Loire Industrie
Nobelclad
Nobelclad
Nobelclad
Klad Inc.
VEAG Kraftwerk
W.H.D. Plant, Edenbridge Metals Ltd.
NiDI and W.H.D. Plant, Edenbridge Metals Ltd.
NiDI and W.H.D. Plant, Edenbridge Metals Ltd.
W.H.D. Plant, Edenbridge Metals Ltd.
Scomark Engineering Ltd.
BP Exploration Operating Company Ltd.
Rockwater Ltd. and UPL
Rockwater Ltd.
Rockwater Ltd.
Mobil Oil Indonesia Inc.
The Japan Steel Works Ltd.
CRC- Evans Pipeline International, Inc.
INDEX
A
Absorber, 158-163
Allseas, 115-116
Aluminium, 164
ASTM A 262, 61, 87-88, 197, 199
ASTM G 48, 61, 87-89, 115, 180, 199, 212
Autoclaves, 88, 154
B
Batten, 97-98
Black Liquor, 165
C
Casting Factor, 40
Centrifugal Casting, 34, 38-40
Chimney, 158
Clad Bends
Manufacturing of Bends from Clad Pipe, 57-61
Manufacturing of Bends from Lined Pipe, 50, 61-63
Clad Fittings
Clad Elbows, 70-73
Clad Fittings Made by Weld Overlaying, 65-66
Clad Fittings Made by Hot Isostatic Pressing, 66-69
Clad Fittings Made from Clad Plate or Pipe, 69-70
Clad Flanges and Valves, 78-80
Clad Manifolds, 76-77
Clad Reducers and Caps, 77-78
Clad Tees, 73-75
CASTI Handbook of Cladding Technology - 2nd Edition
258
Index
Clad Pipes
Centricast Clad Pipe, 38-43
Definitions, 33-34
Explosively Bonded Clad Pipe, 48-50
Lined Pipe, 50-56
Explosively Lined Pipe, 55-56
Hydraulically Lined Pipe, 53-55
Thermo-Hydraulically Lined Pipe, 51-53
Longitudinally Welded Clad Pipe, 34-38
Seamless Pipe Mill Clad Pipe, 43-48
Clad Plate
Backing Steel Types, 10-11
Explosive Bonding, 23-28
Heat Treatment, 19-22
Hot Roll Bonding, 9-10
Inspection Requirements, 22-23
Manufacturing Sequence, 11-16
Optimising Bonding, 16-19
Production Methods, 9
Weld Overlaying, 29-32
Clad Product, Applications
Cladding Technology in Air Pollution Systems, 157-162
Cladding Technology in the Oil & Gas Industry, 123-124
Clad Production Tubing, 124-127
Line Pipe and Manifolds, 135-142
Valves, Pumps, and Joints, 127-129
Vessels and Heat Exchangers, 129-135
Backing Steel, 134
Cladding Alloy, 134-135
Cladding Technology in the Chemical Industry, 149-153
Backing Steel, 150
Cladding Alloy, 150-153
Cladding Technology in Chemical Tankers, 153
Cladding Technology in Metal Purification, 154
Cladding Technology in the Petrochemical Industry, 142-149
Applications, 142-146
Backing Steel, 146
Cladding Alloy, 147-148
Disbonding on Hot Hydrogen, 148-149
Cladding Technology in the Power Industry, 154-157
Cladding Technology in the Pulp and Paper Industry, 165
Cladding Technology in Shipping Applications, 163-164
Index
259
260
Index
Index
261
D
Digester, 165
Drop Weight Tear Test (DWTT), 21, 83, 198
Duplex Stainless Steel, 20, 28, 54, 110-111, 125, 153, 154, 165, 168169, 173, 176, 181, 197
E
Extrusion, 43-46, 75, 90, 180, 206
F
Flux Cored Arc Welding (FCAW), see Welding Processes
G
Gas Tungsten Arc Welding (GTAW), see Welding Processes
H
Hastelloy, 18, 150
Heat Exchanger, 123, 129, 131-135, 143, 146-147, 151-152, 156,
204-205
Hot Hydrogen, 87, 146, 148-149
Hot Isostatic Pressing (HIP), 65, 66-69, 75, 77-78, 189
Hydrogen Disbonding, 87, 127
Hydrometallurgy, 154
I
Inconel, 150, 193
262
Index
J
Japan Steel Works (JSW), 171, 173-174, 183, 185, 188, 192, 200,
209-211, 216
Joint
Alignment, 185
Design, Clad Vessels, 96-100
J-Bevel, 178
J-Preparation, 103
Line, 12
Misalignment, 102
Types
Swivel, 129
Transition, 164
Universal, 129
K
Kawasaki Heavy Industries (KHI), 124, 193
Kiln, 154
L
Liners, see also Clad Pipes
API 5LD, 33
Bends, 61-63, 207
Buckling, 51, 61, 63, 207
Collapse, 50-51
Fatigue, 119-120
Incomplete Penetration, 190
Inconel 82, 192
Inspection, 56, 205
Repairs, 112-113, 208
Seal Welding, 55, 169, 190-191, 193
Tube Liner, 163
UNS N08825, 54, 169, 190-191, 214
UNS S31600, 193-194
Weld Preparation, 104
Liquation Cracking, see Welding Processes, GTAW
Index
263
M
Magnetic, 23, 89, 105, 110, 115, 193, 213
Magnetic Particle, 40, 59
Mooring Buoys, 129
N
NACE TM0177, 87-88, 199
Nippon Steel Corporation (NSC), 21, 118, 170, 182, 189, 191, 193, 205
NKK Corporation, 198, 206
Nuclear Plant, 156
O
Oxidation, 12, 35, 106, 111, 158, 181, 186, 195, 197
P
Plug Mill, 43-44
Polythionic Acid, 147-148
Post Weld Heat Treatment (PWHT), 83, 175
Processo Arcos Saipem Saldatura Orbitale (PASSO), see Welding
Processeses
264
Index
R
Radiographic Testing, 195, 213
Recrystallization, 20-21
Reel Laying, 118-119
Residual Magnetism, 89, 105, 110, 195, 199-200, 202, 213
Rockwater, 119, 169, 177-178
S
Saipem, 105, 113, 172, 192, 199-201
Sandwich, 12-14, 16, 19, 21-22
Scrubber, 100, 158, 161-162
Sensitisation, 62
Separator, 129-131, 145, 156-157
Shielded Metal Arc Welding (SMAW), see Welding Processes
Slurry, 158
Stress Corrosion Cracking (SCC), 62, 144-145, 147, 151-153
Chloride Stress Corrosion Cracking (CSCC), 144, 148
Stepwise Cracking (SWC), 84, 175
Sulphide Stress Corrosion Cracking (SSCC), 84
Submerged Arc Welding (SAW), see Welding Processes
T
Tantalum, 28
Titanium, 1-2, 10, 28, 43, 96-99, 132, 135, 147-148, 150-154, 158,
164-165
Index
265
Tolerances
Backing Steel, 83
Bends, 60-61
Bend Angle, 60
Centricast Clad pipe, 40, 42, 174
Clad pipe, 90-93, 208
Wall Thickness, 90-92, 197
Diameter, 92
Out-of-Roundness, 92-93, 186
Elbows, 61
Explosively Lined Pipe, 55-56
Fittings, 69
Hydraulically Lined Pipe, 53
Laying Clad Pipe, 119
Out-of-Plane, 60
Tolerances (Continued)
Ovality, 60
Pipe
Ends, 209
Fit-Up, 101-102, 104, 113
External Clamps, 182-183
Internal Diameter, 170
Seamless Pipe, 44, 47
Thermo-Hydraulically Lined Pipe, 51
Wall Thickness, 60
Transition Joint, 164
Towing, 119, 179, 206
Tubeplate, 132-133, 156
U
Ultrasonic Testing (UT), 16, 37
V
Vapour Deposition, 127
266
Index
W
Wallpapering, 160-161
Welding Clad Products
Fabricating Clad Vessels, 95-100
Handling Clad Plate, 95-96
Welding Clad Vessels, 96-100
Circumferential Welding of Clad Pipe, 100-112
Handling Clad Pipe, 101
Pipe end Dimensions/Fit-up, 101-102
Weld Preparation, 102-105
Demagnetising of Pipes, 105-106
Back Shielding, 106-107
Choice of Welding Process, 107-108
Choice of Filler Metal, 108-111
Control of Heat Input, 111
Weld Integrity Assessment, 111-112
Welding Repairs During Pipelaying, 112-113
Developments in Clad Pipe Welding Technology, 113-116
Laying Clad Pipe, 116-120
Commissioning Clad Pipelines, 120-121
Welding Processes
Flux Cored Arc Welding (FCAW), 107
Gas Metal Arc Welding (GMAW), 29, 105, 107, 181, 190, 199, 201,
206
Clad Fittings, 66
Clad Valve, 79
Fit-Up, 102
Overlay, 140-141
PGMAW, 107, 111, 113, 189, 206
Power Plant Applications, 156
Plug Welds, 161
Repairs, 116
Root Pass, 114-115, 172, 186, 201, 211-212
Welding Speed, 113-114
Gas Tungsten Arc Welding (GTAW), 6, 29, 35, 107-108, 178, 187,
192
Alloy 625, 170, 189, 191, 194
Autogeneous, 208
Back Shielding, 106-107
Clad Fitting, 66
Centricast Clad Pipe, 108
Demagnetising of Pipes, 105-106
CASTI Handbook of Cladding Technology - 2nd Edition
Index
267
Welding Processes
Gas Tungsten Arc Welding (GTAW) (Continued)
Heat Input, 107, 111-112
J-Laying, 105
Liner Pipe, 51,53
Liquation Cracking, 132
Machines, 186
Settings, 186
Overlay, 128, 133, 198, 209
Pipe Fit-Up, 101-102
PGTAW, 186, 189, 201, 206
Power Plant Application, 156
Repair Welding, 112-113, 198
Root Pass, 186-187, 190, 199, 211-212
Welding Technology, 113-116
Processo Arcos Saipem Saldatura Orbitale (PASSO), 181, 199-201
Shielded Metal Arc Welding (SMAW), 29, 66, 105, 107, 112, 172,
178, 187, 191, 202-203
Submerged Arc Welding (SAW), 35, 156, 189, 198, 206
Z
Zirconium, 2, 12, 28, 98, 148, 151-152, 154