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Silver (339.7nm 1240nm) : Experimental Data (N & K)

This document discusses the optical properties of silver and fitting experimental data to the Drude model. It provides experimental refractive index (n) and extinction coefficient (k) data for silver over the wavelength range of 339.7-1240 nm. It then fits this data to the Drude model, obtaining values for the plasma frequency ωp, collision frequency γ, and infinite frequency dielectric constant ε∞. Additional Drude parameter values reported in other studies are also listed for comparison.

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61 views7 pages

Silver (339.7nm 1240nm) : Experimental Data (N & K)

This document discusses the optical properties of silver and fitting experimental data to the Drude model. It provides experimental refractive index (n) and extinction coefficient (k) data for silver over the wavelength range of 339.7-1240 nm. It then fits this data to the Drude model, obtaining values for the plasma frequency ωp, collision frequency γ, and infinite frequency dielectric constant ε∞. Additional Drude parameter values reported in other studies are also listed for comparison.

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Copyright
© © All Rights Reserved
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Silver (339.

7nm ~ 1240nm)
Experimental data (n & k)
9

n
k

8
7
6
5
4
3
2
1
0
400

600

800

1000

Wavelength (nm)

1200

1() = n2()-k2()
2()=2n()k()
10
0
-10

-20

-30
-40
-50
-60
-70
-80
400

600

800

1000

Wavelength (nm)

1200

Drude model for metal


( ) =

2
p

+ j

jt convention

( ) = 1 ( ) + j 2 ( )

1 ( ) =

2
p

+
2

Real part

p2
2 ( ) = 3
+ 2
Imaginary part

Simultaneous Nonlinear Curve Fit


10
0

= 4.08598
16
p = 1.3316 10
= 1.1308 1014

-10
-20
y=A- B^2/(x^2+C^2);
z= B^2*C/(x^3+x*C^2);

-30
-40

1()

-50

2()

-60

Chi^2/DoF = 0.09344
R^2 = 0.99965
A
B
C

4.08598
? .08897
1.3316E16 ? .0928E13
1.1308E14 ? .8211E12

-70
-80
2.00E+015

4.00E+015

Angular Frequency ()

6.00E+015

Validating Drude parameters for Ag


( ) = b
Re ( ) = b
b

2p
+ i
2

= Re ( ) + i Im ( )

2p

2p
Im ( ) = 3
+ 2

2 + 2
p

reference

fit range(nm)

Set 1 :

5.0,

1.4433E16,

1.4995E14 (from J&C)*

Set 2 :

1.722,

1.155E16,

1.108E14

(form Palik)

1260-2000

Set 3 :

3.9943,

1.329E16,

1.128E14

(form Palik)

375-1240

Set 4 :

5.2573,

1.4525E16,

7.0656E13

(from J&C)

330-660

Set 5 :

4.08598,

1.3316E16,

1.1308E14 (from Palik)

200-1000

340-1240

*C. Oubre and P. Nordlander, J. Phys. Chem. B 17740 (2004)

Set 3
0
dots : reference

-20

line : fitting

-40

4
2
0

-60

-2
-4
-6

-80

-8
-10
350

400

450

500

550

600

650

700

Wavelength (nm)

-100
400

600

800

1000

Wavelength (nm)

1200

Set 5
0
-20
-40

4
2
0

-60

-2
-4
-6

-80

-8
-10
350

400

450

500

550

600

650

700

Wavelength (nm)

-100
400

600

800

1000

Wavelength (nm)

1200

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