CM 1401 Formulae Sheet: E = hc/λ K = (RT) K
CM 1401 Formulae Sheet: E = hc/λ K = (RT) K
Constants
h = 6.626 x 10-34 J s
8
c = 3 x 10 m s
S = k ln W
-1
-1
R = 8.314 J K mol
-1
-1
Stransition = Htransition/T
Ssurroundings = -Hsystem/T
= 760 mm Hg
0 C = 273 K
F = 96485 C mol
-1
Kw = 1 x 10-14
G = G + RT ln Q
23
-1
Formulae
Kp = (RT)n Kc
E = hc/
E = -2.18 x 10
-18
E = -2.18 x 10
(Z /n )
-18
x . m u h/4
PV = nRT
U = q + w
q = mCsT
q = nCmT
U = qv = nCv,mT
H = qp = nCp,mT
w = -PexV
J (Z /nfinal Z /ninital )
= h/mu
H = U + PV
Go = -nFEocell
Ecell = Ecell (RT/nF) ln Q
Ecell = Ecell (0.0591/n) lg Q (at 298 K)
Ecell = (RT/nF) ln K
Ecell = (0.0591/n) lg K (at 298 K)
[A]t = -kt + [A]0 (zero-order)
ln [A]t = -kt + ln [A]0 (first-order)
1/[A]t = kt + 1/[A]0 (second-order)
k = A exp(-Ea/RT)
ln (k2/k1) = (-Ea/R) (1/T2 1/T1)
pH = pKa + log10 ([base]/[acid])