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    Enthalpy of Dilution of Acids

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    widhisaputrawijaya
    The document provides data on the enthalpy of dilution (∆dilH) of various acids when diluted with water. It gives the ∆dilH values in kJ/mol at 25°C for acids like HF, HCl, HClO4, HBr, HI, HNO3, CH3COOH, and C2H4O2 as the acids are diluted from various initial molalities down to infinite dilution. More negative ∆dilH values mean more heat is absorbed during dilution, while less negative/positive values mean heat is released. The data allows calculation of heat effects from diluting these common acids.

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    Enthalpy of Dilution of Acids

    Uploaded by

    widhisaputrawijaya
    121 views1 page
    The document provides data on the enthalpy of dilution (∆dilH) of various acids when diluted with water. It gives the ∆dilH values in kJ/mol at 25°C for acids like HF, HCl, HClO4, HBr, HI, HNO3, CH3COOH, and C2H4O2 as the acids are diluted from various initial molalities down to infinite dilution. More negative ∆dilH values mean more heat is absorbed during dilution, while less negative/positive values mean heat is released. The data allows calculation of heat effects from diluting these common acids.

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    The document provides data on the enthalpy of dilution (∆dilH) of various acids when diluted with water. It gives the ∆dilH values in kJ/mol at 25°C for acids like HF, HCl, HClO4, HBr, HI, HNO3, CH3COOH, and C2H4O2 as the acids are diluted from various initial molalities down to infinite dilution. More negative ∆dilH values mean more heat is absorbed during dilution, while less negative/positive values mean heat is released. The data allows calculation of heat effects from diluting these common acids.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    121 views1 page

    Enthalpy of Dilution of Acids

    Uploaded by

    widhisaputrawijaya
    The document provides data on the enthalpy of dilution (∆dilH) of various acids when diluted with water. It gives the ∆dilH values in kJ/mol at 25°C for acids like HF, HCl, HClO4, HBr, HI, HNO3, CH3COOH, and C2H4O2 as the acids are diluted from various initial molalities down to infinite dilution. More negative ∆dilH values mean more heat is absorbed during dilution, while less negative/positive values mean heat is released. The data allows calculation of heat effects from diluting these common acids.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    Enthalpy of Dilution of Acids

    The quantity given in this table is dilH, the negative of the


    enthalpy (heat) of dilution to infinite dilution for aqueous solutions of several common acids; i.e., the negative of the enthalphy
    change when a solution of molality m at a temperature of 25C is
    diluted with an infinite amount of water. The tabulated numbers
    thus represent the heat produced (or, if the value is negative, the
    heat absorbed) when the acid is diluted. The initial molality m is
    given in the first column. The second column gives the dilution
    ratio, which is the number of moles of water that must be added
    m
    55.506
    20
    15
    10
    9
    8
    7
    6
    5.5506
    5
    4.5
    4
    3.5
    3
    2.5
    2
    1.5
    1
    0.5551
    0.5
    0.2
    0.1
    0.0925
    0.0793
    0.0694
    0.0617
    0.05551
    0.05
    0.02775
    0.01850
    0.01388
    0.01110
    0.00555
    0.00278
    0.00111
    0.000555
    0.000111
    0

    487_S05.indb 85

    Dil. ratio
    1.0
    2.775
    3.700
    5.551
    6.167
    6.938
    7.929
    9.251
    10
    11.10
    12.33
    13.88
    15.86
    18.50
    22.20
    27.75
    37.00
    55.51
    100
    111.0
    277.5
    555.1
    600
    700
    800
    900
    1000
    1110
    2000
    3000
    4000
    5000
    10000
    20000
    50000
    100000
    500000

    HF
    14.88
    14.34
    13.87
    13.81
    13.77
    13.73
    13.69
    13.66
    13.62
    13.58
    13.53
    13.47
    13.45
    13.43
    13.40
    13.36
    13.30
    13.22
    13.20
    13.09
    12.80
    12.79
    12.70
    12.61
    12.50
    12.42
    12.24
    11.29
    10.66
    10.25
    9.874
    8.912
    7.531
    5.439
    3.766
    1.255
    0

    HCl
    45.61
    19.87
    15.40
    10.24
    9.213
    8.201
    7.217
    6.268
    5.841
    5.318
    4.899
    4.402
    3.958
    3.506
    3.063
    2.623
    2.167
    1.695
    1.234
    1.172
    0.761
    0.556
    0.540
    0.502
    0.473
    0.448
    0.427
    0.406
    0.310
    0.251
    0.226
    0.197
    0.142
    0.105
    0.067
    0.042
    0.021
    0

    to one mole of the acid to produce a solution of the molality in the


    first column.

    Reference
    Parker, V. B., Thermal Properties of Aqueous Uni-Univalent
    Electrolytes, Natl. Stand. Ref. Data Ser. - Natl. Bur. Stand. (U.S.) 2, U.S.
    Government Printing Office, 1965.

    dilH in kJ/mol at 25C


    HClO4
    HBr
    48.83
    13.81
    19.92
    7.920
    14.29
    2.013
    8.694
    1.280
    7.719
    0.611
    6.786
    0.046
    5.925
    -0.351
    5.004
    -0.490
    4.590
    -0.628
    4.113
    -0.732
    3.711
    -0.787
    3.330
    -0.820
    2.966
    -0.782
    2.611
    -0.724
    2.301
    -0.623
    1.996
    -0.431
    1.665
    -0.201
    1.314
    0.050
    0.983
    0.075
    0.941
    0.247
    0.649
    0.272
    0.498
    0.272
    0.481
    0.272
    0.452
    0.268
    0.427
    0.264
    0.406
    0.259
    0.385
    0.259
    0.372
    0.226
    0.285
    0.197
    0.234
    0.180
    0.205
    0.167
    0.184
    0.126
    0.130
    0.092
    0.092
    0.059
    0.054
    0.042
    0.038
    0.021
    0.021
    0
    0

    HI
    21.71
    14.02
    7.615
    6.569
    5.607
    4.728
    3.975
    3.577
    3.197
    2.828
    2.460
    2.105
    1.787
    1.527
    1.318
    1.125
    0.933
    0.736
    0.711
    0.536
    0.439
    0.427
    0.402
    0.385
    0.368
    0.351
    0.339
    0.264
    0.218
    0.192
    0.172
    0.121
    0.084
    0.050
    0.038
    0.021
    0

    HNO3
    19.73
    9.498
    6.883
    3.933
    3.368
    2.791
    2.251
    1.749
    1.540
    1.310
    1.109
    0.958
    0.791
    0.665
    0.582
    0.527
    0.506
    0.506
    0.502
    0.498
    0.439
    0.372
    0.368
    0.351
    0.339
    0.326
    0.318
    0.305
    0.247
    0.213
    0.192
    0.176
    0.130
    0.096
    0.063
    0.046
    0.021
    0

    CH2O2
    0.046
    0.038
    0.109
    0.205
    0.230
    0.255
    0.272
    0.280
    0.285
    0.289
    0.289
    0.289
    0.289
    0.289
    0.285
    0.276
    0.259
    0.226
    0.184
    0.176
    0.146
    0.134
    0.134
    0.134
    0.130
    0.126
    0.121
    0.121
    0.117
    0.117
    0.113
    0.109
    0.105
    0.096
    0.084
    0.054
    0.038
    0

    C2H4O2
    2.167
    2.075
    1.962
    1.824
    1.782
    1.724
    1.648
    1.540
    1.477
    1.393
    1.310
    1.218
    1.121
    1.025
    0.912
    0.803
    0.678
    0.544
    0.423
    0.406
    0.331
    0.289
    0.285
    0.285
    0.280
    0.276
    0.272
    0.272
    0.264
    0.259
    0.259
    0.255
    0.243
    0.230
    0.222
    0.209
    0.167
    0

    5-85

    3/14/06 2:40:12 PM

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