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This document summarizes the structure and spectroscopic studies of (E)-N'(2-hydroxy-3-methoxybenzylidene)isonicotinohydrazide. It was synthesized from the reaction of isonicotinohydrazide with 2-hydroxy-3-methoxybenzaldehyde and characterized using various techniques. The compound crystallizes in the monoclinic space group P21/c with unit cell parameters a = 7.323(1) Å, b = 11.202(2) Å, c = 10.495(1) Å, β = 110.92(1)°. Its structure was also examined crystallographically. Schiff bases are important in chemistry

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This document summarizes the structure and spectroscopic studies of (E)-N'(2-hydroxy-3-methoxybenzylidene)isonicotinohydrazide. It was synthesized from the reaction of isonicotinohydrazide with 2-hydroxy-3-methoxybenzaldehyde and characterized using various techniques. The compound crystallizes in the monoclinic space group P21/c with unit cell parameters a = 7.323(1) Å, b = 11.202(2) Å, c = 10.495(1) Å, β = 110.92(1)°. Its structure was also examined crystallographically. Schiff bases are important in chemistry

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STRUCTURE OF ORGANIC COMPOUNDS SPECTROSCOPIC STUDIES AND CRYSTAL STRUCTURE OF (E)-N'(2-HYDROXY-3METHOXYBENZYLIDENE)ISONICOTINOHYDRAZIDE H. Oza a!" M. Y#$%#za!&! H. U'()*+! A.

,-*az%
a

Department of Chemistry, Faculty of Science and Arts, anakkale Onsekiz Mart University, !"#$#%% anakkale, urkey, e"mail& havaozay'hotmail(com
)

*anoscience and echnolo+y !esearch and Application Center ,*A*O!AC-, anakkale Onsekiz Mart University, !"#$#%% anakkale, urkey
c

Department of .hysics, Faculty of Science, Ankara University, !"%/#%% ando0an, Ankara, urkey

*ear 1ast University, Ataturk Faculty of 1ducation, *icosia, Mersin #% urkey Received March 03, 2011

A&./*a+/ 0 The structure of compound has also been examined cyrstallographically. t crystalli!es in the monoclinic space group .21"c #ith a $ %.&%3'1(, ) $ 1&.2)1'2(, c $ 10.*%+'1( ,, $ 110.+2'1(-, 2 $ 12%0.%'3( ,3, D3 $ 1.+1* g.cm.3, !1$ 0.03+/ and 4!2$ 0.0/3) 05 > 2'5(1, respectively. The title compound has been synthesi!ed from the reaction of isonicotinohydra!ide #ith 2.hydroxy.3.methoxyben!aldehyde. t has been characteri!ed by using elemental analysis, M2, R, 13 4MR, 135 4MR and 67.7isible spectroscopic techni8ues.

4TR9:65T 94
2chiff bases are important in diverse field;s chemistry o#ing to their biological activities 01<+1. =part from the biological activities, photochromism is another characteristic of these materials leading to its application in various areas such as the control and measurement of radiation intensity, display systems and optical computers 0)<*1. The tautomerism in the 2chiff base ligands plays an important role for distinguishing their photochromic and thermochromic characteristics 0/<111. t has been proposed that molecules sho#ing thermochromism are planer, #hile those sho#ing photochromism are non.planer 0121, both appearances being associated #ith a proton transfer 0)1. Tautomerism in 2chiff bases #ith 93 group in ortho position to the imino group both in solution and in solid state have been investigated by using spectroscopic and crystallographic techni8ues 013<211.

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