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    Basic Principles of Gas Chromatography: Martin R. Hackman NJ - Dep Office of Quality Assurance

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    yoga nayagi punichelvana
    Gas chromatography is a technique used to separate and analyze mixtures that relies on partitioning between a stationary and mobile phase. The sample is injected into a heated chamber containing the stationary phase, then carried by an inert mobile phase through the column. Compounds are separated based on how they interact differently with the stationary phase and emerge from the column at characteristic times to be detected. Common detectors used include flame ionization, electron capture, and mass spectrometry.

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    Basic Principles of Gas Chromatography: Martin R. Hackman NJ - Dep Office of Quality Assurance

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    yoga nayagi punichelvana
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    Gas chromatography is a technique used to separate and analyze mixtures that relies on partitioning between a stationary and mobile phase. The sample is injected into a heated chamber containing the stationary phase, then carried by an inert mobile phase through the column. Compounds are separated based on how they interact differently with the stationary phase and emerge from the column at characteristic times to be detected. Common detectors used include flame ionization, electron capture, and mass spectrometry.

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    Gas chromatography is a technique used to separate and analyze mixtures that relies on partitioning between a stationary and mobile phase. The sample is injected into a heated chamber containing the stationary phase, then carried by an inert mobile phase through the column. Compounds are separated based on how they interact differently with the stationary phase and emerge from the column at characteristic times to be detected. Common detectors used include flame ionization, electron capture, and mass spectrometry.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    65 views13 pages

    Basic Principles of Gas Chromatography: Martin R. Hackman NJ - Dep Office of Quality Assurance

    Uploaded by

    yoga nayagi punichelvana
    Gas chromatography is a technique used to separate and analyze mixtures that relies on partitioning between a stationary and mobile phase. The sample is injected into a heated chamber containing the stationary phase, then carried by an inert mobile phase through the column. Compounds are separated based on how they interact differently with the stationary phase and emerge from the column at characteristic times to be detected. Common detectors used include flame ionization, electron capture, and mass spectrometry.

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    of 13

    Basic Principles of Gas Chromatography

    Martin R. Hackman
    NJ - DEP Office of Quality Assurance

    THE CHROMATOGRAPHIC PROCESS - PARTITIONING


    (gas or liquid)

    MOBILE PHASE

    Sample in

    Sample out

    STATIONARY PHASE
    (solid or heavy liquid coated onto a solid or support system)

    GC Methods
    Parameter Group
    SDW05.13000s SDW05.24000s

    Method
    EPA 502.2 EPA 551.1

    Compounds
    VOCs Cl-VOCs/Pests

    WPP05.04000s
    WPP06.03000s SHW06.21000s

    EPA 604
    EPA 625 SW-846 8141A

    Phenols
    SVOCs Org-P Pests

    Instrumentation
    Injection Port - Sample introduction

    Manual - Direct Injection


    Automated - Autosampler - Purge and Trap

    Instrumentation - Oven
    Temperature Control
    Isothermal
    240 200

    Gradient

    Temp (deg C)

    160 120 80 40 0 0 10 20 30 Time (min) 40 50 60

    Columns
    Packed

    Capillary

    Polarity

    Non-polar

    Polar

    Phases

    Instrumentation - Detectors
    Destructive
    Mass Spectral (CI/EI) [625] Flame Ionization (FID) [604] Nitrogen-Phosphorus (NPD) [8141A] Flame Photometric (FPD) [8141A] Electrolytic Conductivity (Hall/ELCD) [502.2]

    Instrumentation - Detectors
    Non-Destructive Thermal Conductivity (TCD)

    Electron Capture (ECD) [551.1]


    Photo Ionization (PID) [502.2]

    Chromatograms - 551.1

    Chromatograms - 604

    Supelco PTE-5

    Supelco SPB-50

    m- Cresol

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