PETROLEUM REFINERY ENGINEERING (CHL 794) DEPARTMENT OF CHEMICAL ENGINEERING, IITD TUTORIAL SHEET -5

1. A petroleum cut has the following ASTM D86 distillation data: Volume% 1 ! " Temperature %deg.&' !6. "( ## 1 1. " "

# 1!1

$ 1#1

$" 186."

Ta)le 1.1 gi*es the a and ) constants in the intercon*ersion e+uation %TBP = a(ASTM D86)b) referred to in the A,- method and ta)le 1.. gi*es the constants for Dau)ert/s distillation cur*es (Ti 0 Ai %%Ti'Bi' where T and T stand for ASTM D86 and T1, temperatures respecti*el23 )oth in deg.4. &on*ert these data to T1, data using the A,- method of 5ia6i and Dau)ert and Dau)ert/s method. ,lot the results and compare. T !"# $%$% C&'() ')( *&+ ),# #-. )/&' &* ),# API 0#),&1 2&".0# 3 1/()/""#1 a b .$16# 1. 1$ 1 .".## 1. $ ! .#(.$ 1. (." " .8$. 1. 1#6 # .8# " 1. ..6 $ .$($ 1. 11 $" .8 8 1. !"" T !"# $%4 C&'() ')( *&+ D .!#+)5( 1/()/"" )/&' 6.+7#( *&+ /')#+6&'7#+(/&' I'1#8 '.0!#+ i Ai Bi 1 . ! ( " 6 # #.( 1. (.$ ( !. ! " .8#18 ..".8. !. (1$ .118 .6 .( .#16( .8 .8. .##" 1.66 6 8 1. ."8

Also3 calculate the MeA1, of the petroleum fraction. -f the A,- gra*it2 of this fraction is 6.3 calculate the 7atson/s characteri6ation factor. Also3 di*ide the T1, cur*e of the petroleum cut as calculated from A,method into pseudo8components. &alculate the li+uid *olume percentage of each pseudo8component. .. &onsider the 9uwait e:port crude with the following T1,8*ol% data: T !"# 4%$: T1,8*ol% *olume % " 1 ! " # T1,% &' ( 8" .1" !( ($"

Determine the *olumetric 2ield3 a*erage )oiling point3 molecular weight and specific gra*it2 for the products shown in the ta)le . )elow. T !"# 4%4: T2pical &D; products and their end )oiling points &ut < 1 . ! ( " 6 # 8 $ 1 !. ,roduct >ff gas ?ight straight run naphtha @aphtha 9erosene ?ight diesel Aea*2 diesel Atm. Bas oil Vacuum gas oil Vac. distillate Vac. residue =nd point % &' 1 # 18 .( .$ !( !# !$ "" 8

4or the 9uwait e:port crude %A,- !1."' gi*en in the a)o*e pro)lem. ,erform a material )alance for a &D; using ACSCS for 1 3 1,&D of .$ A,- crude with the following assa2. T !"# 9%$ C+.1# A(( : *olume % T1,% &' 8$.(( (." !.... $ #!.8$ 1(." 11"."6 . 1"(.(( ! ..!.8$ ( .#!.!! " !.6.6# 6 !$!.!! # (#!.8$ #6 ". ."6 8 "(6.11

The crude is fed to a pre8flash separator operating at (" 4 and #" psia. The *apour from this separator )2passes the crude furnace and is remi:ed with the hot %6" 4' li+uid lea*ing the furnace. The com)ined stream is then fed to the distillation column. The column operates with a total condenser3 three side strippers and three pump around. (. 7ith 1 1,D of the following crude %A,-0!6'3 =stimate the products of the atmospheric distillation column. -f the atmospheric residue of the crude is taDen at 6" E 4. -t enters in a *acuum distillation tower to gi*e three products: light *acuum gas oil %6" to 8" 4'3 hea*2 *acuum gas oil %8" 81 " 4' and *acuum residue %1 " E 4'. &alculate the mass flow rate of these products. Then3 calculate the sulphur content %l)Fhr' for each product. ASTM D86% 4' *ol% cum *ol% SB 86 GG 1.. ." ." .6# 16# 1.. 1.# .6#" .1. 1.6 !.! .#.. ."# ..# 6 .#(8 ! . !.1 $.1 .#6" !(# !.$ 1! .##8

!$. (!# (8. ".# "8( 6!6 68$ #(. #$( GG

(.# ".# 8 1 .# " 1 #.8 # 6." . .8

1#.# .!.( !1.( (..1 (#.1 "#.1 6(.$ #1.$ #8.( $$..

.#8$ .8 1 .81( .8." .8(" .8"( .86! .86( .88$ .$!1