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Homework 6 and Answers

1. The physical chemistry homework involves proving an equation for an ideal gas reaction and finding the equilibrium constant at 400K for two reactions. 2. It also involves finding an expression for the standard Gibbs free energy of an ideal gas dissociation reaction given temperature-dependent heat capacity and entropy terms. 3. Additionally, it asks to estimate the temperature at which the equilibrium constant for an ideal gas reaction equals 1, given the equilibrium constant at 600K and assuming the enthalpy is constant.

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Fernando J. Correa Delgado
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92 views5 pages

Homework 6 and Answers

1. The physical chemistry homework involves proving an equation for an ideal gas reaction and finding the equilibrium constant at 400K for two reactions. 2. It also involves finding an expression for the standard Gibbs free energy of an ideal gas dissociation reaction given temperature-dependent heat capacity and entropy terms. 3. Additionally, it asks to estimate the temperature at which the equilibrium constant for an ideal gas reaction equals 1, given the equilibrium constant at 600K and assuming the enthalpy is constant.

Uploaded by

Fernando J. Correa Delgado
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Physical chemistry Homework for Chapter 6

1. Prove that for an ideal-gas reaction

2. At 400 K,

for

. Find

at 400 K for

(a) (b)

3. Consider the ideal-gas dissociation reaction

. For A and B, we have

0 = e + fT + gT 2 , where a, b, c, d, e, f, g are known and C P ,m , B

constants and these equations are valid over the temperature range from T1 to T2. Further, suppose that valid between and and . are known. Find an expression for

4. The

ideal-gas

reaction , , and

at

600K

has

. Estimate

the temperature at which

for this reaction. State approximations made.

Assuming that !Ho is constant.

5. Some vapor pressures of liquid are: T 80.0 100.0 120.0 P/torr (a) 0.08880 0.2729 0.7457

140.0 1.845

Find the average plot of versus 1/T

of vaporization over this temperature range from a

(b) (c)

Find the vapor pressure at 160

Estimate the normal boiling point of Hg.

6. Hydrogen sulfide dissociate according to the following reaction: 2 H2S (g) = 2 H2 (g) + S2 (g) Use the following thermochemical data to answer the following. substance -20.6 -----128.4 1). Evaluate standard state? Som (298K), J. mol-1K-1 205.8 130.7 228.2

for that reaction at 298 K. Is the reaction spontaneous in the

2). Evaluate

at 298 K is in this

3). If at 1400K and 1 bar pressure the degree of dissociation of 0.305, evaluate problem). (you can not use the temperature dependence of

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