Atmosphere Composition

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ATMOSPHERE

DEFINITION : The atmosphere of Earth is a layer of gases surrounding the planet Earth that is retained by Earth's gravity. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night. Dry air contains roughly (by volume) 78.09% nitrogen, 20.95% oxygen, 0.93% argon, 0.039% carbon dioxide, and small amounts of other gases. Air also contains a variable amount of water vapor, on average around 1%. The atmosphere has a mass of about 5 1018 kg, three quarters of which is within about 11 km (6.8 mi; 36,000 ft) of the surface. The atmosphere becomes thinner and thinner with increasing altitude, with no definite boundary between the atmosphere and outer space. An altitude of 120 km (75 mi) is where atmospheric effects become noticeable during atmospheric reentry of spacecraft. The Krmn line, at 100 km (62 mi), also is often regarded as the boundary between atmosphere and outer space.

Composition of dry atmosphere, by volume[2]


ppmv: parts per million by volume (note: volume fraction is equal to mole fraction for ideal gas only, see volume (thermodynamics))

Gas Nitrogen (N2) Oxygen (O2) Argon (Ar) Carbon dioxide (CO2) Neon (Ne) Helium (He) Methane (CH4)

Volume 780,840 ppmv (78.084%) 209,460 ppmv (20.946%) 9,340 ppmv (0.9340%) 390 ppmv (0.039%) 18.18 ppmv (0.001818%) 5.24 ppmv (0.000524%) 1.79 ppmv (0.000179%)

Krypton (Kr) Hydrogen (H2) Nitrous oxide (N2O) Carbon monoxide (CO) Xenon (Xe) Ozone (O3) Nitrogen dioxide (NO2) Iodine (I2) Ammonia (NH3)

1.14 ppmv (0.000114%) 0.55 ppmv (0.000055%) 0.3 ppmv (0.00003%) 0.1 ppmv (0.00001%) 0.09 ppmv (9 106%) (0.000009%) 0.0 to 0.07 ppmv (0 to 7 106%) 0.02 ppmv (2 106%) (0.000002%) 0.01 ppmv (1 106%) (0.000001%) trace

Not included in above dry atmosphere: Water vapor (H2O) ~0.40% over full atmosphere, typically 1%-4% at surface

Earth's atmosphere can be divided into five main layers. These layers are mainly determined by whether temperature increases or decreases with altitude. From lowest to highest , these layers are: Troposphere The troposphere begins at the Earth's surface and extends up to 4-12 miles (6-20 km) high. This is where we live. As the gases in this layer decrease with height, the air become thinner. Therefore, the temperature in the troposphere also decreases with height. As you climb higher, the temperature drops from about 62F (17C) to -60F (-51C). Almost all weather occurs in this region. The height of the troposphere varies from the equator to the poles. At the equator it is around 11-12 miles (18-20 km) high, at 50N and 50S, 5 miles and at the poles just under four miles high. The transition boundary between the troposphere and the layer above is called the tropopause. Both the tropopause and the troposphere are known as the lower atmosphere. Stratosphere The Stratosphere extends from the tropopause up to 31 miles above the Earth's surface. This layer holds 19 percent of the atmosphere's gases and but very little water vapor.

Temperature increases with height as radiation is increasingly absorbed by oxygen molecules which leads to the formation of Ozone. The temperature rises from an average -76F (-60C) at tropopause to a maximum of about 5F (-15C) at the stratopause due to this absorption of ultraviolet radiation. The increasing temperature also makes it a calm layer with movements of the gases slow. The regions of the stratosphere and the mesosphere, along with the stratopause and mesopause, are called the middle atmosphere by scientists. The transition boundary which separates the stratosphere from the mesosphere is called the stratopause. Mesosphere The mesosphere extends from the stratopause to about 53 miles (85 km) above the earth. The gases, including the oxygen molecules, continue to become thinner and thinner with height. As such, the effect of the warming by ultraviolet radiation also becomes less and less leading to a decrease in temperature with height. On average, temperature decreases from about 5F (-15C) to as low as 184F (-120C) at the mesopause. However, the gases in the mesosphere are thick enough to slow down meteorites hurtling into the atmosphere, where they burn up, leaving fiery trails in the night sky. Thermosphere The Thermosphere extends from the mesopause to 430 miles (690 km) above the earth. This layer is known as the upper atmosphere. The gases of the thermosphere are increasingly thinner than in the mesosphere. As such, only the higher energy ultraviolet and x-ray radiation from the sun is absorbed. But because of this absorption, the temperature increases with height and can reach as high as 3,600F (2000C) near the top of this layer. However, despite the high temperature, this layer of the atmosphere would still feel very cold to our skin because of the extremely thin air. The total amount of energy from the very few molecules in this layer is not sufficient enough to heat our skin. Exosphere The Exosphere is the outermost layer of the atmosphere and extends from the thermopause to 6200 miles (10,000 km) above the earth. In this layer, atoms and molecules escape into space and satellites orbit the earth. The transition boundary which separates the exosphere from the thermosphere below it is called the thermopause.

EPA Graphic

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