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1 PEAB ZC311 Assignment I

1. The document contains 10 multi-part chemistry and chemical engineering problems involving concepts like heat transfer, gas behavior, phase changes of substances, and thermodynamic processes. 2. The problems calculate values like temperature, work, heat, internal energy change, enthalpy change, and entropy change for processes like mixing of fluids, gas compression and expansion, heating and cooling of substances, and isothermal compression of liquids. 3. The document provides necessary information like initial and final conditions, properties of substances, and equations to solve each problem.

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M Helmy Aditya
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911 views2 pages

1 PEAB ZC311 Assignment I

1. The document contains 10 multi-part chemistry and chemical engineering problems involving concepts like heat transfer, gas behavior, phase changes of substances, and thermodynamic processes. 2. The problems calculate values like temperature, work, heat, internal energy change, enthalpy change, and entropy change for processes like mixing of fluids, gas compression and expansion, heating and cooling of substances, and isothermal compression of liquids. 3. The document provides necessary information like initial and final conditions, properties of substances, and equations to solve each problem.

Uploaded by

M Helmy Aditya
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOC, PDF, TXT or read online on Scribd
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BIRLA INSTITUTE OF TECHNOLOGY & SCIENCE, PILANI B.

S Process Engineering (Aditya Birla Group - Cement Business) Second Semester 2010-2011 Course No. Course Title Component Questions: 1. A stream of warm water is produced in a steady flow mixing process by combining 1.0 kg s -1 of cool water at 298.15 K (25 C) with 0.8 kg s-1 of hot water at 348.15 K (75 C). During mixing, heat lost to the surrounding at rate of 30 kW. What is the temperature of the warm-water stream? Assume the specific heat of water constant at 4.18 kJ kg-1 K-1.
2. Gas is bled from a tank. Neglecting heat transfer between the gas and the tank, show that mass and energy balances produce the differential equation: dU dm = H ' U m Here, U and m refer to the gas remaining in the tank; H' is the specific enthalpy of the gas leaving the tank. Under what conditions can one assume H' = H 3. One mole of an ideal gas with Cp = (7/2)R and Cv = (512) R expands from P 1 = 8 bar and Tl = 600 K to P2 = 1 bar by each of the following paths: (a) Constant volume; (b) Constant temperature; (c) Adiabatically. Assuming mechanical reversibility, calculate W, Q, U, and H for each process. Sketch each path on a single P V diagram. 4. For methyl chloride at 373.15 K (100C) the second and third virial coefficients are: B = -242.5 cm3 mol-1 C = 25200 cm6 mol-2 Calculate the work of mechanically reversible, isothermal compression of 1 mol of methyl chloride from 1 bar to 55 bar at 373.15 K (100C). Base calculations on the following forms of the virial equation:

: PEAB ZC311 : Chemical Engineering Thermodynamics : Assignment 1

B C + V V2 (b) Z = 1 + B' P + C ' P 2


(a) Z = 1 + Where
C B2 B C' = ( RT ) 2 RT Why don't both equations give exactly the same result?

B' =

5. Estimate the volume occupied by 18 kg of ethylene (molecular weight = 28) at 328.15 K (55 C) and 35 bar using (a) Pitzers generalized correlation for second virial coefficient. (b) Redlich / Kwong (RK) equation 6. How much heat is required when 15 mol of 1-butene initially at 260 C is heated at atmospheric pressure to 1140.65 C.

7. Determine the standard heat of each of the following reaction at 298.15 K (25C) and at 773.15 K (500C): 3NO2 (g) + H2O (l) + 2HNO3 (1) + NO (g) 8. With respect to 1 kg of liquid water: a. Initially at 273.15 K (0oC), it is heated to 373.15 K (100C) by contact with a heat reservoir at 373.15 K (100C). What is the entropy change of the water? Of the heat reservoir? What is Stotal? b. Initially at 273.15 K (0C), it is first heated to 323.15 K (50C) by contact with a heat reservoir at 323.15 K (50C) and then to 373.15 K (100C) by contact with a reservoir at 373.15 K (100C). What is Stotal? c. Explain how the water might be heated from 273.15 K (0C) to 373.15 K (100C) so that Stotal = 0. 9. Estimate the change in enthalpy and entropy when liquid ammonia at 270 K is compressed from its saturation pressure of 381 kPa to 1200 kPa. For saturated liquid ammonia at 270 K, V = 1.551 x m3 kg-1, and = 2.095 x l0-3 K-1. 10. One kilogram of water (Vl = 1003 cm3 kg-1) in a piston/cylinder device at 298.15 K (25C) and 1 bar is compressed in a mechanically reversible, isothermal process to 1500 bar. Determine Q, W, U, H, and S given that = 250 x l0-6 K-1 and = K =45 x l0-6 bar-1.

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