Isomers

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Hexane

2,4-Dimethylpentane, (H3C)2CHCH2CH(CH3)2, 3,3-Dimethylpentane, H3CCH2C(CH3)2CH2CH3, 3-Ethylpentane, H3CCH2CH(CH2CH3)CH2CH3, 2,2,3-Trimethylbutane, CH3C(CH3)2CH(CH3) CH3, this isomer is also known as
[2]

Comm on name

IUPAC name

Text formula

Skeletal formula

normal hexane nhexane

pentamethylethane and triptane. hexane CH3(CH2)4CH3

2(CH3)2CH(CH2)2C isohexa methylpen H3 ne tane

3CH3CH2CH(CH3) methylpen CH2CH3 tane

OCTANE

Isomers[edit]
2,3dimethylb utane CH3CH(CH3)CH( CH3)CH3 Octane has 18 structural isomers (24 including stereoisomers): 2,2CH3C(CH3)2CH2C neohex dimethylb H3 ane utane Octane (n-octane) 2-Methylheptane 3-Methylheptane (2 enantiomers) 4-Methylheptane 3-Ethylhexane 2,2-Dimethylhexane 2,3-Dimethylhexane (2 enantiomers) 2,4-Dimethylhexane (2 enantiomers) 2,5-Dimethylhexane 3,3-Dimethylhexane 3,4-Dimethylhexane (2 enantiomers + 1 meso compound)
*

Heptane
Heptane (n-heptane), H3CCH2CH2CH2CH2 CH2CH3, 2-Methylhexane (isoheptane), H3CCH(CH3)CH2 CH2CH2CH3, 3-Methylhexane, H3CCH2C H(CH3)CH2CH2 CH3 (chiral), 2,2-Dimethylpentane, (H3C)3CCH2CH2CH3, 2,3-Dimethylpentane, (H3C)2CHC H(CH3)CH2 CH3 (chiral),
*

3-Ethyl-2-methylpentane 3-Ethyl-3-methylpentane 2,2,3-Trimethylpentane (2 enantiomers) 2,2,4-Trimethylpentane (isooctane) 2,3,3-Trimethylpentane

2,3,4-Trimethylpentane 2,2,3,3-Tetramethylbutane

Methyl+Ethyl[edit]
2-Methyl-3-ethylheptane 2-Methyl-4-ethylheptane 2-Methyl-5-ethylheptane 3-Methyl-3-ethylheptane 3-Methyl-4-ethylheptane 3-Methyl-5-ethylheptane 4-Methyl-3-ethylheptane 4-Methyl-4-ethylheptane

Straight-chain[edit]
Decane

Nonane[edit]
2-Methylnonane 3-Methylnonane 4-Methylnonane 5-Methylnonane

Trimethyl[edit]
2,2,3-Trimethylheptane 2,2,4-Trimethylheptane 2,2,5-Trimethylheptane 2,2,6-Trimethylheptane 2,3,3-Trimethylheptane 2,3,4-Trimethylheptane 2,3,5-Trimethylheptane 2,3,6-Trimethylheptane 2,4,4-Trimethylheptane 2,4,5-Trimethylheptane 2,4,6-Trimethylheptane 2,5,5-Trimethylheptane 3,3,4-Trimethylheptane 3,3,5-Trimethylheptane 3,4,4-Trimethylheptane 3,4,5-Trimethylheptane

Octane[edit]
Ethyl[edit]
3-Ethyloctane 4-Ethyloctane

Dimethyl[edit]
2,2-Dimethyloctane 2,3-Dimethyloctane 2,4-Dimethyloctane 2,5-Dimethyloctane 2,6-Dimethyloctane 2,7-Dimethyloctane 3,3-Dimethyloctane 3,4-Dimethyloctane 3,5-Dimethyloctane 3,6-Dimethyloctane 4,4-Dimethyloctane 4,5-Dimethyloctane

Hexane[edit]
Methyl+Propyl[edit]
2-Methyl-3-isopropylhexane

Heptane[edit]
Propyl[edit]

Diethyl[edit]
3,3-Diethylhexane 3,4-Diethylhexane

4-n-Propylheptane or 4-propylheptane 4-Isopropylheptane (=trivial name) or 4-(1methylethyl)-hepthane

Dimethyl+Ethyl[edit]
2,2-Dimethyl-3-ethylhexane

2,2-Dimethyl-4-ethylhexane 2,3-Dimethyl-3-ethylhexane 2,3-Dimethyl-4-ethylhexane 2,4-Dimethyl-3-ethylhexane 2,4-Dimethyl-4-ethylhexane 2,5-Dimethyl-3-ethylhexane 3,3-Dimethyl-4-ethylhexane 3,4-Dimethyl-3-ethylhexane

Tetramethyl[edit]
2,2,3,3-Tetramethylhexane 2,2,3,4-Tetramethylhexane 2,2,3,5-Tetramethylhexane 2,2,4,4-Tetramethylhexane 2,2,4,5-Tetramethylhexane 2,2,5,5-Tetramethylhexane 2,3,3,4-Tetramethylhexane 2,3,3,5-Tetramethylhexane 2,3,4,4-Tetramethylhexane 2,3,4,5-Tetramethylhexane 3,3,4,4-Tetramethylhexane

Pentane[edit]
Dimethyl+Propyl[edit]
2,4-Dimethyl-3-isopropylpentane

Methyl+Diethyl[edit]
2-Methyl-3,3-diethylpentane

Trimethyl+Ethyl[edit]
2,2,3-Trimethyl-3-ethylpentane 2,2,4-Trimethyl-3-ethylpentane 2,3,4-Trimethyl-3-ethylpentane

Pentamethyl[edit]
2,2,3,3,4-Pentamethylpentane 2,2,3,4,4-Pentamethylpentane

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