Mole Concept Booklet Solution

Foundation builder
1.

2.

169
31.2
4 ; B : nH 4
1.64
169
76
34.2
136
C : n H 22
2.2 ; D : n H 12
2.4
342
180
Hence [A]
A : nH 4

WH 3 3 9g

WN 3 14 42g

[B]
3.

In one H 2O molecule: 10 proton, 8 neutrons, 10 electrons

369
2mols
189 / mol
Protons = 2N A 10 20 N A

Hence in 36 ml, n H 2O

[C]
4.

n atoms

w
. Hence it should be of same weight W
at.wt

[A]

5.

no. of moles =

[B]
6.

10 3 N A
10 3
NA

wt 103 mol.wt 103 Mo g Momg

Total atoms

= 200 0.05 N A 1020 N A

0.05 N A 3 1022
[C]
7.

Mol. Wt of A 2 B3 150 96 246

For 5 mol, 246 5g = 1.23 kg

[C]
8.

9.

1
16
A:12 g ; B 16 8g ; C : 10 g ; D 8g
2
2

[A]

A : 2.5 5N A 12.5 N A ; B :10NA ; C : 4 3N A 12N A ; D 1.8 8N A 14.4N A .

Hence [A]

10.

200
144
6.43 N A ; C
N A 3 9N A
342
48
D : 2.5 3N A 7.5N A .
A :10N A ; B :11

Hence [A]
11.
12.

13.

14.

[D] obvious

1
1
1
1
3N A ; B :
26N A ; C : 8N A ; D : 2N A
44
114
30
26
Hence [A]
A:

9.2
2 n 1 n 0.4
46
[A]

wt 0.4 30 12g

52 amu
13
4 amu

[C]
15.

One ion contains: 7 + 24 + 1 = 32 e

total es 2 N A 32 64 N A
[B]
16.

n C 0.5 6 3

wt = 36 g

[D]
17.

18.

28
46
36
54
; B: ; C: ; D :
44
46
18
108
[C]
A:

n H 2O

180
10
18

no. of e s 10 10 N A 100 N A
[D]
19.

2.48
0.01
248
nH 2O 5 0.01 molecules 0.05 N A
n Na 2S2O3 .5H 2O

[c]
20.

n Ag
[c]

90 10
1
1

atom N A 5 1022
100 108 12
12

21.

n CO2 n , say. Then n O 2n

22.

8
1
n
16
4

[D]

A : 0.2 14g 2.8g ; B :

3 1023
6 10 23

12g 69 ; C : 32 g ; D : 7 g.

Hence [A]
23.

[D]

1 gram molecule: 44 g
1 molecule of CO 2 = 44 amu

24.

n H n 2 2n 4 10n
n C 2n 1 2n
n C : n H 1: 5
[A]

25.

Total charge = 1 N A 3e 3N A e coulomb

Hence [D]

26.

n H2O 18 333 = 9. Hence [B]

54 96 3 18 18
27.

n H 2O

0.018
103 . Hence, molecules = 103 N A
18

[C]

28.

29.

30.

n N3

4.2
0.3 .
14

total = 0.3 8N A 2.4N A

3.42
0.12
342
atom = 0.12 N A [D]
n C 12 n C12 H 22O11 12

8.4
0.1
84
Each contain (12 + 6 + 24) protons
n MgCO3

Hence, total 0.1 42N A 2.5 1024

[B]
31.

n total
[B]

32.

[D]

4.4 2.24

0.2
44 22.4

molecules = 0.2N A

33.

n gas

w
w

mol.wt. 3a

[B]
34.

n Fe

558.5
10 moles
55.85

In 60 g carbon, n C 5
[A]
35.

twice = 10 moles

Say n Mg3 PO4 2 n ; then n O 8n

8n = 0.25 n

0.25
3.125 102
8

[B]
36.

69.98
Mol.wt 2112 mol.wt 360
100
[D]
12g H 2O

8% H 2O

37.

45g silica
45g silica
43g others

43g others

100goriginal

' w 'grams

80 % of w = water
i.e. 92 % of w = silica others
92
Hence,
w 88g w 95.65
100
45
% of silica
100 47%
95.65
[D]
38.

M3 N2 .

28 % nitrogen

28
3M 28 28 M 24
100
[C]

39.

40.

55.9
46 96 18x 18 x x 10
100
[D]

nx : ny

w 2 : w 2 2 :1
10

20

Hence [B]
41.

Same as question 39. [C]

42.

43.

25.4 8 1 1
: : 2:5
127 16 5 2
Hence I 2O5 . [C]
nI : nO

0.014% mol.wt 2 at.wt of N

0.014
M 2 14 28
100
2800
M
2 105
3
14 10
[D]
i.e.

44.

mol. Wt = 2 VD = 100
71
w chlorine
100 71g
100
w metal 29 g
[A]

45.

Mol.wt. 0.8 28 0.2 32 28.8

M
VD 14.4
2
[C]

46.

Da 2w.r.t air

Da 2 Ma 2 71

Dair M air 29

Hence [A]
47.

30.4
14 16x 14 x 2
100
M
14
oxide
1.44
MO 2
32

Say NOX . Then

Doxide wrt O2
[B]

48.

n H2O n CH3OH 2 4

wt 4 18 729

[D]
49.

Say x g.

x
20

x 15
60 x 100

[A]
50.

Ag 2CO3
2Ag
WAg
[A]

2.7
2 108 2.11g
216 60

51.

n CO2 2 n C2 H5OH 2

WCO2 2 44 88g
Hence [D]
52.

53.

54.

55.

KClO 3
KCl 3 O 2
2
48g
Hence % loss in wt =
100 39.18
122.5
[C]

2
2
n Fe n H 2O
3
3
[A]

1.62
n CaCl2 0.0289
56
0.0289 111
% of CaCl2
100 32.11%
10
[B]
n CaCO3 n CaO

n BaSO4 nSO2 nS (POAC on S)

56.

2
Wiron 56 37.39
3

8 1

32 4

[D]

n NaBr n1 , n KBr n 2 say

n AgBr n Br n1 n 2

0.97
0.00516
108 88

Also, n1 103 n 2 119 0.569

0.56 103 0.00516

0.00516
16
WkBr 119n 2 0.2118g
n2

[B]
57.

WO 3.6769 2.0769 1.6g

with
2 mole
5mole 'O '
1.6
with
' n ' moles

mole 'O '

16
0.2
n
0.04
5
[A]

n : 4Al
1350
50
27

58.

3C

2400
200
12

Al4C3

L.R
given
4Al 144
w 1800 g
given
50 W
[D]

59.

2A
2B
B
2C
3C
4D
2 2 4
nD nA
2 1 3
32

3
[D]

60.

3BaCl 2 2Na 3PO4

Ba 3 PO4 2 6NaCl
n : 0.5

0.2
L.R.

nBa 3 PO4 2

n Na 3PO 4
2

0.1

[D]
61.

Ca OH 2 H 2SO 4
CaSO4 2H 2O
0.5

0.2
LR

n CaSO4 n Ca OH 0.2
2

[A]
62.

A 2B
C 3D
5

8
LR

nB
n
4 ; n D 3 B 12
2
2
Hence [B]
nC

63.

molality

18

n
w solvent

1000 urea : NH 2 C NH 2

||
O

60

1500 1.052 18

[B]

1000 0.192

64.

Molarity

1
n
1000 98 1000 0.01
V mL
1000

[D]
65.

Al3 20 0.2 2 0.2M

40
[A]

66.

1 mole kMnO 4
5 moles FeSO 4

V 0.01
50 0.01
V 10mL
[D]
67.

100
4
n H
0.001 2 2 10
1000

no. of H 2 104 N A 1.2 1020

[B]
68.

3 molal 3 mole NaOH in 1000g solvent

120 1000

1009mL
d 1.11
n
3
Molarity
1000
2.97
V mL
1.009
vol

[A]
69.

with
2X
3 16g Oxygen
with
1g
0.16g Oxygen

3 16
150
0.16 2

[D]
70.

X NaCl

n NaCl
1

0.0177
1000
n NaCl n H 2O 1
18

[A]
71.

3
2Al O2
Al2O3
2
1
n:
n
2
3
with
2 27g Al
mole O2
2
with

1 mole
2
2 27

18g
3

[D]

72.

KClO3
KCl 3 O 2 n O2 3
2
2
2Al 3 O 2
Al2 O 3
2
nO
n Al2O3 2 1
3
2
[A]

73.

Consider 1 c solution
29
d 1000 H 2SO4 3.6 98
100
d = 1.22 g/mL
[A]

N2

74.
n:

3H 2

10

2NH3

15
LR

10 5

10 moles

n N2 5

n H2 0

[A]

Fe2 SO4 3 3BaCl2

3BaSO4 2FeCl3

75.

n:

?
n BaCl2
3

n feCl3
2

1
nBaCl2 2 3 0.75 moles
2

[C]
76.

3CuSO4 2Al
Al2 SO4 3 3Cu
displaces
54g Al
192 g Cu
displaces

27g Al
96g
[C]
77.

CH 4
5

2O2
8

CO2

54=1

4
n CO2 4 ; nCH 4 (remaining) = 1
[A]

2H 2O

78.

X
C10H X nO 2
10CO 2 H 2O
2
X
Hence, n 10
4
X

with
1 mole C10 H X
10 moles
4

with
2.5 moles
40 moles

x 40 1

16
4
2.5
x 16 10 4 24
i.e. 10

[A]
79.

with

100g CaCO3
2mole HCl

25 L
with
g

0.75 M HCl
1000
0.9375g

[D]
80.

2.125
V L Molarity
143.5
2.125 1000
Molarity
0.59
143.5 25
[B]
n AgCl n Cl n HCl

FOUNDATION BUILDER (SUBJECTIVE)

1.

X
2X X
y given . For B :

Y
20
40 20

2.

n CH 4

1.6
0.1moles 6 10 22 molecules
1.6

Each molecule has (6 + 4) = 10e s

total e s 6 1023

3.

n H 2O

18g
1mole
18g mol

1 molecule has (2 + 8) = 10 e s

1 mole contains 10N A electrons.

4.

O 2 :10e,8 protons,8 neutrons per ion.

in1mole:10N A e,8 N A protons,8N A neutrons

5.

Atomic mass = n A mass of one atom

6 1023 6.64 1023 g 40 g

6.

no. of atoms =

wt
1

wt of one atom 3.98 10 23

2.5 1022
7.

removed 10 21 44amu 7.35 102 g

CO2 ,remaining 200 73.5 126.5mg

n CO 2

126.5 103
0.002875
44

8.

1mole N3 ch arg e n A 3e 2.88 105 C

9.

n O nSO 2 2

3.2 103
2 10 4 moles
64

nS n Na 2S2O3 .5H2O 2 2 5 10 3 102

n O : nS
10.

104
102

0.01

n O 3 n NaNO3 2 n NO2
1
m 10m 2 0.03 0.333 0.363
6
1
n N n NaNO3 n NO 2 10 103
6
= 0.01 + 0.166
= 0.176

11.

12.

t s

6 1023
106

6 1017 S

t nr

6 1017
1.67 1014
3600

t yr

1.67 1014
1.9 1010 years
24 365

atomic wt = 6.644 1023 6 1023

= 40 g/mol
40 1000 g
n
1000 moles
40 g / mol

13.

nC

106 g
129 / mol

No. of atoms = n C 6 1023 5 1016

14.

r = 0.1 inch = 0.254 cm

85.6
fe
ball
100
ball Vball density

4
3
0.254 7.75 0.532 g
3
85.6
Fe
0.532 g 0.455g
100
0.455
and no. of atoms = 4.88 1021
n Fe
56

15.

16.

0.086
starch = wt of 1 atom = 31 g
100
3100
starch
3.6 10 4
0.086
VNH 3 n NH3 22.4 L

17.

18.

3.4
22.4 4.48L
17

7.6 1010
1
760
V
10 12
n O2

1 273
RT
22.75
12
60
n moleculs n O 2 n A
1010 2.6 1010
22.75

O3 O 2
600 mL
VmL 600 v mL

600 V
V
48
32 1g
22400
22400
V = 200 mL
19.

Element

% (with in 100 g)

40.2

Mn

26.8

33

k 2 Mn P2

no. of (in 100 g) atom

40.2
1.03
39
26.8
0.48
55
33
1.06
31

ratio
2
1
2

20.

Say

nO n

Then

n H 15n

70
15n 10.5n
100
C10.5H15O or C 21H30O 2 is empirical formula
And

nC

Mol. Wt

1
314
0.00318

C21H30O2
21.

weight

9.03 10 20
0.311g
weight

6.02 1023
mol.wt.
mol.wt 207.33g

131.3 19n 2.7.3 n 4

22.

23.

58.97
102 59.9 n C 5
100
13.81
H
102 14.08 n H 14
100
27.42
N
102 27.97 n N 2
100
C5H14 N 2
C

12
12
CO2 0.9482 0.2586
44
44
n C 0.02155
C

2
H 2O 0.02154
18
n H 0.02154
H

n C : n H 1:1 CH
24.

CO

12
cylinder
100

cylinder r 2 h density
3.14 6.25 10 8.2 1610.7

CO
1
12
n CO

1610.7 3.28
58.9
15.9 100

no.of atoms 3.28 6 10 23

1.98 1024
25.

Mol. Wt = wt of 1 mole mix = 2VD = 76.6

(x mol. NO2 + (1 x) mol. N 2O4 ) = 76.6 g
x 46 1 x 92 76.6

15.4
n NO2 in 1 mole = 0.335
46
100
n mix in100 g
76.6
n NO 2 in100 0.335 n mix
x

= 0.437
26.

molality

n
solvent

1000
C2 H5OH
mol.wt 46

Consider 1L of solvent

N=8
solvent 1.025 1000 8 46 657

molality

27.

8
1000 12.18
657

2NaHCO3
Na 2CO3 CO 2 H 2O

Na 2CO3
no effect
loses

2 84g NaHCO3
62g CO2 H 2O
loses

g
0.124
0.124
168 0.336 g
62
0.336 100
% of NaHCO3
16.8%
2
and Na 2CO3 100 16.8 83.2%

28.

Al 2HCl
AlCl3 3 H 2
2
3
n1 moles
n1moles
2

Mg 2HCl
MgCl2 H 2

n 2 moles

n 2 moles

1 g mix n1 27 n 2 24 1g

3
V
0.92 1.2
n H 2 n1 n 2

2
RT 0.0821 273
= 0.04926
0.05
0.2
0.2
n1
Al
27 0.69
9
9
And Mg 1 0.6 0.49
Exact values: n1

0.18225
0.02025
9

and Al 0.546759
and Mg 0.453259
29.

2CH 3CHO O2 2CH 3COOH

:
n:

20g
20
0.45
40

10g
10
0.31
32

L.R
(A) n CH3COOH n CH 3CHO 0.45

CN3COOH 27.27g.
10 20 44

0.852
32
2
n O2 32 2.727g

(B) n O2 left

O2
I % yeild

23.8
100 87.2%
27.3

30.

3 20 4 40 8 50
n CH n A


3.2 I
2 100 2 100 3 100

31.

n CH 4 n1 and n C2H 4 n 2 ,say

now, n1 16 n 2 28 5g

14.5
0.33
44
n1 0.193 and n 2 0.068

also, n CO2 n1 2n 2

%CH 4

32.

CH 4 100
5

POAC on carbon
n C n K 2CO3 1 n K Zn
2

moles of product

33.

16n1 100
60%.%Cl2H 4 40%
5

2 Fe

CN 6 2

n K2CO 3
12

12

0.0166

n Cu n Cu NO3 2 .3H 2 O (POAC on Cu )

10
product
63.5 124 54
63.5
38.03g

34.

AgNO3 NaCl AgCl NaNO3

5.77
4.77
n
170
58.5
0.0394
0.08
L.R.
n AgCl n AgNO3 0.033
n

 AgCl 0.033 143.5 4.87g

35.

CaCO3
CaO CO 2
n1

n1

MgCO3
MgO CO2
n2

n1 100 n 2 84 1.84 n1 0.01

n 2 56 n 2 40 0.96 n 2 0.01
%CaCO3
36.

0.01 100
100 54.35%
1.84

Cl2 2KOH KCl KClO

H 2O

3KCl
O 2KCl KClO

1 1 3 n Cl
n KClO4 n Cl2 2
1 3 4
4
1385
n Cl 2 4
40
39 35.5 64

Cl2 40 71 2840g

37.

POAC on Cl (eventually on completion)

n Cl2 2 n KCl 1 n KClO4
n KCl

38.

n Cl
142
2 2 4 0.5
71
4
3.5moles

1g KClO3 n 2 moles
n1 moles

KClO 4 KCl

KCl O2

3
146.8
n O2 n 1
n1 0.00437
2
22400
1g
n2
n 0.00379
39 35.5 48 1

3
n 2 0.00284
4
1g O 2 0.79029g

n KClO4

resiude

%KClO 4

0.00284 39 35.5 64
0.79

49.789%

39.

CH 3 x AlCl y CH 4 yCl
Cl AgNO 3 AgCl NO3

100

1. n CH 4 x.n CH 3 x AlCl y

0.996
0.643
y.
108 35.5
15x 27 35.5y

2. n AgCl n Cl y.n CH3 x AlCl y

0.996
0.643
y.
108 35.5
15x 27 35.5y

1 2

in1,

x
1.99g 2
y

0.643 2y
0.222

16
30y 27 35.5y

y 1and x 2

40.

KClO3
KCl O2
2
6.125g

(1)

Zn 2HCl ZnCl 2 H 2

(2)

H 2 1 O 2 H 2O
2
in (1),
3
n O2 n KClO3 0.075
2
in (3),
n H 2 2 n O 2 0.15

(3)

in (2),
n Zn n H 2 0.15

Zn 0.15 65.3 9.795g

41.

(A): B, obviously
(B): A, obviously
7
7
I: n C n B .
2
2

42.

C O 2 CO, CO 2
n1

n2

POAC on C
12
nC
n1 n 2 1
12
POAC on O : n O n1 2n 2

n 2 1.25 1 0.25
and n1 0.75
n CO : n CO2 n1 : n 2 3 :1

20
1.25
16

43.

2NaOH H2SO4 Na 2SO4 2H 2O

n NaOH
15 1 1
4
n H2SO4
7.5 10
2
1000 10 2
H2SO4
strength
1000
VH2SO4 mL

6.125g / L

44.

Molarity

n
10 103
1000
10 3 0.1M
V mL
100

in gram / L 0.1 39 16 1 5.6g / L

45.

n
SO

2
4

100
n H 2SO 4
0.001M 10 4

1000

no. of iom n SO n A 6 1019

2
4

46.

n CuSO4 .5H 2O n Cu 2 0.5 0.01 5 10 3

weight n mol.wt 5 103 249.5

1.2475g
47.

M1V1 M 2 V2 M 3V3
50 0.5 75 0.25
50 75
0.35Molar

M final M 3

48.

49.

Molality

solvent

1000

3 30
1000 0.4molal
250

n I2
n I 2 n C6 H 6

0.2

Say, we have 1 mole mix.

Then, n I2 0.2 and n C6 H 6 0.8
molality

50.

n I2

C6 H 6

1000

0.2
1000 3.205m.
0.8 78

Consider 1L solution.
t solution 1000 1.06 10609.

KCl

10
solution 106g
100

Molailty

51.

n KCl
Vsolution (mL)

1000

106 74.5 1000

1.4228M
1000

30%NH3 . 70%water.
70
solution water 105g
100
100
i.e. solution
150 150g
70

150
Vsolution

166.67mL
density 0.9
i.e.

52.

Consider 1L of solution,
solution 1.025 1000 1025g

n ethanol M V 8 1 8moles

ethanol 8 46 368
molality

n ethanol
1000
solvent

8
1000
1025
368

12.176molal

53.

2SO2 O 2 2SO3
nSO 2 nSO3 nSO3 5

Page 53 of booklet missing. Q 54 50 63

58.

AgCl AgBr
n1

n2

n1 n 2 108 60.94
%Ag

100 n1 143.5 n 2 188 100

n1
0.31955
n2

n1
35.5 100
n
n1 35.5
%Cl
100 2
n1 143.5 n 2 188
n1
143.5 188
n2
4.856%
%Br 100 60.94 4.856 34.2%

59.

CO2 H 2O unbalanced
COOH 2
H SO
2

POAC n C n CO2 1 n COOH 2

10
2
2
90
9

2
V CO2 22.4L 4.977L
9
60.

acid is H3A. salt is Ag3A

1moleAg3A 3mole Ag
n

n Ag 3 A

Ag 0.37 108

0.00114
3
3

0.607
0.00114
mol.wt of Ag 3A

mol.wt 108 3 A 531

A 207
wt of H 3A 210

GET EQUIPPED
ONLY ONE OPTION
1.

N2 3H 2 2NH3
3x

say, wt :14x

14x x
3x

28 2
2
x
3x
tt
y
3y
2
2
NH3 was 40% by mol.

n, t o

2y

40 x
3x

3y 2y
.y
100 2
2

2x
x
5y 2x 2y y
3.5
7
y

i.e. 2y

X N2

x y
2 1
x 2 y

2x 2y y 2 x y 1

1.75 1 0.75

2 2.5
5
0.15

(A)
2.

A n B.(obviously)

M A A A 1.4g and M B n B 0.8

M B 0.8

0.57.
M A 1.4

(C)

3.

with
3.2g metal
0.4g oxygen

64g metal g oxygen

64
0.4 8g
3.2
128g metal with 16g O

i.e. H 2O
(B)
4.

with
4M
4.28g O. sin ce X 4O 6
with
5.72g
4.28g O

MX

5.72 6 16
32
4 4.28

(A)
5.

224

0.01
mol.wt 22400
wt
1
mol.wt

100
n 0.01
n

3 at.wt. 100 at.wt 33.3g

mass of one atom

33.3
5.53 1023g
23
6.02 10

(C)
6.

PV
2 0.35

3.123 10 2
mol.wt RT 0.0821 273
1
i.e.
3.123 102
2 At.wt
at.wt 16
wt of one atom

.
NA
NA
n

(C)
7.

I 2 Cl2 ICl, ICl3

n1

n2

POAC on I
25.4
n
I
n1 n 2
127

n1 0.1

n 2 0.1
POAC on Cl
14.2
n
Cl
n1 3n 2
35.5
n1 : n 2 1:1
(A)

8.

FeSO4 : n1 SO 42 n1 and Fe 2 n1
Fe 2 SO 4 3 : n 2 SO 42 3n 2 and Fe3 2n 2

n1 3n 2 given

n1
3
n2

Fe 2
n
1 3
3
Fe
2n 2
Fe 2
n
n n
1 1 2 3: 2
3
Fe
2n 2
2
(D)
9.

0.36M : V1 say and 0.15M : V2say

M final 0.24

M1V1 M 2 V2
V1 V2

36V1 0.15V2
0.24
V1 V2

0.36
or

V1

V1

V2

V2

0.15
0.24

V
V
0.12 1 0.15 0.24 1 0.24
V2
V2
V 0.09 3
1

V2 0.12 4

(D)
10.

At mass N A mass of an atom

6 1023 3.98 1023 24g

(C)
11.

Fe2 Fe CN 6

Fe 3 56 7

C 6 12 3
(C)
12.

obvious (D)

13.

obvious (B)

14.

1gatom 1mole of atom 14g.

(A)

15.

Na 2CO3 2HCl 2NaCl H 2O CO 2

n HCl 2 n Na 2CO3 VHCl M HCl

 V3 2

1.431
V 9mL.
106

(B)
16.

17.

They must have same mol. wt.

(C)

V2micron sphere
V

20 Asphere

4 2 10 6 3
3
109
3

9
4 2 10
3

(A)
18.

19.

KClO3
KCl O2
2
n o2 0.1 2
n KClO3

3
3
30
2
2
2
122.5
30
% purity
100 81.66%
10
(B)
V m2 m

1 0.65

6.5 10 4 moles
1000
1000
BaCl2 .2H 2 O 137 71 36 6.5 10 4 0.1586g
n

BaCl2 137 71 6.5 10 4 0.1352g

(A)
20.

1.36 V 200 2.4

1.24
500
V 102.941mL
(B)
11.5

100
M C6 H5CH3 9.31g
71

21.

22.

CuSO4 .5H 2O : n, MgSO4 .7H 2O : n 2

M C6H5COOK

total t 5g and anhydrous 3g

n1 249 249n 2 5
and n1 159 120n 2 3
on solving, n1 0.0149 and n 2 0.0052

CuSO4 .7H2O3.729g.
%by t
(C)

3.72
100 74.4%
5

23.

C 7 H 6 O 3 C 4 H 6 O 3 C9 H 8 O 4 C 2 H 4 O 2

: 2g

4g

n : 0.0144 0.039

0.01449

L.R

theoretical yield 0.01449 M Ca H8O 4

2.69

%yeild 80.76%
(A)
24.

2 XI 3Cl 2 2XCl3 3I 2
3

n XI3 n XCl3

0.5
0.236

M 381 M 106.5

M 138.88 139

(B)

25.

2
2
no.of molecular 500cm 0.21nm
n

V Molarity
NA
6 10 23

i.e.V

n
2.395 10 5 L.
4.24
256

(B)
26.

in 10 mL CuCl2 : n, and CuBr2 : n 2

n AgBr 2n 2 and n AgCl 2n,
2n1 143.5 2n 2 188 0.9065g

and 2n1 2n 2 188 1.005g

then n1 0.00115 and cuBr2 0.35g
25% and 58%

(A)
27.

n XH 4 2n and n X2 H6 n, say

n x mXH4 n X2H6X 2 4n
5
4n and 2n X 4 n. 2X 6 5.628
X
5
5
i.e. X 4
2X 6 5.628
X
4X
5 10 5 7.5
or,
5.628
2 2 2 X
17.5
or X
27.86 28
0.628
(A)
i.e.

28.

0.0125 39 80
0.0105M
1mL
42.5
0.0105
n AgNO3
1000
0.00446
n AgNO3 n NaBr 2n Na 2SO 4
M AgNO3

n1

n2

n1 2n 2 0.00446

also, n1 103 n 2 142 2 5 t of 1

29.

th

portion

Let acid be HA
Salt: BaA 2 .2H 2O
BaA 2 H 2SO 4
BaSO4 2HA
n

H 2SO4 H 2SO4
BaSO 4 2HA

4.29 21.64

0.477
137 1000
A 121

30.

HA 122

total moles =n (say)

0.15 n n CH 3 XCOOH and 85n n H 2O

0.15n 60 0.85 n 18 30
n

30
1.234
9 15.3

n NaOH n CH 3COOH 0.15 n 0.18519

VNaOH 18.5 L B

31.

C2 H 6 3.50 2
n1 moles

2CO2 3 H 2O

C2 H 4 3O2
2CO2 2 H 2O
n2 moles

PV
1 40

1.218
RT 0.0821 400
130
also 3.5 n1 3n2 nO2
4.06
32
n1 0.817
n1 n2

n2 0.401
%C2 H 4 333% and C2 H 6 67% A

32.
Al
K
S
O

%
10.5
15.1
24.8
49.6

no. of atom
0.3889
0.388
0.775
3.1

ratio
1
1
2
8

33.

Vmolecule

100
A

300
A

1.299 10 24
mol. Wt N A Vmol desnity

6 1023 1.299 1024 1.2 103 kg m3

939 kg (B)

1.

One and more than one right

3 moles in 1L 1250 g

wNa2S2O3 3 46 64 48 474
474
100 37.92%
1250
3
3
(B) x

0.065
1250 474 46.11
3

18

n
(C) molality of Na
1000
wsolvent
(A) % by weight

3 2
1000 7.73
1250 474

2.

mo. wt = wt of 22.4 L=28.896 g

mol.wt
VD
14.48
2
(A) and (B)

3.

[A] : 32 g

4.

Ca NO3 2 Na2C2O4
CaC2O4 2 NaNO3

millimoles :

[ B]

1
b 4 32 g
2

6
3

3
LR

[A],[C],[D]
5.

1.12
0.02
56
0.02 100 2 g

CaO n CaCO3

wCaCO3

wCaCl2 0.02 111 2.22 g

wNaCl 2.22 g

[ A, C]
6.

NaCl 100 m moles ; n HCl 300 m moles

CaCl2 200 m moles 200 Ca 2 , 400 Cl

[ D] : 32 g

cation 600 3

anions 800 4
Cl 800 2 M

400
A , C
7.

Obvious A,B,D

8.

3 mole NH 3

n H 4

wH 3 14 42 g
WN 3 14 42 g
molecule 3NA 18 10 23
atoms 4 3 N A 72 1023
[ A], [B]. [C],[D]
9.

Obvious : [A], [B]

10.

[B],[C]: obvious others depend on volume

n:
5m
5 millimoles in 100 ml
Hence [C] and [D]

14.

5m

Hence [C], [D]

14
Mol. Wt
22.4 28
11.2

Match the following

1.

2.

13 12
100 38.33%
407
6
(II) wt % of H
100 1.47%
407
(III) wt of H: wt of Cl 6 : 6 35.5
(IV) mo. of C: O =13:2

(I) wt % of C

(a)

wSO2
Wo2

(D)
(A)
(C)

2 s

(b) d 10 5 2 g cc sp. gr 2 s
(c) M 2VD 32 Q
(d) molecular

3.

132
3
44

20
(a) Al 3
0.04 M

400

at anons = 9(R)

(E)

 H 40 0.084

500
Total =0.12 M
Cl 60 40 0.2 M

500
(P), (S)
20
(b) K
0.2M
100
Cl 20 0.2 M

100
(S)
12
(c) K
0.12 M
100
[ P], [Q]
SO42 6 0.06 M

100
[S]
24.5
(d) wH 2 SO4 200
49 n H 2 SO4 1 2
100
H 1 1000 5 M

200
SO42 1 2 1000 2.5M

200
[R]
4.

(A) VSO2 11.2 L

wSO2 32 g

1
total atoms 2 N A
2

(B) n H 2 1 2 VH 2 11.2 L
wH 2 1 g , , total atoms N A P

(C) no. of atoms 0.5 3 N A 1.5 N A

[P], [Q], [R]
(D) 1moleO2 V 22.4 L
Atoms 12 10 23
wt 32 g

[S]

COMPREHENSION
Passage 1
1.

wt of 1 atom 1amu 1.66 1024 g. (C)

2.

n S n H2SO4 100 wt 3200g. (A)

3.

3.4
M s 2 32 M 1882.3 (B)
100

4.

C O 2 n C n C n O2 1
VO 2

20
Vair 22.4C Vair 112L (B)
100

Passage 2
1.

Consider 1 L.
n KOH 6.9 KOH 6.9 56 386.4
30
solu 386.4 solu 1288g
100
d 1.2889g / mL. (A)

2.

3.

4.

134
PV
0.2 2
m H 2SO4 2 n NH3

1000
RT 0.0821 303
MH2SO4 0.06 (C)
1600 0.205
0.2 V 40mL ()
1600 V

n H 2S

n H 2SO4

5 34
5
1
5
34
V 0.2 5 V 25L (A)

n H 2SO4

Passage 3
18g
3 1023 g (D)
23
6 10

1.

m H2O

2.

Avogadros law. (A)

3.

obvious Mass is 16amu. (C)

4.

obvious (A)

Passage 4
1.

AgNO3 NaCl AgCl NaNO 3

5.77
170
0.0339

4.77
n AgCl 0.0339
58.5
wt 4.88g
0.081

n:

L.R (A)

2.

repeated passage 2, Q-2

3.

H2SO4 0.12 98 11.7g (A)

INTEGER

1.

0.5 mole N3 .N 3 has 10e .

5 moles.
2.

10.5 103 kg / m 3 mass 10.5 103 10 12

1.05 10 8 kg
n Ag

3.

1.05 105
atom n Ag n A
108
5.83 1016

MCl X : say. mol.wt M 106.5

n Cl n MClX X
n Cl n Ag

0.22x
M 106.5

0.51
3 103
170

6.4
112s (Dulong petites law)
0.57
0.22 x

3 103 x 3
112 106.5
M

8 2800

4
100 56

4.

n Fe

5.

x 5 20 2
2.6 5x 40 2.6x 52
x 20

6.

n 1

C n H 2n 2 n
O2 n CO2 n 1 H 2 O
2

n 1
2 7 4n 3n 2 7n or n 2
n
4

1440

2
mol.wt 60 12

7.

8.

5
solu 0.3g solu 6g
100

9.

0.25
89600 Fe n 56 n 4.s
100

10.

CO 2 C6 H10 O5

1g a lg ac
2g a lg ac
1gstrach
1g strach

POAC on carbon
n CO2 1 n C6 H10 O 6
5

1
1
6
162
27
1 27
time
8
4.7 10 3

EXPERTISE ATTAINERS
1.

POAC on Co
n CO3O 4 3 n CO 1

CO

0.2125 3
CO n C0 59 0.156g
177 64

PPt 1 n Co

ppt n ppt mol.wt 1.52 g

2.

90
0.5g Fe Fe 2O3 n1
100
10
0.5g Fe
Fe3O 4 n 2
100
0.45
n1 2
n1 0.04
56
0.05
n2 3
n 2 0.0003
56
wt of mix= 160 n1 232 n 2 0.71g

(a)

(b) 0.59 Fe
Fe 2 O 3 n
h2

0.5
n 4.46 103
56

 Fe2 O3 0.7142 g

3.

(i) n AgNO3 n AgCl n NaCl n HCl

n1
n2
2.567
n1 n 2 0.0179
143.5
(ii) NaCl is not affected
1.341
n
Cl n AgCl n 2
143.5
n

0.009345
2

n1 0.0856

Now, n1 58.5 n 2 M 1gram

0.5
53.5
0.009345

4.

4
Z
C x H y Clz O2
xCO2 H 2 O Cl2
2
2

0.22
0.195
n
(1)

x CO2
44
12x y 35.5Z

y n
0.22
0.0804
..(2)

H 2O
12x

35.5z
z
18

768 37.24

0.12
PV 760 1000

0.0012

n
RT
0.0821 382
12x y 35.5z
Solving, x 2; y 4 and z 2

C 2 H 4Cl
5.

Consider 1 mole mix t 55.4

N 2 , NO 2 , N 2O 4
n1

n2

n3

n1 n 2 n 3 1
Now, after heating,

N O

2NO2

NO 2 n 2 2n 3

no. of moles = n1 n 2 2n 3 1 n 3

New Angular mol. Wt 39.57 =

55.4

39.57
1 n3
n 3 0.4

Now, n1 28 n 2 46 n 3 92 55.4
28n1 46n 2 18.6

also n1 n 2 n3 1

(1)

..(3)

 n1 n 2 0.6

.(2)

Solving (1) and (2),

n1 0.5 ,and n 2 0.1
5 :1: 4
n

6.

IO3 n HSO3 n
3 5.8

HSO3
0.8788
1
3
23 127 48

w NaHSO3 9.139 g
I in 1st n IO3

5.8
198

IO3 n I n

IO3 0.00586
1
5
M NaIO3 5.8 198
n

IO3
0.2L 200 mL
M IO
n

7.

AgNO3 KI KNO 3 AgI

2KI KIO3 6HCl 3ICl 3KCl 3H 2O

KIO3
M KI VKI
M 20

KI

2
1
2
M KI 0.3 M

30

1
10

KI, excess n KIO3 n

Now,

KI, excess 10 m mole

2
1
Original KI 50 0.3 15 m mole
KI used 5m mole
n AgNO 3 n KI used 5M.mole w AgNO 3 0.85 g
purity 85%