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    T D T E: We Can Improve This Fit by Adjusting The Maxwell Model To Allow Multiple Relaxation Modes

    Uploaded by

    Shawn Waltz
    The document discusses linear viscoelastic models including the Maxwell model, generalized Maxwell model, and a more general linear viscoelastic model. It provides the equations for each model and compares their abilities to predict material behavior under different conditions like shear thinning.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd

    T D T E: We Can Improve This Fit by Adjusting The Maxwell Model To Allow Multiple Relaxation Modes

    Uploaded by

    Shawn Waltz
    3 views3 pages
    The document discusses linear viscoelastic models including the Maxwell model, generalized Maxwell model, and a more general linear viscoelastic model. It provides the equations for each model and compares their abilities to predict material behavior under different conditions like shear thinning.

    Original Description:

    Rheology Lecture 30

    Original Title

    Lecture 30

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    © Attribution Non-Commercial (BY-NC)

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    The document discusses linear viscoelastic models including the Maxwell model, generalized Maxwell model, and a more general linear viscoelastic model. It provides the equations for each model and compares their abilities to predict material behavior under different conditions like shear thinning.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    3 views3 pages

    T D T E: We Can Improve This Fit by Adjusting The Maxwell Model To Allow Multiple Relaxation Modes

    Uploaded by

    Shawn Waltz
    The document discusses linear viscoelastic models including the Maxwell model, generalized Maxwell model, and a more general linear viscoelastic model. It provides the equations for each model and compares their abilities to predict material behavior under different conditions like shear thinning.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    1

    Faith A. Morrison, Michigan Tech U.


    We can improve this fit by adjusting the Maxwell
    model to allow multiple relaxation modes

    }
    =


    =

    |
    |
    .
    |

    \
    |
    =
    N
    k
    k
    t
    t t
    k
    k
    k
    t
    t d t e
    k
    1
    ) (
    / ) (
    ) (
    ) (
    ) (

    }


    =


    (

    =
    t
    k
    t t
    k
    k
    t d t e
    k
    ) (
    3
    1
    / ) (

    Generalized
    Maxwell
    Model
    2N parameters (can fit anything)
    Predictions of the Generalized Maxwell Model
    Faith A. Morrison, Michigan Tech U.
    Steady shear
    0
    2 1
    1
    = =
    =

    =
    N
    k
    k

    Fails to predict shear
    normal stresses
    Fails to predict shear-
    thinning
    }


    =


    (

    =
    t
    k
    t t
    k
    k
    t d t e
    k
    ) (
    3
    1
    / ) (

    Step shear
    strain
    0
    ) (
    2 1
    1
    /
    = =
    =

    =

    G G
    e t G
    N
    k
    t
    k
    k k

    This function can fit any


    observed data; note that the
    GMM does not predict shear
    normal stresses.
    2
    10
    100
    1,000
    10,000
    1 10 100 1000 10000
    time, t
    G(t), Pa
    k k gk
    1 450 500
    2 100 900
    3 30 1300
    4 5.0 1600
    k=4 k=3 k=2
    k=1

    4
    1 k
    t
    k
    k
    e g

    Faith A. Morrison, Michigan Tech U.
    Fitting G(t) to Generalized Maxwell Model
    Figure 8.4, p. 274 data
    from Einaga et al., PS
    20% soln in chlorinated
    diphenyl
    Faith A. Morrison, Michigan Tech U.
    The Linear-Viscoelastic Models


    0
    0
    =

    +
    t G
    Differential Maxwell
    (one mode):
    ( )
    t d t e
    t t t
    =
    }

    ) (
    0

    Integral Maxwell
    (one mode):
    ( )
    t d t e
    t
    N
    k
    t t
    k
    k k

    (
    (

    =
    }


    =

    ) (
    1

    Generalized Maxwell
    model (N modes):
    3
    Faith A. Morrison, Michigan Tech U.
    The Linear-Viscoelastic Models


    0
    0
    =

    +
    t G
    Differential Maxwell
    (one mode):
    ( )
    t d t e
    t t t
    =
    }

    ) (
    0

    Integral Maxwell
    (one mode):
    ( )
    t d t e
    t
    N
    k
    t t
    k
    k k

    (
    (

    =
    }


    =

    ) (
    1

    Generalized Maxwell
    model (N modes):
    Since the term in brackets is just the predicted relaxation modulus
    G(t), we can write an even more general linear viscoelastic model
    by leaving this function unspecified.
    Faith A. Morrison, Michigan Tech U.
    The Linear-Viscoelastic Models


    0
    0
    =

    +
    t G
    Differential Maxwell
    (one mode):
    ( )
    t d t e
    t t t
    =
    }

    ) (
    0

    Integral Maxwell
    (one mode):
    ( )
    t d t e
    t
    N
    k
    t t
    k
    k k

    (
    (

    =
    }


    =

    ) (
    1

    Generalized Maxwell
    model (N modes):
    t d t t t G
    t
    =
    }

    ) ( ) (
    Generalized Linear-
    Viscoelastic Model:

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