UNIVERSITY OF CAMBRIDGE LOCAL EXAMINATIONS SYNDICATE

General Certificate of Education Ordinary Level

CHEMISTRY 5070/1
PAPER 1 Multiple Choice
Friday 18 JUNE 1999 Morning 1 hour

Additional materials:
Electronic calculator and/or Mathematical tables
Multiple choice answer sheet
Soft clean eraser
Soft pencil (type B or HB is recommended)

TIME 1 hour

INSTRUCTIONS TO CANDIDATES
Do not open this booklet until you are told to do so.
Write your name, Centre number and candidate number on the answer sheet in the spaces provided
unless this has already been done for you.
There are forty questions in this paper. Answer all questions. For each question, there are four
possible answers, A, B, C and D. Choose the one you consider correct and record your choice in soft
pencil on the separate answer sheet.
Read very carefully the instructions on the answer sheet.

INFORMATION FOR CANDIDATES

Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
Mathematical tables are available. You may use a calculator.
A copy of the Periodic Table is printed on page 16.

This question paper consists of 16 printed pages.

SB (KG) QF92362/3
© UCLES 1999 [Turn over
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1 In the Haber process, nitrogen and hydrogen react to form ammonia.

Which set of diagrams represents the molecules of nitrogen, hydrogen and ammonia?

nitrogen hydrogen ammonia

2 An ion X + has 23 nucleons and 10 electrons.

What does the nucleus of the ion X + contain?

protons neutrons
A 12 11
B 11 12
C 10 13
D 9 14

3 Which of the following has the highest electrical conductivity?

A aqueous sugar solution

B solid graphite
C solid sodium chloride
D gaseous carbon dioxide

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4 A mixture of two liquids in equal proportions is fractionally distilled.

When the thermometer first shows a steady reading, at which point will there be the greater
proportion of the liquid with the higher boiling point?

thermometer

C
mixture D
of liquids

heat

5 The apparatus shown is set up, using different gases in the beaker.

beaker

porous pot
oxygen

water

Which gas, when present in the beaker, causes the water level at X to rise?

A carbon dioxide, CO2

B chlorine, Cl2
C nitrogen dioxide, NO2
D methane, CH4

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6 A number for the elements from oxygen to aluminium changes as shown.

number
for the
element

O F Ne Na Mg Al
element

What is this number?

A the Group number of the element in the Periodic Table

B the number of electron shells in an atom
C the number of electrons in the outer shell of an atom
D the number of protons in an atom

7 In an experiment to find the formula of magnesium oxide, magnesium metal is heated in a covered
crucible.

magnesium

heat

Why is the crucible covered with a loose-fitting lid?

A to prevent air escaping from the crucible

B to prevent magnesium carbonate forming
C to prevent magnesium oxide escaping from the crucible
D to prevent water vapour entering the crucible

8 A solid element conducts electricity. The element burns in air to form a white solid. This white solid
dissolves in water to give an alkaline solution.

What is the element?

A aluminium
B calcium
C carbon
D copper
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9 Silver ions react with chloride ions.

Ag+(aq) + Cl −(aq) → AgCl(s)

It is found that 5 cm3 of a 0.1 mol/dm3 solution of the chloride of metal X needs 10 cm3 of
0.1 mol/dm3 silver nitrate for complete reaction.

What is the formula of the chloride?

A XCl 4 B XCl 2 C XCl D X2Cl

10 Which equation represents the combustion of methane with the products collected at 120 °C?

A CH4(l) + 2O2(g) → CO2(g) + 2H2O(l)

B CH4(g) + 2O2(l) → CO2(s) + 2H2O(l)
C CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
D CH4(l) + 2O2(l) → CO2(l) + 2H2O(s)

11 Which change always takes place when aqueous copper(II) sulphate is electrolysed?

A Copper is deposited at the negative electrode.

B Oxygen is evolved at the positive electrode.
C Sulphate ions move towards the negative electrode.
D The colour of the solution fades.

12 The electrolysis shown in the diagram is set up.

carbon + –
electrodes

concentrated aqueous
potassium iodide

What is observed?

at positive electrode at negative electrode

A solution turns brown bubbles of colourless gas
B solution turns brown silvery droplets
C bubbles of colourless gas bubbles of colourless gas
D bubbles of colourless gas solution turns brown

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13 Hydrogen reacts with chlorine.

H2(g) + Cl2(g) → 2HCl(g) ∆H = −184 kJ

Why does ∆H for this reaction have a negative sign?

A Hydrogen and chlorine are covalent, but hydrogen chloride is ionic.

B More bonds are formed than are broken.
C The total energy of bond breaking is less than that of bond forming.
D The speed of the reaction increases as temperature increases.

14 Why is vanadium(V) oxide used in the oxidation of sulphur dioxide to sulphur trioxide?

A It acts as a reducing agent.

B It prevents the decomposition of sulphur trioxide.
C It removes impurities.
D It speeds up the reaction.

15 In the graph, curve X represents the results of the reaction between 1.0 g of granulated zinc and
an excess of acid at 30 °C.

total volume of
gas produced Y
(measured
at r.t.p.)

time

Which changes will produce curve Y?

A using 1.0 g of powdered zinc at 20 °C

B using 1.0 g of granulated zinc at 20 °C
C using 0.5 g of granulated zinc at 40 °C
D using 0.5 g of granulated zinc at 20 °C

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16 Which element in the reaction below is oxidised?

2FeSO4 + Cl2 + H2SO4 → Fe2(SO4)3 + 2HCl

A chlorine
B hydrogen
C iron
D sulphur

17 The word equation shows a chemical reaction.

sulphuric acid + substance Y a salt + water + carbon dioxide

What could substance Y be?

A copper(II) oxide
B magnesium
C sodium carbonate
D sodium hydroxide

18 Solid R is gradually added to aqueous solution S. The changes in pH are shown on the graph.

14

pH 7

0
mass of solid R added

What are R and S?

R S
A insoluble metal oxide hydrochloric acid
B insoluble non-metal oxide sodium hydroxide
C soluble metal oxide hydrochloric acid
D soluble non-metal oxide sodium hydroxide

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19 A solution X forms a white precipitate with dilute sulphuric acid and also with aqueous silver
nitrate.

What could solution X contain?

A barium chloride
B barium nitrate
C magnesium chloride
D magnesium sulphate

20 The diagram shows apparatus used to test the gases produced by burning coal.

to pump

burning coal R

Which substance is placed in tube R to show that sulphur dioxide is formed?

A aqueous potassium dichromate(VI)

B aqueous potassium iodide
C damp red litmus paper
D limewater

21 Which of the following is a typical property of transition metals?

A They form coloured compounds.

B They have low densities.
C They have low melting points.
D They react with cold water to give hydrogen.

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22 The structure of a compound containing an element Y and hydrogen is represented as shown.

Only outer shell electrons are shown.

key
H H x = electron from Y
x x
x x x = electron from H
x Y Y x x
x x
H H
To which group of the Periodic Table does element Y belong?

A III B IV C V D VI

23 The diagram shows the positions of four elements in the Periodic Table.

Which element gains electrons to form negatively charged ions?

I II III IV V VI VII 0

D C B

24 Which substance can be reduced by heating with carbon?

A aluminium oxide
B calcium carbonate
C iron(III) oxide
D magnesium oxide

25 What happens when zinc is placed in aqueous copper(II) sulphate?

A Copper atoms are oxidised.

B Zinc atoms are oxidised.
C Copper ions are oxidised.
D Zinc ions are oxidised.

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26 The table shows some typical properties of metals and non-metals.

Which properties for a metal and for a non-metal are both correct?

metals non-metals
A do not conduct electricity usually have a low melting point
B usually have a high melting point good conductor of heat
C shiny when polished good conductor of electricity
D good conductor of electricity usually dull in appearance

27 The list shows four metals and hydrogen in order of reactivity.

most reactive rubidium

potassium
tin
hydrogen
least reactive gold

Which of the following do not give hydrogen as a product?

A The adding of rubidium to water.

B The adding of tin to dilute hydrochloric acid.
C The electrolysis of aqueous gold chloride.
D The electrolysis of aqueous rubidium chloride.

28 Which substance does not need air as a raw material for its manufacture?

A ammonia
B iron
C sodium
D sulphuric acid

29 Which of the following is a reaction of dilute hydrochloric acid?

A Ammonium chloride reacts to give ammonia.

B Calcium carbonate reacts to give carbon dioxide.
C Copper reacts to give hydrogen.
D Universal Indicator paper turns blue.

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30 The diagram shows a reaction used to manufacture a fertilizer.

ammonia + substance X a fertilizer

What could substance X be?

A lime (calcium oxide)

B nitrogen
C potassium hydroxide
D sulphuric acid

31 Which of the following is not a use of silicon or its compounds?

A making fire-resistant plastics

B making glass
C making polishes
D making smokeless fuel

32 Which statement best confirms that two substances are allotropes of carbon?

A They both reduce heated iron(III) oxide to iron.

B They have different crystalline structures.
C Equal masses of the substances require equal masses of oxygen for complete combustion.
D Equal masses of the substances give equal masses of carbon dioxide, and no other product,
when completely burnt in oxygen.

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33 The structure of butan-1-ol is shown.

H H H H

H C C C C OH

H H H H

Which structure is an isomer of that shown above?

H H H OH

A H C C C C H

H H H H

H H

H C C H
B
H C H H C H

H OH

H H

H C C H H
C
H H C C OH

H H

H H H H

D H C C C C H

H H OH H

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34 The diagram shows the fractional distillation of petroleum.

fraction
X

fraction
Y
heated
petroleum

Which statements about fractions X and Y are correct?

X burns more easily X has a higher boiling point

than Y than Y
A yes yes
B yes no
C no yes
D no no

35 Which set contains all the possible combustion products of methane, CH4?

A carbon, carbon dioxide, carbon monoxide and water

B carbon, carbon monoxide and hydrogen
C carbon dioxide, carbon monoxide, hydrogen and water
D carbon monoxide and water

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36 The structures of two compounds are shown.

H H

H H C H H H H H C H H

H C C C C H H C C C C H

H H H C H H H H C H H

H H

Which statement about these two compounds is correct?

A They are both hydrocarbons.

B They are both saturated compounds.
C They are in the same homologous series.
D They are isomers of each other.

37 Equal masses of coconut oil, butter, margarine and palm oil are separately dissolved in an organic
solvent.

A few drops of aqueous bromine are added to each solution and the mixtures are shaken.

The table shows the results.

Which sample contains the most unsaturation?

sample colour of mixture

A butter orange
B coconut oil dark orange
C margarine yellow
D palm oil colourless

38 When an animal fat is boiled with aqueous sodium hydroxide, a soap and glycerol are formed.

This reaction is an example of

A esterification.
B fermentation.
C hydrolysis.
D polymerisation.

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39 The structure of the monomer of Perspex is shown.

H CH3

C C

H CO2CH3

Which description of Perspex is correct?

type of polymer polymer formed by

A carbohydrate condensation polymerisation
B ester addition polymerisation
C hydrocarbon addition polymerisation
D polyester condensation polymerisation

40 The apparatus shown was set up to prepare ethanoic acid from ethanol.

water out
condenser

cold water
in

ethanol and acidified

potassium dichromate(VI)

heat

What was the purpose of the condenser?

A to make sure air does not react with ethanol

B to stop ethanoic acid changing back to ethanol
C to stop ethanol being converted into ethene
D to stop ethanol vapour escaping

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 DATA SHEET
The Periodic Table of the Elements
Group
I II III IV V VI VII 0
1 4
H He
Hydrogen Helium
1 2

7 9 11 12 14 16 19 20
Li Be B C N O F Ne
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
3 4 5 6 7 8 9 10

23 24 27 28 31 32 35.5 40
Na Mg Al Si P S Cl Ar
Sodium Magnesium Aluminium Silicon Phosphorus Sulphur Chlorine Argon
11 12 13 14 15 16 17 18

39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
16

85 88 89 91 93 96 101 103 106 108 112 115 119 122 128 127 131

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Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

133 137 139 178 181 184 186 190 192 195 197 201 204 207 209

Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Caesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
55 56 57 * 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

226 227

Fr Ra Ac
Francium Radium Actinium
87 88 89 †

140 141 144 150 152 157 159 162 165 167 169 173 175
*58-71 Lanthanoid series
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
†90-103 Actinoid series Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
58 59 60 61 62 63 64 65 66 67 68 69 70 71
a a = relative atomic mass 232 238
Key X X = atomic symbol Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
b b = proton (atomic) number 90 91 92 93 94 95 96 97 98 99 100 101 102 103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).