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Chapter - 7: FTIR - Spectroscopic Studies

This document discusses Fourier transform infrared (FTIR) spectroscopy. It begins by introducing infrared spectroscopy and explaining how molecules absorb specific infrared frequencies that are characteristic of their structure. It then describes the theory behind FTIR spectroscopy, including how it uses Fourier transforms to separate infrared signals from noise. The document outlines the practical aspects of FTIR spectroscopy, including sample preparation techniques and the use of a reference sample for comparison. It provides examples of applications like determining amounts in mixtures and identifying unknown materials.

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Chapter - 7: FTIR - Spectroscopic Studies

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Chapter 7

FTIR Spectroscopic Studies

CHAPTER - 7
FTIR SPECTROSCOPIC STUDIES
7.1. Introduction
Infrared spectroscopy (IR spectroscopy) is the subset of Spectroscopy that
deals with the infrared region of the electromagnetic spectrum. It covers a range of
techniques, the most common being a form of absorption spectroscopy. As with all
spectroscopic techniques, it can be used to identify compounds and investigate sample
composition. A common laboratory instrument that uses this technique is an infrared
spectro photometer. A molecule is a collection of atoms. The atom in a molecule
executes different types of vibrational motion. The energy of most of these molecular
vibrations is quantized and corresponds to that to the infrared regions of the
electromagnetic spectrum. When infra red radiation of the same frequency is allowed
fall on the molecule, the system absorbs energies, carrying the excitation of the
molecule to higher vibrational levels[123]. The molecules absorbing a quantum of
energy give rise to bands characteristic of the molecule from about 200 to 4000 cm-1.
Functional groups can be identified spectra one of the most reliable methods for
understanding the structure of the molecules [124].
The infrared portion of the electromagnetic spectrum is usually divided into
three regions; the near-, mid- and far- infrared, named for their relation to the visible
spectrum. The far-infrared, approximately 40010 cm-1 (100030 m), lying adjacent
to the microwave region, has low energy and may be used for rotational spectroscopy.
The mid-infrared, approximately 4000 400 cm1 (30 2.5 m) may be used to study
the fundamental vibrations and associated rotational-vibrational structure. The higher
261

energy near-IR, approximately 140004000 cm1 (2.50.8 m) can excite overtone or

harmonic vibrations

[125]

. The names and classifications of these sub regions are

merely conventions. They are neither strict division nor based on exact molecular or
electromagnetic properties.
7.2. Theory
FT-IR stands for Fourier Transform Infra Red, the preferred method of
infrared spectroscopy. It was first developed by astronomers in the early 1950s to
study the infrared spectra of distant stars, has now been developed into a very
powerful technique for the detection of very weak signals from the environment
noise. It is a simple mathematical technique to reverse a complex wave into its
frequency components. The conventional IR spectrometers are not of much use for
the far IR region (20 400 cm-1) as the sources are weak and the detectors are
insensitive. FT-IR has made this energy limited region more accessible. It has made
the middle infrared (400 4000 cm-1) also more useful [124].
Infrared spectroscopy exploits the fact that molecules absorb specific
frequencies that are characteristic of their structure. These absorptions are resonant
frequencies, i.e. the frequency of the absorbed radiation matches the frequency of the
bond or group that vibrates. The energies are determined by the shape of the
molecular potential energy surfaces, the masses of the atoms, and the associated
vibronic coupling.
In order for a vibrational mode in a molecule to be "IR active," it must be
associated with changes in the permanent dipole.
A molecule can vibrate in many ways, and each way is called a vibrational
mode. Linear molecules have 3N5 degrees of vibrational modes whereas nonlinear
262

molecules have 3N6 degrees of vibrational modes (also called vibrational degrees of
freedom). As an example H2O, a non-linear molecule, will have 336 = 3 degrees of
vibrational freedom, or modes [124].
Simple diatomic molecules have only one bond and only one vibrational band.
If the molecule is symmetrical, e.g. N2, the band is not observed in the IR spectrum,
but only in the Raman spectrum

[126]

. Unsymmetrical diatomic molecules, e.g. CO,

absorb in the IR spectrum. More complex molecules have many bonds, and their
vibrational spectra are correspondingly more complex, i.e. big molecules have many
peaks in their IR spectra. The atoms in a CH2 group, commonly found in organic
compounds can vibrate in six different ways: symmetric and antisymmetric stretching,
scissoring, rocking, wagging and twisting.
Using the information of FT-IR, We can determine the amount of components
in a mixture, the quality of consistency of a sample and identify unknown materials

7.3. Practical IR spectroscopy

The infrared spectrum of a sample is recorded by passing a beam of infrared
light through the sample. Heated silicon carbide rods, heated ceramic rods coated with
rare earth oxides, tungsten and carbon are used as sources of infrared radiation.
Examination of the transmitted light reveals how much energy was absorbed at each
wavelength. This can be done with a monochromatic beam, which changes in
wavelength over time, or by using a Fourier Transform instrument to measure all
wavelengths at once. From this, a transmittance or absorbance spectrum can be
produced, showing at which IR wavelengths the sample absorbs. Analysis of these
absorption characteristics reveals details about the molecular structure of the sample.

263

When the frequency of the IR is the same as the vibrational frequency of a bond,
absorption occurs. This technique works almost exclusively on samples with covalent
bonds. Simple spectra are obtained from samples with few IR active bonds and high
levels of purity. More complex molecular structures lead to more absorption bands
and more complex spectra. The technique has been used for the characterization of
very complex mixtures.

7.4. Sample preparation

In the Fourier transform infrared spectrum the samples are prepared by the
pressed pellet technique. In this technique a small amount of the ground solid sample
is mixed with about 100 times its weight of potassium bromide (KBr). The finely
ground mixture is pressed under very high pressure to form small pellet. The pellets
are then exposed to a source of continuous infrared radiation. The spectrometer
dispenses. The radiation into a spectrum and the detector converts the radiant energy
into an electrically signal which is amplified electronically and recoded by a chart
recorder.
Liquid samples can be sandwiched between two plates of a salt (commonly
sodium chloride, or common salt, although a number of other salts such as potasium
bromide or calcium fluoride are also used).[127] The plates are transparent to the
infrared light and do not introduce any lines onto the spectra. A means of decoding
the individual frequencies is required. This can be accomplished via a well known
mathematical technique called the Fourier transformation. This transmissions
performed by the computer which them presents the user with the desired spectral
information for analysis.

264

In addition to "standard" transmission FTIR we they also have the following

sample handling capabilities:
1. Horizontal ATR - attenuated total reflectance. Allows measurement of
aqueous solutions, elastic and viscous samples which are difficult to grind
2. Specular reflectance - allows measurement of thin films on metals
3. KBr Discs - allow suspension of powders in IR transparent KBr so they may
be analysed
4. Gas cells - This may be used for FTIR analysis of a gaseous sample (e.g.
headspace analysis or environmental monitoring)
5. Solution cells - for measuring liquid sample in transmission mode.

7.5. Comparison with a reference

Fig. 7.1: Schematics of a two-beam absorption spectrometer.

A beam of infrared light is produced, passed through an interferometer (not

shown), and then split into two separate beams. One is passed through the sample, the
other passed through a reference. The beams are both reflected back towards a
detector, however first they pass through a splitter, which quickly alternates which of
the two beams enters the detector. The two signals are then compared and a printout is
obtained. This "two-beam" setup gives accurate spectra even if the intensity of the
265

light source drifts over time. To take the infrared spectrum of a sample, it is necessary
to measure both the sample and a "reference" (or "control"). This is because each
measurement is affected by not only the light-absorption properties of the sample, but
also the properties of the instrument (for example, what light source is used, what
detector is used, etc.). The reference measurement makes it possible to eliminate the
instrument influence. Mathematically, the sample transmission spectrum is divided by
the reference transmission spectrum.
The appropriate "reference" depends on the measurement and its goal. The
simplest reference measurement is to simply remove the sample (replacing it by air).
However, sometimes a different reference is more useful. For example, if the sample
is a dilute solute dissolved in water in a beaker, then a good reference measurement
might be to measure pure water in the same beaker. Then the reference measurement
would cancel out not only all the instrumental properties (like what light source is
used), but also the light-absorbing and light-reflecting properties of the water and
beaker, and the final result would just show the properties of the solute (at least
approximately).
A common way to compare to a reference is sequentially: First measure the
reference, then replace the reference by the sample, then measure the sample. This
technique is not perfectly reliable: If the infrared lamp is a bit brighter during the
reference measurement, then a bit dimmer during the sample measurement, the
measurement will be distorted. More elaborate methods, such as a "two-beam" setup,
can correct for these types of effects to give very accurate results.

266

7.6. FTIR Spectroscopy

Fourier Transform infrared (FTIR) spectroscopy is a measurement
technique that allows one to record infrared spectra. Infrared light is guided through
an interferometer and then through the sample (or vice versa). A moving mirror inside
the apparatus alters the distribution of infrared light that passes through the
interferometer. The signal directly recorded, called an "interferogram", represents
light output as a function of mirror position. A data-processing technique called
Fourier Transform turns this raw data into the desired result (the sample's spectrum):
Light output as a function of infrared wavelength (or equivalently,wavenumber). As
described above, the sample's spectrum is always compared to a reference.
There is an alternate method for taking spectra (the "dispersive" or "scanning
monochromator method), where one wavelength at a time passes through the sample.
The dispersive method is more common in UV-Vis spectroscopy, but is less practical
in the infrared than the FTIR method. One reason that FTIR is favored is called
"Fellgetts advantage" or the "multiplex advantage": The information at all
frequencies is collected simultaneously, improving both speed and signal-to-noise
ration. Another is called "Jacquinot's Throughput Advantage": A dispersive
measurement requires

detecting much lower light levels than an FTIR

measurement.[128] There are other advantages, as well as some disadvantages,[128] but

virtually all modern infrared spectrometers are FTIR instruments.

7.7. Analyse of the spectra

Step 1
Look first for carbonyl C=O bend. Look for a strong band at 1820 1660cm-1.
This band usually belongs to the most intense absorption band in a spectrum. It will
267

have medium width. If we see the carbonyl band, look for other ends associated with
functional groups that contain the carbonyl by going to step 2. If no C=O band is
present, check for alcohols and go to the step 3.

Step 2
If a C=O is present we want to determine if it is a part of an acid, an ester, or
an aldehyde or ketone. At this time we may not able to distinguish aldehyde from
ketone and you will not be asked to do so.
ACID
Look for indications that an O-H is also present. It has a broad absorption near
3300 2500 cm-1. This actually will overlap the C-H stretch. There will also be a C-O
single band near 1100 1300 cm-1. Look for the carbonyl and band near
1725 1700 cm-1.
ESTER
Look for C=O absorption of medium intensity near 1300 1000 cm-1. There
will be no O-H band.
ALDEHYDE
Look for aldehyde type C-H absorption bands. There are two weak
absorptions to the right of the C-H stretch near 2850 cm-1 and 2750 cm-1 and are
caused by the C-H band that is a part of the CHO aldehyde functional group. Look for
the carbonyl C-O band around 1725 1705 cm-1.

268

Step 3
If no carbonyl band appears in the spectrum looks for an alcohol O-H band.
ALCOHOL
Look for the broad OH band near 3600 3300 cm-1 and a C-O absorption
band near 1300 1000 cm-1.

Step 4
If no carbonyl band and no O-H bands are in the spectrum check for double
bands, C=C from an aromatic or an alkene.
ALKENE
Look for weak absorption near 1650 cm-1 for a double band. There will be a
C-H stretch band near 3000 cm-1.
AROMATIC
Look for the benzene C=C, double bonds which appear as medium to strong
absorption in the region 1650 1450 cm-1. The CH stretch bond is much weaker than
in alkenes.

Step 5
If none of the previous groups can be divided, we may have an alkane.
ALKANE
The main absorption will be the C-H stretch near 3000 cm-1. The spectrum
will be simple with another band near 1450 cm-1.

269

Step 6
If the spectrum still cannot assigned we may have an alkyl bromide.
ALKYL BROMIDE
Look for the C-H stretch and a relatively simple spectrum with an absorption
to the right of 667 cm-1.
Note: Terminal C-CH2:
Absorption at 1600 1675 cm-1
Strong bands at 900 cm-1.
Aromatic ring breathing motions: Observed between 1450 cm-1 and 1600 cm-1
the interpretation of infrared spectra involves the correlation of absorption bands in
the spectrum of an unknown compound with the known absorption frequencies for
types of bands.
A model table is given below which is helpful for analyzing a FT-IR spectrum.

270

Table - 7.1
Analyzing a FTIR specturm
Bond

Frequency range, cm-1

Compound type

2960 2850(s) stretch

Alkanes

1470 1350 (v) Scissoring and

bending

C H

1380 (m-w) Doublet isopropy 1,tbuty1

CH3 Umbrella Deformation

30803020 (m) stretch

Alkanes

1000675 9s) bend

Aromatic Rings

3100300 (m) stretch

Phenyl Ring Substitution Bonds

870 675 (s) bend

Phenyl ring substitution Overtones

200 1600 (w) fingerprint region

33333267 (s) stretch

Alkynes

C =C

Alkenes

1680 1640 (m,w) stretch

C=C

Alkynes

22602100 (w, sh) stretch

C=C

Aromatic Rings

1600, 1500 (w) stretch

C O

Alcohols, ketones, Carboxylic acids

Esters

1260 100 (s) Stretch

C=O

Aldehydes, ketones, Carboxylic acids

Esters

17601670 (2) stretch

Monomeric Alcohols, phenols

36403160 (s, br) stretch

O=H

700610 (b) bend

Hydrogenbondedalcohols, phenols
Carboxylic acids

36003200 (b) stretch

30003300 (m) stretch
35003300 (m) bend

Amines

13401020 (m) stretch

C=N

Nitriles

22602220 (v) Stretch

Nitro Compounds

16601500 (s) asymmetrical stretch

NO2

V = Variable,

m = Medium s Strong

16501580 (m) bend

W weak

271

sh sharp

272

273

7.8. Advantages of FTIR

Some of the major advantages of FT-IR are:

Speed
Because all of the frequencies are measured simultaneously, most
measurements by FT-IR are made in a matter of seconds rather than several minutes.

Sensitivity
Sensitivity is dramatically improved with FT-IR for many reasons. The
detectors employed are much sensitive, the optical throughput is much higher which
results in much lower noise levels, and the fast scans enable the co addition of several
scans in order to reduce the random measurements noise to any desired level (referred
to as signal averaging)

Mechanical Simplicity
The moving mirror in the interferometer is the only continuously moving part
in the instrument. Thus there is very little possibility of mechanical breakdown. FTIR
can be used to identify the chemical from spills, paints, polymers, coating and drugs.
FTIR is perhaps the most powerful tool for identifying types of chemical bonds.
Organic compounds have very rich detailed spectra; inorganic compounds are usually
much simpler.

7.9. Applications
Infrared spectroscopy is widely used in both research and industry as a simple
and reliable technique for measurement, quality control and dynamic measurement. It

274

is also used in forensic analysis in both criminal and civil cases, enabling
identification of polymer degradation for example.
The instruments are now small, and can be transported, even for use in field
trials. With increasing technology in computer filtering and manipulation of the
results, samples in solution can now be measured accurately (water produces a broad
absorbance across the range of interest, and thus renders the spectra unreadable
without this computer treatment). Some instruments will also automatically tell you
what substance is being measured from a store of thousands of reference spectra held
in storage.
Infrared spectroscopy has been highly successful for applications in both
organic and inorganic chemistry. Infrared spectroscopy has also been successfully
utilized in the field of semiconductor microelectronics:[129] for example, infrared
spectroscopy can be applied to semiconductors like silicon, gallium arsenide, gallium
nitride, zinc selenide, amorphous silicon, silicon nitride, etc.

7.10. Results and Discussion

FTIR analysis of binary liquid systems
In the FTIR spectrum of binary liquid mixtures was revealed at room
temperature in the range of 4004000cm1. The FTIR spectrums for binary and
ternary mixtures are represented in Fig 7.1 to 7.30 and their observations are given in
tables 7.2 to 7.31. Liquid mixtures were added and few mg of the composition was
used for making pellets with KBr. The pellets were then exposed to IR radiation. The
FTIR spectrums were taken using Perkin Elmer FTIR spectrometer. The tentative
frequency assignments were made by comparing it with standard values of frequency.
The FTIR spectrum taken shows drastic changes in the frequency values for binary
275

and ternary mixtures. In the binary systems of Cyclohexanone(X1) + Hexane(X2),

Cyclohexanone(X1)

2-Butanone(X2),

Heptane(X1)

Benzaldehyde(X2),

Heptane(X1) + 2-Butanone(X2), Benzaldehyde(X1) + Benzyl Chloride(X2),

Benzaldehyde(X1) + Ethyl Acetate(X2) mixtures the maximum frequency has been
observed in the region 0.6 mole fraction of X1 and 0.4 mole fraction of X2. In
Cyclohexanone(X1) + Benzyl Chloride(X2),

Heptane(X1) + Ethyl Acetate(X2),

Benzaldehyde(X1) + 2-Butanone(X2), Ethyl Acetate (X1) + 2-Butanone(X2)

combinations shows the maximum frequency has been observed in the region 0.7
mole fraction of X1 and 0.3 mole fraction of X2. In Cyclohexanone(X1) +
Heptane(X2),

Hexane(X1) + Heptane(X2), Hexane(X1) + Ethyl Acetate (X2)

combinations the maximum frequency has been observed in the region 0.8 mole
fraction of X1 and 0.2 mole fraction of X2. In Cyclohexanone(X1) +
Benzaldehyde(X2),

Benzaldehyde(X1) + Hexane(X2), Heptane(X1) + Benzyl

Chloride (X2) mixtures the maximum frequency has been observed in the region 0.4
mole fraction of X1 and 0.6 mole fraction of X2. In Hexane(X1) + 2-Butanone(X2),
Ethyl Acetate(X1) + Benzyl Chloride (X2) mixtures the maximum frequency has
been observed in the region 0.3 mole fraction of X1 and 0.7 mole fraction of X2. In
Cyclohexanone(X1) + Ethyl Acetate (X2), Benzyl Chloride (X1) + 2-Butanone (X2)
mixtures the maximum frequency has been observed in the region 0.5 mole fraction of
X1 and 0.5 mole fraction of X2.

FTIR analysis of ternary liquid systems

In the ternary systems, Cyclohexanone(X1) + Hexane(X2) + Heptane(X3)
mixture the maximum frequency has been observed in 0.5, 0.4 mole fractions of X1,

276

0.3,0.5 mole fractions of X2 and 0.2,0.1 mole fractions of X3. In Cyclohexanone(X1)

+ Hexane(X2) + Benzaldehyde(X3) mixture the maximum frequency has been
observed in 0.4, 0.3 mole fractions of X1, 0.2,0.3 mole fractions of X2 and 0.4,0.4
mole fractions

of X3. In Cyclohexanone(X1) + Hexane(X2) + 2-Butanone(X3)

mixture the maximum frequency has been observed in 0.4, 0.2 mole fractions of X1,
0.1,0.4 mole fractions of X2 and 0.5,0.4 mole fractions of X3. In Cyclohexanone(X1)
+ Hexane(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been
observed in 0.4, 0.3 mole fractions of X1, 0.2,0.2 mole fractions of X2 and 0.4,0.5
mole fractions

of X3. In Cyclohexanone(X1) + Heptane(X2) + 2-Butanone(X3)

mixture the maximum frequency has been observed in 0.5, 0.2 mole fractions of X1,
0.3,0.3 mole fractions of X2 and 0.2,0.5 mole fractions of X3. In Cyclohexanone(X1)
+ Heptane(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been
observed in 0.4 mole fraction of X1, 0.5 mole fraction of X2 and 0.1 mole fractions
of X3. In Cyclohexanone(X1) + 2-Butanone(X2) + Benzaldehyde(X3) mixture the
maximum frequency has been observed in 0.4, 0.5 mole fractions of X1, 0.2,0.1 mole
fractions of X2 and 0.4,0.4 mole fractions

of X3. In Cyclohexanone(X1) +

Benzaldehyde(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been

observed in 0.4,0.5,0.2 mole fractions of X1, 0.4,0.4,0.4 mole fractions of X2 and
0.2,0.1,0.4 mole fractions of X3. In Cyclohexanone(X1) + Ethyl Acetate(X2) + 2Butanone(X3) mixture the maximum frequency has been observed in 0.3, mole
fraction of X1, 0.4 mole fraction of X2 and 0.3 mole fraction of X3. In Ethyl
Acetate(X1) + 2-Butanone(X2) + Hexane(X3) mixture the maximum frequency has
been observed in 0.7, 0.5 mole fractions of X1, 0.1,0.2 mole fractions of X2 and
0.2,0.3 mole fractions of X3.
277

So, the observation from the VE study has been confirmed by the FTIR
spectrum measurement. The shift in the frequency values of FTIR spectrum
measurement is generally due to following observed factors:
1. Interstitial accommodation.
2. Strong interactions (H-bond type, or dipole-dipole or dipole-induced dipole
interactions).

278

For Binary systems

Fig-7.1 FTIR spectrums for Cyclohexanone + Hexane mixture:
SPECTRUM
SPECTRUM

SPECTRU M

SPECTRUM

0.9 (CYC) + 0.1 (HEXANE)

SPECTRUM

SPECTRUM
0.6 (CYC) + 0.4 (HEXANE)

0.7 (CYC) + 0.3 (HEXANE)

0.5 (CYC) + 0.5 (HEXANE)

0.8(CYC) + 0.2 (HEXANE)

(1)CYC + (0)H EXANE

100.0

2335.

100.0

413.3

2673.

3937.

991.42
1264.33

2672.30

2063.86
2340. 71

1018.08 864.24

1312.

3949.

105 3. 12 907.55

750 .1 6

156 0. 38

490 .5 7

2063.
2362.

3002.

1872.

652.90

1018.

40
131 1. 99

1119.02

122 2. 35

2940.57

1342.

653.2

3412.

2864.

1416.

1568.

1635.

1023.

1119.

25
3442.

1000

400.0

10
1712.

3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

3414.

2867.

1712.

4000.0

5
3438.

2942.

0.0

4000.0

cm-1

1566.

20
2939.

1425.

5
0.0

4000.0

3412.

1500
cm-1

1223.

1643.

2941.

2000

1120.

%T
45

35
1416.

1119.
1222.

1423.

0.0

0.0
3000

1347.

2925.
490.8

30
1565.

2865.

10
1712.06

3449.14

1021.
2362.
2943.

%T
491.7

928.9

3934.

65
60

1312.
1118.
1425.
1222.

1314.

750.8

2104.

750.3
490.1

750.5

1054.

30
25

4000.0

904.5

1565.

55
902.9

1056.

1424.18

1638.82
286 4. 06

20
15
10

654.6

652.6
905.5

1449.88

30
25

1565.

1054.

650.4

864.6

1806.

1804.

3776.

75
864.5

652.1

2672.

85
80

1805.

65
866.8

703.9

2062.
2670.

2670.

952.8

411.3

1341.

80
75

1316.

1018.

1019.

1870.

2064.

1974.

1969.
2176.

414.2
3771.

2424.
3946.

1114.
2125.

1805.86

1224.

2176.

414.18

187 1. 50

904.6

1342.46

3767.

2363.74

1713.

3000

0.0

2000

1500

1000

400.0

0.0

4000.0

3000

2000

1500

cm-1

1000

400.0

4000.0

3000

2000

cm-1

1500

SJC= Phy-

SJC=phy-

SJC= Phy-

SJC=phy-

SJC= Phy-

CYCLON~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T 5 0.50

SJE497~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T

SJC_PH~1.SP 3601 4000.00 400.00 3.17 99.73 4.00 %T

SJ2057~1.SP 3601 4000.00 400.00 4.26 100.00 4.00 %T

SJC_PH~3.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T

SJ205F~1.SP 3601 4000.00 400.00 10.00 99.99 4.00 %T

RE F 400 0 7 5. 82 2000 7 3. 85 600

344 9.1 4 9 .99 29 40. 57 16. 99 28 64. 06 30. 70 26 72. 30 72. 97 23 63.74 72.06
234 0.7 1 7 2.4 2 206 3.8 6 7 1.9 1 187 1.5 0 74.9 8 180 5.8 6 70.4 2 171 2.0 6 1 0.9 0
163 8.8 2 3 4.6 7 156 0.3 8 5 1.8 5 144 9.8 8 40.4 3 142 4.18 40.5 6 134 2. 46 5 1.1 1
131 1.9 9 4 3.4 5 126 4.3 3 6 8.7 4 122 2.3 5 41.5 1 111 9.0 2 44.1 7 105 3.1 2 6 2.9 7
101 8.0 8 6 4.7 1 991 .42 71. 38 90 7. 55 62.34 864. 24 6 6.33 750 .16 54.80
652 .90 57. 99 49 0. 57 51 .01 414.18 75.32

REF 4000 67.77 2000 66.53

3949.75 64.79 3771.50 63.78 3412.64 9.99 2941.57 12.87
2672.34 54.14 2362.22 56.70 2176.21 61.93 2063.32 61.94
1872.14 63.38 1806.55 50.78 1712.96 11.83 1565.33 31.39
1342.48 31.06 1312.47 28.92 1222.50 28.88 1119.18 29.68
1018.23 45.10 905.55 43.53 864.67 49.49 750.51 40.38 652.67
490.81 38.81 414.20

REF 4000 99.39 2000 86.51

3937.11 94.39 3442.57 3.17 3002.55 45.49 2925.08 46.29
2125.50 77.40 1643.95 25.49 1565.63 50.69 1416.33 38.79
1224.12 84.94 1114.72 80.62 1023.16 35.30 952.89 59.12
703.97 54.58 654.66

REF 4000 96.52 2000 94.52

3946.85 90.09 3767.63 89.85 3414.47 12.99 2942.29 4.26
2670.75 70.86 2424.36 92.42 2335.89 88.13 2176.82 85.87
1969.56 88.72 1870.29 86.76 1804.88 65.07 1713.79 4.26
1425.86 20.60 1314.25 32.48 1223.02 30.59 1119.55 35.78
1019.24 63.08 902.95 56.35 866.88 68.88 750.84 53.98 652.18
491.71 50.03 413.33

REF 4000 85.01 2000 84.30

3412.62 43.20 2939.86 20.75 2864.54 39.42 2670.80 80.23
1805.81 78.08 1712.49 9.96 1565.88 66.48 1425.10 50.33
1312.34 55.04 1222.32 53.27 1118.91 56.43 1054.23 70.92
904.58 70.92 864.55 76.02 750.33 69.99 650.48 75.94 490.12
411.32 79.45

REF 4000 80.81 2000 78.54

3934.56 79.80 3776.88 76.00 3438.20 10.00 2943.43 60.90
2104.26 76.73 1635.55 38.44 1566.96 27.76 1416.20 40.18
1120.65 68.37 1021.85 71.61 928.97 79.75 653.20

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FTIR SPECT RUM

Date: 21-12-2009

FIGURE 5

SPECTRUM

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-.6- .4 C.sp

0 (CYC) + 1 (HEXANE)

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 7-. 3 C.sp

FTIR
Date :

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 8-. 2 C.sp

400.0

FIGURE 6

FIGURE 4

FIGURE 3

FIGURE 2

FIGURE 1

1000

cm-1

C yclohexa none.pk

Spectrum Name: SJC-. 9-. 1 C.sp

100.0

1020.46

3929.03

1019.56

90
392 8.72

1976 .94

1019.04

863.28

1020.14

825.20

1171.48

1018.

41 5.01

862.42

206 4.94

3940.59

206 6.37
1114.

416.70

1416.

2 671.73

904.93

1975.94

2669.38

825.70

496.55

750.11

650.68

1446.30

748.60

1447.60

713.64

45
40

1225.04
1345.67
1348.47

1594.44

2865.7 6

1230 .67

30
2866.5 7

0.0

2866.3 3

1595.75

294 2.30

10
1706.09

2000

1500

1000

400.0

4000.0

3 450.45

1595.69
1706.83

10
3 452.56

20
294 0.82

2000

1500

1000

400.0

4000.0

cm-1

17 10.56

0.0
3000

2000

3432.

17 09.48

0.0
3000

cm -1

1637.

294 1.41

3448.97

0.0
3000

20
1594.76

2 942.22
3457.73

4000.0

668.2

1447.10

712.74

2969.

55
%T

1345.87

1 227.34

1312.18

286 6.81

2338.

1223.65

65 0.99
1449.01

2077.

70
4 93.14

111 8.56

50
749.80

2362.

75
65 0.95

1118.69

60
65 0.83 4 94.52

111 8.20

%T
40

904.21

750.68

1385.60

111 8.21
3072.54

1057.8 4

1060.65

1313.98

1063.59

60
4 98.36

2742.57

1314.29

904.27

825.2 5
1314.81

2664.4 2

13 91.70

714 .94

13 88.23

903.99

70
106 5.78
26 41.57

1 172.14

1172.30

1500

1000

400.0

4000.0

5
3000

2000

cm-1

1500

1000

400.0

cm-1

0.0
4000.0

SJ C-. 6-. 4 C. pk

SJC-.7-.3 C.pk

SJC-.8-.2 C.pk

SJC-.9-.1 C.pk

SJ C-6-~1. SP 3601 4000.00 400.00 6. 32 99. 99 4.00 %T 5 1.00

SJC-7-~1. SP 3601 4000.00 400. 00 6.33 100.00 4.00 %T 5 1. 00

SJC-8-~1. SP 3601 4000.00 400. 00 6.94 99. 99 4.00 %T 5 1.00

SJC-9-~1. SP 3601 4000.00 400. 00 8.41 100.00 4.00 %T 5 1. 00

REF 4000 98 .17 2000 9 4.12 600

39 29. 03 96. 31 3457.73 6.32 3072.54 34.70 2942. 22 13.72 2 866.81 27 .40
27 42. 57 64. 87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .49
14 49. 01 46. 87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.18
11 18. 21 57. 75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25. 70 72.12
74 8.60 44.96 712.74 40. 63 650.99 50.6 6 498. 36 61.31

REF 4 000 97.56 2000 95.26 600

3928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.23
1975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447. 60 45.72 1385.60 47. 60
1348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172. 14 66.61 1118.20 59. 39
1063.59 75.58 1020.14 8 2.05 903. 99 82.04 825.25 75. 63 749.80 49.90
713. 64 48 .66 650.68 54. 43 496.55 59.64

REF 4 000 98.11 2000 96.86 600

3940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29. 08 2669.38 86. 88
2064.94 95.65 1709.48 6. 94 1594.76 23.83 1447.10 46.17 1388.23 59.64
1345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74. 79 1118.56 59. 00
1060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65
750. 11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88. 59

REF 4 000 98.82 2000 97.87 600

3450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671. 73 92.85 2066.37 96. 59
1710.56 8. 39 1594. 44 37. 41 1446.30 57.07 1345.87 57.48 1314.29 60.33
1223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019. 04 90.36 904.21 85.71
863. 28 89 .48 750.68 71. 01 650.95 76.54 4 93. 14 71. 85 415.01 93.25

3000

2000

1500

1000

400.0

cm-1

Hexane.p
Hexane.sp 3601 4000.00 400.00 3.24 99.01 4.00 %T
REF 4000 98.71 2000 89.72
3432.69 3.24 2969.84 72.05 2362.02 81.94 2338.24 84.34
1637.62 24.85 1416.40 89.27 1114.27 96.09 1018.58 97.88

FIGURE 7

Table - 7.2
Observations of FTIR spectrums for Cyclohexanone + Hexane mixture:
1 (CH)
Cm-1
3449.14
2940.57
2864.06
2672.30
2363.74
2340.71
2063.86
1871.50
1805.86
1712.06
1638.82
1560.38
1449.88
1424.18
1342.46
1311.99
1264.33
1222.35
1119.02
1053.12
1018.08
991.42
907.55
864.24
750.16
652.90
490.57
414.18

0.9(CH)
+
0.1(HX)
Cm-1
3949.75
3771.50
3412.64
2941.57
2865.04
2672.34
2362.22
2176.21
2063.32
1974.04
1872.14
1806.55
1712.96
1565.33
1423.06
1342.48
1312.47
1222.50
1119.18
1054.06
1018.23
905.55
864.67
750.51
652.67
490.81
414.20

0.8(CH)
+
0.2(HX)
Cm-1
3937.11
3442.57
3002.55
2925.08
2673.82
2125.50
1643.95
1565.63
1416.33
1316.12
1224.12
1114.72
1023.16
952.89
904.60
703.97
654.66

0.7(CH)
+
0.3(HX)
Cm-1
3946.85
3767.63
3414.47
2942.29
2867.14
2670.75
2424.34
2335.89
2176.82
2064026
1969.56
1870.29
1804.88
1713.79
1568.10
1425.86
1314.25
1223.02
1119.55
1056.47
1019.24
902.95
866.88
750.84
652.18
491.71
413.33

*0.6 (CH)
+
0.4(HX)
Cm-1
3412.62
2939.86
2864.54
2670.80
2062.74
1805.81
1712.49
1565.88
1425.10
1341.35
1312.34
1222.32
1118.91
1054.23
1018.06
904.58
864.55
750.33
650.48
490.12
411.32

0.5(CH)
+
0.5(HX)
Cm-1
3934.56
3776.88
3438.20
2943.43
2362.89
2104.26
1635.55
1566.96
1416.20
1347.59
1120.65
1021.85
928.97
653.20

0.4(CH)
+
0.6(HX)
Cm-1
3943.13
2841.84
2865.33
2672.07
2366.07
2174.64
1605.42
1711.74
1638.91
1565.53
1420.73
1342.57
1312.83
1222.37
1119.20
1054.11
1019.45
904.61
863.42
749.84
652.50
491.76

* Maximum shift in the frequency has been observed.

279

0.3(CH)
+
0.7(HX)
Cm-1
3917.10
2942.71
2867.49
2366.67
2085.61
1708.47
1633.93
1565.03
1417.15
1345.31
1221.89
1119.35
1022.23
953.09
619.88
482.36

0.2(CH)
+
0.8(HX)
Cm-1
3912.54
2939.69
2864.30
2671.80
2062.93
1805.79
1712.68
1638.92
1565.12
1449.43
1425.20
1341.99
1312.04
1222.24
1118.98
1053.34
1017.93
906.51
864.38
750.30
652.47
490.44
411.06

0.1(CH)
+
0.9(HX)
Cm-1
3949.77
2968.27
2935.76
2882.46
2363.00
2339.50
2096.41
1638.55
1561.29
1464.64
1415.21
1116.58
1022.17
928.41
652.83

1 (HX)
Cm-1
3432.69
2969.84
2362.02
2338.24
2077.43
1637.62
1416.40
1114.27
1018.58
668.29

Fig-7.2: FTIR spectrums for Cyclohexanone + Heptane mixture:

SPECTRUM 7 : 0.9 (CYC) + 0.1 (HEPTANE)

SPECTRUM 5 : 0.7 (CYC) + 0.3 (HEPTANE)

SPECTRUM 3 : 0.5 (CYC) + 0.5 (HEPTANE)

SPECTRUM 4 :0.6 (CYC) + 0.4 (HEPTANE)

S P E C T R U M 1 : ( 1 )C Y C + ( 0 ) H E P T A N E

1805.

864.3

60
55

1118.

40
1 31 1. 99

1 11 9 .0 2

14 49 .8 8

50
1565.

1312.
1222.

904.8

750.6

40
35

20 00

150 0

1 000

30 00

20 00

1 50 0

10 00

4 00 .0

cm-1

cm -1

R E F 4 00 0 7 5. 8 2 2 0 0 0 7 3. 8 5 6 0 0
3 4 4 9 . 1 4 9 . 9 9 2 9 4 0. 5 7 1 6. 9 9 28 6 4 . 0 6 3 0 . 7 0 2 6 7 2 .3 0 7 2 . 9 7 2 3 6 3 .7 4 7 2 .0 6
2 3 4 0 . 7 1 7 2 . 4 2 2 0 6 3 .8 6 7 1 . 9 1 1 8 7 1 .5 0 7 4 .9 8 1 80 5 . 8 6 70 .4 2 1 7 1 2 .0 6 1 0 . 9 0
1 6 3 8 . 8 2 3 4 . 6 7 1 5 6 0 .3 8 5 1 . 8 5 1 4 4 9 .8 8 4 0 .4 3 1 42 4 . 1 8 40 .5 6 1 3 4 2 .4 6 5 1 . 1 1
1 3 1 1 . 9 9 4 3 . 4 5 1 2 6 4 .3 3 6 8 . 7 4 1 2 2 2 .3 5 4 1 .5 1 1 11 9 . 0 2 44 .1 7 1 0 5 3 .1 2 6 2 . 9 7
1 0 1 8 . 0 8 6 4 . 7 1 9 9 1 .4 2 7 1. 3 8 90 7 . 5 5 6 2 . 34 8 6 4. 2 4 6 6 .3 3 7 5 0 .1 6 5 4 .8 0
6 5 2 . 9 0 5 7 .9 9 4 9 0. 5 7 5 1 . 0 1 4 1 4 .1 8 7 5 . 3 2

REF 4000 97.30 2000 96.56

3412.54 41.25 2939.69 8.78 2864.30 24.31 2671.80 91.01
1805.79 87.03 1712.68 3.67 1638.92 62.60 1565.12 69.26
1425.20 41.46 1341.99 55.83 1312.04 45.61 1222.24 42.10
1053.34 75.65 1017.93 79.48 906.51 73.08 864.38 81.72 750.30
652.47 81.49 490.44 62.00 411.06

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

2941.

1000

400.0

SJC_PH~4.SP 3601 4000.00 400.00 3.60 99.05 4.00 %T

REF 4000 98.66 2000 97.05
3947.97 96.20 3413.37 17.48 2940.67 4.98 2865.12 13.52
2364.80 82.89 2176.18 92.86 2063.53 92.59 1972.86 94.98
1805.76 78.03 1712.73 3.60 1565.11 59.37 1425.87 25.04
1312.73 31.34 1222.72 29.20 1119.18 34.28 1054.54 61.71
904.80 59.74 864.87 73.28 750.63 58.25 652.38 72.03 490.89
411.60 90.06

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

490 .5

1565.

15 00

1000

400. 0

1421 .

15
10

2000

156 6.

3000

163 7.
286 4.

1565.

2 941.

0.0

4 000.0

1500

652. 2

3417.

171 2.

342 0.

0.0

4000.0

3000

2000

c m-1
2000

SJC= Phy-

1500

1000

400.0

4000.0

3000

cm-1

20 00

1500

1000

400.0

cm -1

SJC= Phy-

SJC=phy-

SJC= Phy-

SJ105F~1.SP 3601 4000.00 400.00 3.16 99.99 4.00 %T

SJC_PH~2.SP 3601 4000.00 400.00 3.25 99.70 4.00 %T

SJ2053~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T

REF 4000 97.99 2000 94.92

3443.13 3.16 2941.84 20.27 2865.33 37.18 2672.07 92.55
2174.64 90.80 1805.42 88.06 1711.74 18.86 1638.91 26.21
1420.73 23.95 1342.57 56.45 1312.83 55.00 1222.37 56.67
1054.11 72.17 1019.45 73.30 904.61 80.74 863.42 84.57 749.84
652.50 55.49 491.76

REF 4000 99.55 2000 95.24

3417.10 3.25 2942.71 63.39 2867.49 82.73 2366.67 92.47
1708.47 59.45 1633.93 31.67 1565.03 29.28 1417.15 45.43
1221.89 92.00 1119.35 80.63 1022.23 79.15 953.09 97.82
482.36 77.26

REF 4000 77.51 2000 75.64

3420.77 10.00 2941.90 14.59 2864.70 33.43 2672.37 74.95
1712.73 12.85 1637.45 36.29 1566.13 30.42 1421.81 30.86
1312.05 47.82 1221.93 46.61 1118.99 46.80 1053.23 63.26
906.17 66.53 863.71 69.62 750.04 57.50 652.29 55.00 490.59

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 7-. 3 C.sp

1711.

3000

cm-1

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FTIR SPECT RUM

Date: 21-12-2009
Spectrum Name: SJC-.6- .4 C.sp

1712.
2940.

4000.0

750.0

1221.

1633.

25
20

0.0

2865.

5
0.0

SJC= PhySJ205B~1.SP 3601 4000.00 400.00 3.67 100.00 4.00 %T

86 3.7
90 6.1
101 8.

1342.

1417.

1420.

3413.

4 00 0 .0

400 .0

1425.

2939.

0.0
30 00

1222.

20
1712.

1 71 2 .0 6

34 49 .1 4

C yc l oh e x a n o n e .p k
C Y C L O N ~ 1 .S P 3 6 0 1 4 0 0 0. 0 0 4 0 0. 0 0 1 0. 0 0 1 0 0 .0 0 4 .0 0 % T 5 0 . 50

236 3.

50
45

30
3443.

131 2.

2 94 0. 57

0.0
4 000 .0

1119.

267 2.

60
55

1708.

50
45

2865.

35
30
2864.

70
65

619.8

111 8.

25
20

1638.

286 4 .0 6

491.7

10 53.

482.3

1022.

2942.

652.5

1119.

1312 .

111 9.

65
60

1345.

286 7.

490.8

1 42 4. 1 8

16 3 8. 82

1222.
1425.

12 2 2. 35

30
25

1312.
1449.

3412.

749.8

1054.

1221.

863.4
904.6

1019.

101 8.

50
45

2085.

1342.
1805.

60
652.3

864.8

%T
4 90 .5 7

236 6.

2174.

70
65
1805.

1638.

65 2. 90
75 0 .1 6
15 60 .3 8

2672.

2063.
2364.

70
65

2366.

1871.

1972.

75
2671.

490.4

50
45

750.3

10 18 .0 8 864 . 24
10 5 3. 12 9 07 .5 5

95
953.0

1054.

1341.

80
906.5

1565.

1 80 5. 86

2176.

3947.

1053.

206 3 .8 6
2 34 0. 71

652.4

1017.

41 4. 18

18 7 1. 50
267 2 .3 0

60
55

411.6

2671.

80
9 91 .4 2
1 26 4. 33
1 34 2. 4 6

70
65

100.0

2062.

85
2 36 3. 74

80
75

100.0

1341.

100. 0

411.0

SPECTRUM 6 : 0.8 (CYC) + 0.2 (HEPTANE)

10 0.0

SPECTRUM 2 : (0)CYC +(1)HEPTANE

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 8-. 2 C.sp

Spectrum Name: SJC-. 9-. 1 C.sp

100.0

1020.46

3929.03

1019.56

90
392 8.72

1976 .94

1019.04

863.28

1020.14

41 5.01

862.42

206 4.94

3940.59

1171.48

825.20

206 6.37

416.70
2 671.73

904.93

1975.94

2669.38

825.70

496.55

749.80

748.60

650.68

1446.30

1447.60

1223.65

%T
1345.87

713.64

712.74

30
2866.3 3

1595.75

1706.09

2000

1500

1000

400.0

4000.0

3 450.45

1595.69
1706.83

17 09.48

2000

1500

1000

400.0

4000.0

cm-1

17 10.56

0.0
3000

2000

3449.

294 1.41

0.0
3000

cm -1

1638.

294 0.82

10
3 452.56

3448.97

0.0
3000

2968.

20
1594.76

294 2.30

2 942.22
3457.73

4000.0

2935.

30
2866.5 7

1561.

1594.44

2865.7 6

1230 .67

0.0

652.8
288 2.

1225.04
1345.67
1348.47

1415.

50
45

1447.10

1 227.34

1312.18

286 6.81

928.4
1022.
1116.

236 3.

750.11

65 0.99
1449.01

209 6.
2339.

65
60

111 8.56

%T
3072.54

1464.

75
70
4 93.14

1118.69

60
65 0.83 4 94.52

111 8.20

111 8.21

65 0.95
750.68

1385.60

904.21
1057.8 4

1060.65

1313.98

1063.59

60
4 98.36

2742.57

1314.29

904.27

825.2 5
1314.81

2664.4 2

13 91.70

714 .94

13 88.23

903.99

70
106 5.78
26 41.57

1 172.14

1172.30

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

cm-1

0.0
4000.0

SJ C-. 6-. 4 C. pk

SJC-.7-.3 C.pk

SJC-.8-.2 C.pk

SJC-.9-.1 C.pk

SJ C-6-~1. SP 3601 4000.00 400.00 6. 32 99. 99 4.00 %T 5 1.00

SJC-7-~1. SP 3601 4000.00 400. 00 6.33 100.00 4.00 %T 5 1. 00

SJC-8-~1. SP 3601 4000.00 400. 00 6.94 99. 99 4.00 %T 5 1.00

SJC-9-~1. SP 3601 4000.00 400. 00 8.41 100.00 4.00 %T 5 1. 00

REF 4000 98 .17 2000 9 4.12 600

REF 4 000 97.56 2000 95.26 600

REF 4 000 98.11 2000 96.86 600

REF 4 000 98.82 2000 97.87 600

3000

2000

1500

1000

400.0

cm-1

Heptane.p
Heptane.sp 3601 4000.00 400.00 3.17 99.99 4.00 %T
REF 4000 83.95 2000 80.08
3449.77 3.17 2968.27 32.42 2935.76 42.98 2882.46 57.01
2339.50 72.71 2096.41 78.11 1638.55 29.09 1561.29 45.85
1415.21 58.44 1116.58 75.81 1022.17 77.56 928.41 83.36

Table - 7.3
Observations of FTIR spectrums for Cyclohexanone + Heptane mixture
1 (CH)
Cm-1
3449.14
2940.57
2864.06
2672.30
2363.74
2340.71
2063.86
1871.50
1805.86
1712.06
1638.82
1560.38
1449.88
1424.18
1342.46
1311.99
1264.33
1222.35
1119.02
1053.12
1018.08
991.42
907.55
864.24
750.16
652.90
490.57
414.18

0.9 (CH)
+
0.1(HP)
Cm-1
3412.54
2939.69
2864.30
2671.80
2062.93
1805.79
1712.68
1638.92
1565.12
1449.43
1425.20
1341.99
1312.04
1222.24
1118.98
1053.34
1017.93
906.51
864.38
750.30
652.47
490.44
411.06

*0.8 CH)
+
0.2 (HP)
Cm-1
3947.97
3413.37
2940.67
2865.12
2671.83
2364.80
2176.18
2063.53
1972.86
1871.69
1805.76
1712.73
1565.11
1425.87
1341.64
1312.73
1222.72
1119.18
1054.54
1018.20
904.80
864.87
750.63
652.38
490.89
411.60

0.7 (CH)
+
0.3(HP)
Cm-1
3443.13
2941.84
2865.33
2672.07
2366.07
2174.64
1805.42
1711.74
1638.91
1565.53
1420.73
1342.57
1312.83
1222.37
1119.20
1054.11
1019.45
904.61
863.42
749.84
652.50
491.76

0.6 (CH)
+
0.4(HP)
Cm-1
3417.10
2942.71
2867.49
2366.67
2085.61
1708.47
1633.93
1565.03
1417.15
1345.31
1221.89
1119.35
1022.23
953.09
619.88
482.36

0.5 (CH)
+
0.5(HP)
Cm-1
3420.77
2941.90
2864.70
2672.37
2363.64
1712.73
1637.45
1566.13
1421.81
1342.75
1312.05
1221.93
1118.99
1053.23
1018.76
906.17
863.71
750.04
652.29
490.59

0.4 (CH)
+
0.6(HP)
Cm-1
3453.13
2951.84
2855.33
2632.07
2346.07
2164.64
1808.42
1716.74
1638.91
1567.53
1428.73
1348.57
1318.83
1225.37
1116.20
1058.11
1012.45
901.61
869.42
743.84
658.50
492.76

* Maximum shift in the frequency has been observed.

280

0.3 (CH)
+
0.7(HP)
Cm-1
3415.53
2936.68
2867.30
2678.80
2061.92
1802.79
1714.68
1636.92
1568.12
1442.43
1424.20
1346.99
1318.04
1223.24
1116.98
1059.34
1012.93
906451
862.38
759.30
656.47
492.44
418.06

0.2 (CH)
+
0.8(HP)
Cm-1
3425.74
2947.96
2869.73
2673.38
2366.64
1718.73
1632.44
1566.13
1424.81
1348.75
1314.02
1226.93
1117.92
1052.23
1018.76
902.17
868.71
755.04
658.29
492.59

0.1 (CH)
+
0.9(HP)
Cm-1
3423.13
2921.84
2825.33
2622.07
2346.07
2184.64
1845.42
1751.74
1688.91
1525.53
1430.73
1342.57
1352.83
1262.37
1169.20
1074.11
1069.45
906.61
867.42
746.84
658.50
499.76

1 (HP)

Cm-1
3449.77
2968.27
2935.76
2882.46
2363.00
2339.50
2096.41
1638.55
1561.29
1464.64
1415.21
1116.58
1022.17
928.41
652.83

Fig-7.3: FTIR spectrums for Cylclohexanone + Benzaldehyde mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 21-12-2009

90
FT I R SP ECT R UM
D ate: 21 -1 2 - 200 9

21 27 .7 7

1071.12

1915.78

2739.45

1390.29

826.08

30 00

20 00

SJ C-1.0 H.pk

748.25
711.65
1234.30

2866.6 1

294 1.90

294 3.23

294 2.44

1596.08

1596.17

10
3459.33

17 01.81

10 00

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

1594.85
17 00.39
3450.26

3 455.32

0.0

4000.0

1702.34

17 03.62

0.0
3000

cm-1

15 00

1312.30

650.93

70 5.60

1211.11

0.0

4000.0

3000

2000

1500

cm-1

SJC-.2-.8 C.pk

1701.38

4 00 0. 0

3443.28

4000.0

3448.46

0 .0

747.51
708.66

1594.54

0.0

400.0

40
1221.66
2867.49

2865.13

746.89

746.47

1595.35

1000

1648.11

651.13
692.51

1207.81

1500

1172.10
1449.77
651.17

40
651.00

1275.09
3072.34

15 93 .9 9

cm-1

502.40

1118.21

50
%T

1309.89

1308.76
2820.04

1 70 9.99

1067.27
1346.06

501.66

747.26

1169.49

2000

2644.38

2741.33

111 8.46

1449.28
1312.26

651.04
691.30

29 41 .0 9

2741.42

50
%T

1450.49

1207.55

2944.45

452.34
1452.97

3000

102 0.51

1068.11

1390.13

825.64

826.41
1391.77

%T
40

2945.26

60
1 35 0.43

34 35 .0 7

2644.03

825.42
526.91
1 117.95

3069.88

825.85

1311.25

14 44 .2 8

1069.62

1387.22

2820.26

535.57

80
102 0.71
1389.46

2739.65

50
%T

1115.63

28 65 .3 7

905.45

454.72

116 9.54

921.99

1016.08
1823.61

7 52 .3 1

1 977.97

2739.06

1914.95
1981.63

80
4 94 .0 6

39 29.45

905.98

2360.34

1019.47

1116.75
1350.39

1071.71

6 51 .4 9

90
1979.11

454.25

1983.61

90 2.94

12 23 .1 3

0.0
4000.0

90
908.34

2360.56

1 00 .0

10 18 .42
1 05 4.8 0
1 11 9.21

100.0

1 978.55

101 6.77

235 6.74

Sp ec tru m Nam e : SJ C- . 1- . 9 C. s p

39 28 .3 5

FT IR SPECT RUM
Date: 21- 12-2009
Spectrum Name: SJC-. 5-. 5 C.sp

100.0

1452.5 3

1915.41

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009
Spectrum Name: SJC-. 4-. 6 C.sp

100.0

Spectrum Name: SJ C-1.0 H.sp

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009
Spectrum Name: SJC-. 3-. 7 C.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009
Spectrum Name: SJC-. 2-. 8 C.sp
ACI C
St. J os ep h 's C olle g e ( Auton om o u s )
T r ic h y - 2

1000

400.0

4000.0

3000

cm-1

SJC-.3-.7 C.pk

2000

1500

1000

400.0

cm-1

SJC-.4-.6 C.pk

SJC-.5-.5 C.pk

4 00 .0

cm -1

SJC-2-~1. SP 3601 4000.00 400. 00 5.03 99. 90 4.00 %T 5 1.00

SJC-3-~1. SP 3601 4000.00 400. 00 5.71 100.00 4.00 %T 5 1. 00

SJC-4-~1. SP 3601 4000.00 400. 00 5.03 99. 95 4.00 %T 5 1.00

SJC-5-~1. SP 3601 4000.00 400. 00 6.32 100.00 4.00 %T 5 1. 00

REF 4 000 98.71 2000 94.94 600

3443.28 5. 03 2944.45 47 .23 2820.26 56.76 2739.06 69.56 2356.74 87.51
1983.61 94.37 1915.41 95.36 1701.81 9.41 1648.11 21.11 1594.54 11.72
1452.53 64.70 1387.22 55.14 1350.39 57.59 1311.25 55. 35 1207.55 45. 79
1169.54 66.14 1116.75 82.95 1071.12 89.20 1016.77 90. 38 825.85 57.65
746. 89 33 .90 691.30 41.19 651.04 43.6 8 454.72 71.54

REF 4 000 98.88 2000 94.24 600

3459.33 10.05 3069.88 3 6.67 2941.90 22.79 2865. 13 37.71 2739.65 60. 71
2360.56 92.47 1978.55 9 2.73 1915.78 93.66 1703. 62 5.71 1596.08 19.41
1450.49 51.70 1391.77 5 2.45 1309.89 41.12 1211. 11 32.34 1117.95 64. 63
1069.62 76.59 1019.47 8 2.16 908. 34 89.63 826.41 57. 00 747.26 31.04
705. 60 32 .67 651.00 43. 23 526.91 66.18 4 54. 25 72. 51

REF 4 000 98.02 2000 93.62 600

3455.32 5. 03 2943.23 22 .17 2867.49 36.69 2741.42 67.05 2644.03 76.53
2360.34 93.23 1979.11 92.66 1702.34 14.15 1596.17 19. 09 1449.28 52. 52
1390.13 53.94 1312.26 48.08 1221.66 43.56 1118.46 64. 10 1068.11 77. 62
1020.71 83.03 905.98 87 .80 825.64 67.20 747.51 41.19 708.66 38.87
650. 93 46 .69 501.66 60.43

REF 4 000 98.65 2000 94.89 600

3929.45 96.28 3450.26 6 .32 2942.44 22.24 2866.61 37.10 2741.33 68.76
2644.38 76.92 1977.97 9 3.82 1700.39 15.00 1594. 85 19.89 1449.77 54. 05
1389.46 54.41 1346.06 5 2.59 1312.30 48.46 1234. 30 43.99 1172.10 63. 52
1118.21 65.38 1067.27 7 8.84 1020.51 84.56 905.45 89.22 825. 42 69.84
748. 25 43 .95 711.65 40. 63 651.17 49.83 5 02. 40 64. 41

SJ C- . 1- . 9 C. pk

SJ C-10~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 % T 5 1.00

SJ C- 1- ~ 1. SP 36 0 1 4 0 00 .0 0 4 00. 0 0 7. 43

REF 4000 99.03 2000 96.69 600

3928.35 97.64 3435.07 6.34 2941.09 26.56 2865.37 49.20 2127.77 93.90
1709.99 18.80 1593.99 18.45 1444.28 63.06 1350.43 49.90 1223.13 73.49
1119.21 78.97 1054.80 91.51 1018.42 92.75 902.94 88.78 752.31 67.75
651.49 68.80 494.06 68.15

99. 87

4. 00 % T 5 1 . 00

REF 4 000 9 9 .3 9 2 000 9 3. 41 6 00

34 48 . 46 8. 1 2 3 07 2. 34 33 .9 0 2 945 . 26 43 .3 8 2 8 20. 0 4 41 .9 4 2 73 9. 45 5 2 .9 3
19 81 . 63 91 . 86 1 9 14. 9 5 92. 6 3 182 3. 61 9 3. 26 1 70 1. 3 8 7. 43 1 59 5. 35 1 3 .6 2
14 52 . 97 58 . 28 1 3 90. 2 9 51. 7 8 130 8. 76 4 4. 33 1 27 5. 0 9 44 .4 0 12 0 7. 81 33. 34
11 69 . 49 51 . 23 1 1 15. 6 3 76. 9 6 107 1. 71 8 3. 44 1 01 6. 0 8 85 .3 6 92 1 .9 9 9 1 .4 6
82 6. 0 8 49 . 4 3 7 46 . 47 27 . 68 6 92 .5 1 36 .6 2 6 51. 1 3 40. 1 9 53 5 .5 7 7 3. 00
45 2. 3 4 69 . 9 7

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FTIR SPECT RUM

Date: 21-12-2009
Spectrum Name: SJC-.6- .4 C.sp

1020.46

3929.03

Spectrum Name: SJC-1BD.sp

100.0

1019.04
863.28

1019.56

90
392 8.72

825.20

1171.48

18 24.00
1072.35

41 5.01

862.42

206 4.94

3940.59

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 9-. 1 C.sp

100.0

1976 .94

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 8-. 2 C.sp

100.0
1020.14

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009

Spectrum Name: SJC-. 7-. 3 C.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 21- 12-2009

206 6.37

236 3.70

3928.23

924.10

1982.17

416.70
2 671.73

904.93

1975.94

2669.38

750.68

1385.60
496.55

749.80

750.11

650.68

1449.01

748.60

1015.97

1310.06
452.91

1453.8 0
2 738.80
116 9.33

111 8.56

1446.30

1447.60

1223.65

%T
40

713.64

2819.60

1447.10

13 87.26

1 227.34

1312.18

545.73
825.54

%T
1345.87

65 0.99

4 93.14

1118.69

60
65 0.83 4 94.52

111 8.20

111 8.21
3072.54

65 0.95

1063.59

60
4 98.36

2742.57

1114.11

1913.80

1057.8 4

904.27
1060.65

1313.98

1314.81

2664.4 2
825.70

825.2 5

106 5.78
13 91.70

904.21

1314.29

714 .94

13 88.23

903.99

1172.30

70
26 41.57

1 172.14

651 .10

1206.73

712.74

1225.04
1345.67

1348.47

69 0.95

1594.44

2865.7 6

746.17

1230 .67
2866.5 7
286 6.81

2866.3 3

1595.75

20
1594.76

20
3 450.45
16 97.38

0.0

294 2.30

2 942.22
1706.09

3457.73

4000.0

1595.69
1706.83

2000

10
3 452.56

1500

1000

400.0

4000.0

294 0.82

1594.54
17 09.48

17 10.56

0.0
3000

2000

cm -1

1500

1000

400.0

4000.0

cm-1

3446.84

294 1.41

3448.97

0.0
3000

2000

1500

1000

400.0

4000.0

0.0
3000

2000

cm-1

1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

400.0

cm-1

SJ C-. 6-. 4 C. pk

SJC-.7-.3 C.pk

SJC-.8-.2 C.pk

SJC-.9-.1 C.pk

SJC-1BD.pk

SJ C-6-~1. SP 3601 4000.00 400.00 6. 32 99. 99 4.00 %T 5 1.00

SJC-7-~1. SP 3601 4000.00 400. 00 6.33 100.00 4.00 %T 5 1. 00

SJC-8-~1. SP 3601 4000.00 400. 00 6.94 99. 99 4.00 %T 5 1.00

SJC-9-~1. SP 3601 4000.00 400. 00 8.41 100.00 4.00 %T 5 1. 00

SJC-1BD.sp 3601 4000.00 400. 00 6. 32 99. 90 4.00 %T 5 1.00

REF 4000 98 .17 2000 9 4.12 600

REF 4 000 97.56 2000 95.26 600

REF 4 000 98.11 2000 96.86 600

REF 4 000 98.82 2000 97.87 600

REF 4 000 99.33 2000 94.67 600

3928.23 97.09 3446.84 6. 32 2819.60 52.37 2738.80 63.28 2363.70 95.08
1982.17 93.61 1913.80 94.42 1824.00 94.71 1697.38 18. 33 1594.54 10. 43
1453.80 66.53 1387.26 52.24 1310.06 55.31 1206.73 48. 10 1169.33 62. 45
1114.11 85.01 1072.35 87.37 1015.97 88.91 924.10 93.62 825.54 55.94
746. 17 35 .49 690.95 41.50 651.10 43.6 5 545.73 67.86 452.91 69. 90

Table - 7.4
Observations of FTIR spectrums for Cyclohexanone + Benzaldehyde mixture:
1(CH)
Cm-1

3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81

0.9(CH)
+ 0.1(BD)
Cm-1

0.8(CH)
+ 0.2(BD)
Cm-1

0.7(CH)
+ 0.3(BD)
Cm-1

0.6(CH)
+ 0.4(BD)
Cm-1

0.5(CH)
+ 0.5(BD)
Cm-1

*0.4(CH)
+ 0.6(BD)
Cm-1

0.3(CH)
+ 0.7(BD)
Cm-1

0.2(CH)
+ 0.8(BD)
Cm-1

0.1(CH)
+ 0.9(BD)
Cm-1

3448.46
3072.34
2945.26
2820.04
2739.45
1981.63
1914.95
1823.61
1701.38
1595.35
1452.97
1390.29
1308.76
1275.09
1207.81
1169.49
1115.63
1071.71
1016.08
921.99
826.08
746.47
692.51
651.13
535.57
452.34

3443.28
2944.45
2820.26
2739.06
2356.74
1983.61
1915.41
1701.81
1648.11
1594.54
1452.53
1387.22
1350.39
1311.25
1207.55
1169.54
1116.75
1071.12
1016.77
825.85
746.89
691.30
651.04
454.72

3459.33
3069.88
2941.90
2865.13
2739.65
2360.56
1978.55
1915.78
1703.62
1596.08
1450.49
1391.77
1309.89
1211.11
1117.95
1069.62
1019.47
908.34
826.41
747.26
705.60
651.00
526.91
454.25

3455.32
2943.23
2867.49
2741.42
2644.03
2360.34
1979.11
1702.34
1596.17
1449.28
1390.13
1312.26
1221.66
1118.46
1068.11
1020.71
905.98
825.64
747.51
708.66
650.93
501.66

3929.45
3450.26
2942.44
2866.61
2741.33
2644.38
1977.97
1700.39
1594.85
1449.77
1389.46
1346.06
1312.30
1234.30
1172.10
1118.21
1067.27
1020.51
905.45
825.42
748.25
711.65
651.17
502.40

3929.03
3457.73
3072.54
2942.22
2866.81
2742.57
2641.57
1976.94
1706.09
1595.75
1449.01
1391.70
1312.18
1230.67
1172.30
1118.21
1065.78
1020.46
904.93
825.70
748.60
712.74
650.99
498.36

3928.72
3448.97
2942.30
2866.57
2664.42
1975.94
1706.83
1595.69
1447.60
1385.60
1348.47
1314.81
1227.34
1172.14
1118.20
1063.59
1020.14
903.99
825.25
749.80
713.64
650.68
496.55

3940.59
3452.56
2941.41
2866.33
2669.38
2064.94
1709.48
1594.76
1447.10
1388.23
1345.67
1313.98
1225.04
1171.48
1118.56
1060.65
1019.56
904.27
862.42
825.20
750.11
714.94
650.83
494.52
416.70

3450.45
2940.82
2865.76
2671.73
2066.37
1710.56
1594.44
1446.30
1345.87
1314.29
1223.65
1118.69
1057.84
1019.04
904.21
863.28
750.68
650.95
493.14
415.01

* Maximum shift in the frequency has been observed.

281

1(BD)
Cm-1

3928.23
3446.84
2819.60
2738.80
2363.70
1982.17
1913.80
1824.00
1697.38
1594.54
1453.80
1387.26
1310.06
1206.73
1169.33
1114.11
1072.35
1015.97
924.10
825.54
746.17
690.95
651.10
545.73
452.91

Fig-7.4: FTIR spectrums for Cylclohexanone + Benzyl Chloride mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2
ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

Spectrum Name: SJC-PH-D-13.sp

100.0

FTIR SPECTRUM
Date: 23-6-2010

1018.37
864 .54

413.81

3930.87

2676.41

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.2+0.8.sp

10 0. 0
80

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.1+0.9.sp

2063.83

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.3+0.7.sp

10 0. 0

Spectrum Name: T5-0.5+0.5.sp

10 0. 0

65 1.44

2720.59

2735.96

1055.52 904.24

3938.72

2868.05

1963.51
2094.44

1077.29

4 91.25

3961.87

1965.52

2341.75
2092.32

1222.93

2340.84

1118.65

2945.41

1267.71

2160.51

1266.77

2870.05

50
562.85

1642.59

1439.70

30
1642.92
1705.86

1642.25

294 0.92

495.10

2942.64

1443.48

2942.09

561.19

1696.36

564.90

%T
40

561.87

40
2864.9 6
1355.79

1259.07

60
1437.36

1266.32

1445.45
3416.27

1116.77

2869.64

1439.41

1446.17

2672.64

1118.22

1266.68

50
%T

3954.27

3846.65

2081.12
3084.07

2953.55

111 9.11

90
2340.29

1118.69

2097.92

1208.42

2672.42

3843.40

2337.88

2346.29

762.30

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.4+0.6.sp

10 0. 0

1644.06

2940.51

695.37

1598.04
694.53

1712.26

0.0
4000.0

3000

2000

1500

1000

400.0

692.94

3 00 0

2 00 0

15 00

10 00

40 0 .0

3 00 0

2 00 0

c m -1

15 00

10 00

40 0 .0

3428.48

3428.60

0. 0

4 00 0. 0

2 00 0

15 00

10 00

40 0 .0

1707.71
3429.92

0. 0
3 00 0

c m -1

693.78

694.98

0. 0

4 00 0. 0

SJ666F~1. SP 3601 4000.00 400.00 7.43 100. 00 4.00 %T 5 1. 00

REF 4 000 98.06 2000 95.04 600
3930.87 96.55 3416.27 3 9.48 2940.92 13.42 2864. 96 30.69 2720.59 91. 03
2676.41 92.15 2063.83 9 4.22 1712.26 7. 43 1598.04 15.54 1445.45 43.83
1355.79 28.26 1222.93 5 2.54 1119.11 60.60 1055. 52 81.18 1018.37 85. 37
904. 24 79 .06 864.54 86. 10 762.30 71.15 6 51. 44 84. 16 491.25 69.72
413. 81 91 .89

1706.87

10
3430.60

3429.25

0. 0

cm-1

SJC-PH-D- 13. pk

0. 0

4 00 0. 0

3 00 0

2 00 0

15 00

c m -1

10 00

40 0 .0

4 00 0. 0

3 00 0

2 00 0

c m -1

15 00

10 00

40 0 .0

c m -1

T5-0. 1+0.9.pk

T5-0. 2+0.8.pk

T5-0. 3+0.7.pk

T5-0. 4+0.6.pk

T5-0. 5+0.5.pk

T5-01_~1.SP 3601 4000.00 400.00 6.34 99.99 4.00 %T 5 1.00

T5-02_~1.SP 3601 4000.00 400.00 6.36 100. 00 4.00 %T 5 1.00

T5-03_~1.SP 3601 4000.00 400.00 6.43 100. 00 4.00 %T 5 1.00

T5-04_~1.SP 3601 4000.00 400.00 6.41 99.99 4.00 %T 5 1.00

T5-05_~1.SP 3601 4000.00 400.00 10.10 99. 99 4.00 %T 5 1.00

REF 4000 99.26 2000 96. 11 600

3938. 72 94.00 3429.25 6.34 2953.55 78.43 2868.05 93. 06 2735.96 97. 82
2346. 29 89.15 2094.44 93.12 1963.51 94.84 1696.36 35. 98 1642. 59 30.10
1446. 17 62.90 1267.71 65.07 1208.42 84.86 1077.29 88. 60 692.94 14. 18
562.85 53.66

REF 4000 99.53 2000 95. 63 600

3430. 60 6.36 2945.41 74.05 2337.88 94.71 2097.92 92.42 1642.25 32.13
1439. 41 64.03 1266. 68 73.56 1118.69 88.87 694.53 20.25 561.87 56.45

REF 4000 99.59 2000 94. 75 600

3961. 87 93.14 3843. 40 92.88 3428.60 6.43 3084.07 69.34 2942.09 37.11
2870. 05 66.58 2672. 42 97.25 2340.29 92.24 2081.12 91.26 1965.52 93.20
1706. 87 16.91 1644. 06 26.02 1443.48 46.32 1266.32 57.76 1118.65 76.37
694.98 11.31 561. 19 50.20

REF 4000 99.46 2000 95. 91 600

3428. 48 6.41 2942.64 50.23 2869.64 76.18 2341.75 93. 90 2092.32 92. 79
1705. 86 30.17 1642.92 32.93 1437.36 61.09 1266.77 77. 76 1118. 22 85.02
695.37 25.73 561.87 59. 38

REF 4000 99.17 2000 95. 95 600

3954. 27 95.23 3846.65 92.46 3429.92 10.10 2940.51 26. 77 2672. 64 96.70
2340. 84 92.84 2160.51 92.74 1707.71 15.06 1439.70 46. 83 1259. 07 66.40
1116. 77 75.84 693.78 17.89 564.90 59.29 495.10 65.64

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2
ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

FT IR SPECT RUM
Date: 2/14/2009
Spectrum Name: EA+BC-11.sp

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.6+0.4.sp

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.7+0.3.sp

10 0. 0

FTIR SPECTRUM
Date: 23-6-2010

Spectrum Name: T5-0.8+0.2.sp

10 0. 0

100.0

Spectrum Name: T5-0.9+0.1.sp

10 0. 0

39 06.50

10 0. 0
80

2670.46

2669.55

3944.24

2669.51

2080.23

2338.25

2343.15

2669.81
2084.29

3939.40

2341.31

2095.48

3772.29

2088.84

2344.19

900.83

892.23

1053.16

70
561.17
492.06

1118.94

562.06

465.12
270 8.50

1223.82

2336.46

1027.31
1956.03
1600.2 2

3435.57

1436.22

1493.17

2960.75

810 .55

1207.69

1439.91

1644.85

695.92

697.16

694.24

2871.56

2941.55

559.3 7

1 074.43

693.96

1435.96

9 27.39

1811.47
189 0.06

2868.60

%T
40

1320.13

494.63

1323.73

%T
1434.46

1117.94
1225.65

60
496.08

1323.52

2871.24

%T
40

70
1117.88
1227.12

495.22

1049.11

1118.67
1327.85
1223.61

7 59.02

1451.17
3034.41
1266.87

1708.49

3427.60

3424.65

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

0. 0
3 00 0

c m -1

2 00 0

2939.32

1709.04

0. 0
3 00 0

0.0
3431.16

1711.02

4 00 0. 0

694.99

2939.64

2940.78

0. 0

15 00

10 00

40 0 .0

4000.0

1710.49

0. 0

3433.17

4 00 0. 0

c m -1

3 00 0

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

3000

2000

1500

1000

400.0

cm-1
3 00 0

2 00 0

c m -1

15 00

10 00

40 0 .0

c m -1

T5-0. 6+0.4.pk

T5-0. 7+0.3.pk

T5-0. 8+0.2.pk

T5-0. 9+0.1.pk

T5-06_~1.SP 3601 4000.00 400.00 6.42 100. 00 4.00 %T 5 1.00

T5-07_~1.SP 3601 4000.00 400.00 10.07 100.00 4. 00 %T 5 1.00

T5-08_~1.SP 3601 4000.00 400.00 6.40 100. 00 4.00 %T 5 1.00

T5-09_~1.SP 3601 4000.00 400.00 8.23 99.96 4.00 %T 5 1.00

REF 4000 99.06 2000 95. 57 600

3427. 60 6.42 2941.55 31.72 2871.24 57.77 2670.46 97.02 2338.25 93.74
2095. 48 91.76 1708. 49 19.24 1644.85 28.54 1434.46 49.21 1327.85 71.75
1223. 61 73.43 1118. 67 75.13 695. 92 26.59 562.06 57.81 495.22 63.12

REF 4000 99.33 2000 96. 62 600

3944. 24 96.24 3424. 65 14.14 2940.78 11.85 2871.56 34.85 2669.55 94.90
2343. 15 93.54 2080. 23 93.77 1711.02 10.07 1439.91 39.45 1320.13 56.70
1223. 82 59.01 1118. 94 64.17 1053.16 80.22 900.83 82.99 697.16 28.24
561.17 67.09 492. 06 64.06

REF 4000 99.35 2000 95. 59 600

3433. 17 6.40 2939.64 15.27 2669.51 96.64 2341.31 93.50 2088.84 92.00
1709. 04 10.13 1435. 96 45.29 1323.52 63.44 1227.12 68.32 1117.88 71.81
694.24 36.13 496. 08 60.45

REF 4000 99.80 2000 96. 31 600

3939. 40 93.21 3431.16 11.48 2939.32 12.63 2669.81 95. 45 2344. 19 93.64
2084. 29 92.85 1710.49 8.22 1436.22 42.62 1323.73 57. 95 1225.65 63. 71
1117. 94 67.64 1049.11 82.69 892.23 82.25 693.96 51.89 494.63 65.04

EA+BC-11. pk
EA9C82~1.SP 3601 4000. 00 400.00 7.08 99.91 4.00 %T 5 2. 00
REF 4 000 98.47 2000 59.62 600
3906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25. 24 2960.75 35. 21
2868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48. 63 1890.06 51. 79
1811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26. 63 1266.87 19. 47
1207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57
759. 02 31 .11 694.99 7. 08 559.37 42.03 465.12 60. 85

Table - 7.5
Observations of FTIR spectrums for Cyclohexanone + Benzyl Cholride mixture
1(CH)

Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81

0.9(CH)
+
0.1(BC)
Cm-1
3938.72
3429.25
2953.55
2868.05
2735.96
2346.29
2094.44
1963.51
1696.36
1642.59
1446.17
1267.71
1208.42
1077.29
692.94
562.85

0.8(CH)
+
0.2(BC)
Cm-1
3430.60
2945.41
2337.88
2097.92
1642.25
1439.41
1266.68
1118.69
694.53
561.87

*0.7(CH)
+
0.3(BC)
Cm-1
3961.87
3843.40
3428.60
3084.07
2942.09
2870.05
2672.42
2340.29
2081.12
1965.52
1706.87
1644.06
1443.48
1266.32
1118.65
694.98
561.19

0.6(CH)
+
0.4(BC)
Cm-1
3428.48
2942.64
2869.64
2341.75
2092.32
1705.86
1642.92
1437.36
1266.77
1118.22
695.37
561.87

0.5(CH)
+
0.5(BC)
Cm-1
3954.27
3846.65
3429.92
2940.51
2672.64
2340.84
2160.51
1707.71
1439.70
1259.07
1116.77
693.78
564.90
495.10

0.4(CH)
+
0.6(BC)
Cm-1
3427.60
2941.55
2871.24
2670.46
2338.25
2095.48
1708.49
1644.85
1434.46
1327.85
1223.61
1118.67
695.92
562.06
495.22

* Maximum shift in the frequency has been observed.

282

0.3(CH)
+ 0.7(BC)
Cm-1

3944.24
3424.65
2940.78
2871.56
2669.55
2343.15
2080.23
1711.02
1439.91
1320.13
1223.82
1118.94
1053.16
900.83
697.16
561.17
492.06

0.2(CH)
+
0.8(BC)
Cm-1
3433.17
2939.64
2669.51
2341.31
2088.84
1709.04
1435.96
1323.52
1227.12
1117.88
694.24
496.08

0.1(CH)
+
0.9(BC)
Cm-1
3939.40
3431.16
2939.32
2669.81
2344.19
2084.29
1710.49
1436.22
1323.73
1225.65
1117.94
1049.11
892.23
693.96
494.63

1(BC)

Cm-1
3906.50
3772.29
3435.57
3034.41
2960.75
2868.60
2708.50
2336.46
1956.03
1890.06
1811.47
1600.22
1493.17
1451.17
1266.87
1207.69
1074.43
1027.31
927.39
810.55
759.02
694.99
559.37
465.12

Fig-7.5: FTIR spectrums for Cyclohexanone + 2-Butanone mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

100.0
1018.37

864.54

2672.01

2671.09

1054.56

904.61

1447.94

1355.79

752.07

50
4 92.34

2940.92

1598.04

3000

2000

1595.67

1000

400.0

3000

2000

1000

400.0

3000

2000

1594.77

2866.21
1351.48

1500

1000

400.0

4000.0

3000

2000

cm-1

294 0.14

294 1.89

1595.99
1712.13

294 1.69

0.0

4000.0

2864.72

30
3444.29

20
1348.4 4

3456.40

1500
cm-1

1347.75

2866.39

0.0

4000.0

1448.26 1313.49

1444.92

1444.77

17 12.15
294 0.72

17 11.76

0.0
1500

cm-1

4 92.55

1222.88

1223.16

2865.20

294 0.98

1712.26

4000.0

752.83
111 9.41

1222.70

1313.17

1596.25

2865.0 6

3458.27

4 91.53
111 9.16

111 9.47

1343.92
1448.0 2

30
3486.61

2864.96

0.0

65 1.80

%T
40

1313.97

1347.44

1712.54

3 425.95

0.0

1500

1000

400.0

17 11.65

0.0

15 95.59

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

cm-1

2000

1500

1000

SJC-Ph-2. pk

SJC-Ph-3. pk

SJC-Ph-4. pk

SJC-Ph-5. pk

SJC-Ph-6. pk

SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00

SJC-Ph-2. sp 3601 4000. 00 400. 00 7.58 100.00 4.00 %T 5 1. 00

SJC-Ph-3. sp 3601 4000. 00 400. 00 7.50 100.00 4.00 %T 5 1. 00

SJC-Ph-4. sp 3601 4000. 00 400. 00 7.33 99.99 4.00 %T 5 1.00

SJC-Ph-5. sp 3601 4000. 00 400. 00 6.67 100.00 4.00 %T 5 1. 00

SJC-Ph-6. sp 3601 4000. 00 400. 00 8.87 100.00 4.00 %T 5 1. 00

REF 4000 98.06 2000 95.04 600

3930.87 96.55 3416.27 39.48 2940.92 13.42 2864.96 30.69 2720.59 91.03
2676.41 92.15 2063.83 94.22 1712.26 7.43 1598.04 15.54 1445.45 43.83
1355.79 28.26 1222.93 52.54 1119.11 60.60 1055.52 81.18 1018.37 85.37
904.24 79.06 864.54 86.10 762.30 71.15 651.44 84.16 491.25 69.72
413.81 91.89

REF 4 000 97.34 2000 96.37 600

3941.98 95.03 3458.27 1 7.89 2940.98 11.48 2865. 06 25.66 2672.01 86. 93
2175.67 92.77 2064.23 9 3.26 1971.59 95.17 1870. 28 94.51 1804.50 83. 19
1711.76 7. 57 1595. 67 17. 94 1447.94 40.63 1347.44 33.99 1313.97 43.78
1222.69 46.44 1119.11 5 2.84 1054.51 75.33 1017. 94 81.43 904.48 71.63
864. 14 80 .18 751.38 63. 17 652.02 74.78 4 91. 26 58. 91 412.78 86.93

REF 4 000 97.50 2000 96.56 600

3938.83 95.20 3486.61 3 0.92 2940.72 10.73 2865. 20 24.67 2671.09 85. 69
2334.58 94.42 2175.95 9 3.18 2063.95 93.35 1971. 50 94.86 1870.77 94. 47
1805.13 82.88 1712.15 7 .50 1633.84 42.74 1596.25 41.54 1448.02 39.83
1343.92 44.12 1313.17 4 3.98 1222.70 43.59 1119. 19 49.62 1054.56 72. 08
1018.22 79.19 904.61 70. 08 864.50 80 .10 750.74 66.53 652.39 79.62
491. 14 60 .66 412.30 88. 11

REF 4 000 96.99 2000 95.42 600

3941.66 93.34 3456.40 9. 17 2941.69 7. 88 2866.39 18.17 267 1.60 82.28
2425.67 95.27 2335.42 93.58 2175.98 90.55 2065.44 91. 20 1970.17 93. 73
1870.36 93.18 1712.13 7. 33 1595.99 11.79 1444.77 31.21 1348.44 26.54
1223.16 40.77 1119.47 47.81 1055.54 71.94 1018.62 79. 94 904.01 69.19
864. 59 79 .53 752.07 58.76 652.13 71.0 4 492.34 54.64 413.79 88. 06

REF 4 000 97.76 2000 96.65 600

3930.88 94.72 3785.94 9 2.03 3425.95 7. 89 2941.89 10.71 2866.21 23.76
2672.09 84.35 2335.31 9 4.61 2175.58 91.97 1970. 58 95.29 1870.08 94. 68
1712.54 7. 87 1595. 59 6.67 1444.92 34 .90 1351. 48 21. 97 1222.88 46.69
1173.09 78.85 1119.41 5 3.87 1055.78 76.45 1018. 44 83.85 903.80 73.44
863. 95 82 .11 752.83 57. 71 651.80 68.48 4 92. 55 55. 19 414.81 87.41

REF 4 000 98.52 2000 97.98 600

3939.27 97.31 3444.29 3 0.13 2940.14 16.16 2864. 72 37.42 2672.28 93. 64
2175.05 95.76 1711.65 8 .86 1594.77 29.37 1448.26 55.70 1347.75 50.15
1313.49 58.91 1222.63 6 0.68 1119.16 66.71 1054. 18 86.31 1018.04 89. 90
905. 04 83 .14 863.78 87. 92 751.37 74.26 6 52. 25 81. 35 491.53 70.87
413. 13 92 .72

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 06- 1-2010

180 4.85

903.84
1053.06

100.0

2 721.81

80
904.56
1055.25

65 2.42

905.44

1222.39

65 1.99

752.27

864 .60

2357.45

FTIR SPECTRUM
Spectrum Name: 2-Butanone

2169.05
379 0.77

415.02

1054.5 5

1313.53

11 19.54

652.62

111 9.39

1449.8 9

2834.19

50
111 9.36

491.86

1247.00

3778.25

2863.8 1

1815.01

586.34

1222.98

751.08

2087.47

774.12

4 91.75

90 4.02

3921.99

4 94.26

4 92.42
751.15

105 5.43

1171.44

2175.01

3939.5 7

864.25

2175.51

2175.74
2670.63

2672.58

2672.25

4 13.86

100.0

863.74

3921.39

412.3 2
1871.35

3941.98

101 8.30

1018.56

1173.23

100.0

3931.83

Spectrum Name: SJC-Ph- 10. sp

100.0

1018.04

ACIC
St.Joseph 's College ( Autonomous )
Trichy-2

FT IR SPECT RUM
Date: 06- 1-2010

Spectrum Name: SJC-Ph- 9.sp

100.0

FT IR S PECTR UM
Dat e: 06 -1 -2 01 0
Sp ect rum Na m e: SJ C-Ph -7. sp

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 06- 1-2010
Spectrum Name: SJC-Ph- 8.sp

400.0

cm-1

SJC-PH-D-13.pk

ACIC
St. J os ep h's C olleg e ( Aut ono m o us )
Tric h y-2

65 2.25
751.37

903.80

1222.69

1445.45
3416.27

863.78

1055.78

1222.63

111 9.19

1018.04

1054.18

863 .95

904.01

4 91.14

50
111 9.11

1222.93

750.74

1633.84

4 91.26

2175.0 5

26 72.09
2175.5 8

864.59

1055.5 4

751.38

2 672.28

905.04

2671.60

65 2.13

413.13
3939.27

1870.08

80
187 0.36
1018.62

864.50

65 2.02

904.48

491.25
1119.11

414.8 1
1173.09

3785.94

2065.44
23 35.42
65 2.39

1805.13
864 .14

1054.51

1970.58
233 5.31

413 .79

2175.95

1017.94

100.0

3930.88

90
1970.17
2425.67

762.30

FT IR SPECT RUM
Date: 06- 1-2010
Spectrum Name: SJC-Ph- 6.sp

100.0

2175.9 8

2063.95

1804.50

1055.52 904.24

412.30

1870.77

233 4.58

3941.66

187 0.28
206 4.23

651.44

3938.83

Spectrum Name: SJC-Ph- 5.sp

1 018.44

1018.22

90
21 75.67

3941.98

2720.59

100.0

1971.50

412.7 8

2063.83

FT IR SPECT RUM
Date: 06- 1-2010

Spectrum Name: SJC-Ph- 4.sp

100.0

19 71.59

2676.41

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 06- 1-2010

Spectrum Name: SJC-Ph- 3.sp

413.81

3930.87

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 06- 1-2010

Spectrum Name: SJC-Ph- 2.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 06- 1-2010

FTIR SPECTRUM
Date: 08-2-2010

SpectrumName: Cyclohexanone

2930.86

1445.49

1409.75
1011.07

1119.2 8

40
1222.78
1448.37
1346.95

%T
1223.01

40
1445.36

40
1351.35

294 2.07

1314.79

1117.88
563.2

2865.71
17 10.70

1594.83

1344.36

1593.26

1594.84

2865.35

1360.76

1626.89

3448.12

2865.95

3475.7 2

3458.65

294 0.50

3437.07
294 0.54

10
2940.74

4000.0

1711.79

3000

17 11.57

1711.95

0.0
2000

0.0

1500

1000

400.0

4000.0

cm-1

4000.0

3000

2000

1500

1000

cm-1

SJ C-P h-7 .p k
SJ C-P h-7 .s p 3 60 1 40 0 0. 00 400 .0 0 7 .84 10 0 .0 0 4. 00 %T 5 1 .0 0
R EF 4 00 0 9 8 .2 4 20 00 9 7 .0 2 6 00
3 9 31 .8 3 96 .1 5 347 5 .7 2 2 4. 90 2 9 40 .74 10 .1 5 2 8 65 .9 5 26 .1 3 267 0.6 3 8 9. 56
2 3 57 .4 5 90 .0 8 217 5 .7 4 9 4. 14 1 7 11 .79 7. 84 1 59 4 .8 3 3 5 .8 8 1 44 5. 36 4 3 .7 8
1 3 44 .3 6 46 .7 0 131 4 .7 9 4 9. 12 1 2 23 .01 49 .9 6 1 1 19 .2 8 57 .2 4 105 5.4 3 7 9. 21
1 0 18 .3 0 85 .1 6 904 .0 2 7 5. 98 86 4 .6 0 84 .3 6 7 5 1 .08 6 9 .3 7 65 2.6 2 7 8 .82
4 9 1. 86 6 4 .3 3 41 3 .8 6 9 0. 77

400.0

159 3.38

0.0

0.0
3000

2000

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

cm-1

0.0

3445.42

SJC-Ph-8. pk

SJC-Ph-9. pk

SJC-Ph-10.pk

SJC-Ph-8. sp 3601 4000. 00 400. 00 7.26 100.00 4.00 %T 5 1. 00

SJC-Ph-9. sp 3601 4000. 00 400. 00 9.63 100.00 4.00 %T 5 1. 00

SJC-PH~1. SP 3601 4000. 00 400. 00 6.50 100.00 4.00 %T 5 1.00

Cl-AN-11.pk

REF 4 000 97.86 2000 96.48 600

3941.98 96.27 3458.65 1 6.44 2940.54 9. 09 2865.35 23.40 2672.25 90.32
2175.51 93.62 1871.35 9 6.24 1804.85 87.89 1711. 95 7.26 1593.26 27.47
1448.37 40.88 1346.95 4 0.04 1313.53 46.24 1222. 78 47.11 1173.23 85. 99
1119.36 55.09 1054.55 8 1.06 1018.04 86.59 905.44 76.63 864. 25 85.20
751. 15 67 .93 652.42 78. 65 491.75 61.55 4 12. 32 90. 08

REF 4 000 98.17 2000 97.25 600

3939.57 96.80 3448.12 2 0.74 2940.50 13.18 2865. 71 33.48 2672.58 92. 77
2175.01 95.21 1711.57 9 .62 1594.84 24.68 1445.49 51.33 1351.35 44.73
1222.98 59.86 1119.39 6 6.51 1055.25 86.13 1018. 56 90.22 904.56 83.81
863. 74 89 .50 752.27 74. 25 651.99 80.62 4 92. 42 69. 00 415.02 91.60

REF 4 000 99.10 2000 98.49 600

3921.39 97.01 3790.77 9 4.70 3437.07 12.79 2942. 07 40.75 2863.81 63. 08
2834.19 65.58 2721.81 8 9.94 2169.05 96.21 1710. 70 30.25 1593.38 6.50
1449.89 70.25 1360.76 2 5.90 1222.39 83.52 1171. 44 93.02 1119.54 84. 70
1053.06 94.37 903.84 94. 36 774.12 66 .41 586.34 73.54 494.26 74.79

Cl-AN-11.sp 3601 4000.00 400.00 6.34 99.17 4.0 0 %T 5 1 .00

4000.0

3000

2000

1500

1000

400.0

cm-1

REF 4000 88.37 20 00 83.26 600

3921.99 87.11 3778.25 73.94 3445.42 6.3 4 2930 .86 71.20 2087.47 82.53
1815.01 86.05 1626.89 35.54 1409.75 68.12 1247.00 74.30 1117.88 55.3 5
1011.07 61.13 563.25 53.03

Table - 7.6
Observations of FTIR spectrums for Cyclohexanone + 2-Butanone mixture:
1(CH)
Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81

0.9(CH)
+ 0.1(2B)
Cm-1

0.8(CH)
+ 0.2(2B)
Cm-1

0.7(CH)
+ 0.3(2B)
Cm-1

*0.6(CH)
+ 0.4(2B)
Cm-1

0.5(CH)
+ 0.5(2B)
Cm-1

0.4(CH)
+ 0.6(2B)
Cm-1

0.3(CH)
+ 0.7(2B)
Cm-1

0.2(CH)
+ 0.8(2B)
Cm-1

0.1(CH)
+ 0.9(2B)
Cm-1

3941.98
3458.27
2940.98
2865.06
2672.01
2175.67
2064.23
1971.59
1870.28
1804.50
1711.76
1595.67
1447.94
1347.44
1313.97
1222.69
1119.11
1054.51
1017.94
904.48

3938.83
3486.61
2940.72
2865.20
2671.09
2334.58
2175.95
2063.95
1971.50
1870.77
1805.13
1712.15
1633.84
1596.25
1448.02
1343.92
1313.17
1222.70
1119.19
1054.56
1018.22
904.61
864.50
750.74
652.39

3941.66
3456.40
2941.69
2866.39
2671.60
2425.67
2335.42
2175.98
2065.44
1970.17
1870.36
1712.13
1595.99
1444.77
1348.44
1223.16
1119.47
1055.54
1018.62
904.01
864.59
752.07
652.13
492.34
413.79

3930.88
3785.94
3425.95
2941.89
2866.21
2672.09
2335.31
2175.58
1970.58
1870.08
1712.54
1595.59
1444.92
1351.48
1222.88
1173.09
1119.41
1055.78
1018.44
903.80
863.95
752.83
651.80
492.55
414.81

3939.27
3444.29
2940.14
2864.72
2672.28
2175.05
1711.65
1594.77
1448.26
1347.75
1313.49
1222.63
1119.16
1054.18
1018.04
905.04
863.78
751.37
652.25
491.53
413.13

3931.83
3475.72
2940.74
2865.95
2670.63
2357.45
2175.74
1711.79
1594.83
1445.36
1344.36
1314.79
1223.01
1119.28
1055.43
1018.30
904.02
864.60
751.08
652.62
491.86
413.86

3941.98
3458.65
2940.54
2865.35
2672.25
2175.51
1871.35
1804.85
1711.95
1593.26
1448.37
1346.95
1313.53
1222.78
1173.23
1119.36
1054.55
1018.04
905.44
864.25
751.15
652.42
491.75
412.32

3939.57
3448.12
2940.50
2865.71
2672.58
2175.01
1711.57
1594.84
1445.49
1351.35
1222.98
1119.39
1055.25
1018.56
904.56
863.74
752.27
651.99
492.42
415.02

3921.39
3790.77
3437.07
2942.07
2863.81
2834.19
2721.81
2169.05
1710.70
1593.38
1449.89
1360.76
1222.39
1171.44
1119.54
1053.06
903.84
774.12
586.34
494.26

864.14
751.38
652.02
491.26
412.78

491.14
412.30

* Maximum shift in the frequency has been observed.

283

1(2B)
Cm-1
3921.99
3778.25
3445.42
2930.86
2087.47
1815.01
1626.89
1409.75
1247.00
1117.88
1011.07
563.25

Fig-7.6: FTIR spectrums for Cyclohexanone + Ethyl Acetate mixture:

ACIC
St.Joseph's College( Autonomous )
Trichy-2
ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

FTIR SPECTRUM
Date: 08-2-2010

ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

Spectrum Name: Cyclohexanone

100.0
1018.37

864.54

FTIR SPECTRUM
Date: 09-3-2010

413.81

3930.87

2676.41

FTIR SPECTRUM
Date: 09-3-2010

Spectrum Name: SJ C-Ph-S-4.sp

10 0. 0
80

FTIR SPECTRUM
Date: 09-3-2010

Spectrum Name: SJ C-Ph-S-3.sp

2063.83

FTIR SPECTRUM
Date: 09-3-2010

Spectrum Name: SJ C-Ph-S-5.sp

10 0. 0

412.01

FTIR SPECTRUM
Date: 09-3-2010

Spectrum Name: SJ C-Ph-S-6.sp

10 0. 0

412.60

Spectrum Name: SJ C-Ph-S-7.sp

10 0. 0

413.43

10 0. 0
413.70

651.44

2720.59

1055.52 904.24

2364.76 2065.06

2672.44

2088.47

3780.79
1382.60

651.40

2363.51

907.14

1310.99

491.25

1119.11

1053.64

1340.94

2867.07

1118.67

904.27

1378.25

905.15

3514.51

1053.72

490.84

1117.99

846.40

1313.15

1444.94

1118.03

1053.60

1312.07

1445.48
1229.67

10
2940.92

2943.02

1758.93

4000.0

3000

2000

1713.81

10
1500

1000

3 00 0

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

3 00 0

2 00 0

4 00 0. 0

3 00 0

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

3 00 0

2 00 0

15 00

10 00

SJ C-PH~3.SP 3601 4000.00 400.00 6. 19 100.00 4.00 %T 5 2.00

REF 4000 78.90 2000 78. 49 600
3781. 77 76.22 3514. 51 52.70 3409.98 53.77 2940.59 10.35 2865.74 20.22
2671. 35 69.49 2066. 97 76.33 1713.00 6.19 1447.87 28.48 1375.48 41.05
1342. 03 38.85 1312. 07 32.46 1237.99 11.62 1118.03 35.97 1051.28 32.43
905.15 52.69 846. 40 40.14 750.72 53.62 649.90 65. 86 557.71 72.65
490.84 48.89 416. 18 76.61

ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 09-3-2010

Spectrum Name: SJ C-Ph-S-10.sp

Spectrum Name: Ethyl Acetate

10 0. 0

90
2671.88

3778.66

3778.61

557.86
906.23

751.06

2489.19

2088.87

1383.37

2671.56

928.0
651.75

864.52

905.41 750.29

2362.08

635.35

1311.35

3161.64

1340.51

1168.92

2088.74

2358.27

100.0

412.20

412.79

3787.98

FTIR SPECTRUM

Spectrum Name: SJ C-Ph-S-11.sp

10 0. 0

40 0 .0

c m -1

SJ C-Ph-S-7.pk

80
863.98

15 00
c m -1

REF 4000 95.96 2000 95. 35 600

3780. 24 88.11 3411. 44 52.61 2941.63 8.45 2866.50 19.81 2670.81 85.20
2356. 77 90.99 2068. 86 92.99 1714.72 7.81 1445.48 30.76 1378.90 49.70
1313. 15 37.56 1236. 88 12.64 1117.99 41.06 1053.60 40.97 904.27 64.32
853.79 60.72 750. 64 65.05 650.16 79.81 556.60 88. 18 490.88 57.85
413.70 85.04

490.75

750.55
904.56

2 00 0

SJ C-PH~2.SP 3601 4000.00 400.00 7. 81 100.00 4.00 %T 5 2.00

651.00

1380.39

3 00 0

SJ C-Ph-S-6.pk

REF 4000 97.61 2000 97. 06 600

3781. 38 92.07 3497. 27 48.00 2941.24 10.23 2866.49 23.76 2670.51 88.70
2355. 74 94.20 2070. 74 94.54 1714.04 7.54 1444.94 36.02 1377.64 49.61
1312. 68 42.95 1238. 06 12.43 1117.68 47.17 1052.09 41.30 904.82 69.64
850.74 67.76 750. 70 70.73 649.02 82.80 491.04 62. 50 413.43 88.05

FTIR SPECTRUM
Date: 09-3-2010

2068.09

4 00 0. 0

SJ C-PH~4.SP 3601 4000.00 400.00 7. 54 100.00 4.00 %T 5 2.00

REF 4000 99.20 2000 98. 63 600

3779. 32 92.84 3464.57 55.53 2943.02 27.47 2867.07 48. 04 2672. 44 94.89
2363. 51 96.74 2088.47 96.33 1758.93 20.13 1446.45 55. 59 1378. 25 46.79
1310. 99 61.03 1241.51 7.69 1114.95 62.58 1053.72 38. 81 907.14 85.19
849.95 79.54 751.03 86. 32 638.34 88.40 490.73 81. 03 412.60 96.53

ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

40 0 .0

c m -1

SJ C-Ph-S-5.pk

SJ D905~1.SP 3601 4000.00 400.00 7. 70 99.99 4.00 %T 5 2. 00

2360.34

40 0 .0

SJ C-Ph-S-4.pk

Spectrum Name: SJ C-Ph-S-9.sp

2671.04

10 00

1237.99

REF 4000 97.24 2000 96. 69 600

3780. 79 90.13 3411. 76 57.34 2941.37 9.65 2865.51 24.46 2671.56 89.81
2364. 76 95.22 2065. 06 95.03 1713.81 7.48 1447.98 38.66 1382.60 62.10
1340. 94 52.75 1312. 48 43.77 1229.67 28.35 1118.67 46.81 1053.64 57.50
905.48 70.40 864. 26 79.01 750.38 71.71 651.40 85. 64 490.42 62.70
412.01 87.97

10 0. 0

1051.28

1713.00

0. 0

SJ D901~1.SP 3601 4000.00 400.00 7. 48 100.00 4.00 %T 5 2.00

FTIR SPECTRUM
Date: 09-3-2010

3778.20

15 00
c m -1

2865.74
2940.59

1714.72

0. 0

SJ C-Ph-S-3.pk

ACIC
St.Joseph's College ( Autonomous )
T ric hy-2

Spectrum Name: SJ C-Ph-S-8.sp

10
1236.88
2941.63

0. 0

c m -1

SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00

REF 4000 98.06 2000 95.04 600
3930.87 96.55 3416.27 39.48 2940.92 13.42 2864.96 30.69 2720.59 91.03
2676.41 92.15 2063.83 94.22 1712.26 7.43 1598.04 15.54 1445.45 43.83
1355.79 28.26 1222.93 52.54 1119.11 60.60 1055.52 81.18 1018.37 85.37
904.24 79.06 864.54 86.10 762.30 71.15 651.44 84.16 491.25 69.72
413.81 91.89

10
1238.06

1241.51

0. 0

4 00 0. 0

SJC-PH-D-13.pk

413.42

1714.04

2941.37

0. 0

10 0. 0

2866.50

2941.24

400.0

cm-1

1447.87

2866.49

2865.51

1598.04
1712.26

0.0

750.72

3409.98

1312.68

1447.98

649.90

853.79

3411.44

1117.68

1052.09
1355.79

1342.03
1375.48

2671.35

60
490.88

50
%T
3497.27

750.64

491.04

50
%T

1312.48
2864.96

2066.97

3781.77

557.71

60
850.74

1446.45

3464.57

70
1378.90

904.82 750.70

60
1114.95

3411.76

416.18

70
1377.64

60
490.42

1445.45
3416.27

650.16

2670.81

849.95

750.38

1222.93

649.02

905.48

50
%T

556.60

80
2355.74

490.73

864.26

2068.86
2356.77

3780.24

2670.51

751.03

2070.74

638.34
2671.56

762.30

90
3781.38

3779.32

651.34

1053.54

1381.89

2671.91

864.46

490.93

490.53

2991.58

622.0
1378.64

60
3413.80

3501.95

50
1116.91

%T
40

1118.41

844.94

1118.80

490.48

40
1449.13

1312.44
1447.89

40
3411.21

1056.51

1225.64

1637.15

1053.70

1313.24

750.40
905.61

3493.45

1053.93

1379.09

1444.69

1052.40

2866.30

1312.37

1118.64

1763.76

2865.29

1447.56

2866.55

1231.49
1233.98

2942.69

1713.85

1242.81

1712.83

2865.37

2940.58

2941.59
2941.51

1241.32

0. 0

4 00 0. 0

3 00 0

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

1714.06

1713.29

0. 0
3 00 0

c m -1

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

c m -1

3449.55

0. 0
3 00 0

2 00 0

15 00

10 00

40 0 .0

4 00 0. 0

0.0
3 00 0

2 00 0

c m -1

15 00

10 00

40 0 .0

4000.0

3000

2000

1500

1000

400.0

cm-1

c m -1

SJ C-Ph-S-8.pk

SJ C-Ph-S-9.pk

SJ C-Ph-S-10.pk

SJ C-Ph-S-11.pk

Cl-AN-1.pk

SJ E905~1.SP 3601 4000.00 400.00 7.48 99.99 4. 00 %T 5 2.00

SJ C-PH~1.SP 3601 4000.00 400.00 7. 63 100.00 4.00 %T 5 2.00

SJ AE41~1.SP 3601 4000.00 400.00 6. 69 100.00 4.00 %T 5 2.00

SJ A651~1.SP 3601 4000. 00 400.00 8.26 99. 99 4.00 %T 5 2.00

Cl-AN-1.sp 360 1 4000.00 4 00.00 6.33 100.00 4.00 %T 5 1 .00

REF 4000 97.39 2000 96. 89 600

3778. 20 89.87 3501.95 58.30 2941.59 10.65 2866.55 24. 05 2671. 04 88.36
2360. 34 93.80 2068.09 95.05 1713.85 7. 48 1444.69 34. 89 1380.39 60. 28
1313. 24 40.80 1233.98 20.54 1118.41 45.28 1053.93 51. 32 904.56 67. 70
863.98 77.30 750.55 69. 40 651.00 83.61 490.93 60. 67 413.42 86.66

REF 4000 97.62 2000 97. 10 600

3787. 98 91.94 3493. 45 51.82 3161.64 76.74 2942.69 19.00 2866.30 35.56
2671. 88 92.46 2358. 27 94.30 2088.74 94.47 1712.83 16.05 1449.13 43.67
1379. 09 39.22 1311. 35 50.60 1241.32 7.62 1168.92 76.15 1116.91 53.11
1052. 40 34.81 906.23 77.10 844.94 42.72 751.06 74.33 635. 35 83.92
557.86 79.85 490. 75 71.81 412.79 89.19

REF 4000 75.70 2000 73. 48 600

3778. 61 65.37 3411. 21 42.81 2941.51 6.68 2865.37 17.25 2671.91 68.29
1714. 06 7.41 1447.56 30.86 1381.89 47.86 1312.37 34.07 1231.49 21.24
1118. 64 37.09 1053. 70 43.97 905. 61 54.98 864.46 61.52 750.40 56.19
651.34 65.91 490. 48 50.28

REF 4000 97.49 2000 96. 94 600

3778. 66 90.23 3413.80 60.94 2940.58 14.43 2865.29 32. 89 2671. 56 92.24
1713. 29 8.25 1447.89 47.51 1383.37 73.34 1340.51 60. 75 1312.44 51. 96
1225. 64 42.35 1118.80 55.58 1053.54 70.66 905. 41 76. 75 864.52 84.16
750.29 76.85 651.75 87. 84 490.53 69.11 412.20 89. 01

REF 4000 99.39 2000 97.58 600

3449.55 6.33 2991.58 69.36 2489.19 98.54 2362.08 89.0 0 2088.87 95.42
1763.76 32.63 1637.15 43.78 1378 .64 67.05 1 242.81 18.73 1056.51 55.12
928.00 97.75 622.08 69.8 6

Table - 7.7
Observations of FTIR spectrums for Cyclohexanone + Ethyl Acetate mixture:
1(CH)

Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81

0.9(CH)
+
0.1(EA)
Cm-1

0.8(CH)
+
0.2(EA)
Cm-1

0.7(CH)
+
0.3(EA)
Cm-1

0.6(CH)
+
0.4(EA)
Cm-1

*0.5(CH)
+ 0.5(EA)
Cm-1

3780.79
3411.76
2941.37
2865.51
2671.56
2364.76
2065.06
1713.81
1447.98
1382.60
1340.94
1312.48
1229.67
1118.67
1053.64
905.48
864.26
750.38
651.40
490.42

3779.32
3464.57
2943.02
2867.07
2672.44
2363.51
2088.47
1758.93
1446.45
1378.25
1310.99
1241.51
1114.95
1053.72
907.14
849.95
751.03
638.34
490.73
412.60

3781.38
3497.27
2941.24
2866.49
2670.51
2355.74
2070.74
1714.04
1444.94
1377.64
1312.68
1238.06
1117.68
1052.09
904.82
850.74
750.70
649.02
491.04
413.43

3780.24
3411.44
2941.63
2866.50
2670.81
2356.77
2068.86
1714.72
1445.48
1378.90
1313.15
1236.88
1117.99
1053.60
904.27
853.79
750.64
650.16
556.60
490.88
413.70

3781.77
3514.51
3409.98
2940.59
2865.74
2671.35
2066.97
1713.00
1447.87
1375.48
1342.03
1312.07
1237.99
1118.03
1051.28
905.15
846.40
750.72
649.90
557.71
490.84
416.18

412.01

0.4(CH)
+
0.6(EA)
Cm-1
3778.20
3501.95
2941.59
2866.55
2671.04
2360.34
2068.09
1713.85
1444.69
1380.39
1313.24
1233.98
1118.41
1053.93
904.56
863.98
750.55
651.00
490.93
413.42

* Maximum shift in the frequency has been observed.

284

0.3(CH)
+
0.7(EA)
Cm-1
3787.98
3493.45
3161.64
2942.69
2866.30
2671.88
2358.27
2088.74
1712.83
1449.13
1379.09
1311.35
1241.32
1168.92
1116.91
1052.40
906.23
844.94
751.06
635.35
557.86
490.75
412.79

0.2(CH)
+
0.8(EA)
Cm-1

0.1(CH)
+
0.9(EA)
Cm-1

3778.61
3411.21
2941.51
2865.37
2671.91
1714.06
1447.56
1381.89
1312.37
1231.49
1118.64
1053.70
905.61
864.46
750.40
651.34
490.48

3778.66
3413.80
2940.58
2865.29
2671.56
1713.29
1447.89
1383.37
1340.51
1312.44
1225.64
1118.80
1053.54
905.41
864.52
750.29
651.75
490.53
412.20

1(EA)

Cm-1
3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08

Fig-7.7: FTIR spectrums for Hexane + Heptane mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/17/2009

FT IR SPECT RUM
Date: 3/5/2008

Spectrum Name: Sample -4.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 3/5/2008

Spectrum Name: Sample -3.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 3/5/2008

Spectrum Name: Sample -2.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 3/5/2008

Spectrum Name: Hex+Bz-11. sp

FT IR SPECT RUM
Date: 3/5/2008

Spectrum Name: Sample -5.sp

100.0

Spectrum Name: Sample -6.sp

100.0

2338.30

100.0
2734.6 7

2339.62

2338.64

3 915.97

90
237 3.48
20 90.58

1120.98

2870.02

652.75
607.50

2959 .60

240 5.48

1120.44

237 3.95
2097.45

1197.33

26 18.71

2870.0 1

237 7.31

1121.63

2098.49
655.39

1122.86

2959 .73

2960.28

2339.1 5

3762.46

1121.90
2869.55

70
2929.60

2727.89

3750.51

2868 .43

11 96.25

2338.41

90
1197.13

2372.302097.43
2372.322100.58

80
3764.62

3762.32

1196.69

3838 .59

656.61

1392.73

2958 .69

1393.19

606.86

1464.50

606.35

607.48

50
1393.87

1393.57

607.11

2928 .53

7 12.33
1117.52

1415.62

1636.19

615.48

13 90.37

1638.32

1636.55

1637.32

1638.05
2880.66

1028.23

1628.07

3443.99

0.0

4000.0

3443.57

0.0
3000

2000

1500

1000

400.0

344 5.52

0.0

4000.0

3000

2000

cm -1

1500

1000

400.0

4000.0

2000

1500

1000

400.0

4000.0

10
2963.34

344 3.87

3444.34

0.0
3000

cm -1

0.0
3000

2000

cm -1

1500

1000

400.0

0.0

4000.0

3000

2000

cm -1

1500

1000

400.0

344 4.54

4000.0

3000

cm -1

2000

1500

1000

Sample -2.pk

Sample -3.pk

Sample -4.pk

Sample -5.pk

Sample -6.pk

HEX_BZ~4.SP 3601 4000.00 400.00 6. 33 9 8.66 4. 00 %T 5 1.00

SAMPLE~2.SP 3601 4000.00 400.00 6. 32 99.82 4.00 %T 3 0.50

SAMPLE~3.SP 3601 4000.00 400.00 6. 32 99.37 4.00 %T 3 0.50

SAMPLE~4.SP 3601 4000.00 400.00 6. 32 99.30 4.00 %T 3 0.50

SA0150~1.SP 3601 4 000.00 400.00 6.32 99.49 4. 00 %T 3 0.50

SA0950~1.SP 3601 4 000.00 400.00 5.02 99.23 4. 00 %T 3 0.50

REF 4000 73.80 2000 56.81 600

3838.59 68.32 3750.51 65.74 3443. 99 6.33 2928.53 47.34 2727.89 65.85
2405.48 63.83 1628.07 19.08 1415. 62 34.75 1117. 52 36. 84 1028. 23 37. 71
712.33 39.7 2 615.48 38. 51

REF 4000 97.36 2000 93.26 600

3915.97 95.60 3764.62 85.95 3443. 57 6.32 2959.60 65.39 2929.60 69.91
2870.02 82.87 2373.48 94.57 2338. 64 96.63 2090. 58 91. 24 1636. 19 41. 18
1392.73 60.54 1196.69 92.30 1120. 98 82.82 652.75 65.73 607. 50 65. 28

REF 4000 95.61 2000 91.14 600

3762.32 82.50 3445.52 6. 32 2960. 28 68.75 2868.43 83.93 2372.32 87.48
2338.30 93.95 2100.58 88.88 1636. 55 37.82 1393. 87 54. 99 1196. 25 87. 87
1120.44 78.05 607.48 59.55

REF 4000 99.16 2000 91.99 600

3444.34 6. 32 2958. 69 62.27 2869. 55 81.89 2372.30 89.99 2339.62 94.81
2097.43 89.64 1638.32 39.59 1393. 19 60.76 1197. 13 93. 32 1121. 90 85. 46
656.61 65.3 7 606.86 65. 33

REF 4000 99.14 2000 90.45 600

3762.46 81.13 3443.87 6. 32 2959. 73 70.00 2870.01 86.87 2373.95 91.14
2338.41 94.97 2097.45 88.13 1637. 32 37.05 1393. 57 57. 58 1197. 33 91. 68
1121.63 82.64 655.39 63.09 606.35 62. 47

REF 4000 93.84 2000 85.92 600

3444.54 5. 02 2963. 34 8.87 2880. 66 32. 87 2734.67 92. 98 2618.71 93. 10
2377.31 85.60 2339.15 95.57 2098. 49 83.63 1638. 05 34. 06 1464. 50 62. 58
1390.37 45.95 1122.86 76.73 607.1 1 54.83

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 3/5/2008
Spectrum Name: Sample -7.sp

FT IR SPECT RUM
Date: 3/7/2008

Spectrum Name: Sample-9. sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 3/7/2008

Spectrum Name: Sample-8. sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 3/7/2008

Spectrum Name: Sample-10.sp

100.0

400.0

cm -1

Hex+Bz-11.pk

Spectrum Name: Sample-11.sp

100.0

2736 .02
3962.13

2338.53

90
3764.86

2607.90
2378.82
2098.42

3918.22

3960 .16

3772.70

1122.81

80
2382.26
20 86.71

2099.25

1195.14

60
1464.69

70
1122.83

1763.36
20 85.72

1122.73

2409.78

3777.70
2968.93

1122.49

11 95.75

3774.28

2882.23

2339.42

181 2.30

2424 .51

20 92.97

3772.95

3960.15

26 23.58

2382.58

1283.78

1465.86

60 4.99

606.54

606.53

1120.95

605.92

608.79
1465.26

2966.7 7
13 89.93

13 90.22

2 881.30

13 89.67
1636.90

1392.11

1 632.89

1628.27

1 634.40

1 634.48

1387.28

2881.5 8

20
2 882.61

2966.4 4

10
3443.50

4000.0

10
343 8.87

2963.43

0.0

343 9.77

0.0
3000

2000

1500

1000

400.0

4000.0

cm -1

0.0
3000

2000

1500

1000

400.0

3440.74

4000.0

cm -1

0.0
3000

2000

1500

1000

400.0

2965.03

3441.07

4000.0

0.0
3000

2000

cm -1

1500

1000

400.0

4000.0

cm -1

3000

2000

1500

1000

400.0

cm -1

Sample -7.pk

Sample-8.pk

Sample-9.pk

Sample-10.pk

Sample-11.pk

SA0160~1.SP 3601 4 000.00 400.00 6.38 98.84 4. 00 %T 3 0.50

Sample-8.sp 3601 4000.00 400.00 6.33 97.51 4. 00 %T 3 1.00

Sample-9.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 0. 50

SA1D50~1.SP 3601 4000. 00 400.00 6.31 98 .56 4.00 %T 3 1 .00

SA1560~1.SP 3601 4 000.00 400.00 7.17 98.93 4. 00 %T 3 1.00

REF 4000 93.08 2000 86.76 600

3764.86 77.62 3443.50 6. 38 2963. 43 8.28 2881.58 31. 36 2736.02 92. 11
2607.90 92.48 2378.82 88.57 2338. 53 96.16 2098. 42 84. 67 1636. 90 37. 04
1464.69 61.36 1389.93 47.68 1122. 81 76.74 604.99 60.69

REF 4000 84.55 2000 80.75 600

3918.22 83.54 3772.95 76.26 3439. 77 6.33 2966.44 19.88 2881.30 45.02
2382.58 82.21 2092.97 79.30 1632. 89 35.32 1465. 86 64. 53 1389. 67 42. 54
1122.49 64.85 606.53 56.10

REF 4000 86.60 2000 80.34 600

3960.16 84.69 3772.70 76. 04 3440. 74 6.31 2966.7 7 52.44 2882.23 71.42
2623.58 86.22 2424.51 84. 47 2099. 25 78.9 5 1812.30 83.05 1634. 40 35.68
1392.11 44.16 1195.14 76. 80 1122. 73 64.7 1 605. 92 55.45

REF 4000 86.21 2000 81.84 600

3960.15 84.79 3774.28 76.92 3441. 07 6.31 2968.93 71.85 2382.26 84.07
2339.42 94.42 2086.71 80.32 1634. 48 35.73 1390. 22 47. 88 1195. 75 79. 21
1122.83 68.61 606.54 58.61

REF 4000 87.45 2000 71.02 600

3962.13 84.51 3777.70 72.93 3438. 87 11.47 2965. 03 7.17 2882.61 25.46
2409.78 73.71 2085.72 70.14 1763. 36 73.25 1628. 27 42. 24 1465. 26 54. 42
1387.28 35.79 1283.78 65.39 1120. 95 58.93 608.79 57.38

Table - 7.8
Observations of FTIR spectrums for Hexane + Heptane mixture:
*0.8(HX)
+
0.2(HP)
Cm-1

0.7(HX)
+
0.3(HP)
Cm-1

0.6(HX)
+
0.4(HP)
Cm-1

0.5(HX)
+
0.5(HP)
Cm-1

0.4(HX)
+
0.6(HP)
Cm-1

0.3(HX)
+
0.7(HP)
Cm-1

0.2(HX)
+
0.8(HP)
Cm-1

0.1(HX)
+
0.9(HP)
Cm-1

1(HP)

Cm-1

0.9(HX)
+
0.1(HP)
Cm-1

3443.19
2964.61
2376.18
2095.63
1639.14

3915.97
3764.62
3443.57
2959.60
2929.60

3762.32
3445.52
2960.28
2868.43
2372.32

3444.34
2958.69
2869.55
2372.30
2339.62

3762.46
3443.87
2959.73
2870.01
2373.95

3444.54
2963.34
2880.66
2734.67
2618.71

3764.86
3443.50
2963.43
2881.58
2736.02

3918.22
3772.95
3439.77
2966.44
2881.30

3960.16
3772.70
3440.74
2966.77
2882.23

3960.15
3774.28
3441.07
2968.93
2382.26

3962.13
3777.70
3438.87
2965.03
2882.61

1394.63
1237.74
1196.98
1120.23
656.26

2870.02
2373.48
2338.64
2090.58
1636.19

2338.30
2100.58
1636.55
1393.87
1196.25

2097.43
1638.32
1393.19
1197.13
1121.90

2338.41
2097.45
1637.32
1393.57
1197.33

2377.31
2339.15
2098.49
1638.05
1464.50

2607.90
2378.82
2338.53
2098.42
1636.90

2382.58
2092.97
1632.89
1465.86
1389.67

2623.58
2424.51
2099.25
1812.30
1634.40

2339.42
2086.71
1634.48
1390.22
1195.75

2409.78
2085.72
1763.36
1628.27
1465.26

607.16

1392.73
1196.69
1120.98
607.50

1120.44
607.48

656.61
606.86

1121.63
655.39
606.35

1390.37
1122.86
607.11

1464.69
1389.93
1122.81
604.99

1122.49
606.53

1392.11
1195.14
1122.73
605.92

1122.83
606.54

1387.28
1283.78
1120.95
608.79

1(HX)

* Maximum shift in the frequency has been observed.

285

Cm-1

Fig-7.8: FTIR spectrums for Benzaldehyde + Hexane mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/17/2009

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/17/2009

Spectrum Name: Hex+Bz-1.sp

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/17/2009

Spectrum Name: Hex+Bz-3.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/17/2009

Spectrum Name: Hex+Bz-2.sp

100.0

FT IR SPECT RUM
Date: 2/17/2009

Spectrum Name: Hex+Bz-4.sp

100.0

FT IR SPECT RUM
Date: 2/17/2009

Spectrum Name: Hex+Bz-5.sp

100.0

Spectrum Name: Hex+Bz-6.sp

100.0

100.0
1 071.69

1982.16

543.19

1826.42

1912.16

1072.33

1110.9 3

19 11.65

40
3392.00

273 8.48

1307.67

1168.30

826.40

3067.51
2 818.96

33 93.85

650.20

826.41

650.77

650.57

1306.83
33 95.06 3067.92

1167.49

545.50

449.83

1308.92
1166.99

2 817.92

1395.18
1453.28

3068.66

825.84
1288.65 1 168.37

2819.24

650.02

649.75

826.37

689.26

688.62

689 .51

344 3.70

1594.93

1594.88

1204.85

74 5.68

1594.67
1204.72

1204.30
74 6.62

30
1205.68

74 6.19

1018.48

2738.18

1454.3 1
27 37.62

3066.35

650.17
826.36

1112.88

1391.72
3391.42

1308.56

690.83

2 819.03

30
1204.57
1595.80

74 6.58

74 6.61

74 6.19

1596.17

2737.99

2 818.28

%T
826.51
1168.75

689.47

2818.41

690.41

1205.49
1596.15

80
450.36

1392.28
3066.90

50
1394.21
273 8.25

1308.161167 .94

929.03

2 547.97

101 4.44
450.27

1454.06
3391.13

60
1453.8 8

50
%T

2737.93
3067.04

1014.96
1071.85

450.49

13 92.47
1454.2 6

1393.10

1981.77

3754 .69

1915.13

1826.60

1912.00

450.64

1454.22

925.83

101 6.32

101 4.06
450.71

90
923.07

1910.37

2965.51

924.21

1912.95

101 4.39

1109.5 9

2370.07 1981.82

90
542.21

1982.01 1826.43
542.80

540.09
924.06

1 110.98

1111.87

1981.61 1825.80

2139.27

924.07

1110.62

90
2236.15

3856.08

2235.20

3856.01
1 981.96

1071.5 3

1072.42

182 6.68

1072.56

1702 .27
1702 .69

1702 .22

0.0

1702 .47

0.0

4000.0

3000

2000

1500

1000

400.0

0.0

4000.0

3000

2000

1500

cm -1

1000

400.0

0.0

4000.0

3000

2000

cm -1

Hex+Bz-1. pk

1702 .49

1500

1000

400.0

0.0

4000.0

3000

2000

cm -1

Hex+Bz-2. pk

1500

1000

400.0

0.0

4000.0

3000

2000

cm -1

Hex+Bz-3. pk

1700.71

1500

1000

400.0

4000.0

3000

cm -1

Hex+Bz-4. pk

2000

1500

1000

Hex+Bz-6. pk

HEB9CA~1.SP 3601 4000.00 400.00 8. 27 9 9.09 4. 00 %T 5 1.00

HEB9CE~1.SP 3601 4000. 00 400.00 7.80 99. 22 4.00 %T 5 1.00

HEB9C2~1.SP 3601 4000. 00 400.00 10.63 9 9.11 4. 00 %T 5 1.00

HEB9C6~1.SP 3601 4000. 00 400.00 8.40 99 .99 4.00 %T 5 1 .00

HEX_BZ~3.SP 3601 4000.00 400.00 9. 86 9 9.23 4. 00 %T 5 1.00

REF 4000 92.26 2000 86.34 600

3856.01 90.52 3393.85 46.16 3067. 04 49.51 2818. 41 44. 59 2737. 93 50. 23
2235.20 91.22 2139.27 91.10 1982. 16 84.60 1911. 65 85. 07 1826. 68 84. 36
1702.22 8. 26 1595. 80 30.55 1454. 26 56.32 1392.47 58.03 1308.16 48.46
1204.57 31.81 1167.94 47.43 1110. 93 73.85 1072. 33 73. 48 1014. 06 73. 77
924.06 81.9 8 826.41 46. 91 746.19 30.22 689. 47 42.35 650 .20 46.94
540.09 83.5 0 450.64 67. 08

REF 4000 94.76 2000 89.96 600

3856.08 93.11 3395.06 44.30 3067. 92 44.11 2819. 03 43. 29 2738. 25 50. 73
2236.15 93.76 1981.61 88.27 1912. 95 88.41 1825. 80 88. 41 1702. 47 7.80
1596.17 30.97 1453.88 58.70 1394. 21 59.03 1306. 83 46. 79 1205. 68 32. 37
1168.75 49.53 1111.87 76.53 1072. 42 78.97 1016. 32 80. 69 925.83 86.07
826.51 50.1 7 746.19 32. 07 690.83 43.67 650. 57 48.64 542 .80 87.24
450.49 73.7 4

REF 4000 95.66 2000 92.16 600

3391.13 67.02 3066.90 62.88 2818. 28 57.05 2737. 99 62. 32 1982. 01 90. 90
1912.00 91.23 1826.43 90.84 1702. 27 10.62 1594. 93 43. 47 1454. 06 68. 37
1392.28 70.62 1308.56 60.92 1204. 72 41.50 1167. 49 59. 39 1110. 62 84. 05
1071.85 83.55 1014.96 84.23 924.2 1 89.78 826. 36 57. 54 746.62 38.97
689.26 53.7 8 650.17 58. 34 542.21 92.08 450. 27 78.20

REF 4000 99.84 2000 96.16 600

3391.42 70.09 3066.35 68.63 2965. 51 80.07 2817. 92 59. 84 2737. 62 65. 08
2370.07 96.25 1981.82 94.85 1910. 37 95.27 1826. 60 94. 62 1702. 49 8.38
1594.67 43.21 1454.31 70.14 1391. 72 73.93 1308. 92 63. 85 1204. 30 40. 13
1166.99 60.60 1109.59 88.40 1071. 69 86.51 1014. 44 86. 78 923.07 94.67
826.37 57.0 9 746.61 35. 79 688.62 53.00 650. 02 58.28 450 .36 80.03

REF 4000 98.44 2000 96.33 600

3754.69 96.07 3443.70 51.89 3068. 66 64.84 2819. 24 66. 54 2738. 18 73. 27
2547.97 89.42 1981.77 95.56 1915. 13 95.57 1700. 71 9.86 1594.88 46.93
1453.28 70.88 1395.18 72.06 1288. 65 60.49 1204. 85 45. 69 1168. 37 64. 08
1112.88 81.67 1071.53 83.86 1018. 48 85.38 929.03 87.61 825. 84 63. 89
745.68 44.7 0 689.51 53. 31 649.75 57.20 545. 50 84.16 449 .83 80.18

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 3/11/2009

3753 .95
1110.58

100.0

1826.65
1981.74

2680.13

1 015.76

1595.35

2727.89
240 5.48

%T
826.12

1 452.54

3069.23
2 820.54

745.66
1287.48

744.29
1202.57

3750.51

651.38

1417.63

2819.86

74 6.32

60
545.52

1115.60

11 70.12

822.62

3069.14

%T
1204.30

825.44

141 3.91

3069.09

1021.49
930.58

27 37.52

2 819.11

543.49

452.01

2736.59
1452.10

928.86

2356.41

1594.92

3838 .59

70
2551.46
2933.15

931.57
1116.42

1118.74

2735.88

6 49.44
688.44

1 071.89

451.51
546.23

2684.53
449.71
1022.40

2556.97

1 167.12
826.57

1980.10
19 12.43

1021.16

2962 .26

1913.16

1309.49

343 8.06

2550.96

1070.57

450.32

1454.7 0
2737.96

2 818.22

100.0

375 4.42

1915.12

1071.97

1392.24
3068.23

100.0

1071.2 4

1980.04

1983.2 2

FT IR SPECT RUM
Date: 2/17/2009
Spectrum Name: Hex+Bz-11. sp

3755 .10

Spec trum Name: HEx+BZ-8. sp

923.97

FT IR SPECT RUM
Date: 2/17/2009
Spectrum Name: Hex+Bz-10. sp

10 0. 0

19 10.32

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/17/2009
Spectrum Name: Hex+Bz-9.sp

100.0

2407.99

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FT IR SPECT RUM
Date: 2/17/2009
Spectrum Name: Hex+Bz-7.sp

2928 .53

1405.56
6 51.10

705.14

1204.80

7 12.33

745.46

1288.79
1204.91

1117.52

1415.62

703.88

1702 .28

0.0
4000.0

1597.28

1287.45

3000

2000

1500

1000

cm -1

10
1698.70

0.0
4000.0

1692.51

20 00

1 50 0

1 0 00

HEx+BZ-8. pk
HE79C2~1.SP 3601 4000. 00 400. 00 7.90 99.24 4.00 %T 5 1.00
REF 4000 99.04 2000 95.92 600
3446. 29 16. 50 3069. 14 55. 81 2819. 86 59.46 2735.88 70.28 2680.13 76.05
2556. 97 78. 16 2356. 41 62. 48 1981. 74 94.70 1913.16 94.10 1826.65 97.63
1692. 51 7.89 1597.28 35. 66 1417.63 57.01 1287.45 35.28 1202.57 46.05
1118. 74 72. 97 1070. 57 74. 88 1022. 40 80.54 928.86 66.02 822. 62 67. 07
744.29 50. 57 699. 67 32.91 543. 49 68.21 449.71 79.49

4 00 .0

3443.99

0.0
3000

2000

1500

1000

400.0

4000.0

0.0
3000

cm -1
3 0 00

c m -1

REF 4000 93.35 2000 89.96 600

3753.95 90.84 3438.06 53.88 3068. 23 65.86 2818. 22 59. 98 2737. 96 64. 77
2407.99 91.88 1983.22 89.05 1910. 32 89.43 1702. 28 8.00 1594.92 40.22
1454.70 66.39 1392.24 69.28 1309. 49 60.83 1204. 30 38. 00 1167. 12 58. 73
1110.58 82.25 1071.97 80.98 1015. 76 81.09 923.97 89.16 826. 57 54. 58
746.32 34.2 5 688.44 49. 13 649.44 53.68 450. 32 74.01

1596.29

10
1698.35

0. 0
4 00 0 .0

HEC9CE~1.SP 3601 4000.00 400.00 8. 01 9 9.65 4. 00 %T 5 1.00

344 0.06

1628.07

10
3446.29

400.0

Hex+Bz-7. pk

699.67

615.48

1028.23

344 3.57

400.0

cm -1

Hex+Bz-5. pk

HEA9C6~1.SP 3601 4000. 00 400.00 7.90 99. 06 4.00 %T 5 2.00

REF 4000 95.76 2000 88.36 600
3392.00 42.17 3067.51 40.85 2818. 96 37.18 2738. 48 43. 57 1981. 96 86. 08
1912.16 86.53 1826.42 85.60 1702. 69 7.90 1596.15 26.12 1454.22 53.83
1393.10 54.44 1307.67 43.97 1205. 49 29.19 1168. 30 43. 76 1110. 98 74. 24
1072.56 74.83 1014.39 75.69 924.0 7 85.56 826. 40 44. 04 746.58 27.49
690.41 39.5 8 650.77 44. 09 543.19 87.96 450. 71 67.18

2000

1500

1000

400.0

4000.0

cm -1

3000

2000

1500

1000

400.0

cm -1

Hex+Bz-9. pk

Hex+Bz-10.pk

Hex+Bz-11.pk

HEX_BZ~1.SP 3601 4000.00 400.00 8. 31 9 8.25 4. 00 %T 5 1.00

HEX_BZ~2.SP 3601 4000.00 400.00 7. 88 9 9.67 4. 00 %T 5 1.00

HEX_BZ~4.SP 3601 4000.00 400.00 6. 33 9 8.66 4. 00 %T 5 1.00

REF 4000 90.78 2000 89.01 600

3755.10 88.09 3443.57 30.77 3069. 09 54.78 2962. 26 59. 31 2819. 11 58. 08
2736.59 66.55 2684.53 74.33 2550. 96 76.84 1980. 04 88. 13 1915. 12 87. 81
1698.35 8. 31 1595. 35 36.75 1452. 10 59.56 1413.91 57.65 1287.48 40.01
1204.80 41.72 1170.12 56.39 1116. 42 70.19 1071. 24 72. 84 1021. 16 75. 88
931.57 70.8 2 825.44 60. 24 745.66 44.11 705. 14 42.12 651 .38 52.70
546.23 72.5 2 451.51 76. 03

REF 4000 98.87 2000 87.61 600

3754.42 95.11 3440.06 26.34 3069. 23 47.77 2933. 15 50. 32 2820. 54 51. 75
2737.52 60.98 2551.46 75.65 1980. 10 86.42 1912. 43 85. 77 1698. 70 7.88
1596.29 27.95 1452.54 49.41 1405. 56 47.92 1288. 79 34. 21 1204. 91 33. 58
1115.60 58.28 1071.89 61.92 1021. 49 63.09 930.58 63.50 826. 12 49. 99
745.46 35.2 1 703.88 35. 16 651.10 43.54 545. 52 66.27 452 .01 70.72

REF 4000 73.80 2000 56.81 600

3838.59 68.32 3750.51 65.74 3443. 99 6.33 2928.53 47.34 2727.89 65.85
2405.48 63.83 1628.07 19.08 1415. 62 34.75 1117. 52 36. 84 1028. 23 37. 71
712.33 39.7 2 615.48 38. 51

Table - 7.9
Observations of FTIR spectrums for Benzaldehyde + Hexane mixture:
1(BD)

Cm-1
3872.55
3752.13
3392.00
3067.51
2818.96
2738.48
1981.96
1912.16
1826.42
1702.69
1596.15
1454.22
1393.10
1307.67
1205.49
1168.30
1110.98
1072.56
1014.39
924.07
826.40
746.58
690.41
650.77
543.19
450.71

0.9(BD)
+
0.1(HX)
Cm-1

0.8(BD)
+
0.2(HX)
Cm-1

0.7(BD)
+
0.3(HX)
Cm-1

0.6(BD)
+
0.4(HX)
Cm-1

0.5(BD)
+
0.5(HX)
Cm-1

*0.4(BD)
+
0.6(HX)
Cm-1

0.3(BD)
+
0.7(HX)
Cm-1

0.2(BD)
+
0.8(HX)
Cm-1

0.1(BD)
+
0.9(HX)
Cm-1

1(HX)

3856.01
3393.85
3067.04
2818.41
2737.93
2235.20
2139.27
1982.16
1911.65
1826.68
1702.22
1595.80
1454.26
1392.47
1308.16
1204.57
1167.94
1110.93
1072.33
1014.06
924.06
826.41
746.19
689.47
650.20
540.09
450.64

3856.08
3395.06
3067.92
2819.03
2738.25
2236.15
1981.61
1912.95
1825.80
1702.47
1596.17
1453.88
1394.21
1306.83
1205.68
1168.75
1111.87
1072.42
1016.32
925.83
826.51
746.19
690.83
650.57
542.80
450.49

3391.13
3066.90
2818.28
2737.99
1982.01
1912.00
1826.43
1702.27
1594.93
1454.06
1392.28
1308.56
1204.72
1167.49
1110.62
1071.85
1014.96
924.21
826.36
746.62
689.26
650.17
542.21
450.27

3391.42
3066.35
2965.51
2817.92
2737.62
2370.07
1981.82
1910.37
1826.60
1702.49
1594.67
1454.31
1391.72
1308.92
1204.30
1166.99
1109.59
1071.69
1014.44
923.07
826.37
746.61
688.62
650.02
450.36

3754.69
3443.70
3068.66
2819.24
2738.18
2547.97
1981.77
1915.13
1700.71
1594.88
1453.28
1395.18
1288.65
1204.85
1168.37
1112.88
1071.53
1018.48
929.03
825.84
745.68
689.51
649.75
545.50
449.83

3753.95
3438.06
3068.23
2818.22
2737.96
2407.99
1983.22
1910.32
1702.28
1594.92
1454.70
1392.24
1309.49
1204.30
1167.12

3446.29
3069.14
2819.86
2735.88
2680.13
2556.97
2356.41
1981.74
1913.16
1826.65
1692.51
1597.28
1417.63
1287.45
1202.57
1118.74
1070.57
1022.40
928.86
822.62
744.29
699.67
543.49
449.71

3755.10
3443.57
3069.09
2962.26
2819.11
2736.59
2684.53
2550.96
1980.04
1915.12
1698.35
1595.35
1452.10
1413.91
1287.48
1204.80
1170.12
1116.42
1071.24
1021.16
931.57
825.44
745.66
705.14
651.38
546.23
451.51

3754.42
3440.06
3069.23
2933.15
2820.54
2737.52
2551.46
1980.10
1912.43
1698.70
1596.29
1452.54
1405.56
1288.79
1204.91
1115.60
1071.89
1021.49
930.58
826.12
745.46
703.88
651.10
545.52
452.01

3838.59
3750.51
3443.99
2928.53
2727.89
2405.48
1628.07
1415.62
1117.52
1028.23
712.33
615.48

1110.58
1071.97
1015.76
923.97
826.57
746.32
688.44
649.44
450.32

* Maximum shift in the frequency has been observed.

286

Cm-1

Fig-7.9: FTIR spectrums for Hexane + 2-Butanone mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/24/2009

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 3-0.7.sp

100.0

3856.29

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 4-0.6.sp

Spectrum Name: RK H 0. 5-0.5.sp

100.0

3921.91

90
2626.86

442.73

3770.76

2363.97

943.46

2112.50

2097.85

3767.49
1110.29

1404.06

866.86

2498.58

2367.63

80
3773.7 9

2366.47

1107.70

20 78.06

2100.44

751.14

3952.3 1
210 4.86

1 422.03

1110.60

3771.15

1410.72

20 87.02

1170 .28

1171 .54

179 0.00

1735.79

2363.47

1 366.54

1 368.01

606.37

2382.32

941.67

1088.5 8

2369.27

2725.15

3755 .04

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 2-0.8.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 1-0.9.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0- 1.sp

665.02

1425.35

2860.10

2982 .89

5 89.29

623.44

5 89.32

600.71

2974.55

573.84

2927 .98

1736.49

1 113.20

1 636.90

1407.50

1172 .15

1636.89

1 633.52

1637.25

1636.57

1 365.79

2983 .14

1736.88

1626.68

343 7.82

0.0

4000.0

3451.21

0.0
3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

4000.0

3457.44

3442.39

0.0

4000.0

cm -1

3450.96

0.0
3000

2000

cm -1

1500

1000

400.0

344 7.85

0.0

4000.0

3000

2000

cm -1

1500

1000

400.0

0.0

4000.0

3000

2000

cm -1

1500

1000

400.0

4000.0

3000

cm -1

2000

1500

1000

RK H 0.1-0.9 .pk

RK H 0.2-0.8 .pk

RK H 0.3-0.7 .pk

RK H 0.4-0.6 .pk

RK H 0.5-0.5 .pk

RKH0-1~1. SP 3601 4000.00 4 00. 00 6.36 98.75 4.00 %T 5 1.00

RKH01-~1. SP 3601 4000.00 4 00. 00 6.32 100.00 4.00 %T 5 1.00

RKH02-~1. SP 3601 4000.00 4 00. 00 6.32 100.00 4.00 %T 5 1.00

RKH03-~1. SP 3601 4000.00 4 00. 00 6.33 100.00 4.00 %T 5 1.00

RKH04-~1. SP 3601 4000.00 4 00. 00 6.32 99.99 4.00 %T 5 1.00

RKH05-~1. SP 3601 4000.00 4 00. 00 6.32 99.44 4.00 %T 5 1.00

REF 4000 93.53 2000 75.30 600

3856.29 85.07 3755.04 78.56 3437. 82 6.36 2927.98 56.76 2860.10 66.08
2725.15 76.93 2626.86 79.50 2498. 58 78.86 2382. 32 75. 27 2100. 44 74. 69
1790.00 73.57 1626.68 21.69 1407. 50 44.85 1113. 20 52. 09 866.86 83.19
623.44 61.6 3 573.84 61. 51 442.73 79.42

REF 4000 99.09 2000 93.09 600

3770.76 91.69 3451.21 6.32 2983. 14 40.57 2369.2 7 91.86 2112.50 90.25
1736.88 24.28 1636.90 46. 89 1425. 35 66.7 5 1365.79 45.92 1172. 15 46.79
1088.58 90.14 943. 46 84.94 751.14 74.13 589.29 65.55

REF 4000 93.55 2000 90.44 600

3442.39 6. 32 2363.97 87.57 2078. 06 89.30 1636.5 7 41.37 1404.06 84.39
1110.29 89.82 665. 02 69.99

REF 4000 91.30 2000 88.85 600

3921.91 89.99 3773.79 85. 99 3457. 44 6.33 2367.6 3 88.22 2087.02 87.88
1636.89 42.85 1410.72 83. 80 1107. 70 85.9 0 606. 37 72.27

REF 4000 99.23 2000 94.43 600

3767.49 92.66 3450.96 6. 32 2982. 89 70.14 2366.47 91.58 2097.85 92.68
1736.49 56.17 1637.25 43.59 1422. 03 85.54 1366. 54 75. 09 1171. 54 76. 45
941.67 96.6 2 589.32 69. 79

REF 4000 98.33 2000 88.98 600

3952.31 96.07 3771.15 84.78 3447. 85 6.32 2974.55 65.76 2363.47 76.63
2104.86 86.82 1735.79 77.32 1633. 52 46.02 1368. 01 77. 12 1170. 28 81. 14
1110.60 86.26 600.71 70.39

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 8-0.2.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 7-0.3.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 6-0.4.sp

FT IR SPECT RUM
Date: 1/27/2009

Spectrum Name: RK H 0. 9-0.1.sp

100.0

400.0

cm -1

RK H 0-1.pk

Spectrum Name: RK H 1- 0.sp

100.0

1259.45
391 9.93
3907.24

942.63
3769.68

90
3775.65

2368.73

2361.63

2098.86

1087.65

3957 .00

3963.75

2100.69

3776.6 1

2364.40

211 5.17

2363.58

3774.8 9

943.56
1171 .35

1167.09

1170 .47

1115.82

3775.59

588.55

753.72

2364.48

1 367.97

1 380.34
1736.42
5 91.28

1382.96

20 97.24

5 93.01

61 4.13

1465.81

%T
40

1465.35

1466.16
1 634.05

50
%T
1636.57

13 76.54

5 88.95
1422.14

1737.27

50
%T
40

2087.18

1461.93

%T
40

1636.45

%T
40

1 634.47

2965.81

1 633.55
1 365.82

2882.41

1172 .40

2981 .15

30
2882.43

2882 .80

1735.24
2964.12

3452.92

345 5.17

0.0

3000

2000

1500

1000

400.0

4000.0

0.0
3000

2000

cm -1

1500

1000

400.0

4000.0

cm -1

10
345 0.00

2965.63

0.0

3451.42

4000.0

2963.80

0.0
3000

2000

1500

1000

400.0

4000.0

0.0
3000

2000

cm -1

1500

1000

400.0

344 9.68

4000.0

cm -1

3000

2000

1500

1000

400.0

cm -1

RK H 0.6-0.4 .pk

RK H 0.7-0.3 .pk

RK H 0.8-0.2 .pk

RK H 0.9-0.1 .pk

RK H 1-0.pk

RKH06-~1. SP 3601 4000.00 4 00. 00 6.33 100.00 4.00 %T 5 1.00

RKH07-~1. SP 3601 4000.00 4 00. 00 6.32 100.00 4.00 %T 5 1.00

RKH08-~1. SP 3601 4000.00 4 00. 00 7.34 99.99 4.00 %T 5 1.00

RKH09-~1. SP 3601 4000.00 4 00. 00 6.32 99.99 4.00 %T 5 1.00

RKH1-0~1. SP 3601 4000.00 4 00. 00 6.32 99.99 4.00 %T 5 1.00

REF 4000 99.10 2000 93.66 600

3907.24 98.01 3769.68 92. 18 3451. 42 6.33 2965.8 1 44.27 2368.73 91.95
2098.86 91.94 1737.27 60. 36 1636. 57 46.8 3 1461.93 83.87 1367. 97 75.33
1171.35 77.58 942. 63 97.16 591.28 68.27

REF 4000 99.29 2000 94.17 600

3775.65 93.36 3455.17 6.32 2981. 15 34.35 2361.6 3 90.81 2115.17 91.16
1735.24 21.06 1636.45 44. 74 1422. 14 60.1 4 1365.82 39.63 1259. 45 91.23
1172.40 41.11 1087.65 89. 22 943.56 80.00 753.72 74.54 588.95 65.65

REF 4000 98.88 2000 94.62 600

3957.00 97.52 3776.61 91.03 3452. 92 15.60 2965. 63 7.34 2882.80 29.34
2364.40 91.63 2100.69 93.43 1736. 42 68.63 1634. 05 59. 54 1466. 16 65. 99
1376.54 70.47 1170.47 80.05 588.5 5 77.06

REF 4000 98.28 2000 89.89 600

3963.75 96.94 3774.89 87.55 3450. 00 6.32 2963.80 8.78 2882.43 30. 01
2363.58 88.32 2087.18 88.17 1634. 47 45.21 1465. 35 65. 82 1380. 34 73. 29
1167.09 87.27 593.01 64.46

REF 4000 92.19 2000 80.27 600

3919.93 90.20 3775.59 79.25 3449. 68 6.32 2964.12 19.48 2882.41 41.18
2364.48 76.31 2097.24 78.71 1633. 55 44.51 1465. 81 70. 76 1382. 96 72. 85
1115.82 81.05 614.13 65.14

Table - 7.10
Observations of FTIR spectrums for Hexane + 2-Butanone mixture:
1(HX)
0.9(HX)
+
0.1(2B)
Cm-1

0.8(HX)
+
0.2(2B)
Cm-1

0.7(HX)
+
0.3(2B)
Cm-1

0.6(HX)
+
0.4(2B)
Cm-1

0.5(HX)
+
0.5(2B)
Cm-1

0.4(HX)
+
0.6(2B)
Cm-1

Cm-1
3856.29
3755.04
3437.82
2927.98
2860.10
2725.15
2626.86
2498.58
2382.32
2100.44
1790.00
1626.68
1407.50
1113.20
866.86
623.44
573.84
442.73

3770.76
3451.21
2983.14
2369.27
2112.50
1736.88
1636.90
1425.35
1365.79
1172.15
1088.58
943.46
751.14
589.29

3442.39
2363.97
2078.06
1636.57
1404.06
1110.29
665.02

3921.91
3773.79
3457.44
2367.63
2087.02
1636.89
1410.72
1107.70
606.37

3767.49
3450.96
2982.89
2366.47
2097.85
1736.49
1637.25
1422.03
1366.54
1171.54
941.67
589.32

3952.31
3771.15
3447.85
2974.55
2363.47
2104.86
1735.79
1633.52
1368.01
1170.28
1110.60
600.71

3907.24
3769.68
3451.42
2965.81
2368.73
2098.86
1737.27
1636.57
1461.93
1367.97
1171.35
942.63
591.28

* Maximum shift in the frequency has been observed.

287

1(2B)

*0.3(HX)
+
0.7(2B)
Cm-1

0.2(HX)
+
0.8(2B)
Cm-1

3775.65
3455.17
2981.15
2361.63
2115.17
1735.24
1636.45
1422.14
1365.82
1259.45
1172.40
1087.65
943.56
753.72
588.95

3957.00
3776.61
3452.92
2965.63
2882.80
2364.40
2100.69
1736.42
1634.05
1466.16
1376.54
1170.47
588.55

0.1(HX)
+
0.9(2B)
Cm-1
Cm-1
3963.75
3774.89
3450.00
2963.80
2882.43
2363.58
2087.18
1634.47
1465.35
1380.34
1167.09
593.01

3919.93
3775.59
3449.68
2964.12
2882.41
2364.48
2097.24
1633.55
1465.81
1382.96
1115.82
614.13

Fig-7.10: FTIR spectrums for Hexane + Ethyl Acetate mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2
ACIC
St. Joseph's College ( Autonomous )
Trichy-2

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FT IR SPECT RUM
Date: 2/18/2009
Spectrum Name: EA+Hex-6.sp

FTIR SPECTRUM
Date: 2/18/2009

Spec trum Name: EA+Hex-1.sp

FTIR SPECTRUM
Date: 2/18/2009

Spec trum Name: EA+Hex-2.sp

10 0. 0

FTIR SPECTRUM
Date: 2/18/2009

Spec trum Name: EA+Hex-3.sp

10 0. 0

FTIR SPECTRUM
Date: 2/18/2009

Spec trum Name: EA+Hex-4.sp

10 0. 0

100.0
3855.32

Spec trum Name: EA+Hex-5.sp

3768.40

2093.17

80
3917.93

3964.09
2091.73
2365.35

3905.70

2493.14

930.11

2088.86

3772.12

2384.79

3770.59

929.20

607.99
2379.02
2092.59

3772.03

3769.87

2931.38

1753.54
1379.58

1050.10

2988.62

2990.04

1378.06

1377.68
1055.31

2928.11

558.53

50
1243.52

%T
40
1760.91
1636.38

1628.57

1049 .37

1371.21

1636.66

1634.83
1634.91

2960.84

557.41

1629.98
1762.09

1762.57

533.17

50
%T
1049.25

2928.17

1054.23

50
1055.03

60
1242.46
1381.22

547.94

617.11
1378.55

2859.60

1111.63

2859.61
616.31
2929.67
2990.08

1110.54

2087.94

3774.67

2098.42

931.21

2378.76

10 0. 0

3972.80

1242.66

30
1243.04

1 741.82

1241.77

3448.96

1242.99

0. 0
4 00 0 .0

3 0 00

20 00

1 50 0

1 0 00

4 00 .0

4 00 0 .0

3450.82

3449.73

0. 0

3449.31

0. 0
3 0 00

20 00

1 50 0

c m -1

1 0 00

4 00 .0

4 00 0 .0

3 0 00

20 00

c m -1

1 50 0

1 0 00

4 00 .0

4 00 0 .0

0.0
4000.0

3448.68

3448.93

0. 0

3 0 00

20 00

1 50 0

c m -1

1 0 00

4 00 .0

3 0 00

20 00

1 50 0

1 0 00

4 00 .0

EA+Hex-3.pk

EA+Hex-4.pk

EA+Hex-5.pk

EA31CE~1. SP 3601 4000.00 400.00 6.32 99. 74 4.00 %T 5 1.00

EA31C2~1.SP 3601 4000. 00 400. 00 6.32 100.00 4. 00 %T 5 1. 00

EA_HEX~4.SP 3601 4000.00 400.00 6. 34 99. 37 4.00 %T 5 1.00

EA_HEX~3.SP 3601 4000.00 400.00 6. 32 99. 58 4.00 %T 5 1.00

EA_HEX~2.SP 3601 4000.00 400.00 6. 33 100.00 4.00 %T 5 1.00

REF 4000 98.67 2000 92.84 600

3964. 09 97. 24 3772. 12 85. 75 3449. 31 6.32 2990.08 60.70 2929.67 61.59
2365. 35 87. 76 2091. 73 90. 07 1762. 09 38.27 1629.98 42.76 1378.55 59.41
1242. 99 19. 75 1055. 03 53. 73 930.11 96.52 616. 31 66. 89

REF 4000 90.10 2000 82.09 600

3917. 93 87. 95 3772.03 75.37 3449.73 6.32 2928. 11 60. 34 2859.61 70.81
2098. 42 80. 11 1753.54 71.73 1628.57 40.24 1379. 58 66.33 1243.52 54.28
1111. 63 69. 40 1050.10 65.81 558.53 59.86

REF 4000 93.46 2000 89.84 600

3770. 59 84. 10 3450. 82 6.34 2988.62 65.19 2493.14 92.57 2384.79 92.61
2088. 86 87. 78 1760. 91 43. 61 1636. 38 42.22 1378.06 64.36 1243.04 26.35
1054. 23 58. 75 929.20 92. 46 617. 11 61.12

REF 4000 93.21 2000 89.78 600

3972. 80 91. 82 3774. 67 85. 42 3448. 93 6.32 2990.04 70.32 2931.38 71.65
2087. 94 87. 89 1762. 57 53. 80 1634. 83 42.26 1377.68 67.09 1242.66 37.01
1055. 31 65. 42 547.94 64. 74

REF 4000 84.37 2000 81.95 600

3905. 70 82. 45 3769.87 73.71 3448.68 6.33 2928. 17 62. 66 2859.60 72.71
2379. 02 81. 84 2092.59 80.92 1634.91 39.67 1381. 22 68.07 1242.46 68.75
1110. 54 69. 20 1049.25 68.98 557.41 62.66

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

ACIC
St.Joseph' s College ( Autono mous )
Trichy-2

FTIR SPECTRUM
Date: 2/18/2009
100. 0

3906.07

Spec trum Name: EA+Hex-11.sp

10 0. 0

90
3964.69

3964.48

3964.05

3964.24

3770.91
2491.89

930.32

3773.07

2091.99

60
60

1116.49

2091.46

60
50
608.91

609.33

1410.74

2405.75

1115.31

2110.78

%T
1378.57

1410.61

1757.54

619.94

2109.27

3772.97

3772.43

50
%T

3772.57

2928.27

1245.29

615.47

621.67

1627.25

40
2929.40

1056.01

2932.51

2964.89

1763.72

1117.56

1627.09

2119.44

1408.65

30
1377.93

FTIR SPECTRUM
Date: 2/18/2009

Spec trum Name: EA+Hex-10.sp

10 0. 0

Sp ectrum Name: EA+Hex-9.sp

1 00. 0

400.0

REF 4000 98.40 2000 91.37 600

3855.32 96.93 3768.40 91.09 3448. 96 6.32 2960.84 53.32 2378.76 92.67
2093.17 89.21 1741.82 27.67 1636. 66 37.95 1371. 21 44. 99 1241. 77 24. 20
1049.37 53.91 931.21 96.86 607.99 71. 80 533.17 68.16

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 2/18/2009

FTIR S PECTRUM
Date: 2/18 /2 009
Spectrum Name: EA+Hex-8 .s p

1000

EA_HEX~1. SP 3601 4000.00 400. 00 6.32 99.36 4.00 %T 5 1.00

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 2/18/2009

1500

EA+Hex-6.pk

c m -1

EA+Hex-2.pk

Spec trum Name: EA+Hex-7.sp

2000
cm -1

4 00 0 .0

c m -1

EA+Hex-1.pk

10 0. 0

3000

0. 0

1055.57

1625.96

1627.46

2928.11
1619.21

1763.23

10
3448.84

1242.87

3446.90

0. 0
4 00 0 .0

3448.43

1242.94

3 0 00

20 00

1 50 0

1 0 00

c m -1

4 00 .0

40 00. 0

3000

20 00

15 00

3437.12

0. 0

0. 0
1 000

4 00. 0

cm-1

0. 0

3447.13

4000.0

4 00 0 .0
3000

2000

1500

1000

cm-1

EA+Hex-7.pk

EA+Hex -8.pk

EA41C6~1.SP 3601 4000. 00 400. 00 7.59 99.33 4.00 %T 5 1.00

EA51CA~1.SP 360 1 40 00. 00 40 0.00 6.93 100.00 4.00 %T 5 1.00

REF 4000 98.10 2000 78.25 600

3906. 07 96. 10 3770. 91 83. 08 3448. 84 7.59 2964.89 26.03 2491.89 78.46
2091. 99 75. 63 1763. 72 21. 24 1627. 25 39.37 1378.57 42.71 1242.87 8.65
1056. 01 36. 36 930.32 79. 15 619. 94 57.13

REF 4 000 97.12 2000 48.79 600

39 64.69 94.69 3773.07 81.25 3446.90 6.93 2932.51 35.60 2405.75 51.64
20 91.46 47.39 1763.23 17.31 1627.46 25.19 1377.93 31.18 1242.94 8.11
10 55.57 28.88 621.67 47 .0 0

0. 0

EA+Hex-9.pk
EA51CE~1.SP 3601 4000.00 400.0 0 6.34 100.00 4.00 %T 5 1.00
REF 4000 84.74 2000 61.21 600
3964.05 83.34 3772.43 70.77 3447.13 6.34 2929.40 43.90 2110.78 59.07
1757.54 65.65 1625.96 32.05 1410.74 56.65 1245.29 58.90 1116.49 59.46
609.33 58.59

3 0 00

20 00

1 50 0

1 0 00

4 00 .0

4 00 0 .0

3 0 00

20 00

c m -1

400.0

1 50 0

1 0 00

4 00 .0

c m -1

EA+Hex-10.pk

EA+Hex-11.pk

EA0607~1. SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00

EA0E07~1.SP 3601 4000.00 400.00 6. 35 99.99 4.00 %T 5 1.00

REF 4000 76.42 2000 65.23 600

3964. 48 74. 66 3772.97 63.95 3448.43 6.33 2928. 27 47. 96 2109.27 63.46
1627. 09 35. 23 1410.61 58.11 1115.31 58.29 608.91 53. 13

REF 4000 75.79 2000 35.78 600

3964. 24 73. 75 3772. 57 57. 82 3437. 12 6.35 2928.11 25.90 2119.44 34.17
1619. 21 21. 51 1408. 65 36. 29 1117. 56 37.55 615.47 44.68

Table - 7.11
Observations of FTIR spectrums for Hexane + Ethyl Acetate mixture:
*0.8(EA)

1 (EA)

0.9(EA)
+

Cm-1

0.1(HX)
Cm-1

0.2(HX)
Cm-1

0.3(HX)
Cm-1

0.4(HX)
Cm-1

0.5(HX)
Cm-1

0.6(HX)
Cm-1

3917.93
3772.03
3449.73
2928.11
2859.61
2098.42
1753.54
1628.57
1379.58
1243.52
1111.63
1050.10
558.53

3770.59
3450.82
2988.62
2493.14
2384.79
2088.86
1760.91
1636.38
1378.06
1243.04
1054.23
929.20
617.11

3972.80
3774.67
3448.93
2990.04
2931.38
2087.94
1762.57
1634.83
1377.68
1242.66
1055.31
547.94

3905.70
3769.87
3448.68
2928.17
2859.60
2379.02
2092.59
1634.91
1381.22
1242.46
1110.54
1049.25
557.41

3855.32
3768.40
3448.96
2960.84
2378.76
2093.17
1741.82
1636.66
1371.21
1241.77
1049.37
931.21
607.99
533.17

3906.07
3770.91
3448.84
2964.89
2491.89
2091.99
1763.72
1627.25
1378.57
1242.87
1056.01
930.32
619.94

3964.09
3772.12
3449.31
2990.08
2929.67
2365.35
2091.73
1762.09
1629.98
1378.55
1242.99
1055.03
930.11
616.31

0.7(EA)

0.6(EA)

0.5(EA)

0.4(EA)

* Maximum shift in the frequency has been observed.

288

0.3(EA)

0.1(EA)

0.2(EA)
+

0.7(HX)
Cm-1

0.8(HX)
Cm-1

0.9(HX)
Cm-1

3964.69
3773.07
3446.90
2932.51
2405.75
2091.46
1763.23
1627.46
1377.93
1242.94
1055.57
621.67

3964.05
3772.43
3447.13
2929.40
2110.78
1757.54
1625.96
1410.74
1245.29
1116.49
609.33

3964.48
3772.97
3448.43
2928.27
2109.27
1627.09
1410.61
1115.31
608.91

1(HX)

+
Cm-1
3964.24
3772.57
3437.12
2928.11
2119.44

Fig-7.11: FTIR spectrums for Heptane + Benzaldehyde mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-J-1.sp

100.0

3927.66

1 072.46

2031.43

38 95.66

3914.34

3781.71

454.31

3924.16

922.50

1909.07
1 072.05

543 .53

1982.09

1014.99

1111.62

1826.00

1013.85

1109.11
101 4.23

450.80
1072.24

450.90

651.75

101 3.14

450.87

774.31

450.65

708.76
1459.80

922.80

377 9.77
1910.5 2

80
1911.9 4

1282.06

1467.24

50
%T

233 3.38
1982.26 1823.92

23 29.95

923.73

541 .80
1981.59
549.5 4
824.80

1205.65

1072.08

2140.56
37 81.38

1825.07
1981.75

1 825.66

1019.2 4

608.97

2331.49

3781.23

923.64

2738.34

2722.97

Spectrum Name: SJC-PH-JO-6. sp

100.0

1110.91

1912.36
3781.88

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-PH-JO-5. sp

100.0

1072.53

930.62
1 116.35

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-PH-JO-4. sp

100.0

90
2542.27

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-PH-JO-3. sp

100.0

90
379 4.95

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-PH-JO-2. sp

100.0

2737.72

3 069.41

1455.10 1309.26

11 67.12

2818.14
13 87.80

296 5.22

2879.83

1455.72 1307.72

27 38.28

13 84.69

1308.11

826.22

11 68.51

1455.67

2738.20

40
1167.87

3067.63

68 9.77

650.63

1387.49
3069.26

1204.69

745.68

1596.03

2874.8 1

296 4.19

745.96

650.63

30
3440.24

688.95

3394.87

1596.46

2876.2 3

3 451.06

825.69

1167.30

1388.72

2864.03
2818.61

68 9.26

2819.58

1204.70

2882.2 9

20
2964.92

650.24

2738.01
68 8.57

1387.56

1696.28
3444.07

826.26

1455.19 1307.95

825.81

650.69
3 068.53

1204.08

1595.40

1203.86
746.35

1595.69

1 362.51

746.33
3443.35

1596.87

3446.47

296 3.39

0.0

4000.0

3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

4000.0

3000

2000

1000

400.0

0.0

4000.0

3000

2000

1500

cm-1

SJC-PH-JO-2.pk

17 01.59

0.0
1500

cm-1

SJC-J-1.pk

17 01.53

1701.59

0.0

4000.0

cm-1

296 4.49

296 3.39

0.0

1000

400.0

SJC-PH-JO-3.pk

17 02.19

0.0

4000.0

3000

2000

1500

cm-1

1000

400.0

4000.0

3000

cm-1

SJC-PH-JO-4.pk

2000

1500

1000

SJC-PH-JO-5.pk

SJC-PH-JO-6.pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00

SJC-PH~1. SP 3601 4000. 00 400. 00 7.89 99. 69 4.00 %T 5 1. 00

SJC-PH~4. SP 3601 4000. 00 400. 00 6.66 99. 78 4.00 %T 5 2. 00

SJ66F3~1. SP 3601 4000.00 400.00 5.99 99.99 4.00 %T 5 2.0 0

SJ6EF3~1.SP 3601 4000.00 400 .00 7.66 100.00 4. 00 %T 5 2.00

SJ6604~1.SP 3601 4000. 00 400.00 6.53 99.91 4.00 %T 5 2. 00

REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

REF 4 000 95.81 2000 94.48 600

3927.66 92.70 3781.71 88.30 3446.47 14.16 2963.39 7.88 2882.29 27.54
2738.34 85.29 2542.27 92.66 2031.43 94.02 1696.28 28. 71 1459.80 54. 91
1384.69 44.14 1282.06 65.12 1205.65 70.99 1116.35 87. 42 1072.46 88. 02
1019.24 88.74 930.62 92 .20 824.80 78.44 708.76 57.49 651.75 65.22
549. 54 78 .72 454.31 85.15

REF 4 000 98.92 2000 91.26 600

3895.66 96.56 3781.88 91.06 3451.06 23.89 3068.53 39. 90 2963.39 12. 54
2876.23 27.95 2738.28 45.53 1981.59 88.94 1912.36 90. 03 1825.66 91. 62
1701.59 6. 65 1596.46 27 .37 1455.72 46.37 1387.56 42.62 1307.72 46.29
1204.70 29.38 1168.51 44.99 1111.62 77.55 1072.53 77. 66 1014.23 78. 65
923. 64 89 .35 826.22 44.29 745.68 25.4 7 689.77 36.06 650.69 40. 26
541. 80 83 .49 450.90 65.50

REF 4 000 98.89 2000 90.36 600

3914.34 96.44 3781.23 91.67 3443.35 18.38 3069.26 37. 08 2964.49 12. 67
2874.81 27.62 2819.58 35.28 2738.20 42.07 2331.49 91. 44 1981.75 87. 57
1911.94 89.04 1825.07 89.52 1701.53 5.98 1596.03 25.01 1455.67 43.91
1387.49 39.39 1308.11 46.00 1204.69 28.52 1167.87 44. 55 1110.91 75. 59
1072.24 75.31 1014.99 76.25 923.73 88.34 825.81 42.13 745 .96 23.78
689. 26 34 .03 650.63 37.30 543.53 78.9 4 450.87 60.93

REF 4 000 98.97 2000 89.20 600

3781.38 93.86 3394.87 3 0.73 3067.63 43.84 2964. 19 26.73 2864.03 39. 01
2818.61 35.71 2738.01 4 0.99 2329.95 92.09 2140. 56 96.58 1982.09 86. 01
1910.52 87.83 1826.00 8 7.49 1701.59 7. 65 1595.69 25.07 1455.19 46.98
1388.72 44.85 1307.95 4 5.65 1204.08 28.15 1167. 30 41.01 1109.11 78. 71
1072.08 73.55 1013.14 7 2.81 922. 50 86.91 825.69 38. 57 746.33 22.63
688. 95 33 .75 650.63 37. 32 450.65 59.52

REF 4 000 98.75 2000 93.82 600

3924.16 96.21 3779.77 90.67 3440.24 33.34 3069.41 60. 40 2965.22 47. 23
2818.14 52.16 2737.72 57.94 2333.38 95.41 1982.26 92. 30 1909.07 93. 65
1823.92 93.85 1702.19 6. 53 1595.40 32.39 1455.10 58.52 1387.80 54.56
1309.26 57.85 1203.86 33.23 1167.12 53.27 1072.05 81. 73 1013.85 81. 71
922. 80 93 .52 826.26 48.04 746.35 27.0 0 688.57 41.50 650.24 46. 69
450. 80 70 .90

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 13- 2-2010

2140.49

3783.77

922.10

2332.01

1910.0 5

921.71

2332.65

3779.18

1981.60 1825.07

1 071.86

1909.34

1982.62

1910.63

1 072.25

1910.16

1 072.24
1011.34

922.12
37 80.86

2964.71

1911.07

1982.44 1826.49

921.88

1982.50 1826.64

2965.78

FT IR SPECT RUM
Date: 13- 2-2010
100.0

2329.54

2965.54
3779.85

922.12

Spectrum Name: SJC-PH-JO-11.sp

100.0

2328.98

2329.14
1982.75 1827.05

Spectrum Name: SJC-PH-JO-10.sp

100.0

100.0
2140.52
3782.72

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-PH-JO-9. sp

Spectrum Name: SJC-PH-JO-8. sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 13- 2-2010

Spectrum Name: SJC-PH-JO-7. sp

1 071.87

1012.18

1 825.75

4 50.84

1 072.35

1011.51

101 1.85

1012.36
450.91

400.0

cm-1

450.67

450.64

3067.58

1454.62

451.05

1454.22
2737.69

1389.89

50
3067.16

1454.75

1389.65

2 738.03

1308.39

1166.93

2818.09

40
650.66

825.89

1309.18

1167.33

826.54

650.78

1167.84

650.56

688.99

688.51

1203.73
746.67

1595.88

1204.23

1203.54

746.81

1308.82
2818.16

40
826.32

1595.35

1595.47

746.69

1389.83

2738.01
3393.17

2817.83

1203.47

1203.75
1596.21

3067.61

13 88.46

2737.63

68 8.53

3456.88

68 8.77
688.84

3068.39

%T
650.36

826.01

2818.27
3395.10

1454.6 2

1308.78 116 6.70

2817.82

3393.20

650.87

826.17

13 88.71

1308.31

2737.97
116 7.62

3067.20

1454.70

746.72

1596.45
746.63
3 449.62

17 02.07
17 02.23

17 02.05

0.0
4000.0

2000

1500

1000

cm-1

400.0

4000.0

3000

2000

1702.37

0.0

0.0
3000

1500

1000

400.0

4000.0

2000

1500

1000

400.0

0.0

4000.0

3000

2000

cm-1

1703.08

0.0
3000

1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

400.0

cm-1

SJC-PH-JO-7.pk

SJC-PH-JO-8.pk

SJC-PH-JO-9.pk

SJC-PH-JO-10.pk

SJC-PH-JO-11.pk

SJC-PH~2. SP 3601 4000. 00 400. 00 7.40 99. 79 4.00 %T 5 2. 00

SJC-PH~3. SP 3601 4000. 00 400. 00 8.57 99. 83 4.00 %T 5 2. 00

SJ6E1 4~1. SP 3601 4000.00 400.00 11.02 99. 89 4.00 %T 5 2. 00

SJ57CE~1. SP 3601 4000. 00 400. 00 6.48 99. 82 4.00 %T 5 2. 00

SJ57C2~1.SP 3601 4000.00 400 .00 9.19 100.00 4. 00 %T 5 2.00

REF 4 000 98.91 2000 89.96 600

3782.72 96.20 3395.10 34.31 3067.16 48.96 2965.78 64. 04 2818.27 37. 38
2738.03 43.12 2329.14 94.09 2140.52 96.60 1982.75 87. 51 1911.07 89. 41
1827.05 88.97 1702.23 7. 40 1596.21 26.49 1454.70 55.08 1389.65 54.17
1308.39 49.90 1203.75 30.14 1167.62 44.37 1072.24 77. 99 1011.34 75. 98
922. 10 89 .47 826.17 40.94 746.69 23.8 1 688.84 37.20 650.87 42. 32
450. 91 66 .32

REF 4 000 99.35 2000 91.49 600

3783.77 96.21 3393.20 45.93 3067.20 55.39 2964.71 59. 91 2818.09 42. 61
2737.97 47.49 2328.98 94.71 2140.49 97.19 1982.50 88. 97 1910.16 90. 65
1826.64 89.75 1702.05 8. 57 1595.47 29.97 1454.75 56.91 1389.89 57.76
1308.31 53.17 1203.73 32.80 1166.93 46.95 1071.87 78. 74 1012.36 77. 12
922. 12 89 .92 825.89 43.20 746.81 25.7 7 688.77 40.01 650.66 44. 75
450. 64 66 .89

REF 4 000 99.22 2000 94.14 600

3779.85 96.02 3456.88 43.95 3067.58 67.71 2965.54 73. 41 2817.82 54. 51
2737.69 59.18 2329.54 96.63 1982.44 92.49 1909.34 93. 70 1826.49 93. 50
1702.07 11.02 1595.35 36.89 1454.62 65.15 1388.71 63. 22 1308.78 62. 55
1203.47 40.03 1166.70 56.47 1071.86 84.36 1012.18 83. 31 922.12 93.44
826. 01 51 .01 746.67 31.13 688.53 46.4 9 650.36 51.60 450.84 73. 67

REF 4 000 99.01 2000 92.28 600

3780.86 91.73 3449.62 18.83 3068.39 56.63 2817.83 44. 06 2737.63 50. 03
2332.01 93.90 1982.62 90.54 1910.05 92.43 1825.75 92. 39 1702.37 6.48
1596.45 24.92 1454.62 57.80 1388.46 53.80 1309.18 53. 78 1203.54 30. 54
1167.33 47.93 1072.25 81.04 1011.51 79.80 921.71 92.45 826.32 41.01
746. 63 21 .38 688.51 34.45 650.56 39.6 1 451.05 65.18

REF 4 000 99.17 2000 91.90 600

3779.18 91.96 3393.17 4 9.55 3067.61 56.55 2818. 16 47.88 2738.01 53. 25
2332.65 92.39 1981.60 8 9.76 1910.63 90.99 1825. 07 90.53 1703.08 9.19
1595.88 32.13 1454.22 6 0.71 1389.83 58.76 1308. 82 52.85 1204.23 32. 12
1167.84 49.04 1072.35 7 8.97 1011.85 78.28 921.88 88.49 826. 54 44.82
746. 72 26 .61 688.99 40. 38 650.78 45.75 4 50. 67 68. 49

Table - 7.12
Observations of FTIR spectrums for Heptane + Benzaldehyde mixture:
0.9(HP)

0.8(HP)

0.7(HP)

*0.6(HP)

0.5(HP)

0.4(HP)

0.3(HP)

0.2(HP)
+

0.1(HP)

+
Cm-1

0.1(BD)
Cm-1

0.2(BD)
Cm-1

0.3(BD)
Cm-1

0.4(BD)
Cm-1

0.5(BD)
Cm-1

0.6(BD)
Cm-1

0.7(BD)
Cm-1

0.8(BD)
Cm-1

0.9(BD)
Cm-1

Cm-1

3794.95
3444.07
2964.92
2879.83
2722.97
1596.87
1467.24
1362.51
774.31
608.97

3927.66
3781.71
3446.47
2963.39
2882.29
2738.34
2542.27
2031.43
1696.28
1459.80
1384.69
1282.06
1205.65
1116.35
1072.46
1019.24
930.62
824.80
708.76
651.75
549.54
454.31

3924.16
3779.77
3440.24
3069.41
2965.22
2818.14
2737.72
2333.38
1982.26
1909.07
1823.92
1702.19
1595.40
1455.10
1387.80
1309.26
1203.86
1167.12
1072.05
1013.85
922.80
826.26
746.35
688.57
650.24
450.80

3782.72
3395.10
3067.16
2965.78
2818.27
2738.03
2329.14
2140.52
1982.75
1911.07
1827.05
1702.23
1596.21
1454.70
1389.65
1308.39
1203.75
1167.62
1072.24
1011.34
922.10
826.17
746.69
688.84
650.87
450.91

3783.77
3393.20
3067.20
2964.71
2818.09
2737.97
2328.98
2140.49
1982.50
1910.16
1826.64
1702.05
1595.47
1454.75
1389.89
1308.31
1203.73
1166.93
1071.87
1012.36
922.12
825.89
746.81
688.77
650.66
450.64

3779.85
3456.88
3067.58
2965.54
2817.82
2737.69
2329.54
1982.44
1909.34
1826.49
1702.07
1595.35
1454.62
1388.71
1308.78
1203.47
1166.70
1071.86
1012.18
922.12
826.01
746.67
688.53
650.36
450.84

3780.86
3449.62
3068.39
2817.83
2737.63
2332.01
1982.62
1910.05
1825.75
1702.37
1596.45
1454.62
1388.46
1309.18
1203.54
1167.33
1072.25
1011.51
921.71
826.32
746.63
688.51
650.56
451.05

3779.18
3393.17
3067.61
2818.16
2738.01
2332.65
1981.60
1910.63
1825.07
1703.08
1595.88
1454.22
1389.83
1308.82
1204.23
1167.84
1072.35
1011.85
921.88
826.54
746.72
688.99
650.78
450.67

1 (HP)

3895.66
3781.88
3451.06
3068.53
2963.39
2876.23
2738.28
1981.59
1912.36
1825.66
1701.59
1596.46
1455.72
1387.56
1307.72
1204.70
1168.51
1111.62
1072.53
1014.23
923.64
826.22
745.68
689.77
650.69
541.80
450.90

3914.34
3781.23
3443.35
3069.26
2964.49
2874.81
2819.58
2738.20
2331.49
1981.75
1911.94
1825.07
1701.53
1596.03
1455.67
1387.49
1308.11
1204.69
1167.87
1110.91
1072.24
1014.99
923.73
825.81
745.96
689.26
650.63
543.53
450.87

3781.38
3394.87
3067.63
2964.19
2864.03
2818.61
2738.01
2329.95
2140.56
1982.09
1910.52
1826.00
1701.59
1595.69
1455.19
1388.72
1307.95
1204.08
1167.30
1109.11
1072.08
1013.14
922.50
825.69
746.33
688.95
650.63
450.65

* Maximum shift in the frequency has been observed.

289

1(BD)

Fig-7.12: FTIR spectrums for Heptane + Benzyl Chloride mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

3832.74

Spectrum Name: T1-0. 5+0.5.sp

100.0

926.22

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T1-0. 4+0.6.sp

100.0

2673.51

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T1-0. 3+0.7.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T1-0. 2+0.8.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T1-2--0.1+0.9 .asc

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: SJC-J-1.sp

2329.91

100.0

1888.85

923.13

3928.10

379 4.95

233 6.30

2148.79

2773.8 9

3941.78

1267.20

1 075.12

2085.56

1 075.12

70
472.08

472.96
1962.21

2962.30

1449.54 1266.95

2961.07

1467.24
774.31

13 96.87

560.2 2

1449.91

50
1450.86

%T
40

2879.83

564.45
1445.90

%T
1267.15

1 074.47

1958.64

1080.95
469.60

70
3821.81

608.97

1959.22

3916.55

111 9.09

2722.97

9 23.81

3939.4 8

3943.95
2158.9 2

1886.71

1962.22

50
560.9 3

1266.90

560.5 4

3057.23

1269.43

1636.74

2956.52

3049.1 2
1639.96

1640.94

1 362.51
1596.87

3000

2000

1500

1000

400.0

693.65

0.0

4000.0

3000

2000

1500

cm-1

1000

400.0

693.78

3000

2000

1500

cm-1

1000

400.0

693.87

691.00

0.0

4000.0

3435.30

3425.62

3433.62

3428.44

3421.26

0.0

4000.0

3058.42

696 .89

20
2964.92

1641.16

30
1637.70

3444.07

0.0

4000.0

3000

2000

cm-1

1500

0.0

1000

400.0

0.0

4000.0

3000

2000

1500

cm-1

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

T1-2--0. 1+0. 9.pk

T1-0.2+0.8 .pk

T1-0.3+0.7 .pk

T1-0.4+0.6 .pk

T1-0.5+0.5 .pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00

T1-2--~1.ASC 3601 4000. 00 400. 00 8.12 99.32 4.00 %T 3 1.00

T1-02_~1.SP 3601 4000. 00 400.00 7.03 99.41 4.00 %T 3 1. 00

T1-03_~1.SP 3601 4000. 00 400.00 7.43 99.83 4.00 %T 3 1. 00

T1-04_~1.SP 3601 4000. 00 400.00 6.36 99.99 4.00 %T 3 1. 00

T1-05_~1.SP 3601 4000. 00 400.00 9.26 99.47 4.00 %T 3 1. 00

REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

REF 4 000 98.96 2000 93.72 600

3941.78 89.03 3832.74 92.98 3421.26 8.12 2773.89 97.31 2673.51 97.20
2158.92 89.12 1637.70 29.86 1396.87 59.09 1267.20 81. 71 1119.09 83. 70
696. 89 31 .11

REF 4 000 98.85 2000 72.44 600

3916.55 82.46 3821.81 72.74 3428.44 7.03 3058.42 34.05 1962.21 70.76
1641.16 37.88 1450.86 54.41 1267.15 51.52 1075.12 83. 25 926.22 95.66
693. 65 9. 49 560.22 58.4 8 469.60 76.88

REF 4 000 99.21 2000 98.58 600

3928.10 93.30 3425.62 14.46 3049.12 44.13 2956.52 48. 84 2329.91 96. 67
1959.22 92.20 1888.85 95.69 1636.74 49.47 1445.90 54. 79 1269.43 50. 28
1080.95 83.96 923.13 93 .04 691.00 7. 43 564.45 56.61 472.96 73. 33

REF 4 000 99.76 2000 95.31 600

3943.95 92.18 3435.30 6. 36 2962.30 67.61 2336.30 93.53 2085.56 92.39
1962.22 93.83 1640.94 35.45 1449.54 64.66 1266.95 65. 24 1075.12 88. 92
693. 78 13 .07 560.93 54.40

REF 4 000 97.29 2000 95.11 600

3939.48 92.27 3433.62 12.01 3057.23 56.94 2961.07 64. 74 2148.79 92. 83
1958.64 91.87 1886.71 94.80 1639.96 40.21 1449.91 58. 61 1266.90 55. 24
1074.47 84.91 923.81 93 .18 693.87 9. 26 560.54 56.01 472.08 76. 32

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010
Spectrum Name: T1-0. 6+0.4.sp
100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T1-0. 7+0.3.sp

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T1-0. 8+0.2.sp

100.0

1888.10

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: T1-0. 9+0.1.sp

100.0

Spectrum Name: EA+BC-11.sp

100.0

1026.35

400.0

cm-1

SJC-J-1.pk

100.0

3937.09

90
233 5.39

233 5.70

3927.4 6

1887.34

2411.56

1956.83

1076.88

2149.02

393 8.15

2154.27
3772.29

465.92

39 06.50

2410.89
111 9.70

3947.94

1 074.40
1 074.56

30 77.27

1266.80

467.87

3042.6 0

1208.92

922.15
1206.80

1394.17

1960.17

925.06
1956.20

1887.23

924.41

1804.23

1208.74

1611.02

1445.88

465.12
1267.22

559.84

50
560.1 6

270 8.50

1397.0 4

1449.82

50
563.68

2336.46

561.6 6

1451.90

9 27.39

189 0.06

2868.60

2959.53

1267.13

1811.47

1451.49
1637.31

1027.31
1956.03

1600.2 2

3423.02
3040.77

1267.39

2957.59

2959.79

3435.57

1493.17

2960.75

810 .55

1207.69

1640.16
1640.46

559.3 7

1 074.43

2957.85

7 59.02

1451.17
3034.41

692.66
1266.87

3 431.07

692.73
692.73

0.0
4000.0

2000

1500

1000

400.0

4000.0

3000

cm-1

2000

1500

1000

694.99

3 427.62

692.85

0.0
3000

0.0
400.0

4000.0

cm-1

0.0
3000

2000

1500

1000

400.0

3430.86

4000.0

0.0
3000

cm-1

2000

1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

400.0

cm-1

T1-0.6+0.4 .pk

T1-0.7+0.3 .pk

T1-0.8+0.2 .pk

T1-0.9+0.1 .pk

EA+BC-11. pk

T1-06_~1.SP 3601 4000. 00 400.00 8.43 99.98 4.00 %T 3 1. 00

T1-07_~1.SP 3601 4000. 00 400.00 7.41 99.99 4.00 %T 3 1. 00

T1-08_~1.SP 3601 4000. 00 400.00 8.00 99.80 4.00 %T 3 1. 00

T1-09_~1.SP 3601 4000. 00 400.00 6.33 99.81 4.00 %T 3 1. 00

EA9C82~1.SP 3601 4000. 00 400.00 7.08 99.91 4.00 %T 5 2. 00

REF 4 000 99.90 2000 98.05 600

3937.09 97.08 3423.02 42.74 3040.77 42.44 2957.59 35. 57 2335.39 94. 55
1956.20 86.05 1888.10 90.42 1804.23 89.13 1611.02 63. 35 1451.90 44. 55
1267.39 38.53 1208.92 72.63 1074.56 76.41 925.06 88.87 692.73 8. 43
559. 84 55 .18 465.92 71.56

REF 4 000 99.71 2000 98.83 600

3927.46 94.33 3431.07 16.25 3042.60 46.09 2957.85 41. 34 2335.70 95. 15
1956.83 90.91 1887.34 94.72 1637.31 47.82 1451.49 50. 04 1267.13 45. 20
1208.74 80.78 1074.40 80.61 924.41 92.22 692.85 7. 41 560.16 52.83
467. 87 71 .17

REF 4 000 98.26 2000 95.21 600

3947.94 86.85 3427.62 8. 00 3077.27 57.94 2959.79 32.72 2411.56 96.78
2154.27 91.90 1960.17 92.33 1887.23 95.77 1640.16 33. 61 1449.82 55. 26
1394.17 65.88 1267.22 60.17 1206.80 90.25 1076.88 85. 22 1026.35 89. 49
922. 15 93 .69 692.73 11.15 561.66 49.3 7

REF 4 000 97.38 2000 93.68 600

3938.15 88.50 3430.86 6. 33 2959.53 48.48 2410.89 95.61 2149.02 89.85
1640.46 30.25 1445.88 66.07 1397.04 65.96 1266.80 75. 76 1119.70 88. 79
692. 66 21 .44 563.68 54.16

REF 4 000 98.47 2000 59.62 600

3906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25. 24 2960.75 35. 21
2868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48. 63 1890.06 51. 79
1811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26. 63 1266.87 19. 47
1207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57
759. 02 31 .11 694.99 7. 08 559.37 42.03 465.12 60. 85

Table - 7.13
Observations of FTIR spectrums for Heptane + Benzyl Chloride mixture:
1(HP)
0.9(HP)
+
0.1(BC)
Cm-1

0.8(HP)
+
0.2(BC)
Cm-1

0.7(HP)
+
0.3(BC)
Cm-1

0.6(HP)
+
0.4(BC)
Cm-1

0.5(HP)
+
0.5(BC)
Cm-1

Cm-1
3794.95
3444.07
2964.92
2879.83
2722.97
1596.87
1467.24
1362.51
774.31
608.97

3941.78
3832.74
3421.2
2773.89
2673.51
2158.92
1637.70
1396.87
1267.20
1119.09
696.89

3916.55
3821.81
3428.44
3058.42
1962.21
1641.16
1450.86
1267.15
1075.12
926.22
693.65
560.22
469.60

3928.10
3425.62
3049.12
2956.52
2329.91
1959.22
1888.85
1636.74
1445.90
1269.43
1080.95
923.13
691.00
564.45
472.96

3943.95
3435.30
2962.30
2336.30
2085.56
1962.22
1640.94
1449.54
1266.95
1075.12
693.78
560.93

3939.48
3433.62
3057.23
2961.07
2148.79
1958.64
1886.71
1639.96
1449.91
1266.90
1074.47
923.81
693.87
560.54
472.08

*0.4(HP)
+
0.6(BC)
Cm-1

3937.09
3423.02
3040.77
2957.59
2335.39
1956.20
1888.10
1804.23
1611.02
1451.90
1267.39
1208.92
1074.56
925.06
692.73
559.84
465.92

* Maximum shift in the frequency has been observed.

290

1(BC)
0.3(HP)
+
0.7(BC)
Cm-1

0.2(HP)
+
0.8(BC)
Cm-1

0.1(HP)
+
0.9(BC)
Cm-1
Cm-1

3927.46
3431.07
3042.60
2957.85
2335.70
1956.83
1887.34
1637.31
1451.49
1267.13
1208.74
1074.40
924.41
692.85
560.16
467.87

3947.94
3427.62
3077.27
2959.79
2411.56
2154.27
1960.17
1887.23
1640.16
1449.82
1394.17
1267.22
1206.80
1076.88
1026.35
922.15
692.73
561.66

3938.15
3430.86
2959.53
2410.89
2149.02
1640.46
1445.88
1397.04
1266.80
1119.70
692.66
563.68

3906.50
3772.29
3435.57
3034.41
2960.75
2868.60
2708.50
2336.46
1956.03
1890.06
1811.47
1600.22
1493.17
1451.17
1266.87
1207.69
1074.43
1027.31
927.39
810.55
759.02
694.99
559.37
465.12

Fig-7.13: FTIR spectrums for Heptane + 2-Butanone mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-1.sp

379 6.71

Spectrum Name: SJC-J-6.sp

100.0

3 925.74

100.0

37 93.09

3919.84

3924.97

2127.72

9 39.52

2152.75

1467.00

1168.73

2724.40
2722.97

2133.9 8

3924.74

604.10

1165.83

70
2722.39

1171.32

2723.06
608.97

1171.14

1467.24

611.49

590.12

1463.6 7

50
774.50

28 33.22

2881.0 8

1466.31

1465.6 4

2834.84

774.24

2879.53

1735.65

2882.12

1736.29

2880.55

773.93

2833.7 8

773.91
773.90

50
%T
2879.83

588.48

1466.0 9

607.14
774.31

27 22.63

1021.01
937.60

2720.21

%T
40

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-5.sp

100.0

379 4.95

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-4.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-3.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-2.sp

100.0

296 4.96

3447.26
2967.38
3444.07

20
2964.92

2966.74

1360.44

1 362.51

3441.28
3437.58

1596.87

296 6.33

1 362.14

2967.45

1 362.68

1 361.93

3445.25

1 362.50

3438.36
1594.90

1597.43

0.0

4000.0

3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

0.0

4000.0

3000

2000

cm-1

SJC-J-1.pk

1599.26

0.0

4000.0

cm-1

1500

1000

400.0

SJC-J-2.pk

1596.16

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

cm-1

SJC-J-3.pk

1596.73

0.0

1500

1000

400.0

4000.0

3000

cm-1

SJC-J-4.pk

2000

1500

1000

SJC-J-6.pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00

SJC-J-2.sp 3601 4000.00 400.00 5.34 98.50 4. 00 %T 5 1.00

SJC-J-3.sp 3601 4000.00 400.00 6.68 99.29 4. 00 %T 5 1.00

SJC-J-4.sp 3601 4000.00 400.00 6.99 98.71 4. 00 %T 5 1.00

SJC-J-5.sp 3601 4000.00 400.00 6.48 99.27 4. 00 %T 5 1.00

SJC-J-6.sp 3601 4000.00 400.00 6.72 99.69 4. 00 %T 5 1.00

REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

REF 4 000 81.24 2000 79.36 600

3924.74 79.66 3796.71 77.77 3437.58 19.83 2966.33 18. 58 2880.55 40. 03
2723.06 72.86 1597.43 5. 34 1466.31 54.01 1362.14 19.05 1165.83 77.23
774. 50 52 .68 607.14 61.13

REF 4 000 94.92 2000 92.95 600

3925.74 92.51 3438.36 10.85 2966.74 28.56 2881.08 52. 92 2724.40 84. 55
2152.75 91.02 1594.90 6. 68 1467.00 66.21 1360.44 27.18 773.90 59.77
611. 49 64 .44

REF 4 000 88.56 2000 85.88 600

3793.09 86.71 3447.26 33.86 2964.96 35.79 2879.53 57. 08 2833.22 56. 60
2720.21 80.32 1599.26 6. 99 1466.09 63.33 1362.68 19.16 1168.73 82.94
773. 91 61 .72 604.10 75.15

REF 4 000 83.27 2000 82.94 600

3919.84 82.16 3441.28 21.00 2967.45 21.89 2882.12 44. 66 2834.84 55. 28
2722.39 74.85 2133.98 81.68 1735.65 49.12 1596.16 6.48 1465.64 56.00
1361.93 19.58 1171.14 69.44 1021.01 81.52 937.60 82.09 774.24 55.71
590. 12 63 .23

REF 4 000 95.97 2000 95.87 600

3924.97 94.42 3445.25 20.72 2967.38 29.99 2833.78 63. 93 2722.63 86. 66
2127.72 94.15 1736.29 41.79 1596.73 6.72 1463.67 64.95 1362.50 19.78
1171.32 71.15 939.52 92 .66 773.93 63.48 588.48 70.02

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-7.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-8.sp

100.0

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-9.sp

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: SJC-J-10.sp

Spectrum Name: SJC-J-11.sp

100.0

2134.6 2

2723.43

9 40.23
2120.11

2124.88

2121.16

941.51

80
2124.20

3925.39

2726.13

9 40.16

27 29.15

9 40.87

3799.99

3926.98

112 0.91

400.0

cm-1

SJC-J-5.pk

2723.22

272 6.68
1171.97

2831.35

2832.12

2830.0 7

594.09

1462.4 8

1171.65

7 70.78

589.83
7 72.60

1171.40

60
590.76

1736.42

588.52

2986.89

7 70.71

7 72.42

2832.1 8

50
2988.35

590.67

1461.6 8

773.73

2832.85

50
%T

1171.83

1736.34

2987.82

1357.24

1736.61
2968.63

1359.60

20
1 361.50

1359.86

1737.56

3438.91

1596.53

3441.96

4000.0

3000

2000

1500

0.0
1000

400.0

4000.0

2000

1500

1000

400.0

4000.0

cm-1

3445.81

0.0
3000

2000

1500

1000

400.0

4000.0

2000

1500

1000

400.0

4000.0

cm-1

SJC-J-9.pk

1595.49

0.0
3000

cm-1

SJC-J-8.pk

1 362.59

10
1596.16

0.0
3000

cm-1

SJC-J-7.pk

3438.81

1592.41

3438.28

1595.85

0.0

3000

2000

1500

1000

400.0

cm-1

SJC-J-10.pk

SJC-J-11.pk

SJC-J-7.sp 3601 4000.00 400.00 6.46 99.24 4. 00 %T 5 1.00

SJC-J-8.sp 3601 4000.00 400.00 6.48 99.56 4. 00 %T 5 1.00

SJC-J-9.sp 3601 4000.00 400.00 6.32 99.38 4. 00 %T 5 1.00

SJC-J-10.sp 3601 4000.00 400. 00 6. 48 99. 84 4.00 %T 5 1.00

SJC-J-11.sp 3601 4000.00 400. 00 7. 03 99. 99 4.00 %T 5 1.00

REF 4 000 82.55 2000 82.12 600

3441.96 12.97 2968.63 27.75 2832.85 59.07 2726.68 74. 50 2124.88 79. 88
1736.61 31.12 1595.85 6. 46 1462.48 55.47 1359.86 20.07 1171.65 55.99
940. 87 78 .64 772.60 54.04 589.83 56.5 1

REF 4 000 92.98 2000 91.83 600

3438.91 17.36 2831.35 68.26 2723.43 84.71 2134.62 90. 16 1596.53 6.48
1359.60 28.00 1120.91 87.96 773.73 59.63 594.09 63.59

REF 4 000 87.32 2000 85.60 600

3438.28 6. 32 2988.35 54 .28 2830.07 70.35 2729.15 81.21 2120.11 82.93
1736.42 49.70 1592.41 12.55 1461.68 68.81 1357.24 36. 54 1171.97 70. 24
940. 23 85 .60 770.78 60.36 590.76 58.5 5

REF 4 000 85.01 2000 84.80 600

3925.39 83.44 3438.81 15.62 2986.89 53.90 2832.18 59. 94 2723.22 77. 05
2124.20 83.21 1736.34 44.75 1596.16 6.48 1361.50 21.09 1171.40 68.10
940. 16 83 .14 772.42 58.51 590.67 63.4 7

REF 4 000 99.04 2000 98.74 600

3926.98 96.87 3799.99 95.07 3445.81 12.13 2987.82 40. 47 2832.12 69. 24
2726.13 89.36 2121.16 95.77 1737.56 19.80 1595.49 7.03 1362.59 17.87
1171.83 49.73 941.51 89 .22 770.71 65.15 588.52 63.33

Table - 7.14
Observations of FTIR spectrums for Heptane + 2-Butanone mixture:
1(HP)
Cm-1
3794.95
3444.07
2964.92
2879.83
2722.97
1596.87
1467.24
1362.51
774.31
608.97

0.9(HP)
+
0.1(2B)
Cm-1

0.8(HP)
+
0.2(2B)
Cm-1

0.7(HP)
+
0.3(2B)
Cm-1

3924.74
3796.71
3437.58
2966.33
2880.55
2723.06
1597.43
1466.31
1362.14
1165.83
774.50
607.14

3925.74
3438.36
2966.74
2881.08
2724.40
2152.75
1594.90
1467.00
1360.44
773.90
611.49

3793.09
3447.26
2964.96
2879.53
2833.22
2720.21
1599.26
1466.09
1362.68
1168.73
773.91
604.10

*0.6(HP)
+ 0.4(2B)
Cm-1
3919.84
3441.28
2967.45
2882.12
2834.84
2722.39
2133.98
1735.65
1596.16
1465.64
1361.93
1171.14
1021.01
937.60
774.24
590.12

0.5(HP)
+
0.5(2B)
Cm-1

0.4(HP)
+
0.6(2B)
Cm-1

0.3(HP)
+
0.7(2B)
Cm-1

0.2(HP)
+
0.8(2B)
Cm-1

0.1(HP)
+
0.9(2B)
Cm-1

3924.97
3445.25
2967.38
2833.78
2722.63
2127.72
1736.29
1596.73
1463.67
1362.50
1171.32
939.52
773.93
588.48

3441.96
2968.63
2832.85
2726.68
2124.88
1736.61
1595.85
1462.48
1359.86
1171.65
940.87
772.60
589.83

3438.91
2831.35
2723.43
2134.62
1596.53
1359.60
1120.91
773.73
594.09

3438.28
2988.35
2830.07
2729.15
2120.11
1736.42
1592.41
1461.68
1357.24
1171.97
940.23
770.78
590.76

3925.39
3438.81
2986.89
2832.18
2723.22
2124.20
1736.34
1596.16
1361.50
1171.40
940.16
772.42
590.67

* Maximum shift in the frequency has been observed.

291

1(2B)
Cm-1
3926.98
3799.99
3445.81
2987.82
2832.12
2726.13
2121.16
1737.56
1595.49
1362.59
1171.83
941.51
770.71
588.52

Fig-7.14: FTIR spectrums for Heptane + Ethyl Acetate mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 04- 2-2010

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: SJC-J-1.sp

100.0

2341.82
2091.63

3926.2 4

Spectrum Name: T2-0. 5+0.5.sp

100.0

90
3937.42

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 4+0.6.sp

100.0

90
2092.63

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 3+0.7.sp

100.0

3944.42

90
379 4.95

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 2+0.8.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 1+0.9.sp

2087.64
2089.68

2341.88

3933.76

1056.26

208 9.59
2722.97

1057.10

378 1.90
1760.48

608.97

2985.63

1467.24

1058.39
774.31

1057.12

2977.21

633.00

1390.89

60
1056.86

13 85.70

630.89

2969.03

13 84.93

60
6 40.28

12 42.86

2964.89

13 84.35

13 86.94
6 38.77

633.59

1761.14

%T
12 42.98

2879.83

40
296 1.06

1762.28

1642.62
1762.43

3444.07

20
2964.92
1596.87

12 42.98

12 43.00

3444.00

1641.33

3440.75

0.0

4000.0

1761.82
1641.73

1641.77

12 42.99

1641.59

3435.67

1 362.51

3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

4000.0

10
3420.70

3432.96

0.0

4000.0

cm-1

0.0
3000

2000

cm-1

1500

1000

400.0

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

cm-1

2000

1500

1000

400.0

cm-1

SJC-J-1.pk

T2-0.1+0.9 .pk

T2-0.2+0.8 .pk

T2-0.3+0.7 .pk

T2-0.4+0.6 .pk

T2-0.5+0.5 .pk

SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00

T2-01_~1.SP 3601 4000. 00 400.00 7.99 99.74 4.00 %T 3 1. 00

T2-02_~1.SP 3601 4000. 00 400.00 6.40 100.00 4.00 %T 3 1 .00

T2-03_~1.SP 3601 4000. 00 400.00 6.34 99.90 4.00 %T 3 1. 00

T2-04_~1.SP 3601 4000. 00 400.00 8.02 99.97 4.00 %T 3 1. 00

T2-05_~1.SP 3601 4000. 00 400.00 6.39 100.00 4.00 %T 3 1 .00

REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67

REF 4 000 99.37 2000 95.61 600

3944.42 97.72 3440.75 7. 99 2985.63 68.54 2092.63 91.01 1762.43 35.79
1642.62 38.32 1385.70 58.71 1242.99 24.28 1058.39 60. 42 633.00 61.40

REF 4 000 99.54 2000 95.78 600

3937.42 93.52 3432.96 6 .40 2977.21 65.61 2091.63 91.40 1762.28 39.26
1641.77 36.66 1384.35 5 9.71 1242.98 27.08 1057. 12 63.32 630.89 57.49

REF 4 000 99.84 2000 95.76 600

3926.24 89.73 3444.00 6. 34 2969.03 57.57 2341.82 94.54 2089.68 91.20
1761.82 38.81 1641.73 34.08 1384.93 57.71 1243.00 27. 85 1056.86 62. 63
633. 59 57 .56

REF 4 000 99.85 2000 96.00 600

3933.76 90.71 3781.90 75.14 3420.70 8.02 2964.89 61.04 2087.64 92.44
1760.48 70.22 1641.33 34.60 1390.89 68.26 1242.86 64. 48 1056.26 84. 99
640. 28 60 .49

REF 4 000 99.52 2000 95.82 600

3435.67 6. 39 2961. 06 44. 06 2341.88 94.46 2089.59 91.67 1761.14 56.23
1641.59 34.28 1386.94 6 1.59 1242.98 47.57 1057. 10 76.47 638.77 58.31

ACIC
St.Joseph's Colleg e ( Autono mous )
Trichy-2
ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FTIR SPECTRUM
Date: 3/11/2009
Spectrum Name: Cl-AN-1.sp
1 0 0. 0

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 6+0.4.sp

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 7+0.3.sp

100.0

FT IR SPECT RUM
Date: 18- 6-2010

Spectrum Name: T2-0. 8+0.2.sp

100.0

2489.19

Spectrum Name: T2-0. 9+0.1.sp

100.0

2088.87
928.00

100.0

2362.08

80
90

39 54.90

2088.75

1462.72
2084.93

3946.3 1

1249.22
1115.43

3940.85

2087.25

1114.81

2095.36

80
2991.58

1056.29
1057.23

622.08
1378.64

1390.99
12 43.15
13 88.10

13 94.47

1760.17
13 85.53

1056.51

656.34

657.87
2 960.80

633.82
1762.00

6 36.95

1637.15

2962.58

12 43.01

1641.34

1641.21

2957.17

0.0

1763.76

1640.75

2958.68

1640.58

3437.11

0.0

20
1242.81

10
3449.55

0. 0
3437.23

3441.69

0.0
4000.0

3000

2000

1500

1000

400.0

4000.0

3000

cm-1

2000

1500

1000

400.0

4000.0

cm-1

4 00 0. 0

3443.85

0.0
3000

2000

1500

1000

400.0

4000.0

3 0 00

20 00

15 00

10 0 0

4 00 .0

cm -1
3000

2000

cm-1

1500

1000

400.0

cm-1

T2-0.6+0.4 .pk

T2-0.7+0.3 .pk

T2-0.8+0.2 .pk

T2-0.9+0.1 .pk

T2-06_~1.SP 3601 4000. 00 400.00 7.97 99.99 4.00 %T 3 1. 00

T2-07_~1.SP 3601 4000. 00 400.00 6.34 99.99 4.00 %T 3 1. 00

T2-08_~1.SP 3601 4000. 00 400.00 7.97 100.00 4.00 %T 3 1 .00

T2-09_~1.SP 3601 4000. 00 400.00 7.95 99.99 4.00 %T 3 1. 00

REF 4 000 99.63 2000 95.68 600

3954.90 97.26 3437.23 7. 97 2962.58 51.23 2088.75 92.18 1762.00 57.81
1641.34 41.22 1385.53 66.49 1243.01 46.85 1057.23 76. 92 633.82 62.32

REF 4 000 99.57 2000 95.58 600

3437.11 6. 34 2957.17 25 .06 2095.36 91.88 1760.17 72.99 1640.58 35.98
1388.10 63.96 1243.15 67.11 1056.29 83.60 636.95 58.13

REF 4 000 99.86 2000 95.70 600

3946.31 94.12 3441.69 7 .97 2958.68 37.05 2084.93 92.67 1641.21 39.33
1462.72 79.27 1390.99 7 2.83 1249.22 96.70 1115. 43 92.09 656.34 64.27

REF 4 000 99.28 2000 95.68 600

3940.85 95.93 3443.85 7. 95 2960.80 63.70 2087.25 92.87 1640.75 41.14
1394.47 77.50 1114.81 93.56 657.87 64.42

Cl-AN-1.p k
Cl-AN-1.s p 3 601 4000.00 400.00 6.33 10 0.00 4.00 %T 5 1.00
REF 4000 99.39 2000 9 7.58 600
3449.55 6.33 2 991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 9 5.42
1763.76 32.63 163 7.15 43.78 1378.6 4 6 7.05 1242.81 18.7 3 1056.51 55. 12
928.00 97.75 6 22.08 6 9.86

Table - 7.15
Observations of FTIR spectrums for Heptane + Ethyl Acetate mixture:
1(EA)

1(HP)
0.9(HP)
+
0.1(EA)
Cm-1

0.8(HP)
+
0.2(EA)
Cm-1

*0.7(HP)
+ 0.3(EA)
Cm-1

0.6(HP)
+
0.4(EA)
Cm-1

0.5(HP)
+
0.5(EA)
Cm-1

0.4(HP)
+
0.6(EA)
Cm-1

0.3(HP)
+
0.7(EA)
Cm-1

0.2(HP) +
0.8(EA)
Cm-1

0.1(HP)
+
0.9(EA)
Cm-1
Cm-1

Cm-1
3933.91
3435.81
2954.98
2665.98
2348.12
2135.82
1640.00
1459.35
1392.35
1225.90
1120.63
657.99

3944.42
3440.75
2985.63
2092.63
1762.43
1642.62
1385.70
1242.99
1058.39
633.00

3937.42
3432.96
2977.21
2091.63
1762.28
1641.77
1384.35
1242.98
1057.12
630.89

3926.24
3444.00
2969.03
2341.82
2089.68
1761.82
1641.73
1384.93
1243.00
1056.86
633.59

3933.76
3781.90
3420.70
2964.89
2087.64
1760.48
1641.33
1390.89
1242.86
1056.26
640.28

3435.67
2961.06
2341.88
2089.59
1761.14
1641.59
1386.94
1242.98
1057.10
638.77
57.56

3954.90
3437.23
2962.58
2088.75
1762.00
1641.34
1385.53
1243.01
1057.23
633.82

* Maximum shift in the frequency has been observed.

292

3437.11
2957.17
2095.36
1760.17
1640.58
1388.10
1243.15
1056.29
636.95

3946.31
3441.69
2958.68
2084.93
1641.21
1462.72
1390.99
1249.22
1115.43
656.34

3940.85
3443.85
2960.80
2087.25
1640.75
1394.47
1114.81
657.87

3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08

Fig-7.15: FTIR spectrums for Benzaldehyde + Benzyl Chloride mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =0+19.67. sp

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =4.82+15. 73.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =2.41+17. 70.sp

100.0

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =7.24+13. 76.sp

100.0

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =9.65+11. 80.sp

100.0

Spectrum Name: Sam =12.07+9. 835.sp

100.0

100.0
1495.51

2540.68

1887.33
1954 .65

2866.83

2 817.92

80
1027.37

1495.36

1495.1 2

1958 .06

2736.78

925.88

1807.15

1020.97

2359.43

1023.51

2361.84

458.71

453.48
453.69
557.83

456.26

1073.45

1074.02
1072.78

1074.55
2359.20

2736.97

2 819.75

2737.87

559.12
559.14

2817.20

1168.03

2737.26

1166.43

1393.77

1393.06

2 817.73

1397.50

2 818.57

11 66.79

1168.03

1452.75

813.02

1452.03

3034.51

823.92

815.57

559.03

559.46

1310.13

557.54

1400.26 1204.8 3

1452.57

1648.19

126 8.72

1597.63

824.59

3033.97
3 066.36

1453.2 8

1205.39

1204.22

1596.78

343 7.67

3073.15

127 1.31

747.40

127 7.16
1597.14

1204.36
126 6.53

3069.79

%T
126 9.20

1268.98

1452.09

3065.58

821.29
3067.86

3070.48

760.56
1452.48

2963.51

928.75
2737.67

2362.73

927.05

1022.76

1398.17
1204.97

1970.64

1965.8 4
925.94

80
462.79

1167.05
2 962.70

60
8 10.75

1637.89

925.20

1960.10
1024.51

2358.99

464.81

1699.23 149 5.29

2960.77

50
%T
303 3.08

90
1962.6 0

2545.69

1074.60

1073.70
1 394.35 1207.06

926.73
1025.73

2361.42

14 95.11

1494.80

1160 .38

746.94

343 9.86

747.14

343 9.42

746.84

344 4.32

1699.03

344 7.49

1698.89

0.0

4000.0

3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

1700.91

0.0

4000.0

3000

2000

1500

cm -1

1000

400.0

0.0

4000.0

3000

2000

1500

cm -1

Sam =2.41+17.70.pk

694.86
1701.17

0.0

4000.0

cm -1

Sam =0+19. 67.pk

1701.42

695.95

695.77

0.0

696.10

10
696.19

344 3.18
696.69

1000

400.0

0.0

4000.0

3000

2000

1500

cm -1

Sam =4.82+15.73.pk

1000

400.0

4000.0

3000

cm -1

Sam =7.24+13.76.pk

2000

1500

1000

Sam =12. 07+9.835.pk

SAM_0_~1.SP 3601 4000.00 400.00 8. 19 1 00. 00 4.00 %T 3 2. 00

SAM_24~2.SP 3601 4000.00 400.00 9. 09 9 9.99 4. 00 %T 3 2.00

SAM_48~1.SP 3601 4000.00 400.00 7. 05 9 9.84 4. 00 %T 3 2.00

SAM_72~1.SP 3601 4000.00 400.00 10.80 100.00 4.00 %T 3 2.00

SAM_96~1.SP 3601 4000.00 400.00 9. 03 9 9.53 4. 00 %T 3 2.00

SAM_12~1.SP 3601 4000.00 400.00 10.98 99. 92 4.00 %T 3 2. 00

REF 4000 99.61 2000 99.02 600

3444.32 31.42 3065.58 52. 84 3033. 08 49.6 3 2960.77 67.54 2866. 83 88.38
2361.42 79.78 1954.65 88. 69 1887. 33 92.5 0 1807.15 90.79 1699. 23 68.22
1637.89 63.83 1495.29 64. 98 1452. 48 48.8 1 1394.35 74.16 1266. 53 41.05
1207.06 75.43 1160.38 83. 44 1073. 70 76.1 4 1027.37 86.66 925.88 91.32
810.75 61.0 7 760. 56 50.09 696. 69 8.19 559.46 56.01 464.81 74.80

REF 4000 99.73 2000 97.37 600

3447.49 15.67 3070.48 53.89 3034. 51 54.06 2962. 70 74. 19 2817. 92 87. 66
2736.78 92.46 2540.68 96.74 2358. 99 85.24 1958. 06 93. 14 1699. 03 26. 02
1648.19 48.37 1495.12 74.20 1452. 03 55.76 1398. 17 68. 40 1268. 72 46. 30
1204.97 67.30 1167.05 80.32 1074. 60 83.18 1025. 73 91. 89 926.73 92.71
813.02 62.7 8 695.77 9.09 5 59. 03 60.03 462.79 78.76

REF 4000 99.51 2000 96.55 600

3443.18 13.70 3073.15 41.73 2819. 75 72.10 2737. 67 80. 92 2545. 69 90. 36
2359.20 75.50 1960.10 91.90 1698. 89 10.57 1495. 36 71. 10 1452. 09 48. 98
1400.26 54.69 1271.31 38.58 1204. 83 52.91 1168. 03 68. 46 1074. 55 79. 23
1024.51 89.32 928.75 88.11 815.57 57. 97 747.40 38.25 695.95 7.05
557.54 55.9 8 458.71 76. 87

REF 4000 99.69 2000 97.42 600

3439.42 35.10 3067.86 54. 14 2963. 51 74.4 0 2817.20 70.15 2736. 97 75.71
2359.43 82.44 1962.60 93. 52 1701. 42 11.7 4 1597.63 47.02 1494. 80 75.98
1452.57 54.02 1393.77 66. 01 1268. 98 48.7 6 1204.22 47.37 1166. 43 67.52
1074.02 81.80 1022.76 89. 54 925.20 92.24 821.29 57.31 747.14 35.39
694.86 10.8 0 559. 14 68.49 456. 26 78. 41

REF 4000 99.49 2000 97.40 600

3439.86 38.48 3066.36 53.18 3033. 97 54.15 2817. 73 64. 78 2737. 26 70. 80
2361.84 84.33 1965.84 94.10 1701. 17 9.03 1596.78 45.36 1495.51 77.77
1453.28 53.72 1393.06 65.17 1310. 13 61.95 1269. 20 49. 82 1204. 36 42. 21
1166.79 63.53 1072.78 81.35 1023. 51 88.83 925.94 90.76 824. 59 56. 31
746.84 34.2 8 696.19 13. 99 559.12 71.66 453. 69 79.39

REF 4000 99.76 2000 97.59 600

3437.67 41.99 3069.79 55.88 2818. 57 66.69 2737. 87 73. 89 2362. 73 92. 48
1970.64 95.50 1700.91 10.98 1597. 14 50.47 1495. 11 85. 31 1452. 75 64. 32
1397.50 68.22 1277.16 55.15 1205. 39 49.42 1168. 03 68. 01 1073. 45 86. 32
1020.97 91.54 927.05 91.33 823.92 62. 41 746.94 41.79 696.10 23.64
557.83 79.5 8 453.48 83. 27

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

1 976.28 1821.6 9
19 11.15

1978.74

100.0

1908.74

925.48

555.32

2365.30

2738.17

33 92.16

1072.68

652 .64

1392.52

27 37.93

3390.58

1452.81
1167.95

1205.67
2738.60

693.96

746 .76

1167.04
65 0.77

2 818.39

1285.60

1169.01

3392.11

824.81

689.23

2 819.15

652.82
1204.67

3390.83

1205.95

3071.24

1596.07

694.76

1596.65

695.80

74 7.24

74 6.45
695.33

0.0
400.0

4000.0

1700.22

0.0
3000

2000

cm -1

1701.95

1700.74

1700.47

1000

2738.32

826.10

1396.15

74 6.88

1205.18

3068.94

1595.96

825.21

128 1.16
1596.0 5

1500

1454.14

1308.46

2 818.69

2000

450.84

450.72

825.54

3066.47

0.0
3000

101 2.18

1112.44
11 67.92

1306.81

2 818.59

1452.23

1205.43
746 .52

4000.0

1910.62

926.88

1394.45

3069.01

548.34

2550.16

1453.08

452.04

1394.61

128 1.88
1595.83

922.30

101 5.51
556.59

50
824.10

2 818.64
3068.18

10 72.61

927.04
1072.00

1980.3 3

1982.52 1826.09

19 13.14

10 22.32
2549.23

139 7.26
1 168.71

1823 .61

451.12

553.80
451.58

1451.93
2737.89
3390.66

1108 .93

2332.07

1072.84

1072.39 927.95

2139.72

1492 .91
202 7.14

10 16.10

11 11.33

2363.98

2140.47

90
1822 .87

1910.83

10 18.08
2550.12

Spectrum Name: Sam =24.14+0. sp

100.0
1110.72

1494.75
1973.32 1820.52

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =21.72+1. 967.sp

100.0

90
1112.48

2361.64

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =19.32+3. 93.sp

100.0
1494 .04

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =16.89+5. 90.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/15/2008

Spectrum Name: Sam =14.48+7. 86.sp

400.0

cm -1

Sam =9.65+11.80.pk

1500

1000

400.0

4000.0

1702 .46

0.0
3000

cm -1

2000

1500

1000

400.0

4000.0

0.0
3000

cm -1

2000

1500

1000

400.0

4000.0

3000

cm -1

2000

1500

1000

400.0

cm -1

Sam =14. 48+7.86.pk

Sam =16. 89+5.90.pk

Sam =19. 32+3.93.pk

Sam =21. 72+1.967.pk

Sam =24. 14+0.pk

SAM_14~1.SP 3601 4000.00 400.00 7. 75 1 00. 00 4.00 %T 3 2. 00

SAM_16~1.SP 3601 4000.00 400.00 7. 53 9 9.99 4. 00 %T 3 2.00

SAM_19~1.SP 3601 4000.00 400.00 10.42 99. 85 4.00 %T 3 1. 00

SAM_21~1.SP 3601 4000.00 400.00 7. 14 9 9.99 4. 00 %T 3 1.00

SAM_24~1.SP 3601 4000.00 400.00 7. 78 9 9.80 4. 00 %T 3 2.00

REF 4000 99.55 2000 95.47 600

3390.66 50.09 3068.18 41. 88 2818. 64 45.5 2 2737.89 53.38 2550. 12 77.80
2361.64 89.14 1976.28 92. 30 1911. 15 92.3 8 1821.69 92.83 1700. 47 7.74
1595.83 35.79 1494.04 84. 79 1451. 93 56.2 4 1397.26 56.41 1281. 88 40.72
1205.43 34.78 1168.71 49. 49 1112. 48 76.0 8 1072.39 76.63 1018. 08 81.55
927.95 74.7 8 824. 10 48.14 746. 52 31. 25 695.80 22. 89 553.80 74.39
451.58 72.7 8

REF 4000 99.34 2000 94.39 600

3390.58 45.03 3066.47 33.83 2818. 69 38.42 2737. 93 45. 81 2549. 23 73. 48
2363.98 85.77 1973.32 89.72 1908. 74 89.98 1820. 52 89. 71 1700. 74 7.53
1596.05 29.28 1494.75 76.42 1452. 81 45.15 1394. 61 50. 67 1281. 16 34. 04
1205.18 27.26 1167.95 41.83 1111. 33 71.55 1072. 00 68. 93 1022. 32 75. 99
927.04 71.2 7 825.21 40. 05 746.76 24.05 695. 33 16.20 556 .59 66.92
452.04 66.6 8

REF 4000 99.56 2000 95.70 600

3392.16 56.03 3069.01 55.70 2818. 59 57.23 2738. 17 63. 97 1978. 74 93. 87
1910.83 94.16 1822.87 93.44 1701. 95 10.42 1595. 96 44. 54 1453. 08 67. 52
1394.45 66.72 1306.81 58.70 1205. 67 43.04 1167. 92 59. 89 1110. 72 84. 70
1072.84 85.51 1016.10 88.45 925.4 8 89.27 825. 54 56. 98 746.88 37.69
693.96 38.1 6 652.64 53. 20 555.32 86.77 451. 12 79.20

REF 4000 99.23 2000 90.91 600

3390.83 28.65 3071.24 29.60 2819. 15 32.65 2738. 60 39. 18 2550. 16 68. 32
2365.30 84.93 2140.47 98.07 2027. 14 91.35 1980. 33 86. 94 1913. 14 86. 83
1823.61 87.25 1700.22 7. 14 1596. 65 25.06 1492.91 85.87 1452.23 49.48
1396.15 41.91 1285.60 34.66 1205. 95 26.63 1169. 01 38. 12 1112. 44 65. 44
1072.61 70.52 1015.51 74.79 926.8 8 67.28 824. 81 37. 12 746.45 23.20
694.76 24.2 1 652.82 31. 36 548.34 68.70 450. 72 60.11

REF 4000 98.63 2000 89.64 600

3392.11 38.45 3068.94 49.16 2818. 39 41.61 2738. 32 47. 07 2332. 07 92. 72
2139.72 96.16 1982.52 87.01 1910. 62 88.53 1826. 09 87. 47 1702. 46 7.77
1596.07 28.46 1454.14 58.66 1392. 52 56.44 1308. 46 50. 72 1204. 67 31. 12
1167.04 45.91 1108.93 82.45 1072. 68 79.76 1012. 18 79. 42 922.30 88.15
826.10 41.8 9 747.24 23. 95 689.23 38.08 650. 77 42.43 450 .84 67.18

Table - 7.16
Observations of FTIR spectrums for Benzaldehyde + Benzyl Chloride mixture:
1 (BD)

Cm-1
3392.11
3068.94
2818.39
2738.32
2332.07
2139.72
1982.52
1910.62
1826.09
1702.46
1596.07
1454.14
1392.52
1308.46
1204.67
1167.04
1108.93
1072.68
1012.18
922.30
826.10
747.24
689.23
650.77
450.84

0.9(BD)
+
0.1(BC)
Cm-1

0.8(BD)
+
0.2(BC)
Cm-1

0.7(BD)
+
0.3(BC)
Cm-1

*0.6(BD)
+
0.4(BC)
Cm-1

0.5(BD)
+
0.5(BC)
Cm-1

0.4(BD)
+
0.6(BC)
Cm-1

0.3(BD)
+
0.7(BC)
Cm-1

0.2(BD)
+
0.8(BC)
Cm-1

0.1(BD)
+
0.9(BC)
Cm-1

1(BC)

3390.83
3071.24
2819.15
2738.60
2550.16
2365.30
2140.47
2027.14
1980.33
1913.14
1823.61
1700.22
1596.65
1492.91
1454.23
1396.15
1285.60
1205.95
1169.01
1112.44
1072.61
1015.51
926.88
824.81
746.45
694.76

3392.16
3069.01
2818.59
2738.17
1978.74
1910.83
1822.87
1701.95
1595.96
1453.08
1394.45
130681
1205.67
1167.92
1110.72
1072.84
1016.10
925.48
825.54
746.88
693.96
65264
555.32
451.12

3390.58
3066.47
2818.69
2737.93
2549.23
2363.98
1973.32
1908.74
1820.52
1700.74
1596.05
1492.75
1452.81
1394.61
1281.16
1205.18
1167.95
1111.33
1072.00
1022.32
927.04
825.21
746.76
695.33
556.59
452.04

3390.66
3068.18
2818.64
2737.89
2550.12
2361.64
1976.28
1911.15
1821.69
1700.47
1595.83
1494.04
1451.93
1397.26
1281.88
1205.43
1168.71
1112.48
1072.39
1018.08
927.95
824.10
746.52
695.80
553.80
451.58

3437.67
3069.79
2818.57
2737.87
2362.73
1970.64
1700.91
1597.14
1495.11
1452.75
1397.50
1277.16
1205.39
1168.03
1073.45
1020.97
927.05
823.92
746.94
696.10
557.83
453.48

3439.86
3066.36
3033.97
2817.73
2737.26
2361.84
1965.84
1701.17
1596.78
1495.51
1453.28
1393.06
1310.13
1269.20
1204.36
1166.79
1072.78
1023.51
925.94
824.59
746.84
696.19
559.12
453.69

3439.42
3067.86
2963.51
2817.20
2736.97
2359.43
1962.60
1701.42
1597.63
1494.80
1452.57
1393.77
1268.98
1204.22
1166.43
1074.02
1022.76
925.20
821.29
747.14
694.86
559.14
456.26

3443.18
3073.15
2819.75
2737.67
2545.69
2359.20
1960.10
1698.89
1495.36
1452.09
1400.26
1271.31
1204.83
1168.03
1074.55
1024.51
928075
815.57
747.40
695.95
557.54
458.71

3447.49
3073.48
2962.70
2817.92
2736.78
2540.68
2358.99
1958.06
1699.03
1648.19
1495.12
1452.03
1398.17
1268.72
1204.97
1167.05
1074.60
1025.73
926.73
813.02
695.77
559.03
462.79

3444.32
3065.58
3033.08
2960.77
2866.83
2361.42
1954.65
1887.33
1807.15
1699.23
1637.89
1495.29
1452.48
1394.35
1266.53
1207.06
1160.38
1073.70
1027.37
925.88
810.75
760.56
696.69
559.46
464.81

* Maximum shift in the frequency has been observed.

293

Cm-1

Fig-7.16: FTIR spectrums for Benzaldehyde + 2-Butanone mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

3956.28

930.50
3942.73

2027.76

2736.34

202 2.06
1311.05

1017.84

2819.42

464.81

1310.27

2815.56

273 7.53
2989.41

70
1168.90

2820.53

456.26

2819.78
824.59

1014.90

2734.92

2818.25

1450.89
460.27
822 .24

1303.20

13 86.52

8 10.75

2032.44

3941.05

454.91

2984.73

2332.11

1016.00

1013.78

2736.48

1027.37

1073.70

1637.89

932.87

2130.63

938.97

1 394.35 1207.06
1699.23 149 5.29

2960.77

Spectrum Name: T3-0. 5+0.5.sp

100.0

2033.45
2737.35

2361.42

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 4+0.6.sp

100.0
2333.28

90
1014.68

925.88

1807.15

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 3+0.7.sp

100.0

2991.86

90
1887.33
1954 .65

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 2+0.8.sp

100.0

1160 .38

2866.83

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 1+0.9.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 29- 6-2010

FT IR SPECT RUM
Date: 2/15/2008
Spectrum Name: Sam =0+19.67. sp
100.0

1202.77

1304.85

823.73

458.13

81 9.82
1393.13

559.46

%T
303 3.08

13 85.07

1376.29

1189.37

1193.13

69 2.77

3065.58

1204.58

689.05
745.04

40
688.57
682.82

821.96

745.92

126 6.53

13 96.80

%T
1197.28

650.09

760.56
1452.48

744.12

344 4.32

741.06

1649.4 6

691.81

17 01.44

3000

2000

1500

1000

400.0

3 451.99

0.0

4000.0

3000

2000

1500

1000

400.0

4000.0

2000

1500

1000

400.0

T3-0.1+0.9 .pk

17 00.34

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

0.0

4000.0

3000

2000

cm-1

T3-0.2+0.8 .pk

743.76

10
17 00.15

3433.85

0.0
3000

cm-1

cm -1

Sam =0+19. 67.pk

1704.63
17 07.96

0.0

4000.0

3 426.16

3 431.30
696.69

0.0

1500

1000

400.0

3424.31

4000.0

cm-1

T3-0.3+0.7 .pk

3000

2000

1500

1000

T3-0.4+0.6 .pk

T3-0.5+0.5 .pk

SAM_0_~1.SP 3601 4000.00 400.00 8. 19 1 00. 00 4.00 %T 3 2. 00

T3-01_~1.SP 3601 4000. 00 400.00 7.88 99.99 4.00 %T 5 1. 00

T3-02_~1.SP 3601 4000. 00 400.00 6.36 99.92 4.00 %T 5 1. 00

T3-03_~1.SP 3601 4000. 00 400.00 10.53 100.00 4. 00 %T 5 1.00

T3-04_~1.SP 3601 4000. 00 400.00 10.79 99.99 4.00 %T 5 1 .00

T3-05_~1.SP 3601 4000. 00 400.00 5.12 99.99 4.00 %T 5 1. 00

REF 4000 99.61 2000 99.02 600

REF 4 000 99.54 2000 90.39 600

3431.30 12.40 2984.73 74.96 2819.42 86.55 2737.35 88. 66 2033.45 89. 50
1707.96 7. 88 1376.29 47 .35 1189.37 49.02 1014.68 94.68 938.97 93.55
822. 24 65 .70 745.92 40.94 692.77 47.8 5 460.27 78.59

REF 4 000 99.92 2000 95.70 600

3942.73 95.56 3451.99 6. 36 2991.86 90.02 2815.56 87.29 2736.34 88.63
2130.63 94.26 1701.44 15.76 1649.46 31.63 1450.89 74. 48 1386.52 64. 68
1310.27 80.27 1202.77 61.59 1168.90 70.44 1017.84 94. 39 930.50 96.86
824. 59 66 .51 745.04 43.68 689.05 48.4 5 650.09 51.20 454.91 80. 57

REF 4 000 99.66 2000 94.32 600

3956.28 96.54 3426.16 1 3.62 2989.41 77.28 2819. 78 79.49 2736.48 83. 48
2027.76 93.89 1704.63 1 0.53 1385.07 55.15 1311. 05 70.83 1193.13 48. 06
1013.78 93.69 932.87 94. 88 823.73 61 .84 744.12 37.63 688.57 44.28
456. 26 76 .40

REF 4 000 99.38 2000 94.17 600

3433.85 10.79 2820.53 82.08 2734.92 86.05 2333.28 97. 87 2022.06 93. 94
1700.15 10.96 1393.13 59.38 1303.20 68.69 1197.28 50. 47 1016.00 92. 70
819. 82 60 .62 741.06 36.28 682.82 40.5 2

REF 4 000 99.58 2000 92.60 600

3941.05 90.22 3424.31 5. 12 2818.25 74.51 2737.53 79.41 2332.11 95.86
2032.44 91.25 1700.34 6. 90 1396.80 55.71 1304.85 67.90 1204.58 49.54
1014.90 90.68 821.96 48 .66 743.76 25.53 691.81 31.26 458.13 66.62

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 29- 6-2010

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 6+0.4.sp

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 8+0.2.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 29- 6-2010

Spectrum Name: T3-0. 7+0.3.sp

100.0

FT IR SPECT RUM
Date: 04- 2-2010

Spectrum Name: T3-0. 9+0.1.sp

100.0

400.0

cm-1

Spectrum Name: SJC-J-11.sp

100.0

100.0
2 407.88

233 6.90

3841.76

233 4.08

9 28.06

925.46

23 25.60

1913.87
2027.07

1012.19

1988.46

3936.33

70
2738.44

1013.52

3799.99

2121.16

3926.98

941.51

2726.13

27 37.84

454.79
2737.73

1309.49

3946.81

1995.68

1015.20

1011.91

233 8.82

1914.74

2025.07

2818.47
453.48

2 824.30

456.62

27 36.26

2832.12
456.05

1304.90

7 70.71

588.52

2821.00

822.84
1389.71

2821.85

1308.25

1391.30

50
1302.34
13 95.57

3084.59

1196.87

3079.94

823.89

50
13 96.30

%T
1204.59

822.26

1171.83

820.61

6 88.01

2987.82
1200.38

743.49

1197.95

30
691.69

688.83

682.04

743.74

744.02

741.93

3431.33
1737.56

17 01.96

1 362.59

10
3445.81

3421.01

0.0

17 01.67

3423.22

0.0

4000.0

3000

2000

1500

1000

400.0

16 98.41

16 99.95

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

cm-1

T3-0.6+0.4 .pk

0.0
3000

2000

1500

1000

400.0

1595.49

0.0

3 421.90

4000.0

3000

cm-1

T3-0.7+0.3 .pk

2000

1500

1000

400.0

4000.0

3000

2000

cm-1

T3-0.8+0.2 .pk

1500

1000

400.0

cm-1

T3-0.9+0.1 .pk

SJC-J-11.pk

T3-06_~1.SP 3601 4000. 00 400.00 6.36 100.00 4.00 %T 5 1 .00

T3-07_~1.SP 3601 4000. 00 400.00 7.87 99.64 4.00 %T 5 1. 00

T3-08_~1.SP 3601 4000. 00 400.00 8.04 99.49 4.00 %T 5 1. 00

T3-09_~1.SP 3601 4000. 00 400.00 6.34 100.00 4.00 %T 5 1 .00

SJC-J-11.sp 3601 4000.00 400. 00 7. 03 99. 99 4.00 %T 5 1.00

REF 4 000 100.00 2000 92.51 600

3431.33 6. 36 2824. 30 64. 14 2738.44 71.59 2336.90 95.13 2025.07 92.19
1701.96 14.14 1389.71 5 3.40 1309.49 69.27 1196. 87 50.48 1011.91 90. 25
928. 06 94 .26 822.84 56. 75 743.49 34.88 6 88. 01 39. 51 454.79 71.62

REF 4 000 98.82 2000 90.97 600

3936.33 93.51 3841.76 94.15 3421.01 7.87 3084.59 57.89 2821.00 63.73
2737.73 70.31 2334.08 96.40 1988.46 90.77 1914.74 93. 22 1701.67 8.08
1391.30 47.90 1308.25 57.53 1200.38 38.82 1012.19 86. 53 925.46 91.72
823. 89 47 .79 743.74 25.97 688.83 31.7 4 453.48 67.80

REF 4 000 98.56 2000 90.34 600

3423.22 8. 70 3079.94 53 .85 2821.85 58.55 2736.26 66.54 2338.82 95.68
1995.68 90.29 1698.41 8. 04 1395.57 50.35 1302.34 54.78 1197.95 37.70
1013.52 85.45 820.61 45 .97 741.93 25.02 682.04 28.94 456.62 66.17

REF 4 000 99.21 2000 91.71 600

3946.81 94.63 3421.90 6 .34 2818.47 70.21 2737.84 74.90 2407.88 98.27
2325.60 97.66 2027.07 9 0.96 1913.87 94.69 1699. 95 10.11 1396.30 54. 87
1304.90 64.35 1204.59 4 8.62 1015.20 87.01 822.26 48.87 744. 02 27.55
691. 69 32 .76 456.05 66. 00

REF 4 000 99.04 2000 98.74 600

3926.98 96.87 3799.99 95.07 3445.81 12.13 2987.82 40. 47 2832.12 69. 24
2726.13 89.36 2121.16 95.77 1737.56 19.80 1595.49 7.03 1362.59 17.87
1171.83 49.73 941.51 89 .22 770.71 65.15 588.52 63.33

Table - 7.17
Observations of FTIR spectrums for Benzaldehyde + 2-Butanone mixture:
0.9(BD)

0.8(BD)

*0.7(BD)

0.6(BD)

0.5(BD)

0.4(BD)

0.3(BD)

0.2(BD)

0.1(BD)

Cm-1

0.1(2B)
Cm-1

0.2(2B)
Cm-1

0.3(2B)
Cm-1

0.4(2B)
Cm-1

0.5(2B)
Cm-1

0.6(2B)
Cm-1

0.7(2B)
Cm-1

0.8(2B)
Cm-1

0.9(2B)
Cm-1

Cm-1

3928.23
3446.84
2819.60
2738.80
2363.70
1982.17
1913.80
1824.00
1697.38
1594.54
1453.80
1387.26
1310.06
1206.73
1169.33
1114.11
1072.35
1015.97
924.10
825.54
746.17
690.95
651.10
545.73
452.91

3946.81
3421.90
2818.47
2737.84
2407.88

3423.22
3079.94
2821.85
2736.26
2338.82

2325.60
2027.07
1913.87
1699.95
1396.30

1995.68
1698.41
1395.57
1302.34
1197.95
1013.52
820.61
741.93
682.04
456.62

3936.33
3841.76
3421.01
3084.59
2821.00
2737.73
2334.08
1988.46
1914.74
1701.67
1391.30
1308.25
1200.38
1012.19
925.46
823.89
743.74
688.83
453.48

3431.33
2824.30
2738.44
2336.90
2025.07
1701.96
1389.71
1309.49
1196.87
1011.91
928.06
822.84
743.49
688.01
454.79

3941.05
3424.31
2818.25
2737.53
2332.11
2032.44
1700.34
1396.80
1304.85
1204.58
1014.90
821.96
743.76
691.81
458.13

3433.85
2820.53
2734.92
2333.28
2022.06
1700.15
1393.13
1303.20
1197.28
1016.00
819.82
741.06
682.82

3956.28
3426.16
2989.41
2819.78
2736.48
2027.76
1704.63
1385.07
1311.05
1193.13
1013.78
932.87
823.73
744.12
688.57
456.26

3942.73
3451.99
2991.86
2815.56
2736.34
2130.63
1701.44
1649.46
1450.89
1386.52
1310.27
1202.77
1168.90
1017.84
930.50
824.59
745.04
689.05
650.09
454.91

3431.30
2984.73
2819.42
2737.35
2033.45
1707.96
1376.29
1189.37
1014.68
938.97
822.24
745.92
692.77
460.27

3921.99
3778.25
3445.42
2930.86
2087.47
1815.01
1626.89
1409.75
1247.00
1117.88
1011.07
563.25

1 (BD)

1304.90
1204.59
1015.20
822.26
744.02
691.69
456.05

* Maximum shift in the frequency has been observed.

294

1(2B)

Fig-7.17: FTIR spectrums for Benzaldehyde + Ethyl Acetate mixture:

ACIC
St.Jos eph's College ( Autonomous )
Trichy-2

FTIR S PECT RUM

Date: 23-6-2010

ACIC
St.J os ep h's Colle g e ( Auto nomo us )
Trich y-2

FTIR S PECTR UM
Date: 21-1 2-200 9

23 42 .0 5

9 24 .5 5

3 824.49
5 44 .0 4

9 25 .0 1

27 38 .8 1

1 39 7.28

825.54

927.36

50
%T
1 28 9.65

2819.60

0.0
1594.54

30 00

2 000

1 500

100 0

400 .0

400 0.0

30 00

2 000

cm-1
30 00

20 00

1 50 0

1 00 0

40 0. 0

cm-1

1 500

100 0

R EF 4 000 99 .3 3 2000 9 4.6 7 600

3 92 8.23 97.09 34 46.8 4 6.3 2 2 819.60 52 .37 2 738 .80 6 3.2 8 2 363.70 95 .0 8
1 98 2.17 93.61 19 13.8 0 94. 42 1 824 .00 94.71 169 7.38 18. 33 15 94 .54 10.43
1 45 3.80 66.53 13 87.2 6 52. 24 1 310 .06 55.31 120 6.73 48. 10 11 69 .33 62.45
1 11 4.11 85.01 10 72.3 5 87. 37 1 015 .97 88.91 924 .10 9 3.6 2 8 25.54 55. 94
7 46 .17 35 .49 6 90. 95 41.50 651 .10 43.6 5 5 45.73 67. 86 45 2.9 1 69.9 0

T4-08_~1.S P 3601 4000.00 400.00 7.67 100.00 4.00 %T 5 1.00

REF 4000 98.47 2000 94.83 600

3426.97 28.43 3074.62 56.80 2822.34 64.77 2738.81 74.71 2543.76 90.90
2342.05 95.64 1982.50 94.39 1915.68 94.66 1700.87 9.07 1600.13 35.70
1397.28 59.71 1289.65 48.64 1207.65 43.35 1022.33 89.37 924.55 89.05
824.79 59.18 741.17 36.73 544.04 78.22 452.99 78.43

REF 4000 99.49 2000 93.14 600

3946.88 96.74 3402.54 26.54 3069.09 33.63 2825.68 38.79 2739.72 49.44
1983.45 92.59 1916.65 92.30 1698.37 7.67 1605.97 28.26 1400.35 47.52
1228.31 30.02 925.01 77.31 819.31 50.75 719.78 28.16 540.81 74.24
452.23 73.20

Spectrum Name: T4-0.4+0.6.sp

Spectrum Name: T4-0.3+0.7.sp

2669.71

80
1119.87

1637.15

1394.82

703.05

30
1763.76

1286.37

3425.57

20
690.23

1260.52

1248.47

1242.81

10
3430.96

4 00 .0

4 00 0. 0

1056.51

40
543.80

1403.64

4 00 0.0
3 0 00

20 00

cm -1

1685.89

3434.47

0 .0

1690.47

10 0 0

622.08
1378.64

50
%T

926.22

0. 0
15 00

2991.58

60
544.56

2996.97

20
20

692.06

20 00

930.37
1052.99
808.71

805.02

1248.62
1686.44

3 0 00

2362.08

2556.94
2833.61

50
%T
1056.78

701.69

1405.99

3442.32

4 00 0. 0

2088.87

2663.95

2552.21

1599.10

2999.42

2489.19

928.00

2352.41

2661.10

2992.63

3067.72

2089.94

1119.52

0. 0

FTIR SPECTRUM
Date: 3/11/2009
Spectrum Name: Cl-AN-1.sp

3944.19

1914.06

2828.90

543.85

928.09

400.0

1 0 0. 0

545.98

931.36
1416.36

811.86

2826.21
2997.04

1000

ACIC
St.Joseph's Colleg e ( Autono mous )
Trichy-2
FTIR SPECTRUM
Date: 23-6 -2010

1500
cm -1

2000

REF 4000 98.93 2000 95.20 600

3937.36 90.52 3824.09 86.52 3427.15 5.11 2996.89 48.88 2824.44 62.89
2738.24 73.70 2670.77 73.47 2557.58 73.29 2353.71 88.24 2087.20 94.54
1982.95 94.39 1914.00 92.78 1686.42 6.82 1402.21 36.22 1246.93 14.71
1056.49 54.95 927.51 56.11 811.14 49.50 690.96 21.84 544.62 48.94

Spectrum Name: T4-0.1+0.9.sp

60
816.01

3000

400.0

T4-05_~1.SP 3601 4000.00 400.00 5.11 99.54 4.00 %T 5 1.00

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

1062.06

2556.93

1000

T4-0.5+0.5.pk

1 00 .0

2740.53

50
1056.82

1500
cm-1

1916.25

3814.90

2558.07

2000

452.08
2669.85

454.80
2355.10

3000

REF 4000 98 .6 0 2000 92.52 600

3404.26 25. 71 30 69.00 52. 52 2821. 75 51.64 2738. 30 60.23 2338.90 94.09
1986.61 92. 20 19 12.24 93. 37 1704. 01 9. 00 1600.11 31.32 1451.57 61. 63
1389.34 51. 76 12 34.43 26. 85 1053. 37 65.10 921.84 89.99 825.35 51.00
744. 45 31. 91 689. 00 40. 61 45 2. 32 7 3. 64

3940.58

342 7.1 5

4000.0

T 4-0.6+0. 4. pk

1 00 .0

1119.47

2739.54

400.0

T 4-06_~1. SP 3 601 4000.00 400 .0 0 9 .0 0 9 9.80 4.00 %T 5 1.00

Spectrum Name: T4-0.2+0.8.sp

1915.24

1914.54

1000

REF 4000 99.54 2000 92.98 600

3940.27 95.72 3824.49 93.52 3408.17 21.31 3073.65 37.37 2823.61 43.92
2740.09 52.20 2554.09 67.40 1981.36 91.95 1915.75 91.37 1700.85 8.28
1601.44 31.42 1397.86 49.12 1234.35 31.64 1069.95 75.17 927.36 74.68
822.83 52.79 737.91 32.79 543.34 72.29 451.45 74.20

90
90

2089.29

1500

T4-07_~1.SP 3601 4000.00 400.00 8.28 99.84 4.00 %T 5 1.00

FTIR SPECTRUM
Date: 23-6 -2010

1 0 0. 0

1983.47

2000

T4-0.7+0.3.pk

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 23 -6-2010

16 86.42

0.0
3000

cm -1

ACIC
St.Joseph's Colleg e ( Autono mous )
Trichy-2

FTIR SPECTRUM
Date: 23 -6-2010

3928.98

1246 .9 3

0.0

1704.01

0.0
4000.0

T4-0.8+0.2.pk

T4-09_~1.S P 3601 4000.00 400.00 9.07 99.84 4.00 %T 5 1.00

ACIC
St.Joseph's Colleg e ( Autono mous )
Trichy-2

1 0 0. 0

690.96

10
10
170 0.8 5

400 .0

cm-1

T4-0.9+0.1.pk

SJ C-1BD.sp 36 01 4 000 .0 0 4 00.00 6.3 2 99. 90 4 .00 %T 5 1.00

544 .62

140 2.2 1

20
12 34.43

3404.26

0.0

400 0.0

0. 0

SJ C-1BD.pk

8 11.14
299 6.8 9

744.45

1600.11

16 98 .3 7

92 7.5 1
1 056 .49

737.91

3408.17

17 00 .8 7

82 5.35

68 9.00
1 234.35

1601.44

1697.38
3446.84

13 89.34
282 1.75

3 073.65

71 9.78

1 60 5.97

50
%T

306 9.00

2823 .61

34 02 .5 4

20
20

282 4.4 4

1397.86

1 22 8.31

34 26 .9 7

2738.30

8 22.8 3

28 25 .6 8

1 60 0.13

30 69 .0 9

690.95
746.17

198 2.9 5

25 57.58

452.32

1053.37
1451 .57

2740.09
7 41 .1 7

30
651.10

1206.73

12 07 .6 5

1387.26

45 1.45
543.34

1069 .95

2 554.09

8 19 .3 1
1 40 0.35

27 39 .7 2

40 00 . 0

382 4.0 9

1 912.2 4

82 4.79

30 74 .6 2

545.73

2 353.71

92 1.84

1 915.75

28 22 .3 4

452.91

1169.33

208 7.2 0191 4.0 0

273 8.2 4

233 8.90 19 86.61

198 1.3 6

39 40.2 7

45 2.23

45 2.99

60
1015.97
1310.06

1453.80

26 70.77
393 7.3 6

2738.80

100.0

Spec trum Name: T4-0.6+0.4.sp

100.0

5 40 .8 1

1 91 6.65

1114.11

1913.80

Spectrum Name: T4-0.5+0.5.s p

924.10

1982.17

FTIR S PECTRUM
Date: 23-6-2010

FT IR SPECT RUM
Date: 23 -6-2010

100.0

19 83 .4 5
1 02 2.33

1 91 5.68

2363.70

3928.23

3 94 6.88

19 82 .5 0
2 54 3.76

80
1072.35

FTIR SPECTRUM
Date: 23-6-2010
Spectrum Name: T4-0.7+0.3.sp

1824.00

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

Spectrum Name: T 4-0.8+0.2.s p

100.0

Sp ectrum Name: SJC-1BD.sp

10 0. 0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR S PECT RUM

Date: 23-6-2010

Spectrum Name: T 4-0.9+0.1.s p

100.0

15 00

10 0 0

cm -1

T4-0.4+0.6.pk

T4-0.3+0.7.pk

T4-04_ ~1.SP 3601 4000.00 400 .00 5.75 99.86 4.00 %T 5 1.0 0

T4-03_ ~1.SP 3601 4000.00 400 .00 7.89 99.82 4.00 %T 5 1.0 0

REF 4000 99.20 2000 9 4.56 600

3928.98 90.25 3442.32 5.75 2997.04 36.93 2826.21 48.37 2739.5 4 60.28
2669.71 59.20 2558.07 59.58 2355.10 82.30 2089.29 92.87 19 83.47 93.67
1914.54 90.96 1686.44 6.12 1405.99 33.11 1248.62 12.39 1119.8 7 65.48
1056.82 54.72 928.09 45.31 811.86 45.36 692.06 1 7.95 543.85 44.55
454.80 67.65

REF 4000 99.42 2000 9 5.74 600

3425.57 24.94 3067.72 44.25 2999.42 44.20 2828.90 48.65 27 40.53 61.46
2669.85 58.80 2556.93 59.51 1915.24 93.73 1690.47 7.89 1599.1 0 42.03
1416.36 50.30 1286.37 27.15 1119.47 80.61 1062.06 75.59 93 1.36 55.80
816.01 68.31 701.69 36.35 54 5.98 69.45 452.08 85.58

1698.70

0 .0
3 00 0

2 00 0

1 50 0

1 00 0

4 00 .0

4 00 0.0

3449.55

3 00 0

2 00 0

cm-1

4 00 .0

1 50 0

1 00 0

4 00 .0

cm-1

0. 0
4 00 0. 0

3 0 00

20 00

15 00

10 0 0

4 00 .0

cm -1

T4-0.2+0.8.pk

T4-0.1+0.9.pk

T4-02_~1.SP 3601 4000.00 400.00 6.38 99.99 4.00 %T 5 1.00

T4-01_~1.SP 3601 4000.00 400.00 7.67 100.00 4.00 %T 5 1.00

REF 4000 99.26 2000 88.24 600

3940.58 92.24 3814.90 88.53 3430.96 6.38 2992.63 51 .91 2661.10 69.15
2552.21 66.66 2352.41 74.98 1916.25 88.91 168 5.89 10.13 1403.64 31.61
1248.47 16.32 1119.52 55.26 1056.78 49.95 926 .22 40 .29 805.02 50.50
690.23 20.43 543.80 37.44

REF 4000 99.63 2000 96.95 600

3944.19 96.64 3434.47 9.28 2996.97 51.18 2833 .61 64.69 2663.95 74.61
2556.94 74.70 2089.94 95.37 1 914.06 96.4 9 1698.70 7.67 1394.82 39.57
1260.52 19.75 1052.99 65.44 9 30.37 69.32 808.71 67.28 703.05 35.76
544.56 62.42

Table - 7.18
Observations of FTIR spectrums for Benzaldehyde + Ethyl Acetate mixture:
1 (BD)

Cm-1

3928.23
3446.84
2819.60
2738.80
2363.70
1982.17
1913.80
1824.00
1697.38
1594.54
1453.80
1387.26
1310.06
1206.73
1169.33
1114.11
1072.35
1015.97
924.10
825.54
746.17
690.95
651.10
545.73
452.91

0.9(BD)

0.8(BD)

0.7(BD)

*0.6(BD)

0.5(BD)

0.4(BD)

0.3(BD)

0.2(BD)

0.1(BD)

0.1(EA)
Cm-1

0.2(EA)
Cm-1

0.3(EA)
Cm-1

0.4(EA)
Cm-1

0.5(EA)
Cm-1

0.6(EA)
Cm-1

0.7(EA)
Cm-1

0.8(EA)
Cm-1

0.9(EA)
Cm-1

3944.19
3434.47
2996.97
2833.61
2663.95
2556.94
2089.94
1914.06
1698.70
1394.82
1260.52
1052.99
930.37
808.71
703.05
544.56

3940.58
3814.90
3430.96
2992.63
2661.10
2552.21
2352.41
1916.25
1685.89
1403.64
1248.47
1119.52
1056.78
926.22
805.02
690.23
543.80

3425.57
3067.72
2999.42
2828.90
2740.53
2669.85
2556.93
1915.24
1690.47
1599.10
1416.36
1286.37
1119.47
1062.06
931.36
816.01
701.69
545.98
452.08

3928.98
3442.32
2997.04
2826.21
2739.54
2669.71
2558.07
2355.10
2089.29
1983.47
1914.54
1686.44
1405.99
1248.62
1119.87
1056.82
928.09
811.86
692.06
543.85
454.80

3937.36
3824.09
3427.15
2996.89
2824.44
2738.24
2670.77
2557.58
2353.71
2087.20
1982.95
1914.00
1686.42
1402.21
1246.93
1056.49
927.51
811.14
690.96
544.62

3404.26
3069.00
2821.75
2738.30
2338.90
1986.61
1912.24
1704.01
1600.11
1451.57
1389.34
1234.43
1053.37
921.84
825.35
744.45
689.00
452.32

* Maximum shift in the frequency has been observed.

295

3940.27
3824.49
3408.17
3073.65
2823.61
2740.09
2554.09
1981.36
1915.75
1700.85
1601.44
1397.86
1234.35
1069.95
927.36
822.83
737.91
543.34
451.45

3946.88
3402.54
3069.09
2825.68
2739.72
1983.45
1916.65
1698.37
1605.97
1400.35
1228.31
925.01
819.31
719.78
540.81
452.23

3426.97
3074.62
2822.34
2738.81
2543.76
2342.05
1982.50
1915.68
1700.87
1600.13
1397.28
1289.65
1207.65
1022.33
924.55
824.79
741.17
544.04
452.99

1(EA)

Cm-1

3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08

Fig-7.18: FTIR spectrums for Benzyl Chloride + 2-Butanone mixture:

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

100.0

FTIR SPECT RUM

Date: 2/23/2008

22 35.79

Spectrum Name: Sam =3.s p

100.0

213 9.83

20 27 .0 8

9 23 .4 3

2 13 9.0 3

1 01 2.1 8
1 072 .2 8

19 10 .17

65 0.60

6 50.23

82 6.70

6 88.70

1 454 .6 1 1 310 .20

306 6.7 2

27 38.47

13 91.15

28 18.73

7 47 .3 9

689 .19
11 68 .19
3 393 .99

1204.32

159 6.1 8

1597.13

120 3.8 3
747 .7 8

747.33

10
17 02 .00

3000

2000

15 00

100 0

400.0

0 .0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

40 00.0

cm-1

3 000

2000

1500

1000

SAM_1~1.SP 3601 4000.00 400.00 8.04 99.86 4.00 %T 3 1.00

SAM_2~1.SP 3601 4000.00 400.00 9.18 99.98 4.00 %T 3 1.00

SAM_3~2.SP 3601 4000.00 400.00 9.36 99.92 4.00 %T 3 1.00

REF 4000 99.14 2000 89.33 600

3394.11 31.28 3072.11 51.40 2818.42 48.88 2738.34 53.57 2372.89 93.94
2330.26 93.64 2235.79 97.53 2139.83 96.21 2026.52 89.18 1982.86 86.85
1911.14 88.44 1826.50 87.25 1701.69 8.03 1596.72 33.01 1454.12 61.66
1392.85 56.13 1308.72 56.19 1204.25 35.78 1166.91 52.28 1109.92 80.91
1073.38 80.67 1012.73 81.15 922.40 89.82 826.07 47.98 746.86 29.08
688.87 42.31 650.60 46.50 450.67 70.58

REF 4000 99.84 2000 93.13 600

3392.13 50.39 3067.40 62.67 2818.44 55.53 2738.20 59.65 2367.01 92.64
2332.27 92.66 2236.38 98.68 2139.34 97.78 2027.08 92.62 1983.03 91.02
1910.17 92.08 1826.27 90.69 1702.00 9.18 1655.24 45.74 1595.90 39.27
1454.70 65.13 1392.10 63.91 1310.13 60.34 1204.12 38.07 1166.83 55.09
1108.54 86.82 1072.28 83.86 1012.18 85.07 923.43 91.83 826.70 50.84
747.06 31.09 688.70 46.57 650.23 51.30 450.89 74.49

REF 4000 99.12 2000 92.30 600

3396.11 35.96 3070.63 61.26 2818.50 59.99 2738.21 64.26 2373.11 95.85
2330.79 96.13 2235.76 98.05 2139.03 96.82 2027.29 91.74 1983.09 90.43
1911.42 91.70 1825.70 90.59 1701.38 9.35 1654.81 41.64 1596.48 40.79
1454.41 67.49 1392.53 62.65 1310.26 62.41 1204.34 41.37 1166.82 58.69
1109.80 84.41 1072.43 84.63 1012.95 86.94 923.24 91.48 826.64 53.85
746.91 33.76 688.63 47.68 650.17 51.53 450.96 74.90

REF 40 00 99 .3 4 20 00 9 2 .99 600

33 9 6.05 3 9.35 3 0 69.4 1 54.0 6 281 8. 69 48. 05 27 38 .46 54 .69 2 32 9.9 1 9 6.2 6
21 3 8.94 9 7.57 1 9 83.0 9 91.3 5 191 1. 55 92. 50 18 26 .24 91 .44 1 70 3.5 3 8 .98
15 9 7.13 3 4.18 1 4 53.9 9 62.7 4 139 1. 81 57. 85 13 08 .28 56 .99 1 20 4.3 2 3 8.1 6
11 6 8.77 4 8.45 1 1 09.3 3 84.9 0 107 3. 80 83. 60 10 11 .83 84 .65 9 25 .2 8 91 .7 7
82 5 .98 50 .4 5 7 47. 33 31 .29 69 0 .0 5 46 .11 6 51.0 3 50 .52 45 1.1 9 73.8 7

1500

1000

REF 4000 99.20 2000 90.29 600

3393.99 32.63 3066.72 49.01 2981.95 58.79 2818.73 40.37 2738.47 45.18
2405.59 95.68 2329.51 94.80 2138.99 96.05 2027.34 89.59 1984.22 87.57
1911.03 89.28 1826.92 87.47 1703.87 7.35 1596.18 27.64 1454.61 48.79
1391.15 47.10 1310.20 49.05 1203.83 28.43 1168.19 36.29 1106.93 83.07
1073.17 76.76 1011.61 79.05 928.64 87.21 826.38 40.72 747.78 22.49
689.19 37.55 650.30 41.85 451.17 66.64

FTIR SPECTRUM
Date: 2/21/2008

Spectrum Name: Sam = 1 0.sp

Spectrum Name: Sam = 1 1.sp

1 00 .0

1 00 .0
2339.69

1024.29

3399.05

2983.47
2819.42

1387.82

1169.24

1596.94

938.37

2984.67

548.46
752.00

1289.16

%T
934.40

40
1597.56

3446.56

933.60

2823.30

40
747.32

746.48 654.22

1451.42

1204.29

2370.90

593.27
2558.19

1596.96
747.69

2098.22

3069.90

689.04

1204.37

547.41

2668.13

50
%T

1170.93

2552.77

594.50

805.24

2558.32

826.81
650.21

691.22

750.45

1073.49

547.54
821.56

1126.20

1324.68

70
1124.97

2736.41
1454.30

1311.01
1391.35

1072.21

2670.86

70
2819.21
2984.11

650.64

1024.90

1916.64
450.85

80
451.46

1073.33

826.54

1025.96

1917.31

451.50

2738.64

1309.35

400.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 2/21/2008

Spectrum Name: Sam = 9 .sp

1453.55

3069.09

1000

SAM_6~1.SP 3601 4000.00 400.00 7.36 99.92 4.00 %T 3 2.00

4 00 . 0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

90
1016.45
933.56

935.87

2738.97

1500
c m -1

REF 4000 99.81 2000 96.51 600

3393.76 58.42 3067.49 63.29 2818.81 62.12 2738.32 68.14 2331.93 97.79
1982.81 95.37 1912.98 95.82 1825.18 95.14 1703.44 8.94 1595.99 47.21
1454.20 67.73 1391.37 65.94 1310.66 63.92 1204.91 43.62 1168.61 55.98
1109.98 86.79 1072.58 87.48 1015.10 90.79 930.45 92.50 826.77 60.21
747.39 38.72 689.11 55.98 650.24 59.36 451.16 82.34

1 00 .0

1109.88

2000

SAM_5~2.SP 3601 4000.00 400.00 8.95 99.98 4.00 %T 3 1.00

1 0 00

FTIR SPECTRUM
Date: 2/21/2008

1984.33

1012.35

3000

SAM _4 ~1.S P 3 601 40 0 0.0 0 4 00 .0 0 8 .9 9 9 9 .8 7 4.0 0 % T 3 1 .0 0

1 50 0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

Spectrum Name: Sam = 8 .sp

1983.33

4000 .0

Sam =4. pk

2 0 00

1110.76

400.0

Sam = 6.pk

30 00

cm -1

FTIR SPECTRUM
Date: 2/21/2008
1 00 .0

2000

Sam = 5.pk

4 0 00 . 0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

Spectrum Name: Sam = 7 .sp

3 000

cm-1

Sam = 3.pk

1 00 .0

0.0

40 00.0

1703.53

0 .0

Sam = 2.pk

FTIR SPECTRUM
Date: 2/21/2008

1 703 .87

0 .0

400.0

c m -1

Sam =1.pk

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

10
17 03.44

170 1.38

0.0

4000.0

17 01 .69

0.0

6 50.30

8 26.38

690.05

451 .17

1 204 .9 1
651.03

825.98
1168.77

3396.05

101 1.6 1
107 3.1 7

65 0.24

826 .7 7

116 8.61

6 89 .11

1391.81

2818.69

7 46 .9 1

1 911 .0 3
2 981 .95

1 310 .6 6

15 95.99

2738.46

3069.41

15 96.48

3 396 .1 1

74 7.06

9 28.64

1308.28

50
%T

1 204 .3 4

12 04.12

74 6.86

1 826 .9 2

1 39 1.37

3 393 .7 6

50
%T
1453.99

15 95 .9 0

12 04 .2 5
15 96 .7 2

3 394 .1 1

2 027 .3 4
198 4.2 2

14 54 .20

3 067 .4 9
281 8.81

451.19

6 88 .6 3

688 .8 7

232 9.51

45 1.16

273 8.32

1109.33
1011.83

65 0.1 7

1 106 .93

925.28
1826.24

70
826 .6 4

24 05.59
9 30 .45

1 072 .5 8

1911.55
1983.09

13 92 .53
1 310 .2 6 1 16 6.8 2

11 66.83

19 12 .98

1073.80

2138.94
2329.91

16 54 .81 1 45 4.41

273 8.21
3 070 .6 3
281 8.50

13 10 .1 3

33 92 .1 3
82 6.07

45 0.96

1 39 2.10

2 73 8.2 0

2 818 .4 4

116 6.91

80
1 45 4.70

3 067 .4 0

13 08 .7 2

16 55.24

1 39 2.85

19 82 .81 18 25 .18

101 5.10

1 00 .0

1 072 .4 3
450 .8 9

45 0.67

14 54 .1 2

27 38 .3 4
3 072 .1 1
28 18 .4 2

FTIR SPECTRUM
Date: 2/21/2008

2 138 .99

11 09.98

2 331 .9 3

Spectrum Nam e: Sam = 4.s p

9 23 .24
10 12 .95

1 825 .7 0

19 83 .09

1 01 2.7 3

19 11 .42

202 7.29

11 09 .9 2

FT IR SPECT RUM
Date: 2/23/ 2008

1 10 9.80

23 30.79

23 32.27 19 83.03 1 82 6.27

Spectrum Name: Sam = 6.sp

10 0.0

22 35 .7 6

23 67 .0 1
9 22 .4 0

1 82 6.50
19 82.86
19 11 .14

2 373 .1 1

213 9.34

20 26 .5 2
2 33 0.2 6

Spectrum Name: Sam =5.s p

10 0.0

1 10 8.5 4

22 36.38
107 3.38
2 37 2.89

ACIC
St.Joseph's College ( Autonomous )
Trichy-2
FTIR SPECTRUM
Date: 2/23/2008

ACIC
St.J os ep h 's C olleg e ( Aut onom o us )
T richy-2

FTIR SPECTRUM
Date: 2/23/2008

Spectrum Name: Sam = 2.sp

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 2/23/2008
Spectrum Name: Sam =1.sp

1453.62

1174.81

708.66

1176.11

1418.90

2985.42

1419.42

2987.29

706.48
707.39

1288.32

1289.26

1172.99

1374.94

3446.41
3450.46

1705.87

4 00 0.0

0 .0
3 00 0

2 00 0

1 50 0

1 00 0

4 00 .0

4 00 0.0

cm-1

2 00 0

1 50 0

1 00 0

4 00 .0

3449.47

1690.02

0 .0
3 00 0

1698.20

1703.56

0 .0

4 00 0.0

3 00 0

cm-1

2 00 0

1 50 0

1 00 0

4 00 .0

1724.52

0 .0

4 00 0.0

3 00 0

2 00 0

cm-1

1 50 0

1 00 0

4 00 .0

4 00 0.0

3 00 0

2 00 0

cm-1

1 50 0

1 00 0

4 00 .0

cm-1

Sam = 7.pk

Sam = 8.pk

Sam = 9.pk

Sam = 10.pk

Sam = 11.pk

SAM_7~1.SP 3601 4000.00 400.00 9.19 99.85 4 .00 %T 3 2.0 0

SAM_8~1.SP 3601 4000.00 400.00 8.38 99.85 4 .00 %T 3 2.0 0

SAM_9~1.SP 3601 4000.00 400.00 6.87 99.57 4 .00 %T 3 2.0 0

SAM_10~1.SP 3601 4000.00 400.00 6.95 99.68 4.00 %T 3 2.00

SAM_11~1.SP 3601 4000.00 400.00 6.34 99.25 4.00 %T 3 1.00

REF 4000 99.75 2000 96.32 600

3399.05 57.33 3069.09 63.15 2983.47 64.86 281 9.42 62.71 2738.97 69.66
1983.33 95.46 1705.87 9.19 1596.94 49.46 1453.55 66 .53 1387.82 62.11
1309.35 64.96 1204.37 45.42 1170.93 52.92 110 9.88 86.60 1012.35 90.83
935.87 90.76 826.54 64.55 747 .69 44 .24 691.22 60.37 650.64 64.96
451.50 86.71

REF 4000 99.10 2000 95.75 600

3446.56 36.47 2984.11 68.93 2819.21 67.88 273 8.64 73.35 1984.33 94.86
1703.56 8.37 1596.96 48.66 1454.30 65.93 1391.35 61 .11 1311.01 65.22
1204.29 44.16 1169.24 54.53 1110.76 84.92 107 3.33 86.65 1016.45 91.12
933.56 91.56 826.81 61.89 747 .32 41 .10 689.04 54.92 650.21 58.33
451.46 83.18

REF 4000 99.46 2000 90.97 600

3446.41 23.54 3069.90 45.63 2984.67 40.80 282 3.30 51.11 2736.41 61.18
2670.86 59.71 2558.19 59.51 1917.31 89.76 169 8.20 6.87 1597.56 43.17
1451.42 54.01 1418.90 40.44 1288.32 28.23 117 4.81 42.16 1124.97 74.46
1072.21 80.23 1024.29 90.34 933.60 51.24 821.56 67.89 746 .48 51.87
706.48 31.65 654.22 52.72 547 .54 68 .63 450.85 87.84

REF 4000 99.53 2000 95.68 600

3450.46 19.61 2985.42 39.89 2668.13 69.66 255 8.32 67.90 1916.64 94.53
1690.02 6.95 1419.42 38.35 1324.68 46.40 1289.26 27 .86 1176.11 42.53
1126.20 77.73 1073.49 84.46 1025.96 94.37 934 .40 50 .29 805.24 77.29
750.45 79.91 707.39 30.60 594 .50 76 .48 547.41 69.65

REF 4000 99.25 2000 84.80 600

3449.47 6.34 2987.29 35.70 2552.77 91.18 2370.90 75 .22 2339.69 84.29
2098.22 82.03 1724.52 7.85 1453.62 48.10 1374.94 24 .73 1289.16 60.26
1172.99 28.20 1024.90 96.34 938.37 70.56 752.00 64.59 708 .66 45.53
593.27 58.47 548.46 67.08

Table - 7.19
Observations of FTIR spectrums for 2-Butanone + Ethyl Acetate
0.9(BC)

0.8(BC)

0.7(BC)

0.6(BC)

*0.5(BC)

0.4(BC)

0.3(BC)

0.2(BC)

0.1(BC)

Cm-1

0.1(2B)
Cm-1

0.2(2B)
Cm-1

0.3(2B)
Cm-1

0.4(2B)
Cm-1

0.5(2B)
Cm-1

0.6(2B)
Cm-1

0.7(2B)
Cm-1

0.8(2B)
Cm-1

0.9(2B)
Cm-1

Cm-1

3394.11
3072.11
2818.42
2738.34
2372.89

3392.13
3067.40
2818.44
2738.20
2367.01

3396.11
3070.63
2818.50
2738.21
2373.11

3396.05
3069.41
2818.69
2738.46
2329.91

3393.76
3067.49
2818.81
2738.32
2331.93

2330.26
2235.79
2139.83
2026.52
1982.86

2332.27
2236.38
2139.34
2027.08
1983.03

2330.79
2235.76
2139.03
2027.29
1983.09

2138.94
1983.09
1911.55
1826.24
1703.53

1982.81
1912.98
1825.18
1703.44
1595.99

1911.14
1826.50
1701.69
1596.72
1454.12

1910.17
1826.27
1702.00
1655.24
1595.90

1911.42
1825.70
1701.38
1654.81
1596.48

1597.13
1453.99
1391.81
1308.28
1204.32

1454.20
1391.37
1310.66
1204.91
1168.61

1392.85
1308.72
1204.25
1166.91
1109.92

1454.70
1392.10
1310.13
1204.12
1166.83

1168.77
1109.33
1073.80
1011.83
925.28

1109.98
1072.58
1015.10
930.45
826.77

3446.56
2984.11
2819.21
2738.64
1984.33
1703.56
1596.96
1454.30
1391.35
1311.01
1204.29
1169.24
1110.76
1073.33
1016.45
933.56
826.81
747.32
689.04
650.21
451.46

3449.47
2987.29
2552.77
2370.90
2339.69
2098.22
1724.52
1453.62
1374.94
1289.16
1172.99
1024.90
938.37
752.00
708.66
593.27
548.46

1108.54
1072.28
1012.18
923.43

747.39
689.11
650.24
451.16

688.87
650.60
450.67

747.06
688.70
450.89

825.98
747.33
690.05
651.03
451.19

3446.41
3069.90
2984.67
2823.30
2736.41
2670.86
2558.19
1917.31
1698.20
1597.56
1451.42
1418.90
1288.32
1174.81
1124.97
1072.21
1024.29
933.60
821.56
746.48
706.48
654.22
547.54
450.85

3450.46
2985.42
2668.13
2558.32
1916.64
1690.02
1419.42
1324.68
1289.26
1176.11
1126.20
1073.49
1025.96
934.40
805.24
750.45
707.39
594.50
547.41

1073.38
1012.73
922.40
746.86

1454.41
1392.53
1310.26
1204.34
1166.82
1109.80
1072.43
1012.95
923.24
746.91
688.63
450.96

3399.05
3069.09
2983.47
2819.42
2738.97
1983.33
1705.87
1596.94
1453.55
1387.82
1309.35
1204.37
1170.93
1109.88
1012.35
935.87
826.54
747.69
691.22
650.64
451.50

1 (BC)

3393.99
3066.72
2981.95
2818.73
2738.47
2405.59
2329.51
2138.99
2027.34
1984.22
1911.03
1826.92
1703.87
1596.18
1454.61
1391.15
1310.20
1203.83
1168.19
1106.93
1073.17
1011.61
928.64
747.78
689.19
650.30
451.17

* Maximum shift in the frequency has been observed.

296

1(2B)

Fig-7.19: FTIR spectrums for Ethyl Acetate + Benzyl Chloride mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/14/2009

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 1.sp

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 3.sp

100.0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 2.sp

100.0

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 4.sp

100.0

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 5.sp

100.0

Spectrum Name: EA+BC- 6.sp

100.0

3 964.11

3918.91

2084.37

3921.12
2340.59

3957.8 7

3775.26

3775.5 3

1 889.30

70
3067.61

1817.37

3776.47

1381.27
2965.86

1723.04

620.59

13 89.69

1610.33

1451.41

1956 .79

1000

400.0

3000

2000

1500

1000

400.0

1761.67

3000

2000

1500

1451.06

400.0

1265.27

10
694.94

3000

2000

1500

1000

400.0

0.0

4000.0

3000

2000

1500

cm -1

EA+BC-3.pk

695.62

0.0

4000.0

1000

400.0

4000.0

3000

cm -1

EA+BC-4.pk

2000

1500

1000

EA+BC-5.pk

EA+BC-6.pk

EA_BC-~4. SP 3601 4000.00 4 00. 00 6.33 99.84 4.00 %T 5 1.00

EA_BC-~1. SP 3601 4000.00 4 00. 00 6.35 99.94 4.00 %T 5 1.00

EA_BC-~2. SP 3601 4000.00 4 00. 00 8.83 100.00 4.00 %T 5 1.00

EAE083~1. SP 3601 4000.00 4 00. 00 7.15 100.00 4.00 %T 5 2.00

EAE883~1. SP 3601 4000.00 4 00. 00 6.95 100.00 4.00 %T 5 2.00

EAE093~1. SP 3601 4000.00 4 00. 00 8.67 99.99 4.00 %T 5 2.00

REF 4000 98.26 2000 61.61 600

3964.11 93.33 3776.47 67.73 3437. 83 6.35 2928.87 40.87 2115.59 58.76
1817.37 68.83 1723.04 57.79 1610. 33 34.28 1379. 47 44. 37 1242. 98 36. 73
1118.19 31.32 697.37 35.99 620.03 43. 80 559.44 49.88

REF 4000 98.23 2000 95.06 600

3918.91 96.12 3775.26 84. 22 3451. 07 10.0 9 3067.61 48.72 3034. 19 45.50
2965.86 58.33 2340.59 92. 81 2084. 37 94.0 0 1957.48 89.45 1889. 30 92.01
1763.12 55.78 1625.53 52. 11 1492. 95 67.4 8 1451.41 45.74 1381. 27 62.42
1253.88 23.09 1107.37 60. 80 1067. 81 55.7 3 927. 99 89.85 809. 62 64. 19
760.92 51.5 2 695. 67 8.82 559.29 50.52 467.04 68.36

REF 4000 97.79 2000 53.46 600

3921.12 94.46 3774.33 75. 22 3436. 06 23.0 1 3033.29 24.66 1956. 79 47.84
1891.42 50.22 1761.67 27. 52 1599. 84 37.4 7 1450.39 27.33 1377. 21 36.99
1249.46 8. 69 1061.68 28.92 928.36 51.66 810.08 38.59 759. 95 31.90
695.28 7.15 559.59 40.30 466.15 57.44

REF 4000 98.98 2000 73.22 600

3775.53 88.58 3433.62 55. 25 3033. 16 39.2 5 2961.40 51.44 1955. 96 67.24
1889.21 69.55 1764.05 65. 42 1598. 56 60.0 1 1493.24 56.73 1451. 21 38.77
1381.19 66.13 1264.45 25. 83 1071. 85 55.6 1 927. 66 71.26 810. 37 53. 78
761.09 45.5 0 694. 94 6.95 559.24 54.20 465.43 72.70

REF 4000 98.18 2000 71.48 600

3916.71 95.98 3776.62 84.25 3435. 76 43.35 3033. 47 37. 84 2961. 25 48. 64
1956.21 65.29 1889.50 67.83 1811. 99 69.25 1765. 78 67. 67 1598. 42 55. 26
1492.95 56.29 1451.06 39.15 1265. 27 27.62 1072. 82 53. 03 1031. 02 59. 53
927.48 67.8 8 810.22 50. 27 760.92 42.27 695. 62 8.67 559.42 51.00
465.89 68.1 8

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/14/2009

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 7.sp

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 8.sp

100.0

FT IR SPECT RUM
Date: 2/14/2009

Spectrum Name: EA+BC- 9.sp

Spectrum Name: EA+BC- 11.sp

100.0

FTIR SPECTRUM
Date: 2/14/2009

3908.14

400.0

cm -1

REF 4000 75.33 2000 41.99 600

3957.87 72.68 3776.13 59.06 3443. 70 6.33 2990.70 33.10 2375.94 39.21
2106.73 40.14 1766.66 38.80 1607. 16 27.22 1389. 69 38. 26 1243. 16 26. 83
1114.03 32.93 620.59 45.10

100.0

559.42

760.92
3033.47

1264.45

10
695.28

1249.46

1000

cm -1

EA+BC-2.pk

1450.39

695.67

0.0

4000.0

cm -1

EA+BC-1.pk

761.09

3436.06

10
3451.07

0.0

4000.0

810.22

1492.95

1451.21

1377.21

465.89

1072.82

1061.68

3033.29

20
1253.88

10
3437.83

1500
cm -1

559.24

3033.16

8 10.08

1599.84

2000

810.37

759.95

0.0
3000

927.48

1031.02
1598.42

1071.85
1493.24

2961.40

29 61.25

1118.19

1243.16

344 3.70

4000.0

1 889.50
1956 .21 17 65.78

1381.19

3433.62

3435.76

697.37

1 114.03
1607.16

465.43

17 64.05

50
%T

928.36

1891.42

559.59
1242.98

237 5.94

2990.70

0.0

181 1.99

70
927.66

1889.21
1955 .96

466.15

%T
559.29

2928 .87
1766.66

3776.62

1598.56

760.92

3034.19

620.03

13 79.47
210 6.73

3774.33

1067.8 1

1625.53

1107.37

1763.12

%T
559.44

8 09.62
1492.95

50
%T

467.04

2115.59
3776.13

50
%T

3916 .71

927.99

1957 .48

100.0

Spec trum Name: EA+BC-10.sp

1810.23

3906.50

10 0. 0
80

3773.20

3773.85

80
90

2524.74

3774.7 0

3772.2 9

2709.24

1889.76

2 338.23

1891.62

80
927.24

2869.48

811.07

2961.58

60
1208.69

758.79
344 6.99

1451.38

3432.65

1500

1000

3000

2000

1500

400.0

4000.0

3000

2000

1500

1000

1027.31
1 600.22

3034.41
126 6.87

694.99

0.0
4000.0

695.01

3000

2000

20 00

1 50 0

1 0 00

4 00 .0

EA+BC-10.pk

EA_BC-~3. SP 3601 4000.00 4 00. 00 7.32 99.99 4.00 %T 5 1.00

EAE8A3~1.SP 3601 4000. 00 400.00 7.31 10 0.00 4. 00 %T 5 2.00

REF 4000 98.72 2000 81.52 600

3908.14 96.36 3773.20 87.62 3446. 99 35.66 3034. 34 33. 30 2961. 58 45. 87
2869.48 66.48 2709.24 78.12 2524. 74 80.31 2338. 23 75. 23 1956. 02 69. 47
1889.76 73.30 1810.23 74.35 1761. 76 74.92 1601. 62 56. 57 1493. 38 55. 11
1451.38 36.25 1265.76 25.95 1209. 60 54.50 1161. 44 58. 88 1073. 99 51. 88
1029.68 60.99 927.24 70.66 809.95 48. 15 758.79 38.23 695.21 7.31
559.57 47.3 1 465.40 64. 47

REF 4000 98.97 2000 71.06 600

3773.85 87.59 3435.20 49. 88 3033. 88 34.3 2 2960.87 47.62 2868. 79 63.95
2336.49 69.32 1956.00 63. 59 1890. 40 66.4 6 1811.93 67.89 1600. 27 57.82
1493.61 53.47 1451.51 36. 27 1266. 47 26.2 2 1208.69 55.80 1073. 76 54.70
1028.04 62.74 927. 51 69.32 810.70 49.54 759.61 40.26 694. 82 7.31
559.42 51.0 3 465. 61 70.35

1500

1000

400.0

cm -1
3 0 00

c m -1

EAE893~1. SP 3601 4000.00 4 00. 00 7.45 99.99 4.00 %T 5 2.00

759.02

1451.17

10
400.0
4 00 0 .0

REF 4000 98.09 2000 60.09 600

3774.70 84.76 3435.13 41.14 3034. 24 36.80 2961. 08 46. 92 1956. 43 55. 84
1891.62 57.84 1814.22 59.48 1600. 19 48.94 1493. 15 50. 68 1451. 65 35. 85
1266.03 26.31 1073.74 48.88 928.4 7 60.94 811. 07 48. 01 760.48 41.33
694.87 7.45 558.97 47.51 4 66. 13 65.92

1207 .69

1493 .17

2960.75

0. 0

cm -1

EA+BC-9.pk

559.37
810.55

3435.57

1265.93

1000

cm -1

EA+BC-8.pk

927.39

181 1.47
1890.06
1956.03
1074.43

760.18

20
694.82

0.0

4000.0

cm -1

810.96

1451.82

10
695.21

0.0
400.0

1493.40

40
126 6.47

126 5.76

10
694.87

2000

EA+BC-7.pk

2960.91

559.62

1451.51

3033.50

0.0

2336.46
2868.60

1073.25

3033.88

465.12
2708.50

50
%T
1599.21

3034.34
126 6.03

927.60

1955.94

559.42

810.70

2960.87

466.26

1812.72
1890.82

1073.76
149 3.61

3435.20
559.57

3773.89

1028.04
1600.27

%T
8 09.95

759.61

1451.65
3034.24

3000

465.61

1956 .00
181 1.93

1073.9 9
1209.60

760.48

4000.0

2868.79

1601.62
1493.38

558.97

2961 .08
3435.13

927.51
1 890.40

465.40
1029.68

50
%T

181 4.22
1073.74

2336.49

1761.76

928.47

1956.4 3

1600.19

1161.44

1956 .02
466.13

1493 .15

EA+BC-11. pk
EA9C82~1.SP 3601 4000.00 400.00 7. 08 99. 91 4.00 %T 5 2. 00

EA9C8E~1. SP 3601 4000.00 400.00 7.68 100.00 4.00 %T 5 2.00

REF 4000 99.10 2000 73.01 600
3773. 89 89. 40 3432.65 57.28 3033.50 43.83 2960. 91 56.07 1955.94 68.06
1890. 82 70. 10 1812.72 71.44 1599.21 61.13 1493. 40 59.52 1451.82 42.89
1265. 93 31. 38 1073.25 59.33 927.60 71.78 810.96 56.08 760.18 47.55
695.01 7.68 559.62 58. 26 466.26 75.75

REF 4000 98.47 2000 59.62 600

3906.50 94.80 3772.29 83.63 3435. 57 39.14 3034. 41 25. 24 2960. 75 35. 21
2868.60 51.22 2708.50 60.11 2336. 46 56.86 1956. 03 48. 63 1890. 06 51. 79
1811.47 53.04 1600.22 42.75 1493. 17 41.14 1451. 17 26. 63 1266. 87 19. 47
1207.69 41.07 1074.43 41.36 1027. 31 49.25 927.39 55.87 810. 55 38. 57
759.02 31.1 1 694.99 7.08 5 59. 37 42.03 465.12 60.85

Table - 7.20
Observations of FTIR spectrums for Ethyl Acetate + Benzyl Chloride mixture:
0.9(EA)

0.8(EA)

0.7(EA)

0.6(EA)

0.5(EA)

0.4(EA)

*0.3(EA)

0.2(EA)

0.1(EA)

Cm-1

0.1(BC)
Cm-1

0.2(BC)
Cm-1

0.3(BC)
Cm-1

0.4(BC)
Cm-1

0.5(BC)
Cm-1

0.6(BC)
Cm-1

0.7(BC)
Cm-1

0.8(BC)
Cm-1

0.9(BC)
Cm-1

Cm-1

3957.87
3776.13
3443.70
2990.70
2375.94

3964.11
3776.47
3437.83
2928.87
2115.59
1817.37
1723.04
1610.33
1379.47
1242.98
1118.19
697.37
620.03
559.44

3918.91
3775.26
3451.07
3067.61
3034.19
2965.86
2340.59
2084.37
1957.48
1889.30

3921.12
3774.33
3436.06
3033.29
1956.79
1891.42
1761.67
1599.84
1450.39
1377.21
1249.46
1061.68
928.36
810.08
759.95
695.28
559.59
466.15

3775.53
3433.62
3033.16
2961.40
1955.96
1889.21
1764.05
1598.56
1493.24
1451.21
1381.19
1264.45
1071.85
927.66
810.37
761.09
694.94
559.24
465.43

3916.71
3776.62
3435.76
3033.47
2961.25
1956.21
1889.50
1811.99
1765.78
1598.42
1492.95
1451.06
1265.27
1072.82
1031.02
927.48
810.22
760.92
695.62
559.42
465.89

3774.70
3435.13
3034.24
2961.08
1956.43
1891.62
1814.22
1600.19
1493.15
1451.65
1266.03
1073.74
928.47
811.07
760.48
694.87
558.97
466.13

3908.14
3773.20
3446.99
3034.34
2961.58
2869.48
2709.24
2524.74
2338.23
1956.02
1889.76
1810.23
1761.76
1601.62
1493.38
1451.38
1265.76
1209.60
1161.44
1073.99
1029.68
927.24
809.95
758.79
695.21
559.57
465.40

3773.85
3435.20
3033.88
2960.87
2868.79
2336.49
1956.00
1890.40
1811.93
1600.27
1493.61
1451.51
1266.47
1208.69
1073.76
1028.04
927.51
810.70
759.61
694.82
559.42
465.61

3773.89
3432.65
3033.50
2960.91
1955.94
1890.82
1812.72
1599.21
1493.40
1451.82
1265.93
1073.25
927.60
810.96
760.18
695.01
559.62
466.26

3906.50
3772.29
3435.57
3034.41
2960.75
2868.60
2708.50
2336.46
1956.03
1890.06
1811.47
1600.22
1493.17
1451.17
1266.87
1207.69
1074.43
1027.31
927.39
810.55
759.02
694.99
559.37
465.12

1 (EA)

2106.73
1766.66
1607.16
1389.69
1243.16
1114.03
620.59

1763.12
1625.53
1492.95
1451.41
1381.27
1253.88
1107.37
1067.81
927.99
809.62
760.92
695.67
559.29
467.04

* Maximum shift in the frequency has been observed.

297

1(BC)

Fig-7.20: FTIR spectrums for Ethyl Acetate + 2-Butanone mixture:

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

2489.19

2488.21

2089.05

1164.40

2489.94

3755.77

931.02

1409.82

Spec trum Name: Cl-AN-6.sp

1165.69

10 0. 0

2090.50

2093.87

3778.13

1245.49

2378.86
3768.93

2376.34
2928.83

1110.28

935.24
2091.95

932.09

2375.18

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-5.sp

10 0. 0

2089.01
2365.16
2369.39

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-4.sp

10 0. 0

928.00

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-3.sp

10 0. 0

2088.87
2362.08

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-2.sp

10 0. 0

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-1.sp

10 0. 0

1418.32

1739.40

1168.70
1244.60

1113.89

1049.78
2991.58

1021.27

622.08
1378.64

622.77

623.89

1373.67

577.76

1056.34

595.26

2990.28

574.78

1056.51

%T
40

2990.51
1376.73

%T
40

50
2990.49

%T
40

1056.63

1637.33

1375.96

1056.35

1637.15

1637.35

1637.41

1757.15

1637.90

1636.17

1242.87

1763.76

1762.32
1242.81

1761.48

1242.82
3449.55

3449.85

0. 0
3 0 00

20 00

1 50 0

1 0 00

4 00 .0

3450.69

0. 0

4 00 0 .0

3 0 00

20 00

c m -1

1 50 0

1 0 00

4 00 .0

3450.23

0. 0

4 00 0 .0

1242.79

3450.45

0. 0

4 00 0 .0

3 0 00

20 00

c m -1

1 50 0

1 0 00

4 00 .0

0. 0

4 00 0 .0

3 0 00

20 00

c m -1

1 50 0

1 0 00

4 00 .0

0. 0

3447.05

4 00 0 .0

3 0 00

20 00

c m -1

1 50 0

1 0 00

4 00 .0

4 00 0 .0

c m -1

3 0 00

20 00

1 50 0

1 0 00

Cl-AN-2.pk

Cl-AN-3.pk

Cl-AN-4.pk

Cl-AN-5.pk

Cl-AN-6.pk

Cl-AN-1.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00

Cl-AN-2.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00

Cl-AN-3.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00

Cl-AN-4.sp 3601 4000.00 400. 00 6.34 99.75 4.00 %T 5 1.00

Cl-AN-5.sp 3601 4000.00 400. 00 6.34 99.61 4.00 %T 5 1.00

Cl-AN-6.sp 3601 4000.00 400. 00 6.34 99.58 4.00 %T 5 1.00

REF 4000 99.39 2000 97.58 600

3449. 55 6.33 2991.58 69.36 2489. 19 98.54 2362. 08 89. 00 2088.87 95.42
1763. 76 32. 63 1637.15 43.78 1378.64 67.05 1242. 81 18.73 1056.51 55.12
928.00 97. 75 622.08 69.86

REF 4000 98.71 2000 96.65 600

3449. 85 6.33 2369.39 92.94 2089. 05 94.90 1739. 40 79. 26 1637.90 39.82
1409. 82 86. 69 1244.60 78.23 1110.28 81.86 1049. 78 78.70 574. 78 61.81

REF 4000 98.69 2000 96.73 600

3450. 45 6.33 2990.51 56.61 2488. 21 97.59 2365. 16 92. 03 2089.01 94.12
1762. 32 21. 07 1637.33 43.39 1376.73 53.59 1242. 82 11.07 1164.40 84.67
1056. 35 45. 12 931.02 94.74 623.89 63.96

REF 4000 97.57 2000 95.86 600

3755. 77 94. 19 3450. 69 6.34 2990.49 54.27 2489.94 96.40 2375.18 94.86
2090. 50 93. 31 1761. 48 19. 31 1637. 41 42.15 1375.96 51.98 1242.79 10.20
1165. 69 79. 36 1056. 63 45. 21 932.09 93.90 622. 77 66. 13

REF 4000 95.93 2000 94.61 600

3778. 13 93. 82 3447. 05 6.34 2928.83 84.16 2376.34 93.57 2093.87 93.59
1636. 17 39. 47 1418. 32 81. 88 1245. 49 93.11 1113.89 76.66 1021.27 78.67
577.76 63. 78

REF 4000 95.44 2000 93.34 600

3768. 93 89. 15 3450. 23 6.34 2990.28 63.10 2378.86 93.82 2091.95 91.68
1757. 15 41. 96 1637. 35 45. 43 1373. 67 65.02 1242.87 35.39 1168.70 78.44
1056. 34 65. 29 935.24 93. 23 595. 26 64.81

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-9.sp

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-10.sp

10 0. 0

90
2370.49
3775.07

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-8.sp

10 0. 0

Spec trum Name: Cl-AN-11.sp

10 0. 0

3921.99

3920.45

3765.76
938.26

2092.69

ACIC
St. Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 3/11/2009

Spec trum Name: Cl-AN-7.sp

10 0. 0

1109.66

2094.28
2368.72

70
1005.30

2087.47

2104.31

594.26

2089.51

1247.00

3778.25

3772.35

1164.26

1815.01

2380.41

3906.73

2930.86

1409.75

1011.07

3769.93
2989.86

1373.15

1114.23

1056.57

2988.64

595.48
1746.98

1635.10

1008.88

2375.62

1370.94

%T
40

1405.90

1242.92

1635.26

1757.83

1008.25

50
1243.00

1243.50

586.32

563.25

40
2988.97

1167.31
1367.68

1628.07

1636.11

1117.88

40
670.17

1116.30

4 00 .0

c m -1

Cl-AN-1.pk

1626.89

1740.66
1242.82

3448.38

3448.32

0. 0
4 00 0 .0

3449.47

0. 0
3 0 00

20 00

1 50 0

1 0 00

4 00 .0

4 00 0 .0

c m -1

0. 0
3 0 00

20 00

1 50 0

1 0 00

4 00 .0

0. 0

3449.06

4 00 0 .0

3 0 00

c m -1

20 00

1 50 0

1 0 00

4 00 .0

4 00 0 .0

0. 0
3 0 00

20 00

c m -1

1 50 0

1 0 00

4 00 .0

3445.42

4 00 0 .0

3 0 00

c m -1

20 00

1 50 0

1 0 00

4 00 .0

c m -1

Cl-AN-7.pk

Cl-AN-8.pk

Cl-AN-9.pk

Cl-AN-10. pk

Cl-AN-11. pk

Cl-AN-7.sp 3601 4000.00 400. 00 6.32 99.45 4.00 %T 5 1.00

Cl-AN-8.sp 3601 4000.00 400. 00 6.34 100.00 4. 00 %T 5 1.00

Cl-AN-9.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00

Cl-AN-10. sp 3601 4000. 00 400.00 6.33 100.00 4.00 %T 5 1. 00

Cl-AN-11. sp 3601 4000. 00 400.00 6.34 99.17 4. 00 %T 5 1.00

REF 4000 97.51 2000 95.13 600

3775. 07 92. 31 3448. 38 6.32 2989.86 58.27 2370.49 92.46 2092.69 93.04
1757. 83 34. 82 1635. 10 45. 07 1373. 15 58.91 1242.82 26.44 1164.26 68.31
1109. 66 66. 78 1056. 57 56. 70 1005. 30 75.18 938.26 92.74 594. 26 65. 12

REF 4000 80.85 2000 77.99 600

3765. 76 75. 87 3448.32 6. 34 2988. 64 56.76 2368. 72 74. 98 2094.28 76.58
1746. 98 48. 38 1635.26 38.45 1370.94 57.05 1242. 92 49.25 1114.23 57.80
595.48 52. 73

REF 4000 71.37 2000 68.30 600

3906. 73 69. 57 3769.93 61.87 3449.06 6.33 2375. 62 65. 34 2089.51 67.56
1636. 11 34. 39 1405.90 57.02 1243.50 56.03 1116. 30 44.72 1008.25 47.96
670.17 42. 17

REF 4000 84.49 2000 80.62 600

3920. 45 83. 10 3772.35 71.56 3449.47 6.33 2988. 97 43. 60 2380.41 82.93
2104. 31 79. 26 1740.66 29.75 1628.07 38.07 1367. 68 44.01 1243.00 53.09
1167. 31 42. 59 1008.88 58.20 586.32 53.29

REF 4000 88.37 2000 83.26 600

3921. 99 87. 11 3778. 25 73. 94 3445. 42 6.34 2930.86 71.20 2087.47 82.53
1815. 01 86. 05 1626. 89 35. 54 1409. 75 68.12 1247.00 74.30 1117.88 55.35
1011. 07 61. 13 563.25 53. 03

Table - 7.21
Observations of FTIR spectrums for Ethyl Acetate + 2-Butanone mixture:
1 (EA)
Cm-1
3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08

0.9(EA)
+
0.1(2B)
Cm-1
3449.85
2369.39
2089.05
1739.40
1637.90
1409.82
1244.60
1110.28
1049.78
574.78

0.8(EA)
+
0.2(2B)
Cm-1
3450.45
2990.51
2488.21
2365.16
2089.01
1762.32
1637.33
1376.73
1242.82
1164.40
1056.35
931.02
623.89

*0.7(EA)
+
0.3(2B)
Cm-1
3755.77
3450.69
2990.49
2489.94
2375.18
2090.50
1761.48
1637.41
1375.96
1242.79
1165.69
1056.63
932.09
622.77

0.6(EA)
+
0.4(2B)
Cm-1
3778.13
3447.05
2928.83
2376.34
2093.87
1636.17
1418.32
1245.49
1113.89
1021.27
577.76

0.5(EA)
+
0.5(2B)
Cm-1
3768.93
3450.23
2990.28
2378.86
2091.95
1757.15
1637.35
1373.67
1242.87
1168.70
1056.34
935.24
595.26

0.4(EA)
+
0.6(2B)
Cm-1
3775.07
3448.38
2989.86
2370.49
2092.69
1757.83
1635.10
1373.15
1242.82
1164.26
1109.66
1056.57
1005.30
938.26
594.26

* Maximum shift in the frequency has been observed.

298

0.3(EA)
+
0.7(2B)
Cm-1
3765.76
3448.32
2988.64
2368.72
2094.28
1746.98
1635.26
1370.94
1242.92
1114.23
595.48

0.2(EA)
+
0.8(2B)
Cm-1
3906.73
3769.93
3449.06
2375.62
2089.51
1636.11
1405.90
1243.50
1116.30
1008.25
670.17

0.1(EA)
+
0.9(2B)
Cm-1
3920.45
3772.35
3449.47
2988.97
2380.41
2104.31
1740.66
1628.07
1367.68
1243.00
1167.31
1008.88
586.32

1(2B)
Cm-1
3921.99
3778.25
3445.42
2930.86
2087.47
1815.01
1626.89
1409.75
1247.00
1117.88
1011.07
563.25

For Ternary mixtures:

Fig-7.21: FTIR spectrums for Cyclohexanone + Hexane + Heptane mixture:
ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/22/2008

413.75

2 176.94

3 948.52

415.92

1019 .51

1 342.88
1970 .70 180 5.14
865 .83

267 1.60

236 1.71

65 2.99

1342 .76

8 64.5 2
1056 .75905.36

65 3.03

10 54.19

267 2.73

65 3.46

267 3.01

9 04.9 9

1 312 .31

50
341 2.01

11 19.24
131 4.03
122 3.01

50
34 50.5 9

11 20.90

1 312 .96
122 2.31

492 .92

6 53.8 1

122 3.74

3442 .33

11 19.43

14 52.3 4

2865 .82

293 9.48

23 67.3 6
267 0.73

65 2.59

41 3.69

1969 .33

21 77.1 8
65 2.49

7 50.1 7

18 05.0 0
4 90.57

865.9 5
105 5.68

605.2 9

6 71.08

11 19.03

3 504.58
341 0.73

122 2.36

341 4.02

491 .15

50
11 19.22
1 314.10

2868 .13

1391 .42

122 3.00

13 92.30

144 4.68
2865 .13

1395 .51

1640 .67

1 641.05
235 8.57

164 0.01

286 6.70
2 940 .26

2 940 .88
171 1.12

2 941 .82

171 2.69

2 940 .30

2 940 .39

171 2.17
171 2.63

3000

2000

171 1.15

1500

1000

0.0
4000.0

400.0

3000

2000

c m-1

1500

1000

0.0
4000.0

400.0

3000

2000

1500

c m-1

1000

0.0
4000.0

400.0

344 1.89

2 940 .43

2 939 .73

3000

2000

c m-1

1500

1000

0.0
4000.0

400.0

3442 .72

3000

2000

1500

c m-1

1000

0.0
4000.0

400.0

171 2.58

3442 .93

3000

2000

1500

c m-1

1000

0.0
4000.0

400.0

3000

2000

171 2.76

1500

c m-1

1000

0.0
4000.0

400.0

3000

2000

c m-1

1500

400.0

Sample-5.pk

Sample-6.pk

Sample-7.pk

Sample-8.pk

Sample-9.pk

Sampe- 10.pk

Sampe- 11.pk

Sample-4.sp 3601 4000.00 400.00 8.43 99.99 4.00 %T 3 1.00

Sample-5.sp 3601 4000.00 400.00 7.51 99.99 4.00 %T 3 1.00

Sample-6.sp 3601 4000.00 400.00 8.16 100.00 4.00 %T 3 1.00

Sample-7.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 1.00

Sample-8.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 3 1.00

Sample-9.sp 3601 4000.00 400.00 6.32 99.99 4.00 %T 3 0.75

Sampe- 10.sp 3601 4000.00 400.00 9.14 100.00 4.00 %T 3 1.00

Sampe- 11.sp 3601 4000.00 400.00 8.37 100.00 4.00 %T 3 1.00

REF 4000 97.81 2000 97.05 600

3948.52 96.28 3412.01 53.26 2940.39 10.75 2866.33 25.76 2670.59 90.98
2358.73 89.51 2176.94 95.31 2064.94 95.22 1970.70 96.02 1805.14 87.08
1712.63 8.42 1444.01 44.13 1314.03 50.51 1223.01 48.26 1119.24 54.46
1055.45 76.87 1018.64 82.56 904.24 73.85 865.83 83.54 750.64 73.63
652.99 85.58 491.29 65.88 413.75 88.37

REF 4000 89.33 2000 89.05 600

3450.59 50.34 2940.26 18.84 2865.14 40.07 2671.90 83.52 2361.71 84.49
1711.12 7.51 1448.81 57.57 1424.79 58.06 1342.88 65.22 1312.32 59.70
1223.71 51.56 1120.51 62.07 1055.88 78.51 1019.51 83.30 905.11 78.16
864.80 81.87 750.96 77.67 653.03 81.80 492.28 73.35 415.92 88.32

REF 4000 98.34 2000 97.70 600

3442.33 45.68 2940.88 20.63 2865.82 45.24 2671.60 91.76 2361.63 88.89
2065.75 96.95 1711.15 8.16 1447.85 62.93 1423.73 62.87 1342.76 71.44
1312.31 65.86 1223.74 56.24 1120.90 68.06 1056.75 85.28 905.36 86.07
864.52 89.04 750.64 83.29 653.46 85.64 492.38 78.87 413.67 91.62

REF 4000 98.57 2000 96.09 600

3441.89 6.31 2939.73 9.03 2869.57 29.76 2672.73 96.06 2365.72 75.70
2066.40 93.81 1712.17 11.88 1640.67 34.38 1452.34 52.22 1391.42 45.20
1343.39 69.50 1312.96 64.65 1222.31 62.45 1119.43 54.53 1054.19 81.73
1019.48 83.58 904.99 84.68 863.28 85.64 749.44 64.07 653.81 64.34
491.58 68.63 415.62 90.49

REF 4000 98.44 2000 95.39 600

3442.72 6.33 2941.82 18.80 2868.13 47.92 2673.01 97.10 2364.26 90.05
2090.47 93.00 1712.69 20.22 1641.05 32.36 1451.04 59.40 1392.30 43.59
1343.77 73.70 1313.47 71.61 1221.45 69.57 1119.64 58.89 1020.47 83.48
903.21 88.46 748.07 62.12 653.88 59.49 605.29 60.18 492.92 67.40

REF 4000 98.59 2000 90.95 600

3863.90 83.44 3747.72 73.42 3442.93 6.32 2939.48 65.43 2868.94 83.44
2523.97 97.04 2358.57 30.87 2032.01 90.24 1640.01 28.38 1395.51 41.16
1117.96 63.95 1031.16 80.53 671.08 54.50 434.46 85.53

REF 4000 98.76 2000 98.22 600

3414.02 55.34 2940.30 18.24 2865.13 41.11 2671.13 95.49 2372.20 96.52
2064.24 97.11 1804.81 92.90 1712.58 9.13 1448.16 60.75 1340.50 72.24
1312.45 64.60 1222.36 61.11 1119.03 65.78 1054.35 85.44 1018.20 89.60
905.32 84.05 864.51 89.53 750.17 81.53 652.59 89.35 490.57 77.45
411.88 94.22

REF 4000 97.87 2000 97.50 600

3948.18 96.47 3504.58 61.49 3410.73 59.93 2940.43 10.32 2866.70 24.62
2670.73 89.76 2367.36 95.65 2177.18 95.74 2064.69 95.68 1969.33 96.15
1805.00 86.01 1712.76 8.37 1444.68 42.73 1314.10 49.22 1223.00 47.13
1119.22 53.82 1055.68 75.35 1018.52 82.15 904.12 72.30 865.95 82.42
750.67 73.30 652.49 87.11 491.15 65.74 413.69 88.21

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/23/2008

206 5.52

2 670.3 8

865.6 4

19 67.86

394 8.09

65 2.53

10 18.6 9

23 72.1 9 2 063 .26

39 49.58
26 72.12

490 .97

11 19.19

134 0.74
180 5.50

90 3.80

491 .16

26 71.5 8

237 0.23

206 4.97

864.5 1

50
341 2.46

1119 .25

7 50.1 0

7 50.1 9

491 .05

1395 .95

60
1 119.2 2
122 2.54

1640 .21

2 940 .32

2 864 .65

2 939 .12
171 2.75

3000

2000

1500

1000

3000

2000

1500

1000

0.0
4000.0

400.0

3000

2000

c m-1

1 312 .93

11 19.27

1000

0.0
4000.0

400.0

3446 .62

2 942 .83
1 713.4 3

2000

1500

1000

0.0
4000.0

400.0

29 40.96

171 2.81

2000

1500

1000

0.0
4000.0

400.0

3000

2 867.0 3

2 940 .75

3000

2000

c m-1

Sampe- 15.pk

1500

1000

0.0
4000.0

400.0

171 2.82

3000

2000

c m-1

Sampe- 16.pk

1 637.6 2

2865 .85

171 2.77

3000

c m-1

Sampe- 14.pk

60 6.71

30
34 48.4 4

3446 .36

1500
c m-1

Sampe- 13.pk

655 .37
13 93.69

%T
164 0.37

2 940 .72

17 12.02

171 3.21

294 1.43

0.0
4000.0

400.0

c m-1

Sampe- 12.pk

2866 .55

122 2.64

3 419.7 5

0.0
4000.0

65 2.80

7 50.2 4
491 .14

1 449.22
163 8.31

286 8.71

11 19.83

1 448.87

294 4.18

142 6.32

286 6.24

10 54.66

60
131 2.81 1119 .23
122 2.55

16 40.6 5

1 448.99

1729 .51

122 2.64

122 1.54

491 .06

145 0.02

209 2.08

233 8.38

80
864 .70

6 07.17

%T
11 19.21
131 2.57

122 2.95

144 5.60

2368 .87
134 0.61

18 05.7 1

905.36
655.54

490 .97

131 5.50

286 6.06

FTIR S PECTRUM
Date: 2/25/2008

131 3.92

18 72.0 2
23 67.4 8
217 5.74

80
65 2.84

11 19.83
2 869.3 7

750 .88

340 9.40

13 12.77

144 4.79

267 1.50
8 64.5 9
1054 .60
905.39

41 2.60

1 018.2 7

134 0.61

80
65 3.11

100.0

2064 .36

41 2.47

1805 .42

23 71.71

10 18.3 5
1054 .59
905.53

122 2.75

206 4.97
26 71.7 6

80
122 0.65

16 40.0 5
1 313.65
341 3.01

90
209 1.08
2374 .64

10 18.1 6 865.3 7

105 4.78

904.74 7 50.4 4

4 14.9 3
65 2.44

18 06.01

105 5.31

Spectrum Na me: Sampe-19.sp

100.0
101 8.35

13 42.36

19 73.10

65 2.48
866.04

Spectrum Na me: Sampe-18.sp

100.0
41 2.58

2 176.2 2

21 77.2 6

1055 .53
7 50.5 1
904.49

FTIR S PECTRUM
Date: 2/25/2008

Spectrum Na me: Sampe-17.sp

100.0

233 9.07

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/25/2008

Spectrum Na me: Sampe-16.sp

100.0
993.17

187 1.50

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/25/2008

Spectrum Na me: Sampe-15.sp

100.0

101 8.34

23 73.36

2374 .29 206 4.95

267 0.70

4 14.46

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/25/2008

Spectrum Na me: Sampe-14.sp

100.0

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/23/2008

Spectrum Na me: Sampe-13.sp

413.5 9

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/23/2008

Spectrum Na me: Sampe-12.sp

1500

1000

0.0
4000.0

400.0

34 46.2 4

3000

2000

c m-1

Sampe- 17.pk

1500

1000

400.0

c m-1

Sampe- 18.pk

Sampe- 19.pk

Sampe- 12.sp 3601 4000.00 400.00 9.52 100.00 4.00 %T 3 1.00

Sampe- 13.sp 3601 4000.00 400.00 6.69 100.00 4.00 %T 3 1.00

Sampe- 14.sp 3601 4000.00 400.00 7.36 122.21 4.00 %T 3 1.00

Sampe- 15.sp 3601 4000.00 400.00 6.32 98.54 4.00 %T 3 1.00

Sampe- 16.sp 3601 4000.00 400.00 8.23 99.99 4.00 %T 3 1.00

Sampe- 17.sp 3601 4000.00 400.00 8.36 99.99 4.00 %T 3 1.00

Sampe- 18.sp 3601 4000.00 400.00 7.09 99.99 4.00 %T 3 1.00

Sampe- 19.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 1.00

REF 4000 98.57 2000 98.17 600

3413.01 60.31 2940.32 13.51 2866.06 34.75 2670.70 94.38 2374.29 97.23
2064.95 97.04 1712.75 9.51 1444.79 54.55 1313.65 60.42 1222.75 57.80
1119.19 63.29 1055.53 83.40 1018.69 88.13 904.49 81.31 865.64 88.62
750.51 80.45 652.53 89.76 490.97 74.44 413.59 92.15

REF 4000 97.77 2000 97.28 600

3948.09 96.54 3412.46 53.01 2941.43 6.69 2868.71 18.07 2670.38 89.88
2373.36 96.19 2177.26 95.57 2065.52 95.54 1967.86 96.11 1713.21 9.16
1445.60 37.56 1315.50 47.19 1222.95 45.81 1119.25 52.62 1055.31 75.42
1018.34 81.83 904.74 72.45 866.04 82.66 750.44 72.47 652.48 86.55
491.16 64.59 414.46 89.22

REF 4000 99.77 2000 99.52 600

3949.58 98.65 3409.40 64.26 2939.12 11.66 2864.65 25.52 2672.12 92.47
2372.19 98.36 2176.22 97.75 2063.26 97.62 1973.10 98.24 1871.50 97.62
1806.01 88.79 1712.02 7.36 1640.05 73.02 1450.02 45.33 1426.32 47.61
1342.36 56.84 1312.57 47.97 1222.64 44.62 1119.21 50.78 1054.78 77.58
1018.16 83.48 993.17 91.83 903.80 72.93 865.37 83.49 750.88 73.12
652.44 88.31 490.97 65.00 414.93 95.54

REF 4000 96.58 2000 93.48 600

3446.36 6.32 2944.18 43.11 2869.37 70.48 2374.64 89.18 2339.07 96.15
2091.08 91.47 1729.51 46.84 1638.31 38.77 1395.95 53.30 1220.65 83.91
1119.83 72.02 655.54 68.70 607.17 68.84

REF 4000 98.14 2000 96.53 600

3446.62 25.03 2940.72 11.02 2866.24 30.81 2671.76 94.24 2370.23 93.79
2064.97 94.76 1805.50 91.51 1712.77 8.23 1640.21 56.95 1448.99 53.16
1340.74 67.49 1312.77 59.26 1222.54 56.10 1119.22 59.55 1054.59 83.12
1018.35 87.30 905.53 80.81 864.51 86.78 750.10 73.72 653.11 80.94
491.05 70.52 412.58 91.48

REF 4000 98.05 2000 96.57 600

3448.44 30.41 2940.75 11.92 2865.85 30.47 2671.58 93.57 2371.71 94.61
2064.97 94.70 1805.42 90.22 1712.81 8.36 1640.65 58.52 1448.87 51.86
1340.61 65.88 1312.81 58.10 1222.55 55.22 1119.23 58.70 1054.60 81.98
1018.35 86.35 905.39 79.69 864.59 86.16 750.19 73.89 652.84 82.13
491.06 70.37 412.47 91.06

REF 4000 97.14 2000 95.36 600

3419.75 19.72 2940.96 7.09 2867.03 19.94 2671.50 91.03 2367.48 92.87
2175.74 93.52 2064.36 92.94 1872.02 95.53 1805.71 86.63 1712.82 7.60
1640.37 49.06 1449.22 40.00 1340.61 55.36 1312.93 47.27 1222.64 44.46
1119.27 48.31 1054.66 75.30 1018.27 81.08 905.36 71.88 864.70 80.70
750.24 64.94 652.80 75.90 491.14 60.74 412.60 86.69

REF 4000 99.44 2000 95.37 600

3446.24 6.31 2942.83 46.68 2866.55 72.01 2368.87 92.69 2338.38 94.69
2092.08 93.00 1713.43 41.53 1637.62 39.94 1393.69 62.24 1313.92 87.78
1221.54 86.97 1119.83 78.32 655.37 66.55 606.71 67.27

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/26/2008

267 1.62

217 6.602

064.1 3

267 1.24

236 6.84
1018 .18

864.8 4

865 .59

65 2.96

267 2.32

206 5.06

134 1.00

6 53.2 1

1018 .43

236 4.43

1 055.3 3 904.65

267 0.86

8 64.45

4 90.25

20 96.3 8

80
1 458.9 6
28 72.16

121 9.78

1 026.1 8

23 71.9 1

11 20.39

252 2.83

3821 .18

2098 .52

865.50
10 18.48
65 2.96
1 055.5 4
904.44
7 50.1 0

7 49.7 4
4 90.70

7 50.2 7

100.0

1 204.4 4

2098 .33

236 1.85
653.48

1 054.4 5 905.50

7 50.2 2

905.33

Spectrum Na me: Sample-27.sp

100.0

26 77.47

206 5.34

1 054.5 5

FTIR S PECTRUM
Date: 3/7/2008

Spectrum Na me: Sample-26.sp

100.0

413 .74

206 5.56

2 365.1 0
180 5.04

FTIR S PECTRUM
Date: 3/7/2008

Spectrum Na me: Sample - 25.sp

100.0

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/26/2008

Spectrum Na me: Sample - 24.sp

100.0

4 12.55

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/26/2008

Spectrum Na me: Sample - 23.sp

100.0

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/26/2008

Spectrum Na me: Sample - 22.sp

41 4.08

1 018.9 4

1 340 .50

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/26/2008

Spectrum Na me: Sample - 21.sp

100.0

412 .37

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/26/2008

Spectrum Na me: Sample - 20.sp

100.0

20 95.7 6

2872 .26
23 71.0 3

236 3.45

656 .97

490 .97
4 90.61

131 3.60

11 19.14

1 312 .82

11 19.14

164 1.75

122 0.73
11 20.41

1 312 .69

11 19.03
122 2.22

659 .33

659 .07

745 .19

37 41.4 3

603.8 2

29 45.05

13 94.13

122 2.69

1 458.3 3

236 3.45

1 313.77

1 450.06

3 415.7 9

11 20.49

1119 .23

122 2.53
144 6.46

1000

c m-1

Sample-4.pk

100.0

1 312 .45
1 448.16

11 19.64

286 9.57

0.0
4000.0

11 17.96

7 48.0 7

1 451 .04

122 3.71

2 866.3 3

8 64.5 1

905.32

904.12 7 50.6 7

286 5.14

10 18.2 0
10 54.35

374 7.72

122 1.45

7 49.4 4

1018 .52

180 4.81

237 2.20

43 4.46
1 031.1 6

65 3.88

1313 .47

142 3.73

144 4.01

2 064 .69

90 394 8.18

206 4.24

267 1.13

286 8.94

236 5.72

144 7.85

11 20.51
14 24.7 9
1 448.81
1 312 .32

3863 .90

102 0.47

1 019.4 8

491 .58
491 .29

100.0

41 1.88

90
2032 .01

903.21

1343 .77

86 3.28
492 .38

70
492 .28

FTIR S PECTRUM
Date: 2/23/2008
Spectrum Na me: Sampe-11.sp

100.0

2 523.9 7

209 0.47
236 4.26

415 .62
13 43.3 9

7 50.6 4

1 055.8 8 905.11 7 50.9 6

904.24 7 50.6 4

236 1.63

80
864 .80

267 1.90

1 055.4 5

Spectrum Na me: Sampe-10.sp

100.0

1 340 .50

206 5.75

206 6.40

267 0.59
235 8.73

FTIR S PECTRUM
Date: 2/23/2008

Spectrum Na me: Sample-9.sp

100.0

41 3.67

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 3/7/2008

Spectrum Na me: Sample-8.sp

100.0

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 3/7/2008

Spectrum Na me: Sample-7.sp

100.0

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 3/7/2008

Spectrum Na me: Sample-6.sp

100.0

101 8.64

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/22/2008

Spectrum Na me: Sample-5.sp

206 4.94

ACI C
St.Joseph's College ( Autonomous )
Trichy- 2

FTIR S PECTRUM
Date: 2/22/2008

Spectrum Na me: Sample-4.sp

100.0

606 .22

2 957.50

2869 .35

11 20.06

50
145 6.34

122 2.47

1 448.98

341 3.73

1 450.30

13 93.87

1716 .72

13 93.90

3 417.6 5

2866 .57

2 867.4 8

3440 .92

164 0.38

13 93.11

30
163 9.62

295 3.79
2 866.6 4

287 7.21

164 0.64

163 8.29

286 8.82

173 3.70

2 941 .10
171 3.15
2 941 .40

0.0
4000.0

3000

2 941 .24

171 2.84

2000

29 42.07

171 2.94

1500

1000

400.0

0.0
4000.0

3000

c m-1

2000

1500

1000

400.0

0.0
4000.0

c m-1

3000

2000

1500

1000

400.0

0.0
4000.0

3000

c m-1

3445 .53

1 713 .40

2000

1500

1000

400.0

0.0
4000.0

c m-1

3444 .92

3444 .36

3000

2000

1500

1000

400.0

0.0
4000.0

c m-1

3000

2000

1500

1000

400.0

0.0
4000.0

3441 .76

c m-1

3000

2000

1500

1000

400.0

0.0
4000.0

c m-1

294 8.94

3000

2000

1500

1000

c m-1

Sample - 20.pk

Sample - 21.pk

Sample - 22.pk

Sample - 23.pk

Sample - 24.pk

Sample - 25.pk

Sample-26.pk

Sample-27.pk

SAMP LE~1.SP 3601 4000.00 400.00 8.14 100.00 4.00 %T 3 1.00

SAMP LE~2.SP 3601 4000.00 400.00 10.45 100.00 4.00 %T 3 1.00

SAMP LE~3.SP 3601 4000.00 400.00 8.75 99.99 4.00 %T 3 1.00

SAMP LE~4.SP 3601 4000.00 400.00 6.54 99.99 4.00 %T 3 1.00

SA811D~1.SP 3601 4000.00 400.00 6.32 99.19 4.00 %T 3 1.00

SA891D~1.SP 3601 4000.00 400.00 6.33 97.92 4.00 %T 3 1.00

SA2D8C~1.SP 3601 4000.00 400.00 6.35 100.00 4.00 %T 3 0.75

SA259C~1.SP 3601 4000.00 400.00 6.34 97.60 4.00 %T 3 0.75

REF 4000 98.31 2000 97.63 600

3413.73 45.12 2941.40 9.61 2866.64 26.54 2671.62 92.71 2366.84 91.32
2176.60 96.16 2064.13 95.95 1805.04 89.03 1712.84 8.14 1448.98 47.80
1340.50 62.59 1312.82 54.79 1222.47 51.64 1119.14 55.97 1054.55 79.09
1018.18 83.77 905.33 77.80 864.84 85.98 750.27 75.45 652.96 85.92
490.61 70.35 412.37 91.63

REF 4000 98.37 2000 97.82 600

3415.79 56.60 2941.10 15.37 2866.57 38.37 2671.24 94.81 2365.10 90.64
2065.56 96.84 1713.15 10.45 1446.46 57.79 1313.60 64.76 1222.53 61.98
1119.14 65.87 1055.33 84.60 1018.94 88.03 904.65 84.59 865.59 90.60
750.22 83.08 653.21 89.81 490.70 78.81 414.08 93.47

REF 4000 98.88 2000 97.75 600

3440.92 37.68 2941.24 12.54 2867.48 37.03 2672.32 96.11 2364.43 87.69
2065.06 96.52 1712.94 8.75 1641.75 65.66 1450.06 59.71 1341.00 74.64
1312.69 67.93 1222.22 64.77 1119.03 66.45 1054.45 86.20 1018.43 88.88
905.50 86.73 864.45 91.49 749.74 81.51 653.48 86.39 490.25 78.54
412.55 94.72

REF 4000 98.57 2000 97.54 600

3417.65 41.11 2942.07 6.54 2868.82 21.84 2670.86 93.30 2361.85 91.55
2065.34 95.79 1713.40 9.59 1450.30 46.71 1313.77 58.65 1222.69 56.52
1119.23 61.18 1055.54 81.95 1018.48 86.45 904.44 79.76 865.50 87.34
750.10 76.50 652.96 85.87 490.97 72.99 413.74 92.27

REF 4000 99.08 2000 95.08 600

3445.53 6.32 2957.50 54.14 2872.16 76.64 2363.45 78.10 2098.33 92.54
1640.38 38.12 1458.96 81.51 1394.13 60.12 1204.44 95.36 1120.39 83.84
659.33 66.76

REF 4000 97.77 2000 89.50 600

3444.36 6.33 2953.79 30.89 2869.35 57.50 2363.45 60.82 2096.38 87.52
1716.72 41.97 1640.64 30.08 1458.33 62.18 1393.87 44.66 1219.78 85.18
1120.41 70.91 659.07 63.85

REF 4000 99.42 2000 93.97 600

3441.76 6.35 2945.05 61.75 2872.26 83.30 2371.91 84.56 2098.52 91.84
1639.62 31.53 1393.90 44.28 1120.49 70.26 1026.18 86.89 606.22 59.70

REF 4000 97.44 2000 94.76 600

3821.18 80.17 3741.43 68.94 3444.92 6.34 2948.94 7.74 2877.21 33.66
2677.47 96.56 2522.83 96.67 2371.03 81.33 2095.76 92.35 1733.70 21.41
1638.29 26.84 1456.34 50.65 1393.11 37.05 1220.73 72.88 1120.06 55.45
745.19 70.36 656.97 66.47 603.82 65.82

Table - 7.22
Observations of FTIR spectrums for
Cyclohexanone + Hexane + Heptane mixture
S1
(Cm-1)
3948.52
3412.01
2940.39
2866.33
2670.59
2358.73
2176.94
2064.94
1970.70
1805.14
1712.63
1444.01
1314.03
1223.01
1119.24
1055.45
1018.64
904.24
865.83
750.64
652.99
491.29
413.75

S2
(Cm-1)
3450.59
2940.26
2865.14
2671.90
2361.71
1711.12
1448.81
1424.79
1342.88
1312.32
1223.71
1120.51
1055.88
1019.51
905.11
864.80
750.96
653.03
492.28
415.92

S3
(Cm-1)
3442.33
2940.88
2865.82
2671.60
2361.63
2065.75
1711.15
1447.85
1423.73
1342.76
1312.31
1223.74
1120.90
1056.75
905.36
864.52
750.64
653.46
492.38
413.67

S4
(Cm-1)

S5
(Cm-1)
3442.72
2941.82
2868.13
2673.01
2364.26
2090.47
1712.69
1641.05
1451.04
1392.30
1343.77
1313.47
1221.45
1119.64
1020.47
903.21
748.07
653.88
605.29
492.92

3441.89
2939.73
2869.57
2672.73
2365.72
2066.40
1712.17
1640.67
1452.34
1391.42
1343.39
1312.96
1222.31
1119.43
1054.19
1019.48
904.99
863.28
749.44
653.81
491.58
415.62

* Maximum shift in the frequency has been observed.

299

S6
(Cm-1)

S7
(Cm-1)

*S8
(Cm-1)

3863.90
3747.72
3442.93
2939.48
2868.94
2523.97
2358.57
2032.01
1640.01
1395.51
1117.96
1031.16
671.08
434.46

3414.02
2940.30
2865.13
2671.13
2372.20

3948.18
3504.58
3410.73
2940.43
2866.70
2670.73
2367.36
2177.18
2064.69
1969.33
1805.00
1712.76
1444.68
1314.10
1223.00
1119.22
1055.68

2064.24
1804.81
1712.58
1448.16
1340.50
1312.45
1222.36
1119.03
1054.35
1018.20
905.32
864.51
750.17
652.59
490.57
411.88

1018.52
904.12
865.95
750.67
652.49
491.15
413.69

400.0

S9
(Cm-1)
3413.01
2940.32
2866.06
2670.70
2374.29
2064.95
1712.75
1444.79
1313.65
1222.75
1119.19
1055.53
1018.69
904.49
865.64
750.51
652.53
490.97
413.59

S17
(Cm-1)
3413.73
2941.40
2866.64
2671.62
2366.84
2176.60
2064.13
1805.04
1712.84
1448.98
1340.50
1312.82
1222.47
1119.14
1054.55
1018.18
905.33
864.84
750.27
652.96
490.61
412.37

S10
(Cm-1)
3948.09
3412.46
2941.43
2868.71
2670.38
2373.36
2177.26
2065.52
1967.86
1713.21
1445.60
1315.50
1222.95
1119.25
1055.31
1018.34
904.74
866.04
750.44
652.48
491.16
414.46

S18
(Cm-1)
3415.79
2941.10
2866.57
2671.24
2365.10
2065.56
1713.15
1446.46
1313.60
1222.53
1119.14
1055.33
1018.94
904.65
865.59
750.22
653.21
490.70
414.08

*S11
(Cm-1)
3949.58
2939.12
2864.65
2672.12
2372.19
2176.22
2063.26
1973.10
1871.50
1806.01
1712.02
1640.05
1450.02
1426.32
1342.36
1312.57
1119.21
1054.78
1018.16
993.17
903.80
865.37
750.88
652.44
490.97
414.93

S19
(Cm-1)
3440.92
2941.24
2867.48
2672.32
2364.43
2065.06
1712.94
1641.75
1450.06
1341.00
1312.69
1222.22
1119.03
1054.45
1018.43
905.50
864.45
749.74
653.48
490.25
412.55

S12
(Cm-1)

S13
(Cm-1)

3446.36
2944.18
2869.37
2374.64
2339.07
2091.08
1729.51
1638.31
1395.95
1220.65
1119.83
655.54
607.17

3446.62
2940.72
2866.24
2671.76
2370.23
2064.97
1805.50
1712.77
1640.21
1448.99
1340.74
1312.77
1222.54
1119.22
1054.59
1018.35
905.53
864.51
750.10
653.11
491.05
412.58

S20
(Cm-1)
3417.65
2942.07
2868.82
2670.86
2361.85
2065.34
1713.40
1450.30
1313.77
1222.69
1119.23
1055.54
1018.48
904.44
865.50
750.10
652.96
490.97
413.74

3448.44
2940.75
2865.85
2671.58
2371.71
2064.97
1805.42
1712.81
1640.65
1448.87
1340.61
1312.81
1222.55
1119.23
1054.60
1018.35
905.39
864.59
750.19
652.84
491.06
412.47

S15
(Cm-1)
3419.75
2940.96
2867.03
2671.50
2367.48
2175.74
2064.36
1872.02
1805.71
1712.82
1640.37
1449.22
1340.61
1312.93
1222.64
1119.27
1054.66
1018.27
905.36
864.70
750.24
652.80
491.14
412.60

S21
(Cm-1)

S22
(Cm-1)

S23
(Cm-1)

3445.53
2957.50
2872.16
2363.45
2098.33
1640.38
1458.96
1394.13
1204.44
1120.39
659.33

3444.36
2953.79
2869.35
2363.45
2096.38
1716.72
1640.64
1458.33
1393.87
1219.78
1120.41
659.07

3441.76
2945.05
2872.26
2371.91
2098.52
1639.62
1393.90
1120.49
1026.18
606.22

* Maximum shift in the frequency has been observed.

300

S14
(Cm-1)

S16
(Cm-1)
3446.24
2942.83
2866.55
2368.87
2338.38
2092.08
1713.43
1637.62
1393.69
1313.92
1221.54
1119.83
655.37
606.71

S24
(Cm-1)
3821.18
3741.43
3444.92
2948.94
2877.21
2677.47
2522.83
2371.03
2095.76
1733.70
1638.29
1456.34
1393.11
1220.73
1120.06
745.19
656.97
603.82

Fig-7.22: FTIR Spectrums for Cyclohexanone+Hexane+Benzaldehyde mixture:

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

4 12.11

1018.31

2673.85

3938.94

100.0

FT IR SPECT RUM
Date: 15- 2-2010

Spectrum Name: SJC-PH-R-4.s p

100.0

Spectrum Name: SJC-Ph- Ram-6. sp

100.0
45 2.53

233 3.47

2177.10

394 1.40

1980.80

3780.00

3942.53

1020.84

2332.62

3879.66

1911.94
904.98

20 62.83

65 1.39

3778.63

1017.83

2719.87

1 981.01

905.90

492.81

1055.22

1065.69

863 .92

905.31

FT IR SPECT RUM
Date: 15- 2-2010

Spectrum Name: SJC-Ph- Ram-5. sp

412.8 5

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

Spectrum Name: SJC-PH-R-3.s p

864.4 1

2062.95

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

Spectrum Name: SJC-PH-R-2.s p

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

Spectrum Name: SJC-PH-R-1.s p

753.33

905.35

418.93

39 44.01

2737.45

6 50.00

1173.10

1919.88
4 93.86

1022.50

771.73

1067.51
650.1 7

1168.60

60
1450.30

751.20

111 9.02
3411.73

716.0 0

1314.39

%T
40

1448.45

1 117.51

3068.38

294 2.05

1000

400.0

4000.0

1449.82
1351.29
2867.10

3000

2000

1000

400.0

1600.92

1207.97

748.09

3000

2000

cm-1

1500

1000

400.0

4000.0

712.49

294 1.61

1067.87
2660.71

1358.41

1115.74

1680.71

3431.03

0.0

4000.0

159 6.62

652.81

2944.18

0.0
1500

1310.74
2864.0 4

294 0.98

908.16

1 117.20

1 231.91

2942.12

1709.72

0.0
1500

cm-1

17 12.22
1599.12

3415.15

10
1610.93

2000

715.5 0

1173.76

1355.77
2865.8 6

10
1712.31

3000

17 07.78

0.0
3000

2000

1500

cm-1

1000

400.0

1708.08

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

SJC-PH-R-2. pk

SJC-PH-R-3. pk

SJC-PH-R-4. pk

SJC-Ph-Ram-5.pk

SJC-Ph-Ram-6.pk

SJC-PH~1. SP 3601 4000. 00 400. 00 6.26 99. 99 4.00 %T 5 1. 00

SJC-PH~2. SP 3601 4000. 00 400. 00 6.50 100.00 4.00 %T 5 1.00

SJC-PH~3. SP 3601 4000. 00 400. 00 6.49 100.00 4.00 %T 5 1.00

SJC-PH~4. SP 3601 4000. 00 400. 00 6.32 99. 99 4.00 %T 5 1. 00

SJ0CDA~1.SP 3601 4000.00 400.00 7.94 100.00 4. 00 %T 5 1.00

SJ0CDE~1.SP 3601 4000. 00 400. 00 6.39 99.99 4.00 %T 5 1.00

REF 4 000 98.25 2000 96.06 600

3938.94 97.04 3411.73 52.70 2940.35 9.74 2864.51 26.53 2719.87 91.57
2673.85 92.26 2062.95 95.42 1712.31 6.25 1595.53 21.53 1448.45 43.12
1356.25 31.74 1313.77 46.95 1222.96 48.18 1119.02 57. 28 1055.22 80. 45
1018.31 84.36 905.31 78 .16 864.41 85.62 753.33 74.15 651.39 85.70
490. 92 70 .17 412.11 91.67

REF 4 000 97.37 2000 95.11 600

3941.40 95.43 3447.65 2 5.12 3068.38 36.53 2942. 05 8.93 2865.86 18.47
2677.62 67.45 2177.10 9 5.51 2062.83 94.36 1709. 72 6.50 1610.93 14.98
1449.22 34.37 1355.77 2 1.05 1314.39 34.71 1228. 24 27.77 1173.10 52. 26
1118.35 47.06 1061.64 6 6.75 1020.84 78.21 905.35 74.45 863. 92 79.36
771. 73 62 .88 716.00 57. 27 650.00 69.13 4 93. 86 65. 76 412.85 87.29

REF 4 000 77.21 2000 72.09 600

3942.53 75.80 3415.15 1 7.93 3068.64 16.61 2942. 12 6.49 2867.10 11.75
2652.26 36.82 1919.88 6 8.40 1712.22 7. 33 1599.12 18.08 1449.82 23.07
1420.51 23.96 1351.29 2 1.79 1313.28 20.81 1231. 91 15.33 1173.76 26. 82
1117.20 27.85 1066.08 3 9.55 1022.50 47.21 905.78 45.87 863. 94 49.16
778. 24 42 .28 751.20 41. 13 715.50 28.18 6 50. 71 41. 57 496.88 49.73
418. 93 76 .12

REF 4 000 63.78 2000 54.03 600

3944.01 62.08 3431.03 6. 32 2944.18 6. 49 2660.71 11.93 192 0.32 47.18
1680.71 8. 45 1600.92 8. 82 1358.41 11.43 1115.74 16.17 106 7.87 20.30
908. 16 23 .42 712.49 18.25 652.81 23.7 9 502.47 29.97

REF 4 000 98.65 2000 96.86 600

3780.00 93.97 3443.67 5 2.90 3067.21 71.46 2940. 98 34.80 2864.31 56. 07
2737.45 79.95 2333.47 9 7.95 1980.80 96.21 1707. 78 7.94 1596.20 55.95
1450.30 62.85 1389.44 7 1.18 1310.84 62.49 1209. 02 48.87 1168.60 68. 58
1116.50 74.37 1065.69 8 3.89 1017.83 86.77 904.98 90.09 826. 63 71.00
748. 17 49 .99 691.79 65. 27 650.17 67.50 4 92. 81 83. 60 452.53 86.34

REF 4 000 98.20 2000 93.19 600

3879.66 96.56 3778.63 90.32 3401.34 43.48 3065.75 54. 75 2941.61 20. 26
2864.04 37.16 2737.66 59.25 2332.62 94.93 1981.01 91. 57 1911.94 93. 23
1815.10 88.88 1708.08 6. 39 1596.62 36.27 1449.79 46.04 1390.87 56.08
1310.74 46.16 1207.97 32.12 1168.39 52.68 1117.51 62. 37 1067.51 73. 46
1016.38 76.52 905.90 82 .22 826.80 53.97 748.09 32.86 690.97 49.34
650. 41 53 .04 491.84 75.33 452.10 75.5 6

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 15- 2-2010
Spectrum Name: SJC-Ph- Ram-7. sp

4 13.92

FT IR SPECT RUM
Date: 08- 2-2010

Spectrum Name: SJC-PH-R-10. sp

100.0

ACIC
St.Joseph's College( Autonomous )
Trichy-2

FT IR SPECT RUM
Date: 08- 2-2010

Spectrum Name: SJC-PH-R-9.s p

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

Spectrum Name: SJC-PH-R-8.s p

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

400.0

cm-1

SJC-PH-R-1. pk

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

650.41
690.97

1449.79

502.47

3447.65

1595.53

294 0.35

4000.0

6 50.71
3068.64

1 228.24

2864.51

0.0

40
3 401.34

1066.08

826.80

116 8.39

1209.02

7 78.24

265 2.26

1449.22

1390.87

3065.75

%T
748.17

1420.51

30
1356.25

1310.8 4

2864.3 1

1920.3 2

905.78

131 3.77

1596.20
3443.67

496.88

111 8.35

%T
1313.28

1222.96

452.10

691.79
2737.66

491.84

1016.38

826.63

3067.21
863 .94

1061.64

26 77.62

1815.10

70
1116.50

1389.44
4 90.92

FTIR SPECTRUM
Date: 09-2-2010

Spectrum Name: SJC-PH-R-12.sp

Spectrum Name: SJC-PH-R-11. sp

100.0

859.50

413.82

100.0

1018.69

864.13
3879.79

1912.46

233 3.39

3778.22

1 020.26

3938.95

3 940.62

906.21

13 91.08

80
10 16.80

1068.29

1171.4 2

2677.10

1424.28

650.48

904.32

1066.39

3064.87

650.23
1173.34

756.09
1061.04

1207.69

747.84
3415.96

1312.62
826 .55

650.67

2738.03

1451.19
3067.46

%T
748.94

120 8.42
2864.30

542.68

1 115.66

117 0.05

3396.20

714.03

50
1452.05
1355.60

1596.55

1452.44

1226.45

748.74

650.77
2821.39

1207.97

1 227.20

694.68

1385.06

1212.54

825.94

1169.75

1310.83
2864.67

1118.31

1446.64

453.57

1359.62

715.87

2824.68

3069.74

649.91

1169.23

3 401.83

4 94.41

716.2 1

111 8.42

27 37.74

1117.22

904.82
2668.26

6 91.45

2737.03
826.57

1168.65

2863.59

1070.67
1115.27

1313.51

4 92.90
759.83

1315.48

650.41
1450.10
1310.35

3 403.81

1018.94

80
451.56

1068.16

716.42
1059.36

60
826.78

3066.66

1913.50
497.40

906.16

1914.26

4 93.29

10 19.45

1979.60

90
1 977.33

451.75
903.77

2178.50

451.85

1116.70

2737.81

690 .06

1916.9 9

864.11

492.69

1 975.38

420 .36

1816.49
1 981.38

1354.33

747.88

2943.84

1593.14
294 1.47

1445.59

1354.11

294 2.14

3420.68

1229.02

3075.36

1597.23

294 0.63

1616.13

2866.27

1601.98

1352.97

2867.97

3435.76

1700.99
1707.39

294 1.32

0.0

17 12.23

0.0

4000.0

3000

2000

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

0.0

171 3.05

4000.0

1705.98

1706.69

294 2.12

0.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

1500

cm-1

1000

400.0

1595.99

0.0

0.0
4000.0

3000

2000

cm-1

1500

1000

4000.0

400.0

3000

2000

1500

1000

SJC-PH-R-8. pk

SJC-PH-R-9. pk

SJC-PH-R-10.pk

SJC-PH-R-11.pk

SJC-PH-R-13.pk

SJ0CD2~1.SP 3601 4000. 00 400.00 7.07 100.0 0 4.00 %T 5 1 .00

SJC90F~1. SP 3601 4000. 00 400. 00 6.72 100.00 4.00 %T 5 1.00

SJD9 0B~1. SP 3601 4000.0 0 400.00 6. 60 100.00 4.00 %T 5 1. 00

SJ8E4 3~1. SP 3601 4000.00 400.00 6.60 100. 00 4.00 %T 5 1. 00

SJ8653~1.SP 3601 4000. 00 400.00 7.33 100.00 4.00 %T 5 1 .00

SJ8663~1.SP 3601 4000.00 400.00 7.19 99.98 4.00 %T 5 1.00

REF 4 000 98.78 2000 95.10 600

3879.79 97.45 3778.22 9 2.66 3403.81 48.02 3066. 66 58.45 2941.47 30. 36
2863.59 47.86 2737.81 6 5.84 2333.39 96.15 1981. 38 93.87 1912.46 95. 06
1816.49 92.48 1707.39 7 .06 1596.55 43.54 1450.10 55.80 1391.08 63.45
1310.35 54.27 1207.69 3 9.29 1168.65 58.96 1116. 70 69.43 1068.29 78. 37
1016.80 81.64 906.21 87. 39 826.78 61 .10 747.84 40.07 691.45 55.73
650. 41 59 .56 492.69 81. 92 451.85 80.70

REF 4 000 98.01 2000 96.65 600

3938.95 96.66 3415.96 3 8.82 2941.32 8. 41 2866.27 21.88 2677.10 81.58
1712.23 6. 72 1616. 13 20. 97 1446.64 38.43 1354.11 28.73 1315.48 41.59
1226.45 35.90 1171.42 6 5.07 1118.42 51.90 1059. 36 71.62 1020.26 81. 56
904. 32 77 .41 864.13 83. 43 759.83 68.24 7 16. 42 73. 39 650.48 78.37
492. 90 68 .36 413.92 89. 65

REF 4 000 83.43 2000 82.79 600

3940.62 82.36 3420.68 2 4.49 3069.74 34.00 2942. 12 6.79 2867.97 16.04
2668.26 61.89 2178.50 8 2.36 1713.05 6. 60 1601.98 19.48 1445.59 30.54
1352.97 25.76 1229.02 2 5.16 1173.34 45.96 1118. 31 41.51 1061.04 56. 95
904. 82 64 .57 864.11 68. 72 756.09 57.48 7 16. 21 53. 11 650.23 62.03
494. 41 56 .07 420.36 81. 47

REF 4 000 99.08 2000 96.37 600

3401.83 59.27 3064.87 6 0.72 2940.63 23.94 2864. 30 43.46 2824.68 58. 96
2737.03 74.58 1975.38 9 5.17 1916.99 94.64 1706. 69 6.59 1593.14 32.35
1452.05 54.68 1424.28 6 5.03 1355.60 53.21 1313. 51 52.05 1227.20 49. 41
1208.42 46.25 1169.23 6 5.09 1117.22 67.68 1066. 39 82.99 1019.45 85. 56
903. 77 87 .82 859.50 89. 47 826.57 71.01 7 48. 94 49. 22 715.87 63.15
690. 06 66 .77 649.91 66. 40 493.29 84.48 4 51. 75 89. 78 413.82 95.01

REF 4 000 99.34 2000 95.98 600

3396.20 61.37 3067.46 5 3.46 2942.14 30.61 2864. 67 47.56 2737.74 69. 99
1977.33 94.66 1914.26 9 3.78 1705.98 7. 33 1597.23 30.17 1451.19 58.73
1359.62 53.12 1310.83 5 2.74 1212.54 43.33 1170. 05 61.83 1115.66 71. 49
1068.16 82.84 1018.69 8 6.70 906. 16 87.88 826.55 68. 26 748.74 49.65
714. 03 59 .23 650.67 65. 29 497.40 88.23 4 51. 56 88. 84

REF 4000 99.41 2000 97.82 600

3435.76 16.46 3075.36 36.79 2943.84 39.15 2821.39 47.32 2738.03 61.49
1979.60 96.58 1913.50 96.31 1700.99 12.81 1595.99 7.19 1452.44 59.85
1385.06 44.86 1354.33 43.00 1312.62 51.91 1207.97 45.16 1169.75 62.34
1115.27 80.03 1070.67 85.60 1018.94 89.20 825.94 59.29 747.88 38.21
694.68 46.63 650.77 49.53 542.68 72.65 453.57 76.93

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 15- 2-2010
Spectrum Name: SJC-Ph- Ram-13.sp

Spectrum Name: SJC-PH-R-16. sp

100.0

90
2544.31

924.23

416.91

2944.94

Spectrum Name: SJC-PH-R-18. sp

100.0

544.35

1169.05

100.0

746.04

749.24

2866.56

1000

400.0

4000.0

1313.21

294 1.98

1597.06

32 04.98
3439.15

2000

1000

400.0

4000.0

1453.58

2738.07

651.06

826.14

690.87
745.60

3068.32

29 39.93

116 8.70

13 87.96

1206.19

3395.62

2822.60

651.09

1284.43

688.77

3393.43
1205.73

2939.60

746.54

2865.74

1597.63
1705.04

0.0
1500

cm-1

713.73

1169.43

2821.81

1233.66
2867.0 0

294 2.50

17 07.38

3000

13 87.84
1283.71

1232.55

3000

2000

0.0
1500

1000

400.0

4000.0

2000

1500

1000

400.0

4000.0

cm-1

16 99.87

1595.44

17 00.04

0.0

1704.78

3000

cm-1

10
1595.24

1596.58

294 2.04

1500
cm-1

450.78

6 50.63

32 06.39
3437.50

713.83

3069.60
714.23

543.54

1114.31

824.51

2 737.70

11 71.23
748.64

1311.21

50
%T

1451.25

1312.84

0.0
2000

1823.64

2550.33

449.42

3068.4 7

1349.30

17 02.36

3000

542 .09

827.30

1116.64

1 117.27
1173.58

1450.6 8

1232.20
3438.23

0.0

9 27.79
1070.83
1114.41

1068.13

1351.48

1452.1 2

3069.5 2

1312.33

1979.33
1016.43

2551.07

60
13 88.27

2739.08

650.83

3071.40

1071.31

1494.04

2660.12

50
%T

139 0.10

2654.89

40
1449.07

1205.51

2028.28
23 31.96

1914.27

70
499.13

1021.77

499.66
827.56
1068.55

749.53

713.17
1596.60

3914.04

236 3.84

1416.62

50
%T

650.43
11 72.62

3443.99

1019.30

90
2026.94
1979.12

907.07

906.79

1116.46

%T
650.82
690.37

1914.88
2140.59

3792.24

1 823.31

3 795.21
392 5.94

1917.85

498.23

1386.35

826.54

1306.91

23 68.76

9 28.44

826.33
1350.22

2 740.59
1390.11

102 1.40

1066.51

1453.37

2819.26
3069.37

3922.57

1023.35

904.94

70
2658.54

2738.06

1 975.95
4 52.91

862.84

1920.05

450.97

3 780.75

415.38

1 111.47

90
1972.99

FT IR SPECT RUM
Date: 09- 2-2010

Spectrum Name: SJC-PH-R-17. sp

100.0

3938.64

191 7.73

1017.16

1913.01

197 5.62

1981.03 1 821.90
3 778.62

4000.0

FT IR SPECT RUM
Date: 09- 2-2010

1072.42

3880.0 0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 09- 2-2010

Spectrum Name: SJC-PH-R-15. sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 09- 2-2010

Spectrum Name: SJC-PH-R-14. sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 09- 2-2010

400.0

cm-1

SJC-Ph-Ram-7.pk

3000

2000

0.0
1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

cm-1

SJC-Ph-Ram-13.pk

SJC-PH-R-14.pk

SJC-PH-R-15.pk

SJC-PH-R-16.pk

SJC-PH-R-17.pk

SJC-PH-R-18.pk

SJC833~1.SP 3601 4000.00 400 .00 7.30 99.94 4.00 %T 5 1. 00

SJ8E6 3~1. SP 3601 4000.00 400.00 6.68 100. 00 4.00 %T 5 1. 00

SJ8673~1.SP 3601 4000. 00 400.00 6.46 99.99 4.00 %T 5 1. 00

SJ8E7 3~1. SP 3601 4000.00 400.00 6.50 99.99 4.00 %T 5 1.0 0

SJ8683~1.SP 3601 4000. 00 400.00 7.11 100.00 4.00 %T 5 1 .00

SJ8E8 3~1. SP 3601 4000.00 400.00 5.97 99.99 4.00 %T 5 1.0 0

REF 4 000 98.94 2000 95.23 600

3880.00 97.52 3778.62 91.98 3443.99 39.30 3069.37 56. 01 2944.94 60. 40
2819.26 57.97 2738.06 65.71 2544.31 90.10 1981.03 94. 00 1913.01 94. 35
1821.90 94.34 1702.36 7. 30 1596.60 37.53 1453.37 64.88 1390.11 59.98
1306.91 54.95 1205.51 38.59 1169.05 58.47 1111.47 82. 24 1072.42 85. 10
1017.16 87.43 924.23 90 .74 826.54 55.59 746.04 35.00 690.37 45.92
650. 82 50 .68 544.35 83.49 450.97 74.7 0

REF 4 000 98.27 2000 97.28 600

3438.23 22.03 3071.40 3 1.13 2941.98 12.86 2866. 56 25.99 2740.59 63. 84
2658.54 69.83 1975.62 9 5.96 1917.73 95.96 1707. 38 6.67 1597.06 15.45
1449.07 43.07 1386.35 4 3.09 1350.22 37.79 1312. 33 37.44 1232.20 27. 42
1172.62 50.12 1116.46 5 2.66 1066.51 69.17 1021. 40 78.49 904.94 80.66
826. 33 70 .30 749.53 47. 29 713.17 39.72 6 50. 43 55. 01 498.23 69.56
416. 91 91 .23

REF 4 000 97.69 2000 93.33 600

3938.64 96.09 3439.15 17.67 3204.98 20.38 3069.52 19. 75 2942.50 8.60
2867.00 17.05 2654.89 50.10 1972.99 90.61 1920.05 89. 66 1705.04 6.46
1597.63 16.40 1450.68 33.65 1416.62 34.65 1390.10 34. 69 1349.30 32. 89
1313.21 27.17 1233.66 19.40 1173.58 37.72 1117.27 40. 43 1068.55 55. 77
1023.35 65.10 906.79 66 .72 862.84 69.76 827.56 62.70 749.24 43.31
714. 23 28 .64 650.83 46.11 499.66 63.6 8 415.38 86.82

REF 4 000 98.22 2000 95.44 600

3922.57 97.21 3780.75 94.64 3437.50 23.47 3206.39 27. 10 3068.47 25. 41
2942.04 11.42 2865.74 23.02 2739.08 52.99 2660.12 63. 17 2368.76 89. 94
1975.95 93.32 1917.85 92.81 1704.78 6.50 1596.58 11.01 1451.25 38.78
1388.27 36.99 1351.48 35.53 1312.84 31.71 1232.55 25. 70 1171.23 40. 49
1116.64 49.61 1068.13 63.34 1021.77 70.81 907.07 76.89 827.30 55.57
748. 64 34 .17 713.73 31.12 650.63 44.1 5 499.13 69.05 452.91 78. 41

REF 4 000 99.39 2000 92.88 600

3925.94 97.82 3795.21 9 7.45 3395.62 28.99 3069. 60 33.11 2939.93 29. 94
2821.81 35.56 2737.70 4 5.22 2551.07 68.33 2363. 84 85.55 2026.94 93. 29
1979.12 89.42 1914.27 8 8.85 1823.31 90.27 1700. 04 7.11 1595.24 11.65
1452.12 50.18 1387.84 4 1.29 1283.71 36.69 1206. 19 31.67 1169.43 43. 78
1114.41 66.70 1070.83 7 4.27 1016.43 78.20 927.79 76.94 824. 51 48.12
745. 60 31 .11 690.87 36. 23 651.06 39.50 5 42. 09 74. 76 449.42 69.53

REF 4 000 99.18 2000 91.35 600

3914.04 97.96 3792.24 97.20 3393.43 27.17 3068.32 30. 72 2939.60 28. 94
2822.60 32.14 2738.07 41.52 2550.33 67.71 2331.96 87. 73 2140.59 98. 16
2028.28 91.40 1979.33 87.44 1914.88 86.06 1823.64 85. 97 1699.87 5.97
1595.44 8. 81 1494.04 73 .72 1453.58 44.36 1387.96 36.00 1311.21 33.37
1284.43 32.58 1205.73 26.12 1168.70 38.59 1114.31 65. 30 1071.31 70. 10
1019.30 74.33 928.44 71 .32 826.14 39.26 746.54 24.33 713.83 32.95
688. 77 31 .17 651.09 33.64 543.54 70.9 9 450.78 61.25

301

400.0

Table - 7.23
Observations of FTIR Spectrums for
Cyclohexanone + Hexane + Benzaldehyde mixture
S1 (Cm-1)

S2 (Cm-1)

S3 (Cm-1)

S4 (Cm-1)

*S5(Cm-1)

S6 (Cm-1)

S7 (Cm-1)

S8 (Cm-1)

3938.94
3411.73
2940.35
2864.51
2719.87
2673.85
2062.95
1712.31
1595.53
1448.45
1356.25
1313.77
1222.96
1119.02
1055.22
1018.31
905.31
864.41
753.33
651.39
490.92
412.11

3941.40
3447.65
3068.38
2942.05
2865.86
2677.62
2177.10
2062.83
1709.72
1610.93
1449.22
1355.77
1314.39
1228.24
1173.10
1118.35
1061.64
1020.84
905.35
863.92
771.73
716.00
650.00
493.86
412.85

3942.53
3415.15
3068.64
2942.12
2867.10
2652.26
1919.88
1712.22
1599.12
1449.82
1420.51
1351.29
1313.28
1231.91
1173.76
1117.20
1066.08
1022.50
905.78
863.94
778.24
751.20
715.50
650.71
496.88

3944.01
3431.03
2944.18
2660.71
1920.32
1680.71
1600.92
1358.41
1115.74
1067.87
908.16
712.49
652.81
502.47

3780.00
3443.67
3067.21
2940.98
2864.31
2737.45
2333.47
1980.80
1707.78
1596.20
1450.30
1389.44
1310.84
1209.02
1168.60
1116.50
1065.69
1017.83
904.98
826.63
748.17
691.79
650.17
492.81
452.53

3879.66
3778.63
3401.34
3065.75
2941.61
2864.04
2737.66
2332.62
1981.01
1911.94
1815.10
1708.08
1596.62
1449.79
1390.87
1310.74
1207.97
1168.39
1117.51
1067.51
1016.38
905.90
826.80
748.09
690.97

3879.79
3778.22
3403.81
3066.66
2941.47
2863.59
2737.81
2333.39
1981.38
1912.46
1816.49
1707.39
1596.55
1450.10
1391.08
1310.35
1207.69
1168.65
1116.70
1068.29
1016.80
906.21
826.78
747.84
691.45

3938.95
3415.96
2941.32
2866.27
2677.10
1712.23
1616.13
1446.64
1354.11
1315.48
1226.45
1171.42
1118.42
1059.36
1020.26
904.32
864.13
759.83
716.42
650.48
492.90
413.92

S11 (Cm-1)
3396.20
3067.46
2942.14
2864.67
2737.74
1977.33
1914.26
1705.98
1597.23
1451.19
1359.62
1310.83
1212.54
1170.05
1115.66
1068.16
1018.69
906.16
826.55
748.74
714.03
650.67
497.40
451.56

S12 (Cm-1)
3435.76
3075.36
2943.84
2821.39
2738.03
1979.60
1913.50
1700.99
1595.99
1452.44
1385.06
1354.33
1312.62
1207.97
1169.75
1115.27
1070.67
1018.94
825.94
747.88
694.68
650.77
542.68
453.57

S14 (Cm-1)
3438.23
3071.40
2941.98
2866.56
2740.59
2658.54
1975.62
1917.73
1707.38
1597.06
1449.07
1386.35
1350.22
1312.33
1232.20
1172.62
1116.46
1066.51
1021.40
904.94
826.33
749.53
713.17
650.43
498.23
416.91

S15 (Cm-1)
3938.64
3439.15
3204.98
3069.52
2942.50
2867.00
2654.89
1972.99
1920.05
1705.04
1597.63
1450.68
1416.62
1390.10
1349.30
1313.21
1233.66
1173.58
1117.27
1068.55
1023.35
906.79
862.84
827.56
749.24
714.23
650.83
499.66
415.38

*S16 (Cm-1)
3922.57
3780.75
3437.50
3206.39
3068.47
2942.04
2865.74
2739.08
2660.12
2368.76
1975.95
1917.85
1704.78
1596.58
1451.25
1388.27
1351.48
1312.84
1232.55
1171.23
1116.64
1068.13
1021.77
907.07
827.30
748.64
713.73
650.63
499.13
452.91

S10 (Cm-1)
3401.83
3064.87
2940.63
2864.30
2824.68
2737.03
1975.38
1916.99
1706.69
1593.14
1452.05
1424.28
1355.60
1313.51
1227.20
1208.42
1169.23
1117.22
1066.39
1019.45
903.77
859.50
826.57
748.94
715.87
690.06
649.91
493.29
451.75
413.82

S13 (Cm-1)
3880.00
3778.62
3443.99
3069.37
2944.94
2819.26
2738.06
2544.31
1981.03
1913.01
1821.90
1702.36
1596.60
1453.37
1390.11
1306.91
1205.51
1169.05
1111.47
1072.42
1017.16
924.23
826.54
746.04
690.37
650.82
544.35
450.97

* Maximum shift in the frequency has been observed.

302

S17 (Cm-1)
3925.94
3795.21
3395.62
3069.60
2939.93
2821.81
2737.70
2551.07
2363.84
2026.94
1979.12
1914.27
1823.31
1700.04
1595.24
1452.12
1387.84
1283.71
1206.19
1169.43
1114.41
1070.83
1016.43
927.79
824.51
745.60
690.87
651.06
542.09
449.42

S9 (Cm-1)
3940.62
3420.68
3069.74
2942.12
2867.97
2668.26
2178.50
1713.05
1601.98
1445.59
1352.97
1229.02
1173.34
1118.31
1061.04
904.82
864.11
756.09
716.21
650.23
494.41
420.36

S18 (Cm-1)
3914.04
3792.24
3393.43
3068.32
2939.60
2822.60
2738.07
2550.33
2331.96
2140.59
2028.28
1979.33
1914.88
1823.64
1699.87
1595.44
1494.04
1453.58
1387.96
1311.21
1284.43
1205.73
1168.70
1114.31
1071.31
1019.30
928.44
826.14
746.54
713.83
688.77
651.09
543.54
450.78

Fig-7.23: FTIR Spectrums for Cyclohexanone+Hexane+2-Butanone mixture:

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 11-5-2010

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 11-5-2010

Spectrum Name: SJC-0.5+ 0.4+0.1.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 11-5-2010

Spectrum Name: SJC-0.5+0.2+0.3.sp

FTIR SPECTRUM
Date: 11-5-2010

Spectrum Name: SJC-0.5+ 0.3+0.2.sp

10 0.0

Spectrum Name: SJC-0.4+ 0.5+0.1.sp

10 0.0

4 19.47

3 92 7.77

393 2.10

4 14 .9 9

2 17 7.5 2

37 85.81

4 21 .74

2 67 1.1 1

393 4.64

1 018 .9 0 86 4.78

6 51.22
74 9.00

2 17 7.20

26 69.96

37 83 .01

217 7.76

2 67 0.99

1 054 .3 7
90 4.99

65 2.5 9

4 91.24
4 91.22

4 91.27

1 56 3.2 9

1 11 8.9 7

1 11 9.0 0

1 11 8.9 7

1 56 4.9 5

50
131 4.03

%T
1 22 2.9 0

1 22 3.0 3

1 565 .6 0

1 11 9.1 0

131 4.76
1 22 2.6 8

%T
131 5.28

1 32 3.2 2
1 22 2.4 6

1 56 3.3 7

65 2.2 6
7 49 .8 5

7 50 .0 6
4 92.23

1 11 9.4 9

1 222 .6 6

143 2.69

1 326 .1 9

14 27 .0 9

14 35.37

143 2.95

30
2 86 7.00

3 451 .0 1
28 66.78
14 33 .02

8 65 .1 7

26 70 .57

8 65.27
10 54.47 90 5.07

9 03 .0 3

4 93 .54

2 177 .8 1

65 1.9 3
7 49 .6 7

65 2.4 9
7 49 .8 0

15 64 .39

4 15 .32

39 28.61

10 55.01
10 54.65 90 4.34

105 7.20

4 14 .2 3

23 42.34

3 792 .1 7

90 2.2 9

101 8.93
3 92 8.52

23 45.32

3 79 1.1 3

21 75.90

26 70 .15

3 785 .7 5

FTIR SPECTRUM
Date: 11-5-2010

Spectrum Name: SJC-0.5+ 0.1+0.4.sp

3 45 5.1 7

2 87 1.0 0

3 43 1.3 2

2 867 .4 7

28 71.39
34 46.59

29 41.96

29 41.36

34 47.99
29 42.53

171 3.47

171 6.75

0.0

29 41.39

0 .0

4000.0

300 0

2000

15 00

1000

400.0

171 4.66

29 41.90

0 .0

40 00.0

3 000

2000

1500

c m -1

1000

400.0

171 4.55

171 3.50

0 .0

40 00.0

3 000

2000

1500

c m -1

1000

400.0

0 .0

40 00.0

3 000

2000

1500

c m -1

1000

400.0

40 00.0

3 000

2000

1500

c m -1

1000

400.0

c m -1

SJ C-0.5+ 0.2+0.3.pk

SJ C-0.5+0.4+0.1.pk

SJ C-0.5+0.3+0.2.pk

SJ C-0.5+0.1+0.4.pk

SJ C-0.4+0.5+0.1.pk

SJ C-05~3.SP 3601 4000.00 400.00 7.01 99.99 4.00 %T 3 1.00

SJ C-05~1.SP 3601 4000.00 400.00 8.63 100.00 4.00 %T 3 1.00

SJ C-05~2.SP 3601 4000.00 400.00 9.53 99.99 4.00 %T 3 1.00

SJ C-05~4.SP 3601 4000.00 400.00 8.40 100.00 4.00 %T 3 1.00

SJ C-04~1.SP 3601 4000.00 400.00 9.42 100.00 4.00 %T 3 1.00

REF 4000 99.14 2000 97.22 600

3932.10 95.11 3785.75 88.95 3447.99 11.09 2942.53 7.04 2871.39 22.58
2670.15 90.51 2177.52 94.13 1716.75 7.01 1564.39 42.74 1433.02 28.34
1326.19 47.76 1222.90 51.67 1119.49 60.38 1057.20 79.81 902.29 79.69
749.00 67.39 651.22 69.55 493.54 58.54 421.74 87.07

REF 4000 97.38 2000 95.95 600

3927.77 94.92 3785.81 91.13 3446.59 20.08 2941.96 13.16 2866.78 31.31
2671.11 91.09 2175.90 93.59 1713.47 8.62 1563.37 52.20 1427.09 37.56
1314.03 53.58 1222.46 51.74 1118.97 58.70 1054.65 78.80 1018.90 82.94
904.34 77.78 864.78 85.54 749.80 70.63 652.49 74.55 491.27 61.74
414.99 88.90

REF 4000 98.50 2000 97.10 600

3934.64 95.56 3791.13 92.36 3431.32 25.85 2941.39 9.87 2871.00 27.68
2669.96 91.54 2345.32 95.97 2177.20 95.09 1714.66 9.53 1564.95 61.02
1435.37 37.28 1323.22 52.57 1223.03 55.18 1119.00 62.60 1055.01 79.88
903.03 81.11 749.67 76.41 651.93 81.89 492.23 68.75 419.47 94.89

REF 4000 98.21 2000 97.04 600

3928.52 95.87 3783.01 90.94 3455.17 29.09 2941.90 9.59 2867.47 27.08
2670.99 91.04 2342.34 95.38 2177.76 94.99 1714.55 8.39 1565.60 60.85
1432.95 37.92 1315.28 51.52 1222.66 49.88 1119.10 57.18 1054.47 78.24
1018.93 82.27 905.07 77.78 865.27 86.14 750.06 73.20 652.59 79.97
491.22 66.00 414.23 92.44

REF 4000 98.41 2000 97.41 600

3928.61 96.81 3792.17 93.24 3451.01 32.96 2941.36 13.64 2867.00 34.31
2670.57 93.30 2177.81 95.75 1713.50 9.41 1563.29 64.11 1432.69 45.05
1314.76 58.31 1222.68 56.08 1118.97 63.21 1054.37 82.27 904.99 81.26
865.17 87.97 749.85 76.69 652.26 81.48 491.24 69.21 415.32 92.23

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

10 0.0

100.0

3 87 9.9 9
26 71.61

37 80 .5 0

8 64 .75

80
1 96 5.1 3

26 69.71

100.0
10 18.18

5 86 .5 1

1 87 3.58
11 72 .7 8

20 71.33

3 78 7.1 2

100.0

865 .1 6

23 38 .0 2

23 45.83

Spectrum Name: SJ C-0.3+0.5+0.2.sp

10 18 .5 9
391 5.77

21 78 .12

2 670 .3 7

3 78 1.01

38 79 .9 8

2 33 8.9 6

2 17 6.60

21 77.85

37 78 .8 5

86 5.33

9 03.90

586 .8 3

26 69 .97

10 55 .3 9
6 52 .3 3
74 9.87

9 05.19

10 55 .0 0

37 12 .6 0
9 05.48

6 52 .5 1

24 52 .7 1
2 16 8.1 4

3 94 2.4 1

13 45.44

9 05 .1 9

26 70 .9 1

6 52 .4 3

10 38 .2 8

7 50 .4 3

10 51 .94

75 0.22
49 1.33

8 97.71

38 22 .3 8
41 5.4 8

1 87 4.69
11 72 .6 7

41 4.48

10 54 .3 8

65 2.1 0

FTIR SPECT RUM

Date: 14-5-2010

Spectrum Name: SJ C-0.4+0.1+0.5.sp

4 16 .8 0

42 1.0 8

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 11-5-2010

Spectrum Name: SJ C-0.4+0.2+0.4.sp

100.0

2 178 .9 8

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 11-5-2010

Spectrum Name: SJ C-0.4+0.3+0.3.sp

393 8.94

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 11-5-2010

FTIR SPECTRUM
Date: 11-5-2010
Spectrum Name: SJC-0.4+ 0.4+0.2.sp

15 65 .5 3

4 92.19

1 11 9.34

75 0.41

1 11 9.05

12 22 .5 2

49 1.72

4 96.64

74 6.93

49 1.95
1 31 5.13

%T
1 431 .8 6

6 50 .4 9

13 37 .2 8

131 6.69
12 22 .4 7

15 64.86

1 11 9.30

1 22 2.43

%T
1 22 3.7 5

15 66 .0 9

1 11 9.22

1 11 9.1 4

131 6.80
12 22 .2 6

40
13 24 .15

34 18 .7 9

2 87 6.47

14 29 .99

28 67 .2 7
14 36.06

3 453 .9 8

2 86 8.11

1 432 .5 7

20
2 868 .0 7

3 459 .5 5

1 42 2.18

40 00.0

17 27 .8 5

2 94 6.3 1

29 41 .7 8

1 569 .4 1

17 13 .96

17 14 .49

0.0

3 000

3 456 .5 2

29 41 .4 4

171 3.81
29 39.87

0 .0
2000

1500

1000

29 41 .7 5

0.0

4000.0

400.0

3000

2000

15 00

100 0

400.0

c m -1

17 15 .54

0.0

4000.0

3000

2000

15 00

cm-1

100 0

400.0

34 21 .5 3

0.0

4000.0

3000

2000

15 00

cm-1

100 0

400.0

4000.0

3000

2000

15 00

cm-1

100 0

SJ C-0.4+0.3+0.3.pk

SJ C-0.4+0.2+0.4.pk

SJ C-0.4+0.1+0.5.pk

SJ C-0.3+0.5+0.2.pk

SJ C-04~2.SP 3601 4000.00 400.00 7.82 100.00 4.00 %T 3 1.00

SJ C-04~3.SP 3601 4000.00 400.00 9.31 99.99 4.00 %T 3 1.00

SJ C-04~4.SP 3601 4000.00 400.00 8.41 100.00 4.00 %T 3 1.00

SJ 67A7~1.SP 3601 4000.00 400.00 8.30 99.99 4.00 %T 3 1.00

SJ C-03~1.SP 3601 4000.00 400.00 6.34 99.52 4.00 %T 3 1.00

REF 4000 99.42 2000 98.11 600

3938.94 97.29 3787.12 94.60 3418.79 36.62 2939.87 7.82 2669.71 86.12
2345.83 95.88 2178.98 95.63 2071.33 95.81 1965.13 96.70 1713.81 12.52
1436.06 33.84 1324.15 44.97 1223.75 49.71 1119.14 58.98 1051.94 75.25
897.71 74.41 750.43 73.95 652.10 85.17 492.19 66.77 421.08 93.59

REF 4000 97.99 2000 96.97 600

3879.99 96.44 3780.50 89.78 3453.98 29.07 2941.44 13.17 2867.27 33.97
2671.61 92.60 2178.12 95.35 1713.96 9.31 1565.53 63.91 1431.86 45.00
1315.13 59.59 1222.43 57.89 1119.05 64.97 1054.38 83.43 905.19 82.44
864.75 88.35 749.87 74.93 652.33 78.69 491.33 67.36 416.80 89.65

REF 4000 97.80 2000 96.23 600

3915.77 95.10 3781.01 87.36 3456.52 16.57 2941.78 12.31 2868.11 28.83
2670.37 90.09 2338.02 95.17 2176.60 93.50 1873.58 96.45 1714.49 8.40
1564.86 54.39 1429.99 33.80 1316.69 51.41 1222.47 50.84 1172.78 76.93
1119.22 58.60 1055.00 78.43 1018.59 82.67 905.19 77.64 865.16 86.37
750.22 68.56 652.51 74.78 586.51 83.06 491.95 61.85 414.48 90.10

REF 4000 97.44 2000 96.43 600

3879.98 95.57 3778.85 87.88 3459.55 23.37 2941.75 9.92 2868.07 25.52
2670.91 89.55 2338.96 95.84 2177.85 94.44 1874.69 96.28 1715.54 8.29
1566.09 66.74 1432.57 36.59 1345.44 51.23 1316.80 51.49 1222.26 50.68
1172.67 72.06 1119.30 59.24 1055.39 80.07 1018.18 84.62 905.48 77.81
865.33 86.59 750.41 70.54 652.43 78.85 586.83 85.12 491.72 63.49
415.48 87.79

REF 4000 98.62 2000 95.71 600

3942.41 87.88 3822.38 88.96 3712.60 81.90 3421.53 6.34 2946.31 14.78
2876.47 36.88 2669.97 89.12 2452.71 94.26 2168.14 89.76 1727.85 16.71
1569.41 11.99 1422.18 19.55 1337.28 57.99 1222.52 66.59 1119.34 70.60
1038.28 77.83 903.90 87.27 746.93 66.93 650.49 56.70 496.64 65.81

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 14-5-2010

2 67 0.27

395 1.27

100.0

1 966 .0 2

3 948 .4 4

6 52 .5 4

2 17 8.62

1 01 8.35 8 65 .7 5
1 57 2.05

583 .5 5

21 76.88

26 69 .94

1 17 5.15

6 51 .8 0

2 34 2.1 0

3 77 7.76
1 87 1.9 3
24 55 .7 7

3 943 .0 7
267 0.93

80 3 950 .9 2

6 51 .7 3

9 04.02

75 0.92

21 74 .2 7

1 018 .4 6

65 2.24
86 5.76

70
105 4.85

74 9.97

9 04.66
49 2.53

19 67 .6 5

2 17 6.6 7
26 70 .38

6 52 .5 7

75 1.18
10 57 .84

10 56 .70
49 1.12

1 87 3.57

1 01 8.7 8
9 05.30
9 03.19

9 04.80 75 0.48

41 5.06
4 14 .3 6

3 77 6.76
3 830 .3 0

26 69 .4 7

10 54 .9 2

100.0

864 .8 5
10 54 .3 6

2 34 7.1 7

2 34 6.9 9

3 94 1.39

Spectrum Name: SJ C-0.2+0.3+0.5.sp

4 18.26
1 96 4.66

383 3.01

1 96 4.53

38 32 .8 2

FTIR SPECT RUM

Date: 14-5-2010

Spectrum Name: SJ C-0.2+0.5+0.3.sp

4 19.41

21 76 .78

38 53.71

FTIR SPECT RUM

Date: 14-5-2010

Spectrum Name: SJ C-0.3+0.2+0.5.sp

100.0

4 14 .3 2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 14-5-2010

Spectrum Name: SJ C-0.3+0.3+0.4.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 14-5-2010

Spectrum Name: SJ C-0.3+0.4+0.3.sp

400.0

cm-1

SJ C-0.4+0.4+0.2.pk

49 3.13

1 569 .5 1

1 57 0.65

49 1.42

75 0.25

341 0.86
1 11 9.50

1 11 9.68

50
1 11 9.13

1 11 9.05

15 69.15

%T
40

%T
15 66 .8 5
12 22 .4 7
1 33 0.60

13 26 .0 7

1 22 2.8 1

49 1.05

%T
12 23 .0 0

1 31 5.23

1 31 5.52
12 22 .3 4

%T
1 11 9.05

341 4.30

1 31 5.24
12 22 .7 5

34 17 .9 6
1 43 6.33

14 29 .82

341 1.57

1 43 5.96

1 43 4.11
1 43 4.89

2 86 7.2 9

2 87 3.3 2

28 67.80

34 19 .9 4

2 867 .2 5

28 72.00

29 41 .2 4

10
29 42 .3 9

29 41 .4 0

17 13 .99

17 15 .29

0.0

4000.0

3000

2000

15 00

100 0

400.0

3000

2000

2 94 1.72

17 15 .34

17 14 .98

0.0

2 94 1.1 9

4000.0

15 00

cm-1

100 0

400.0

17 14 .15

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

0.0
3000

cm-1

2000

15 00

100 0

400.0

4000.0

3000

cm-1

2000

15 00

100 0

cm-1

SJ C-0.3+0.4+0.3.pk

SJ C-0.3+0.3+0.4.pk

SJ C-0.3+0.2+0.5.pk

SJ C-0.2+0.5+0.3.pk

SJ C-0.2+0.3+0.5.pk

SJ C-03~2.SP 3601 4000.00 400.00 8.61 100.00 4.00 %T 3 1.00

SJ C-03~3.SP 3601 4000.00 400.00 6.44 100.00 4.00 %T 3 1.00

SJ C-03~4.SP 3601 4000.00 400.00 8.23 100.00 4.00 %T 3 1.00

SJ C-02~3.SP 3601 4000.00 400.00 8.43 99.99 4.00 %T 3 1.00

SJ C-02~1.SP 3601 4000.00 400.00 7.36 100.00 4.00 %T 3 1.00

REF 4000 97.90 2000 97.40 600

3951.27 95.73 3853.71 96.78 3410.86 60.84 2941.40 9.53 2867.29 24.43
2670.27 89.76 2176.78 95.54 1966.02 96.26 1713.99 8.61 1572.05 77.82
1436.33 38.17 1315.23 48.03 1222.81 46.34 1119.13 54.51 1054.92 76.65
1018.35 82.20 904.80 73.84 865.75 83.46 750.48 74.41 652.54 86.76
491.12 65.68 414.32 90.21

REF 4000 97.75 2000 96.86 600

3941.39 94.67 3832.82 96.29 3414.30 43.93 2941.19 6.44 2872.00 19.59
2669.47 87.60 2346.99 94.64 2178.62 94.45 1964.53 95.83 1715.29 9.95
1569.51 65.51 1435.96 32.09 1326.07 46.46 1223.00 50.57 1119.50 60.11
1056.70 78.21 903.19 76.24 750.92 75.18 651.80 84.95 492.53 66.99
419.41 92.10

REF 4000 99.73 2000 98.75 600

3948.44 95.86 3833.01 98.35 3417.96 41.79 2941.24 13.01 2873.32 28.04
2669.94 91.40 2347.17 96.17 2176.88 96.16 1964.66 97.58 1715.34 8.22
1569.15 61.37 1434.89 29.68 1330.60 44.83 1222.47 49.46 1175.15 67.80
1119.68 59.71 1057.84 78.62 904.02 77.02 751.18 74.53 651.73 85.37
583.55 91.19 493.13 67.20 418.26 93.49

REF 4000 98.07 2000 96.37 600

3950.92 92.90 3830.30 95.48 3776.76 94.24 3419.94 23.91 2942.39 10.92
2867.80 28.53 2670.93 91.36 2342.10 94.72 2174.27 93.72 1873.57 96.91
1714.98 8.43 1566.85 51.73 1429.82 35.93 1315.52 53.91 1222.34 52.63
1119.05 60.25 1054.36 80.66 1018.78 83.99 905.30 79.98 864.85 87.45
749.97 72.20 652.57 76.22 491.42 65.36 414.36 91.40

REF 4000 96.78 2000 95.18 600

3943.07 92.03 3777.76 94.63 3411.57 38.88 2941.72 7.36 2867.25 18.69
2670.38 82.41 2455.77 91.88 2176.67 91.37 1967.65 93.91 1871.93 94.73
1714.15 8.10 1570.65 66.73 1434.11 31.88 1315.24 42.58 1222.75 41.23
1119.05 48.96 1054.85 71.38 1018.46 77.46 904.66 69.53 865.76 80.08
750.25 68.00 652.24 79.36 491.05 58.63 415.06 85.13

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 14-5-2010

FTIR SPECT RUM

Date: 14-5-2010

Spectrum Name: SJ C-0.2+0.4+0.4.sp

Date: 14-5-2010

Spectrum Name: SJ C-0.1+0.5+0.4.sp

100.0

4 14 .2 9

Spectrum Name: SJ C-0.1+0.4+0.5.sp

100.0

2 34 3.73

41 4.72

41 4.20

58 6.41
3 829 .3 9

10 17 .8 2

1 96 7.01

245 7.50

3 94 4.73

15 68 .5 7

21 75.94

37 78.36

1 87 2.91
3 828 .9 4

2 458 .0 4

1 87 2.4 0

80
8 65 .8 8

2 670 .4 4

21 76 .2 9

6 52 .4 1

86 5.57

10 55 .8 0

11 72 .86

1 17 2.68

18 71.91

2 670 .3 3

101 8.54

101 8.14

19 68.99
2 34 3.0 0

3 94 4.45

217 5.42
394 8.44

267 0.38

6 52 .4 1

86 5.35

10 55 .4 7

9 05.23

1 96 8.75

6 52 .2 2

9 04.93

10 55 .3 3
9 04.46

75 0.79

75 0.49

15 67 .7 1

49 1.68

75 0.12

60
49 1.45

1 11 9.34

49 1.29

50
1 11 9.25

1 56 2.00

1 317 .3 5

1 34 6.81
12 22 .1 8

1 11 9.12
131 6.09
12 22 .4 9

131 6.46
12 22 .4 7

341 2.78

1 433 .4 6

341 4.11
1 43 4.23

1 433 .3 2
34 15 .7 2

28 68.98

28 68.71

20
28 68.76

10
29 42 .4 5

29 41 .6 9

17 15 .39

29 41 .7 8

0.0
4000.0

17 15 .00

17 15 .29

0.0
3000

2000

15 00

100 0

400.0

4000.0

0.0
3000

cm-1

2000

15 00

100 0

400.0

4000.0

3000

cm-1

2000

15 00

100 0

400.0

cm-1

SJ C-0.2+0.4+0.4.pk

SJ C-0.1+0.5+0.4.pk

SJ C-0.1+0.4+0.5.pk

SJ C-02~2.SP 3601 4000.00 400.00 8.37 100.00 4.00 %T 3 1.00

SJ C-01~1.SP 3601 4000.00 400.00 7.97 99.99 4.00 %T 3 1.00

SJ C-01~2.SP 3601 4000.00 400.00 7.99 100.00 4.00 %T 3 1.00

REF 4000 97.73 2000 96.70 600

3944.73 92.92 3829.39 95.14 3412.78 40.63 2941.69 10.02 2868.98 24.39
2670.33 85.88 2457.50 94.72 2175.94 93.51 1967.01 95.36 1871.91 95.62
1715.39 8.36 1568.57 70.95 1433.46 34.43 1346.81 47.11 1317.35 48.48
1222.18 48.02 1172.68 66.02 1119.34 56.72 1055.80 76.86 1017.82 82.55
905.23 73.74 865.88 83.76 750.79 70.37 652.41 83.03 586.41 89.54
491.68 64.38 414.29 89.37

REF 4000 97.35 2000 95.87 600

3944.45 93.13 3778.36 95.78 3414.11 35.99 2941.78 7.97 2868.76 21.04
2670.44 85.92 2343.00 92.83 2176.29 92.63 1968.99 94.78 1872.40 95.52
1715.00 8.14 1567.71 71.39 1434.23 33.44 1316.46 46.64 1222.47 46.05
1172.86 74.42 1119.25 54.73 1055.47 76.65 1018.14 82.63 904.93 73.67
865.57 83.59 750.49 69.36 652.41 81.03 491.45 61.88 414.72 87.52

REF 4000 97.46 2000 95.35 600

3948.44 88.43 3828.94 93.56 3415.72 29.30 2942.45 12.01 2868.71 27.61
2670.38 85.39 2458.04 93.31 2343.73 92.34 2175.42 91.36 1968.75 94.07
1872.91 95.54 1715.29 7.99 1562.00 59.09 1433.32 33.35 1316.09 47.37
1222.49 46.07 1119.12 53.77 1055.33 73.98 1018.54 80.27 904.46 73.25
865.35 82.71 750.12 67.53 652.22 77.64 491.29 60.94 414.20 88.92

303

400.0

Table - 7.24
Observations of FTIR Spectrums for
Cyclohexanone + Hexane + 2-Butanone mixture
S1

(Cm-1)

3927.77
3785.81
3446.59
2941.96
2866.78
2671.11
2175.90
1713.47
1563.37
1427.09
1314.03
1222.46
1118.97
1054.65
1018.90
904.34
864.78
749.80
652.49
491.27
414.99

S10 (Cm-1)
3942.41
3822.38
3712.60
3421.53
2946.31
2876.47
2669.97
2452.71
2168.14
1727.85
1569.41
1422.18
1337.28
1222.52
1119.34
1038.28
903.90
746.93
650.49
496.64

(Cm-

S2
1

3934.64
3791.13
3431.32
2941.39
2871.00
2669.96
2345.32
2177.20
1714.66
1564.95
1435.37
1323.22
1223.03
1119.00
1055.01
903.03
749.67
651.93
492.23
419.47

S3 (Cm1
)

3932.10
3785.75
3447.99
2942.53
2871.39
2670.15
2177.52
1716.75
1564.39
1433.02
1326.19
1222.90
1119.49
1057.20
902.29
749.00
651.22
493.54
421.74

3928.52
3783.01
3455.17
2941.90
2867.47
2670.99
2342.34
2177.76
1714.55
1565.60
1432.95
1315.28
1222.66
1119.10
1054.47
1018.93
905.07
865.27
750.06
652.59
491.22
414.23

S11 (Cm1
)

S12 (Cm1
)

3951.27
3853.71
3410.86
2941.40
2867.29
2670.27
2176.78
1966.02
1713.99
1572.05
1436.33
1315.23
1222.81
1119.13
1054.92
1018.35
904.80
865.75
750.48
652.54
491.12
414.32

3941.39
3832.82
3414.30
2941.19
2872.00
2669.47
2346.99
2178.62
1964.53
1715.29
1569.51
1435.96
1326.07
1223.00
1119.50
1056.70
903.19
750.92
651.80
492.53
419.41

(Cm)

S13 (Cm-1)
3948.44
3833.01
3417.96
2941.24
2873.32
2669.94
2347.17
2176.88
1964.66
1715.34
1569.15
1434.89
1330.60
1222.47
1175.15
1119.68
1057.84
904.02
751.18
651.73
583.55
493.13
418.26

S5 (Cm-1)
3928.61
3792.17
3451.01
2941.36
2867.00
2670.57
2177.81
1713.50
1563.29
1432.69
1314.76
1222.68
1118.97
1054.37
904.99
865.17
87.97
749.85
652.26
491.24
415.32

(Cm-

S6
1

3938.94
3787.12
3418.79
2939.87
2669.71
2345.83
2178.98
2071.33
1965.13
1713.81
1436.06
1324.15
1223.75
1119.14
1051.94
897.71
750.43
652.10
492.19
421.08

(Cm-

S14 (Cm1
)

*S15

3950.92
3830.30
3776.76
3419.94
2942.39
2867.80
2670.93
2342.10
2174.27
1873.57
1714.98
1566.85
1429.82
1315.52
1222.34
1119.05
1054.36
1018.78
905.30
864.85
749.97
652.57
491.42
414.36

3944.73
3829.39
3412.78
2941.69
2868.98
2670.33
2457.50*
2175.94
1967.01*
1871.91
1715.39
1568.57
1433.46
1346.81*
1317.35
1222.18
1172.68*
1119.34
1055.80
1017.82
905.23
865.88
750.79
652.41
586.41
491.68
414.29

* Maximum shift in the frequency has been observed.

304

S7
(Cm-1)
3879.99
3780.50
3453.98
2941.44
2867.27
2671.61
2178.12
1713.96
1565.53
1431.86
1315.13
1222.43
1119.05
1054.38
905.19
864.75
749.87
652.33
491.33
416.80

(Cm)

3915.77
3781.01
3456.52
2941.78
2868.11
2670.37
2338.02
2176.60
1873.58
1714.49
1564.86
1429.99
1316.69
1222.47
1172.78
1119.22
1055.00
1018.59
905.19
865.16
750.22
652.51
586.51
491.95
414.48

*S9

(Cm-

3879.98
3778.85
3459.55
2941.75
2868.07
2670.91
2338.96
2177.85
1874.69
1715.54
1566.09
1432.57
1345.44*
1316.80
1222.26
1172.67
1119.30
1055.39
1018.18
905.48
865.33
750.41
652.43
586.83
491.72
415.48

S16 (Cm1
)

S17 (Cm1
)

S18 (Cm1
)

3943.07
3777.76
3411.57
2941.72
2867.25
2670.38
2455.77
2176.67
1967.65
1871.93
1714.15
1570.65
1434.11
1315.24
1222.75
1119.05
1054.85
1018.46
904.66
865.76
750.25
652.24
491.05
415.06

3944.45
3778.36
3414.11
2941.78
2868.76
2670.44
2343.00
2176.29
1968.99
1872.40
1715.00
1567.71
1434.23
1316.46
1222.47
1172.86
1119.25
1055.47
1018.14
904.93
865.57
750.49
652.41
491.45
414.72

3948.44
3828.94
3415.72
2942.45
2868.71
2670.38
2458.04
2343.73
2175.42
1968.75
1872.91
1715.29
1562.00
1433.32
1316.09
1222.49
1119.12
1055.33
1018.54
904.46
865.35
750.12
652.22
491.29
414.20

Fig-7.24: FTIR Spectrums for Cyclohexanone+Hexane+Ethyl Acetate mixture:

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010
Spectrum Name: II-0.5+0.4+0.1.s p

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.5+0.2+0.3.s p

100.0

4 18 .7 1

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.5+0.3+0.2.s p

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.5+0.1+0.4.s p

100.0

Spectrum Name: II-0.4+0.5+0.1.s p

100.0

100.0
425 .6 3

3 89 2.1 1

26 69 .5 3

2 074 .4 1

39 03 .7 3

2 08 0.52

42 1.72

20 81.80

26 68 .6 3

2 66 9.7 5

2 669 .5 9

6 51 .7 3

89 7.0 0

90 0.30

2 07 7.60

2 07 7.36
266 5.99

3 77 9.91

89 8.1 7

10 51 .4 3

6 47 .7 2

74 9.72

10 51 .7 6

9 02.72

49 1.83
6 51 .2 6
74 8.28
49 3.18

1 11 8.53

8 91 .0 7

70
6 49 .3 6

74 7.44

6 48 .8 4

10 53 .0 2

1 11 8.72

74 8.69

49 2.57

10 57 .58

74 9.35
1 05 4.9 8

13 21 .92
132 1.25
1 22 5.20

50
%T

11 16 .6 3

132 0.60

49 4.14

60
49 2.25

1 11 7.62
122 6.98

50
%T

1 11 7.81

%T
132 1.54

1 433 .3 4

1 43 7.33

1 43 5.88

13 25 .7 5

1 43 8.50

28 72 .4 9

30
3 429 .4 3

171 2.60

1 43 7.55

12 33 .88

10
29 40 .2 0

17 14 .02

294 0.97

28 70 .9 5

3 428 .3 2

3 458 .6 5

10
34 47.47

34 41.46

29 40 .4 7

12 36 .0 8

2 87 3.48

12 32 .42

17 14 .55

10
29 41 .8 5
17 15 .62

0.0

4000.0

3000

2000

15 00

100 0

400.0

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

29 41 .6 2

0.0

4000.0

3000

2000

15 00

cm-1

100 0

400.0

17 15 .20

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

3000

2000

cm-1

15 00

100 0

II-0.5+0.3+0.2.pk

II-0.5+0.2+0.3.pk

II-0.5+0.1+0.4.pk

II-0.4+0.5+0.1.pk

II-05_~1.SP 3601 4000.00 400.00 10.54 100.00 4.00 %T 3 1.00

II-05_~2.SP 3601 4000.00 400.00 12.73 100.00 4.00 %T 3 1.00

II-05_~3.SP 3601 4000.00 400.00 11.41 99.99 4.00 %T 3 1.00

II-05_~4.SP 3601 4000.00 400.00 9.43 100.00 4.00 %T 3 1.00

II-04_~2.SP 3601 4000.00 400.00 8.48 99.92 4.00 %T 3 1.00

REF 4000 99.54 2000 97.02 600

3892.11 95.99 3441.46 11.77 2940.47 14.06 2872.49 36.90 2669.53 96.35
2080.52 94.02 1712.60 10.53 1433.34 46.19 1321.92 60.84 1226.98 56.68
1118.53 67.72 1051.43 81.27 897.00 83.43 748.28 67.32 651.26 69.65
493.18 67.58

REF 4000 99.66 2000 98.24 600

3429.43 33.01 2940.20 12.74 2873.48 31.79 2669.59 95.07 2074.41 96.46
1714.02 12.73 1437.33 46.04 1321.25 55.65 1225.20 55.07 1118.72 64.52
1051.76 79.75 900.30 81.53 749.72 77.47 651.73 85.14 491.83 72.65
418.71 96.08

REF 4000 99.21 2000 96.75 600

3447.47 13.80 2940.97 14.63 2669.75 95.13 2081.80 93.88 1714.55 11.40
1435.88 45.22 1320.60 56.75 1236.08 34.46 1117.62 64.06 1053.02 67.33
898.17 81.84 748.69 68.01 648.84 69.85 492.57 65.37

REF 4000 99.19 2000 97.31 600

3903.73 97.71 3779.91 87.12 3458.65 15.67 2941.85 10.19 2870.95 27.16
2668.63 93.92 2077.36 94.59 1715.62 9.43 1438.50 40.02 1321.54 50.81
1233.88 30.79 1117.81 57.71 1054.98 64.19 902.72 77.72 749.35 67.98
649.36 73.31 492.25 62.35 421.72 88.37

REF 4000 99.82 2000 97.90 600

3428.32 22.80 2941.62 8.58 2665.99 94.01 2077.60 95.25 1715.20 8.48
1437.55 35.96 1325.75 45.68 1232.42 41.60 1116.63 60.07 1057.58 71.24
891.07 76.98 747.44 72.60 647.72 79.84 494.14 66.25 425.63 92.22

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010
Spectrum Name: II-0.4+0.4+0.2.s p

100.0

2 669 .5 7

2 458 .3 4

2 66 8.75

2 341 .0 8

4 13.61

26 68.67

1 05 2.49

80
13 24 .2 5

8 64 .45

74 9.13

6 50 .9 2

88 8.3 0

49 2.04

1 11 7.57

396 2.41

49 2.27

9 04.50 75 0.44

1 11 8.37

123 0.42

1 43 7.02

13 26 .2 2

4 99 .3 0

28 70.58

50
%T

7 41 .87

1 43 5.70

122 9.04

1 11 8.48

142 5.06

6 48 .9 9

1 31 3.64

28 77.47

14 42 .8 6

2 873 .1 3

4 98.79

64 9.82

49 1.29

50
%T
10 53 .2 3

1 43 6.00

7 40 .76

12 26 .9 4

11 16 .0 0

1 05 5.52

132 0.55

50
%T

2 08 0.46
10 39 .5 1

2 34 7.4 12 08 0.88

1 87 2.4 6
6 51 .0 7

74 8.53
1 11 8.11

132 0.95

2 676 .7 2

38 80 .7 4

90 1.76

6 51 .0 4

1 05 2.38

100.0
38 25 .2 2

2 670 .4 4

3 77 6.04

89 8.1 6

Spectrum Name: II-0.3+0.5+0.2.s p

100.0

19 70.29

21 76 .51

3 78 2.7 4

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.4+0.1+0.5.s p

2 33 5.0 7 20 66.83
39 28 .0 7

2 07 8.29

2 081 .3 4

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.4+0.2+0.4.s p

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.4+0.3+0.3.s p

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010

400.0

cm-1

II-0.5+0.4+0.1.pk

1 23 8.95

341 3.97

29 42 .3 7

12 33 .61
34 45.73

2 86 6.83

10
34 49 .9 7

29 41 .2 9

29 40 .7 6

3000

2000

15 00

100 0

400.0

4000.0

3000

2000

15 00

100 0

400.0

0.0

4000.0

17 13 .35

17 14 .01

0.0

cm-1

29 41 .0 0

17 13 .37
29 41 .6 5

0.0

4000.0

1 64 2.9 2

17 14 .49

17 14 .47

0.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

34 40.05

0.0

341 5.84

3000

2000

cm-1

15 00

100 0

400.0

4000.0

3000

2000

cm-1

15 00

100 0

II-0.4+0.3+0.3.pk

II-0.4+0.2+0.4.pk

II-0.4+0.1+0.5.pk

II-0.3+0.5+0.2.pk

II-04_~1.SP 3601 4000.00 400.00 9.60 100.00 4.00 %T 3 1.00

II-04_~3.SP 3601 4000.00 400.00 10.33 99.81 4.00 %T 3 1.00

II-04_~4.SP 3601 4000.00 400.00 8.31 99.99 4.00 %T 3 1.00

II5C66~1.SP 3601 4000.00 400.00 6.35 99.20 4.00 %T 3 1.00

II-03_~1.SP 3601 4000.00 400.00 7.96 99.96 4.00 %T 3 1.00

REF 4000 99.86 2000 97.10 600

3449.97 12.99 2941.29 11.14 2669.57 95.67 2341.08 96.65 2081.34 94.27
1714.47 9.59 1436.00 45.77 1320.95 57.65 1230.42 47.28 1118.11 64.73
1052.38 75.20 898.16 82.88 748.53 69.99 651.04 73.87 492.27 70.29

REF 4000 99.49 2000 97.98 600

3782.74 90.20 3445.73 20.44 2940.76 12.12 2873.13 32.93 2668.75 95.94
2078.29 96.16 1714.49 10.33 1437.02 47.47 1320.55 57.98 1229.04 49.32
1118.37 65.05 1052.49 76.98 901.76 83.41 749.13 74.82 651.07 79.66
492.04 71.98

REF 4000 97.42 2000 96.27 600

3928.07 96.14 3776.04 89.59 3413.97 27.54 2941.65 8.31 2866.83 19.50
2670.44 88.41 2458.34 96.38 2335.07 95.60 2176.51 93.66 2066.83 93.08
1970.29 94.93 1872.46 94.87 1714.01 8.95 1442.86 34.27 1313.64 41.61
1233.61 21.46 1118.48 46.22 1053.23 51.64 904.50 67.82 864.45 79.02
750.44 66.04 650.92 78.34 491.29 59.01 413.61 86.68

REF 4000 99.20 2000 93.16 600

3962.41 72.69 3880.74 96.45 3825.22 95.65 3415.84 6.35 2942.37 26.62
2870.58 56.63 2676.72 95.78 2347.41 88.49 2080.88 87.23 1713.37 12.25
1642.92 17.62 1425.06 44.56 1324.25 68.36 1238.95 30.16 1116.00 66.99
1055.52 64.88 741.87 49.84 648.99 45.25 499.30 59.20

REF 4000 99.89 2000 96.26 600

3440.05 7.96 2941.00 15.90 2877.47 41.24 2668.67 97.07 2080.46 93.04
1713.35 11.50 1435.70 51.04 1326.22 64.14 1226.94 70.52 1117.57 73.41
1039.51 87.11 888.30 86.69 740.76 68.35 649.82 68.86 498.79 70.63

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.3+0.4+0.3.s p

Spectrum Name: II-0.3+0.3+0.4.s p

100.0

Spectrum Name: II-0.3+0.2+0.5.s p

100.0

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.2+0.5+0.3.s p

100.0

400.0

cm-1

II-0.4+0.4+0.2.pk

Spectrum Name: II-0.2+0.4+0.4.s p

100.0

4 24 .02

3 93 3.85

2 07 8.83
39 37.63

20 81.34

26 69 .3 4

26 69 .3 0

90
39 27 .8 5

2 08 0.05

26 70 .0 5

2 67 1.22

20 81.78

2 66 9.7 1

2 08 0.63

3 92 9.90

2 34 9.9 0

37 83 .5 1

2 342 .9 0

9 02.41
9 02.76

90 0.94

89 7.1 2

49 1.88

49 2.70

89 5.0 3

6 49 .8 5
74 9.99

6 49 .9 3
74 7.80
49 3.82

1 05 5.13

10 52 .1 0

1 11 8.07

1 11 7.61

10 52.81

10 52 .0 7

6 49 .3 9
74 9.61

6 50 .4 1
74 8.41
49 3.13

1 11 8.47

60
13 22 .22

1 11 7.55

1 11 7.82

132 1.52

74 7.25

49 4.00

132 1.15

10 50 .8 0

6 50 .7 6

122 9.92

132 0.89
132 1.64

1 43 4.87

1 43 7.18

1 43 4.67
12 34 .06

1 43 7.60

1 43 6.71

12 34 .73

2 87 0.49

1 64 7.0 8

28 73 .4 5

12 35 .7 6

34 23 .0 1

12 36 .8 6

10
29 40 .6 7
29 40 .2 9

3000

2000

15 00

100 0

400.0

17 14 .43

3000

2000

cm-1

15 00

100 0

400.0

4000.0

29 40 .7 3

2000

15 00

100 0

400.0

4000.0

cm-1

17 14 .75

17 13 .78

0.0
3000

cm-1

29 41 .9 1

3 43 6.37

3 454 .2 8

0.0

4000.0

29 41 .5 1

17 16 .2 2

17 16 .2 0

0.0

4000.0

3 43 3.03

0.0

0.0
3000

2000

15 00

100 0

400.0

34 38 .3 3

4000.0

cm-1

3000

2000

15 00

100 0

cm-1

II-0.3+0.4+0.3.pk

II-0.3+0.3+0.4.pk

II-0.3+0.2+0.5.pk

II-0.2+0.5+0.3.pk

II-0.2+0.4+0.4.pk

II-03_~2.SP 3601 4000.00 400.00 9.04 100.00 4.00 %T 3 1.00

II-03_~3.SP 3601 4000.00 400.00 10.22 100.00 4.00 %T 3 1.00

II-03_~4.SP 3601 4000.00 400.00 7.99 99.95 4.00 %T 3 1.00

II-02_~3.SP 3601 4000.00 400.00 11.44 100.00 4.00 %T 3 1.00

II-02_~2.SP 3601 4000.00 400.00 6.35 99.99 4.00 %T 3 1.00

REF 4000 99.01 2000 96.54 600

3933.85 93.10 3783.51 84.94 3433.03 11.69 2940.29 9.27 2669.71 93.22
2081.34 92.81 1716.20 9.04 1436.71 35.96 1321.64 48.39 1236.86 25.98
1117.55 58.50 1050.80 59.00 900.94 77.65 749.61 66.42 649.39 71.54
492.70 63.10

REF 4000 99.48 2000 97.92 600

3937.63 95.10 3423.01 28.17 2940.67 10.22 2669.30 93.58 2342.90 96.75
2078.83 95.36 1716.22 11.15 1437.60 39.91 1320.89 50.40 1235.76 30.04
1117.82 59.69 1052.10 63.20 902.76 79.41 749.99 74.40 649.85 80.86
491.88 68.84 424.02 93.79

REF 4000 99.78 2000 96.45 600

3454.28 7.99 2941.51 14.43 2870.49 35.29 2669.34 95.75 2349.90 96.16
2080.05 92.87 1714.43 11.76 1647.08 37.48 1437.18 47.02 1321.52 59.69
1234.73 37.89 1117.61 64.96 1055.13 70.62 902.41 83.62 747.80 66.40
649.93 68.45 493.82 67.96

REF 4000 99.55 2000 96.55 600

3927.85 96.56 3436.37 11.44 2940.73 15.92 2873.45 37.07 2670.05 95.79
2081.78 93.32 1713.78 11.76 1434.67 46.45 1321.15 59.50 1234.06 43.40
1118.07 66.45 1052.07 73.76 897.12 83.08 748.41 66.72 650.41 68.99
493.13 67.13

REF 4000 99.29 2000 95.23 600

3929.90 89.76 3438.33 6.35 2941.91 16.94 2671.22 95.45 2080.63 91.51
1714.75 13.36 1434.87 48.11 1322.22 61.05 1229.92 52.70 1118.47 66.67
1052.81 78.27 895.03 82.96 747.25 61.49 650.76 61.51 494.00 61.43

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 17-6-2010

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.2+0.3+0.5.s p

100.0

2 34 4.5 1
2 07 6.52

Spectrum Name: II-0.1+0.4+0.5.s p

100.0

42 1.94

3 94 0.58

FTIR SPECT RUM

Date: 17-6-2010

Spectrum Name: II-0.1+0.5+0.4.s p

100.0

26 72 .03
3 92 8.6 1

20 85.27

26 69 .43

2 670 .7 4

20 87.90

3 93 3.26

2 34 9.2 6

10 53 .4 2
6 50 .0 3

9 02.61

1 11 7.82
13 23 .47

75 0.12

49 4.42

4 96.62

60
49 2.03

12 34 .44

10 51 .5 0

11 17 .3 0

60
1 32 1.16

742 .8 9

10 54 .27

74 7.54
6 48 .7 8

14 30 .48

50
1 11 8.02

6 49 .8 0

%T
1 433 .5 1

132 1.29

1 43 8.31

1 644 .4 5

20
17 13 .58

10
2 94 0.2 5

4000.0

1 23 8.01

29 42 .2 2

12 35 .1 9
34 70.79

10
17 16 .7 2

0.0

0.0
3000

2000

15 00

100 0

400.0

4000.0

cm-1

II-0.2+0.3+0.5.pk

29 43 .0 1

17 16 .3 7

34 45.13

3 441 .7 8

0.0
3000

2000

15 00

100 0

400.0

4000.0

cm-1

II-0.1+0.5+0.4.pk

3000

2000

15 00

100 0

400.0

cm-1

II-0.1+0.4+0.5.pk

II-02_~1.SP 3601 4000.00 400.00 7.51 100.00 4.00 %T 3 1.00

II-01_~2.SP 3601 4000.00 400.00 6.33 99.99 4.00 %T 3 1.00

II-01_~1.SP 3601 4000.00 400.00 7.98 100.00 4.00 %T 3 1.00

REF 4000 99.01 2000 97.21 600

3940.58 96.76 3470.79 18.71 2940.25 7.51 2669.43 91.92 2344.51 95.91
2076.52 94.43 1716.72 8.73 1438.31 31.69 1321.29 41.67 1235.19 23.71
1118.02 53.22 1051.50 57.90 902.61 74.18 750.12 69.96 650.03 78.86
492.03 62.46 421.94 92.09

REF 4000 99.19 2000 95.33 600

3928.61 94.91 3441.78 6.33 2942.22 27.15 2672.03 97.64 2087.90 91.53
1713.58 19.06 1644.45 33.74 1430.48 59.26 1323.47 74.31 1234.44 60.72
1117.82 75.41 1053.42 81.51 742.89 62.74 649.80 59.88 496.62 67.04

REF 4000 100.00 2000 96.38 600

3933.26 87.64 3445.13 7.98 2943.01 13.62 2670.74 96.22 2349.26 93.97
2085.27 92.19 1716.37 13.14 1433.51 49.31 1321.16 64.71 1238.01 32.96
1117.30 68.09 1054.27 67.52 747.54 65.20 648.78 64.29 494.42 69.10

305

400.0

Table - 7.25
Observations of FTIR Spectrums for
Cyclohexanone + Hexane + Ethyl Acetate mixture
*S8
(Cm-1)

S1
(Cm-1)

S2
(Cm-1)

S3
(Cm-1)

S4
(Cm-1)

S5
(Cm-1)

S6
(Cm-1)

3892.11
3441.46
2940.47
2872.49
2669.53
2080.52
1712.60
1433.34
1321.92
1226.98
1118.53
1051.43
897.00
748.28
651.26
493.18

3429.43
2940.20
2873.48
2669.59
2074.41
1714.02
1437.33
1321.25
1225.20
1118.72
1051.76
900.30
749.72
651.73
491.83
418.71

3447.47
2940.97
2669.75
2081.80
1714.55
1435.88
1320.60
1236.08
1117.62
1053.02
898.17
748.69
648.84
492.57

3903.73
3779.91
3458.65
2941.85
2870.95
2668.63
2077.36
1715.62
1438.50
1321.54
1233.88
1117.81
1054.98
902.72
749.35
649.36
492.25
421.72

3428.32
2941.62
2665.99
2077.60
1715.20
1437.55
1325.75
1232.42
1116.63
1057.58
891.07
747.44
647.72
494.14
425.63

3449.97
12.99
941.29
2669.57
2341.08
2081.34
1714.47
1436.00
1320.95
1230.42
1118.11
1052.38
898.16
748.53
651.04
492.27

S10
(Cm-1)

S11
(Cm-1)

S12
(Cm-1)

* S13
(Cm-1)

S14
(Cm-1)

S15
(Cm-1)

S16
(Cm-1)

S17
(Cm-1)

S18
(Cm-1)

3440.05
2941.00
2877.47
2668.67
2080.46
1713.35
1435.70
1326.22
1226.94
1117.57
1039.51
888.30
740.76
649.82
498.79

3933.85
3783.51
3433.03
2940.29
2669.71
2081.34
1716.20
1436.71
1321.64
1236.86
1117.55
1050.80
900.94
749.61
649.39
492.70

3937.63
3423.01
2940.67
2669.30
2342.90
2078.83
1716.22
1437.60
1320.89
1235.76
1117.82
1052.10
902.76
749.99
649.85
491.88
424.02

3454.28
2941.51
2870.49
2669.34
2349.90
2080.05
1714.43
1647.08
1437.18
1321.52
1234.73
1117.61
1055.13
902.41
747.80
649.93
493.82

3927.85
3436.37
2940.73
2873.45
2670.05
2081.78
1713.78
1434.67
1321.15
1234.06
1118.07
1052.07
897.12
748.41
650.41
493.13

3929.90
3438.33
2941.91
2671.22
2080.63
1714.75
1434.87
1322.22
1229.92
1118.47
1052.81
895.03
747.25
650.76
494.00

3940.58
3470.79
2940.25
2669.43
2344.51
2076.52
1716.72
1438.31
1321.29
1235.19
1118.02
1051.50
902.61
750.12
650.03
492.03
421.94

3928.61
3441.78
2942.22
2672.03
2087.90
1713.58
1644.45
1430.48
1323.47
1234.44
1117.82
1053.42
742.89
649.80
496.62

3933.26
3445.13
2943.01
2670.74
2349.26
2085.27
1716.37
1433.51
1321.16
1238.01
1117.30
1054.27
747.54
648.78
494.42

* Maximum shift in the frequency has been observed.

306

S7
(Cm-1)
3782.74
3445.73
2940.76
2873.13
2668.75
2078.29
1714.49
1437.02
1320.55
1229.04
1118.37
1052.49
901.76
749.13
651.07
492.04

3928.07
3776.04
3413.97
2941.65
2866.83
2670.44
2458.34*
2335.07*
2176.51*
2066.83
1970.29*
1872.46*
1714.01
1442.86
1313.64
1233.61
1118.48
1053.23
904.50
864.45*
750.44
650.92

S9
(Cm-1)
3962.41
3880.74
3825.22
3415.84
2942.37
2870.58
2676.72
2347.41
2080.88
1713.37
1642.92
1425.06
1324.25
1238.95
1116.00
1055.52
741.87
648.99
499.30

Fig-7.25: FTIR Spectrum for Cyclohexanone + Heptane + 2-Butanone mixture:

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010
Spectrum Name: K-0.5+0.4+0.1.sp
100.0

21 77 .81
37 90 .16

2 670 .3 7

37 89 .6 9

89 6.3 5

1 05 0.6 6

6 51 .5 7
74 7.97
6 49 .1 0

90 0.51

75 0.13

6 51 .9 8
2 66 9.8 7

6 48 .8 2
89 4.6 4

74 9.25
1 042 .0 9

89 7.8 0 75 0.46

15 78.58
49 2.68

49 1.60

49 1.53

1 22 4.49

1 57 2.28

1 11 9.21

1 05 1.2 5
49 1.83
15 78.02

1 12 0.34

12 22 .7 5
13 24 .6 0

50
12 23 .1 3

49 4.07

1 11 9.07

13 24 .44

1 11 9.07

50
1 57 3.60

12 24.33

13 23 .23

1 574 .7 1

39 40.31

1 05 0.7 9
1 11 8.41

4 19 .2 2

21 79 .43
1 96 3.83

37 89.34

196 2.54

26 69 .4 4

6 51 .2 3

90 3.28 74 9.93

20 79 .9 5

37 85 .5 4

2 67 0.55

1 04 5.71

Spectrum Name: K-0.4+0.5+0.1.sp

100.0
4 27.00

3 90 8.21

21 79 .10

42 5.55

196 6.64

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.5+0.1+0.4.sp

100.0
4 26 .9 6

392 1.77

2 07 6.42
3 786 .9 3

2 67 1.46

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.5+0.2+0.3.sp

100.0

39 10.00

3 927 .8 6

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.5+0.3+0.2.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

1 22 4.00

40
13 27 .5 8

341 4.34

34 24 .9 9
1 432 .5 2

13 24 .42
1 43 5.16

1 43 4.25

34 23 .9 3
1 43 4.92

3 43 1.92

171 3.01

29 41 .1 9

3000

2000

15 00

100 0

400.0

3000

2000

15 00

100 0

400.0

2 94 0.68

0.0

4000.0

17 13 .60

17 16 .1 6
29 41 .2 1

0.0

4000.0

cm-1

17 15 .03
29 40 .9 7

0.0

4000.0

3 429 .8 5

17 14 .75

29 39 .6 0

0.0

1 43 5.79

3000

2000

cm-1

15 00

100 0

400.0

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

cm-1

K-0.5+0.4+0.1.pk

K-0.5+0.3+0.2.pk

K-0.5+0.2+0.3.pk

K-0.5+0.1+0.4.pk

K-0.4+0.5+0.1.pk

K-05_0~2.SP 3601 4000.00 400.00 9.82 99.90 4.00 %T 3 1.00

K-05_0~4.SP 3601 4000.00 400.00 10.23 99.76 4.00 %T 3 1.00

K-05_0~1.SP 3601 4000.00 400.00 8.75 100.00 4.00 %T 3 1.00

K-05_0~3.SP 3601 4000.00 400.00 8.54 99.97 4.00 %T 3 1.00

K-04_0~4.SP 3601 4000.00 400.00 7.28 100.00 4.00 %T 3 1.00

REF 4000 99.17 2000 98.33 600

3927.86 97.62 3790.16 93.89 3431.92 25.82 2939.60 9.82 2671.46 93.03
2177.81 96.75 1713.01 12.78 1574.71 51.30 1432.52 38.27 1324.44 56.65
1224.49 62.53 1118.41 68.52 1045.71 80.98 896.35 83.59 747.97 77.57
649.10 77.48 492.68 66.69

REF 4000 97.55 2000 96.74 600

3910.00 95.60 3786.93 91.42 3424.99 40.85 2941.19 10.60 2670.37 90.02
2076.42 95.29 1966.64 95.90 1714.75 10.23 1578.58 69.76 1435.16 37.39
1323.23 49.60 1223.13 53.11 1119.07 60.85 1050.79 77.48 900.51 77.23
750.13 75.49 651.57 83.89 491.53 65.50 425.55 89.97

REF 4000 99.23 2000 98.37 600

3921.77 96.69 3789.69 91.84 3423.93 32.60 2940.97 8.75 2670.55 89.90
2179.10 96.60 1715.03 10.38 1572.28 64.52 1434.25 37.82 1324.60 52.74
1222.75 56.65 1119.21 64.61 1050.66 81.78 903.28 81.96 749.93 78.31
651.23 84.13 491.60 68.24 426.96 91.12

REF 4000 98.04 2000 97.28 600

3908.21 96.15 3785.54 90.33 3429.85 23.73 2941.21 8.54 2669.44 89.09
2079.95 95.38 1962.54 96.49 1716.16 10.22 1573.60 53.11 1434.92 28.75
1327.58 44.24 1224.33 53.20 1120.34 61.64 1042.09 77.27 894.64 78.25
749.25 74.91 648.82 80.41 494.07 64.16 427.00 89.24

REF 4000 99.33 2000 98.32 600

3940.31 96.10 3789.34 95.35 3414.34 42.10 2940.68 7.28 2669.87 84.64
2179.43 95.50 1963.83 96.77 1713.60 12.96 1578.02 66.37 1435.79 28.76
1324.42 41.48 1224.00 47.47 1119.07 56.32 1051.25 72.17 897.80 71.50
750.46 72.61 651.98 85.08 491.83 63.74 419.22 93.12

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010
Spectrum Name: K-0.4+0.4+0.2.sp

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.4+0.1+0.5.sp

100.0

Spectrum Name: K-0.3+0.5+0.2.sp

100.0

4 20.72

42 0.48
39 32.99

217 9.02

37 89 .4 1

1 96 5.25
21 82 .1 2

37 87 .9 5

21 78 .76

37 82.97

2 34 5.2 1

1 96 3.79

2 34 5.4 2

1 96 5.21

3 94 0.88
37 93 .3 4

3 928 .2 8

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.4+0.2+0.4.sp

100.0
4 23 .6 1
1 96 4.93

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.4+0.3+0.3.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

39 35 .5 2

26 70 .4 6

2 67 0.15

2 17 8.74

6 51 .6 5

2 66 9.9 8

21 78 .2 3

39 39 .3 5

6 51 .5 0

75 0.07

1 05 0.6 4

10 46.46

1 11 9.31

75 0.88

9 04.43

89 8.8 5

75 0.89

104 9.50

49 2.56

75 0.38
1 05 1.31

10 52 .4 4

49 2.57

49 1.91

49 2.57

1 11 9.06

15 74 .3 6

6 49 .3 6
74 8.74

89 6.5 3
49 1.72

6 52 .0 2

2 66 9.8 6

2 66 9.78

89 7.4 2
90 0.45

6 52 .1 5

1 11 9.13
12 23 .4 1

1 11 9.13

1 11 9.70

15 71.88

12 23 .1 7
1 57 3.96

13 27 .8 4

1 22 5.12

13 24 .45

12 22 .4 3

12 23 .6 2

34 20 .3 8

13 25 .9 1
13 26 .4 8

30
34 20 .1 8

34 22 .5 2

1 43 4.77

34 17 .9 5
1 432 .9 7

1 43 6.94

3 429 .4 5

2000

1 43 4.72

17 14 .08
29 40 .4 1

15 00

100 0

400.0

17 13 .52

2 93 8.54

17 14 .52

0.0
3000

1 43 5.12

17 13 .81
29 40 .9 9

0.0
4000.0

133 5.01

29 40 .5 7

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

17 15 .76

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

2 94 1.00

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

cm-1

K-0.4+0.4+0.2.pk

K-0.4+0.3+0.3.pk

K-0.4+0.2+0.4.pk

K-0.4+0.1+0.5.pk

K-0.3+0.5+0.2.pk

K-04_0~3.SP 3601 4000.00 400.00 8.00 100.00 4.00 %T 3 1.00

K-04_0~2.SP 3601 4000.00 400.00 7.64 99.90 4.00 %T 3 1.00

K-3DF8~1.SP 3601 4000.00 400.00 7.49 99.92 4.00 %T 3 1.00

K-04_0~1.SP 3601 4000.00 400.00 7.71 100.00 4.00 %T 3 1.00

K-03_0~1.SP 3601 4000.00 400.00 7.38 100.00 4.00 %T 3 1.00

REF 4000 99.23 2000 98.31 600

3928.28 97.12 3789.41 94.26 3420.18 32.19 2940.99 8.00 2670.15 88.97
2179.02 96.30 1964.93 97.41 1713.81 10.65 1574.36 61.29 1434.77 32.15
1324.45 47.04 1223.17 52.20 1119.06 60.14 1050.64 76.91 900.45 77.75
750.07 75.44 651.50 83.69 491.72 66.40 423.61 92.14

REF 4000 98.11 2000 97.27 600

3932.99 97.00 3793.34 93.61 3429.45 23.44 2940.41 7.64 2670.46 90.96
2178.76 95.19 1714.52 8.80 1573.96 48.63 1432.97 31.01 1327.84 49.24
1223.41 56.27 1119.31 63.99 1046.46 78.38 897.42 80.35 748.74 75.72
649.36 78.36 492.56 64.76

REF 4000 99.78 2000 98.87 600

3935.52 97.82 3787.95 95.14 3420.38 44.36 2938.54 7.49 2669.98 87.49
2182.12 97.01 1965.25 97.69 1714.08 10.56 1436.94 30.32 1326.48 40.34
1225.12 47.69 1119.13 57.37 1049.50 72.60 896.53 71.96 750.88 75.38
651.65 88.20 492.57 65.54

REF 4000 99.37 2000 98.60 600

3939.35 98.30 3782.97 95.53 3422.52 34.32 2940.57 7.71 2669.78 89.42
2345.21 96.10 2178.23 96.51 1963.79 97.33 1715.76 8.45 1435.12 28.42
1335.01 40.96 1222.43 47.63 1119.70 57.17 1052.44 75.66 904.43 74.39
750.89 72.98 652.15 85.39 492.57 64.82 420.48 93.12

REF 4000 99.31 2000 98.39 600

3940.88 97.51 3417.95 33.69 2941.00 7.38 2669.86 87.62 2345.42 96.99
2178.74 95.74 1965.21 97.00 1713.52 10.84 1571.88 58.34 1434.72 28.05
1325.91 43.04 1223.62 48.99 1119.13 57.91 1051.31 74.24 898.85 74.30
750.38 73.48 652.02 84.58 491.91 65.77 420.72 93.08

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.3+0.4+0.3.sp

Spectrum Name: K-0.3+0.3+0.4.sp

Spectrum Name: K-0.3+0.2+0.5.sp

100.0

2 180 .1 3

6 51 .4 0

234 8.64

FTIR SPECT RUM

100.0
42 8.14

21 78 .21
3 78 9.03

21 79 .8 4

2 34 3.2 6

37 82.24

1 96 5.92

2 10 4.10

2 67 1.13
2 17 8.69

6 51 .0 6

2 67 0.0 6

Spectrum Name: K-0.1+0.5+0.4.sp

100.0
1 050 .8 7

39 37.80

39 43.56

2 66 9.64

Date: 16-6-2010

Spectrum Name: K-0.2+0.5+0.3.sp

100.0
1 96 4.98

3 94 7.7 2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

80
90 4.72

3 94 3.9 2

2 67 1.36

37 86.76

9 04.89

26 70.35

6 51 .0 5

89 7.4 8
74 9.82

89 7.7 2 75 0.66

1 04 8.33

1 11 9.68

74 9.81

90 2.02

6 51 .3 1

1 04 8.26

10 50 .5 9
74 9.97

10 49.65
49 2.57

49 3.15

49 2.07

1 11 9.82

1 11 9.54

1 12 0.29

1 57 2.30

74 8.22
6 50 .7 1

12 21 .6 4
49 3.63

12 21 .9 7
12 23 .5 7

1 11 9.32

50
12 23 .4 2

49 2.18

50
133 3.54

13 38 .7 2

%T
12 23 .2 4

13 28 .8 2

1 57 1.43

1 33 1.72

13 28 .5 8

1 568 .4 8

3 430 .9 3

34 25 .2 8

1 43 6.36

1 433 .5 1

30
1 43 5.72

3000

2000

15 00

100 0

400.0

1 433 .0 3

3000

2000

cm-1

15 00

100 0

400.0

17 15 .95

17 13 .95

29 41 .4 8

0.0

4000.0

34 23 .5 7

17 14 .55
29 39 .8 1

0.0

4000.0

30
14 29 .48

10
17 15 .30
29 41.02

0.0

3 430 .7 2

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

cm-1

17 17 .8 2
34 45.99

29 41 .7 7

3000

29 44.90

0.0
2000

15 00

100 0

400.0

4000.0

cm-1

3000

2000

15 00

100 0

cm-1

K-0.3+0.4+0.3.pk

K-0.3+0.3+0.4.pk

K-0.3+0.2+0.5.pk

K-0.2+0.5+0.3.pk

K-0.1+0.5+0.4.pk

K-03_0~2.SP 3601 4000.00 400.00 7.51 100.00 4.00 %T 3 1.00

K-03_0~3.SP 3601 4000.00 400.00 7.65 99.93 4.00 %T 3 1.00

K-03_0~4.SP 3601 4000.00 400.00 9.73 100.00 4.00 %T 3 1.00

K-02_0~3.SP 3601 4000.00 400.00 7.30 100.00 4.00 %T 3 1.00

K-01_0~1.SP 3601 4000.00 400.00 7.26 99.83 4.00 %T 3 1.00

REF 4000 99.73 2000 98.89 600

3947.72 98.61 3430.93 33.97 2941.02 7.51 2669.64 92.03 2348.64 94.44
2180.13 97.06 1715.30 10.34 1436.36 33.99 1328.82 48.36 1223.57 55.35
1119.68 64.00 1048.33 79.43 897.48 79.89 749.82 77.84 651.40 84.62
492.57 67.46

REF 4000 99.83 2000 99.04 600

3943.56 98.35 3425.28 37.78 2939.81 7.65 2670.06 89.88 2179.84 97.17
1964.98 98.03 1714.55 10.79 1435.72 31.90 1331.72 44.84 1223.42 53.48
1120.29 63.14 1049.65 78.05 897.72 77.50 750.66 77.54 651.06 87.20
493.15 69.19

REF 4000 99.35 2000 98.42 600

3937.80 97.43 3789.03 93.55 3430.72 31.63 2941.48 9.72 2671.13 92.68
2178.21 96.79 1715.95 10.37 1572.30 63.99 1433.51 38.82 1333.54 54.93
1221.97 60.15 1119.54 68.23 1050.87 84.74 904.72 84.64 749.81 78.61
651.05 83.22 492.07 69.32

REF 4000 98.92 2000 97.87 600

3943.92 97.27 3782.24 95.36 3423.57 23.43 2941.77 7.30 2670.35 89.35
2343.26 96.51 2178.69 95.36 1965.92 96.87 1713.95 12.16 1571.43 48.29
1433.03 27.28 1328.58 44.75 1223.24 51.41 1119.32 59.60 1050.59 76.06
902.02 76.81 749.97 71.82 651.31 77.25 492.18 59.82 428.14 86.56

REF 4000 99.12 2000 97.67 600

3786.76 91.53 3445.99 9.56 2944.90 7.26 2671.36 94.64 2104.10 95.20
1717.82 12.62 1568.48 39.46 1429.48 33.03 1338.72 56.45 1221.64 64.05
1119.82 70.14 1048.26 84.62 904.89 86.55 748.22 69.83 650.71 67.40
493.63 61.30

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 16-6-2010

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.2+0.4+0.4.sp

Spectrum Name: K-0.1+0.4+0.5.sp

100.0

3 794 .2 5

2 34 4.6 9

1 96 5.12

100.0

20 97 .0 7

80
1 04 5.98

39 75 .4 3

89 9.2 1
10 48 .5 1

89 7.5 1 75 0.87

9 07.65

3 78 1.74
2 67 0.71

6 51 .6 2

2 67 0.1 8

3 88 6.01
2 10 7.05

3 78 3.94

20 79 .9 3

3 94 4.50

FTIR SPECT RUM

Date: 16-6-2010

Spectrum Name: K-0.2+0.3+0.5.sp

100.0

6 49 .8 1

70
11 21 .09

74 9.44
1 05 0.7 5

74 7.82
49 3.53

1 12 2.09

49 4.34

11 73.29
12 19 .57

1 12 0.98

6 49 .5 1
49 5.14

16 41 .7 2

50
12 21 .1 2

12 23 .0 1

40
1 570 .2 6

13 38 .9 3

133 4.74

30
1 570 .0 5
142 7.04

1 43 6.37

3 427 .7 3

0.0
4000.0

1 432 .4 4

34 37.78

0.0
2000

15 00

100 0

400.0

4000.0

cm-1

K-0.2+0.4+0.4.pk

0.0
3000

17 21 .4 8

17 16 .7 8

2 94 1.84

17 15 .21

29 41.41

3000

2000

15 00

100 0

400.0

34 44.68

4000.0

cm-1

K-0.2+0.3+0.5.pk

2 94 5.9 2

3000

2000

15 00

100 0

400.0

cm-1

K-0.1+0.4+0.5.pk

K-02_0~1.SP 3601 4000.00 400.00 7.34 99.80 4.00 %T 3 1.00

K-02_0~2.SP 3601 4000.00 400.00 7.19 99.97 4.00 %T 3 1.00

K-01_0~2.SP 3601 4000.00 400.00 6.39 99.86 4.00 %T 3 1.00

REF 4000 99.71 2000 98.70 600

3944.50 97.61 3794.25 96.99 3427.73 27.70 2941.41 7.34 2670.18 87.97
2344.69 97.32 2079.93 96.27 1965.12 97.41 1715.21 9.63 1436.37 29.10
1334.74 41.04 1223.01 50.79 1120.98 60.60 1050.75 76.07 897.51 74.68
750.87 73.60 651.62 86.35 493.53 67.62

REF 4000 99.64 2000 98.71 600

3783.94 94.21 3437.78 14.35 2941.84 7.19 2670.71 91.00 2097.07 96.08
1716.78 10.28 1570.26 41.98 1432.44 24.87 1338.93 42.62 1221.12 54.71
1122.09 64.10 1048.51 80.76 899.21 81.68 749.44 73.14 649.81 76.63
494.34 63.76

REF 4000 98.58 2000 96.89 600

3975.43 97.27 3886.01 96.99 3781.74 91.07 3444.68 6.39 2945.92 9.08
2107.05 94.09 1721.48 13.74 1641.72 41.92 1570.05 32.40 1427.04 30.79
1219.57 67.56 1173.29 68.82 1121.09 71.98 1045.98 84.96 907.65 89.57
747.82 68.49 649.51 63.03 495.14 59.83

307

400.0

Table - 7.26
Observations of FTIR Spectrum for
Cyclohexanone + Heptane + 2-Butanone mixture
S1
(Cm-1)
3927.86
3790.16
3431.92
2939.60
2671.46
2177.81
1713.01
1574.71
1432.52
1324.44
1224.49
1118.41
1045.71
896.35
747.97
649.10
492.68

*S2
(Cm-1)

S3
(Cm-1)

S4
(Cm-1)

S5
(Cm-1)

S6
(Cm-1)

S7
(Cm-1)

S8
(Cm-1)

S9
(Cm-1)

3910.00
3786.93
3424.99
2941.19
2670.37
2076.42*
1966.64*
1714.75
1578.58
1435.16
1323.23
1223.13
1119.07
1050.79
900.51
750.13
651.57
491.53
425.55

3921.77
3789.69
3423.93
2940.97
2670.55
2179.10
1715.03
1572.28
1434.25
1324.60
1222.75
1119.21
1050.66
903.28
749.93
651.23
491.60
426.96

3908.21
3785.54
3429.85
2941.21
2669.44
2079.95
1962.54
1716.16
1573.60
1434.92
1327.58
1224.33
1120.34
1042.09
894.64
749.25
648.82
494.07
427.00

3940.31
3789.34
3414.34
2940.68
2669.87
2179.43
1963.83
1713.60
1578.02
1435.79
1324.42
1224.00
1119.07
1051.25
897.80
750.46
651.98
491.83
419.22

3928.28
3789.41
3420.18
2940.99
2670.15
2179.02
1964.93
1713.81
1574.36
1434.77
1324.45
1223.17
1119.06
1050.64
900.45
750.07
651.50
491.72
423.61

3932.99
3793.34
3429.45
2940.41
2670.46
2178.76
1714.52
1573.96
1432.97
1327.84
1223.41
1119.31
1046.46
897.42
748.74
649.36
492.56

3935.52
3787.95
3420.38
2938.54
2669.98
2182.12
1965.25
1714.08
1436.94
1326.48
1225.12
1119.13
1049.50
896.53
750.88
651.65
492.57

3939.35
3782.97
3422.52
2940.57
2669.78
2345.21
2178.23
1963.79
1715.76
1435.12
1335.01
1222.43
1119.70
1052.44
904.43
750.89
652.15
492.57
420.48

* Maximum shift in the frequency has been observed.

S10
(Cm-1)

S11
(Cm-1)

S12
(Cm-1)

S13
(Cm-1)

*S14
(Cm-1)

S15
(Cm-1)

S16
(Cm-1)

S17
(Cm-1)

S18
(Cm-1)

3940.88
3417.95
2941.00
2669.86
2345.42
2178.74
1965.21
1713.52
1571.88
1434.72
1325.91
1223.62
1119.13
1051.31
898.85
750.38
652.02
491.91
420.72

3947.72
3430.93
2941.02
2669.64
2348.64
2180.13
1715.30
1436.36
1328.82
1223.57
1119.68
1048.33
897.48
749.82
651.40
492.57

3943.56
3425.28
2939.81
2670.06
2179.84
1964.98
1714.55
1435.72
1331.72
1223.42
1120.29
1049.65
897.72
750.66
651.06
493.15

3937.80
3789.03
3430.72
2941.48
2671.13
2178.21
1715.95
1572.30
1433.51
1333.54
1221.97
1119.54
1050.87
904.72
749.81
651.05
492.07

3943.92
3782.24
3423.57
2941.77
2670.35
2343.26
2178.69
1965.92
1713.95
1571.43
1433.03
1328.58
1223.24
1119.32
1050.59
902.02
749.97
651.31
492.18
428.14

3944.50
3794.25
3427.73
2941.41
2670.18
2344.69
2079.93
1965.12
1715.21
1436.37
1334.74
1223.01
1120.98
1050.75
897.51
750.87
651.62
493.53

3783.94
3437.78
2941.84
2670.71
2097.07
1716.78
1570.26
1432.44
1338.93
1221.12
1122.09
1048.51
899.21
749.44
649.81
494.34

3786.76
3445.99
2944.90
2671.36
2104.10
1717.82
1568.48
1429.48
1338.72
1221.64
1119.82
1048.26
904.89
748.22
650.71
493.63

3975.43
3886.01
3781.74
3444.68
2945.92
2107.05
1721.48
1641.72
1570.05
1427.04
1219.57
1173.29
1121.09
1045.98
907.65
747.82
649.51
495.14

* Maximum shift in the frequency has been observed.

308

Fig-7.26: FTIR Spectrum for Cyclohexanone + Heptane + Ethyl Acetate

mixture:
ACIC
St.Joseph's College ( Autonomous )
Trichy-2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010
Spectrum Name: K-0.5+0.4+0.1.sp

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.5+0.2+0.3.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.5+0.3+0.2.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.5+0.1+0.4.sp

100.0

Spectrum Name: K-0.4+0.5+0.1.sp

100.0

20 70 .8 7

2 34 5.1 6

3 94 4.06

207 1.77

26 73 .75

39 36.07

42 1.36

39 38 .05

2 34 3.7 9

2 34 0.8 4

1 96 5.04

3 93 5.1 9

26 69 .0 8

2 07 7.54

26 68 .92

21 76 .6 7

41 9.41

3 83 3.35

4 19 .0 6

2 34 8.2 4

2 07 4.5 7

26 69 .69

3 94 5.35

2 07 8.34

26 69 .0 3

2 17 7.3 5

1 05 2.79

6 51 .6 7

6 51 .7 5
6 50 .0 0

89 7.9 1
10 51 .0 8

74 9.92

90 1.86

9 02.70

1 22 5.09

9 02.15 75 0.20
75 0.04

1 11 8.90

49 1.80

287 0.92

4 96.89

1 32 8.29

1 11 8.72

50
%T

49 2.25

10 53.78

742 .9 5

1 11 8.22

49 1.90

1 118 .8 8

13 23 .41

35 01 .5 0

1 22 6.25

34 13 .8 5

1 43 7.88

1 43 7.91

34 17 .5 9

1 43 5.14

1 43 8.81

12 32 .44
29 42 .6 1

34 17 .2 3

16 41 .0 0

28 72 .5 1

17 13 .82
17 15 .16

2000

29 41 .6 2

29 41 .2 6

0.0
3000

12 34 .32

2 87 1.43

28 71.55

17 13 .80

17 13 .39
29 39 .9 5

0.0
4000.0

1 05 5.6 1

50
%T

13 22 .6 8

142 4.92

6 49 .9 4 49 3.57
74 8.13

%T
13 22 .66

13 23 .22
122 7.06

10 54.45

1 11 7.70

%T
65 0.23

15 00

100 0

400.0

0.0

3 42 8.39

4000.0

3000

2000

cm-1

15 00

100 0

400.0

3000

2000

15 00

100 0

400.0

17 13 .68

3 428 .1 1

0.0

4000.0

cm-1

4000.0

29 41 .0 7

0.0
3000

2000

cm-1

15 00

100 0

400.0

4000.0

3000

2000

cm-1

15 00

100 0

K-0.5+0.3+0.2.pk

K-0.5+0.2+0.3.pk

K-0.5+0.1+0.4.pk

K-0.4+0.5+0.1.pk

K-05_0~4.SP 3601 4000.00 400.00 7.72 100.00 4.00 %T 5 1.00

K-05_0~2.SP 3601 4000.00 400.00 5.05 99.67 4.00 %T 5 1.00

K-05_0~3.SP 3601 4000.00 400.00 9.59 100.00 4.00 %T 5 1.00

K-05_0~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 %T 5 1.00

K-04_0~2.SP 3601 4000.00 400.00 7.79 99.99 4.00 %T 5 1.00

REF 4000 99.01 2000 97.72 600

3944.06 95.52 3417.59 31.96 2939.95 7.72 2669.08 91.33 2345.16 95.30
2176.67 95.39 2071.77 95.23 1713.39 10.73 1437.88 33.99 1323.22 45.30
1227.06 45.74 1118.72 57.87 1051.08 71.72 897.91 74.03 749.92 71.31
651.67 81.65 491.80 64.54 421.36 92.63

REF 4000 98.59 2000 95.34 600

3936.07 95.48 3428.39 5.05 2942.61 30.93 2870.92 59.30 2673.75 96.25
2077.54 91.12 1713.80 15.21 1641.00 23.84 1424.92 45.14 1328.29 70.06
1225.09 72.97 1118.90 67.80 1052.79 84.31 742.95 57.43 650.23 54.04
496.89 63.92

REF 4000 99.32 2000 98.07 600

3938.05 96.77 3417.23 29.49 2941.26 12.04 2871.55 26.38 2668.92 92.97
2343.79 96.42 2074.57 95.36 1715.16 9.59 1437.91 34.75 1322.66 47.31
1232.44 33.70 1118.22 56.05 1053.78 64.96 902.70 76.07 750.04 70.82
650.00 78.91 492.25 65.04 419.06 91.88

REF 4000 99.11 2000 95.70 600

3935.19 94.03 3428.11 6.34 2941.62 13.91 2871.43 31.14 2669.69 94.04
2340.84 95.23 2078.34 91.31 1713.68 8.16 1435.14 34.49 1322.68 50.15
1234.32 30.26 1117.70 56.93 1054.45 63.96 901.86 76.88 748.13 56.85
649.94 59.34 493.57 58.08

REF 4000 97.58 2000 96.34 600

3945.35 92.87 3833.35 94.76 3501.50 45.15 3413.85 43.26 2941.07 7.79
2872.51 20.19 2669.03 88.55 2348.24 93.11 2177.35 93.90 2070.87 93.92
1965.04 95.19 1713.82 11.00 1438.81 34.08 1323.41 44.64 1226.25 44.50
1118.88 55.61 1055.61 71.13 902.15 72.43 750.20 71.84 651.75 82.91
491.90 64.24 419.41 91.14

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010
Spectrum Name: K-0.4+0.4+0.2.sp

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.4+0.2+0.4.sp

100.0

41 9.26

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.4+0.3+0.3.sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.4+0.1+0.5.sp

100.0

400.0

cm-1

K-0.5+0.4+0.1.pk

Spectrum Name: K-0.3+0.5+0.2.sp

100.0

42 4.67

39 40 .61

2 075 .3 8

3 94 4.64

207 4.65

42 2.41

26 69 .0 2

26 69 .2 7

2 670 .3 9

3 94 6.8 7

26 69 .3 0

6 50 .6 1

2 075 .5 6

394 3.67
2 344 .7 0

2 34 5.73

2 07 9.66

26 69 .0 6
20 83.01

23 46 .4 7

2 344 .9 9

2 34 5.81

104 9.38
89 8.5 9

6 51 .2 5

90 0.40

75 0.32

89 8.4 2

90 0.92

6 50 .8 8

10 52 .0 7

8 91 .6 6

6 49 .2 2
74 9.66

74 9.75

49 1.77

49 2.05

10 50 .3 4

1 11 8.38

74 9.76

1 05 1.6 2

49 2.31

49 2.30

1 11 8.15

1 11 8.24
6 51 .7 5
74 6.08
49 5.09

11 17 .4 7

1 11 8.37

1 22 6.18

1 05 2.0 8

132 5.52

132 1.67
13 22 .80

13 22 .61

123 1.33

13 22 .71

34 17 .0 1

1 43 8.09

1 43 8.07

12 33 .34

1 43 5.57

12 32 .34

1 43 5.17

1 43 6.17
34 19 .7 2

12 37 .1 5

20
34 20 .1 8

10
17 14 .31

29 41 .0 4
17 15 .56

29 39 .5 1

29 40 .4 7

0.0

4000.0

3000

2000

15 00

100 0

400.0

17 14 .42

0.0

4000.0

3000

2000

cm-1

34 24 .2 3

10
17 15 .94

29 42 .2 6

0.0

15 00

100 0

400.0

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

3 43 1.37

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

4000.0

29 40 .0 7

171 2.57

3000

2000

cm-1

15 00

100 0

400.0

cm-1

K-0.4+0.4+0.2.pk

K-0.4+0.3+0.3.pk

K-0.4+0.2+0.4.pk

K-0.4+0.1+0.5.pk

K-0.3+0.5+0.2.pk

K-04_0~4.SP 3601 4000.00 400.00 8.61 100.00 4.00 %T 5 1.00

K-04_0~3.SP 3601 4000.00 400.00 7.82 100.00 4.00 %T 5 1.00

K-04_0~1.SP 3601 4000.00 400.00 7.77 100.00 4.00 %T 5 1.00

K-3309~1.SP 3601 4000.00 400.00 10.75 100.00 4.00 %T 5 1.00

K-03_0~4.SP 3601 4000.00 400.00 8.03 100.00 4.00 %T 5 1.00

REF 4000 99.25 2000 97.20 600

3940.61 95.40 3419.72 26.55 2942.26 8.61 2669.27 92.07 2345.81 92.90
2075.38 94.24 1714.31 9.40 1438.09 36.51 1322.80 48.27 1231.33 39.79
1118.38 57.89 1052.07 67.95 898.59 76.31 749.75 70.11 651.25 77.79
492.05 65.16 422.41 93.28

REF 4000 99.37 2000 98.30 600

3944.64 96.25 3417.01 40.21 2939.51 7.82 2669.02 92.20 2344.70 96.38
2074.65 95.96 1715.94 11.30 1438.07 35.30 1322.61 46.61 1233.34 35.75
1118.15 59.17 1050.34 65.49 900.40 76.71 750.32 75.62 650.61 85.23
491.77 68.07 419.26 94.32

REF 4000 99.21 2000 96.92 600

3943.67 93.28 3420.18 19.86 2940.47 7.77 2669.30 91.57 2345.73 93.85
2075.56 93.65 1714.42 9.43 1436.17 33.41 1322.71 46.02 1232.34 35.86
1118.37 56.41 1051.62 65.84 898.42 75.36 749.76 67.25 650.88 74.13
492.31 63.19 424.67 92.31

REF 4000 99.34 2000 97.42 600

3946.87 94.31 3424.23 19.82 2941.04 15.40 2670.39 93.77 2346.47 93.22
2079.66 94.18 1715.56 10.74 1435.57 38.71 1321.67 51.82 1237.15 27.01
1117.47 59.41 1052.08 59.90 900.92 78.67 749.66 68.52 649.22 72.71
492.30 65.32

REF 4000 99.56 2000 95.83 600

3431.37 8.24 2940.07 8.25 2669.06 94.48 2344.99 91.44 2083.01 91.93
1712.57 8.03 1435.17 37.18 1325.52 52.74 1226.18 57.63 1118.24 64.30
1049.38 80.57 891.66 78.32 746.08 60.24 651.75 62.19 495.09 60.19

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.3+0.4+0.3.sp

Spectrum Name: K-0.3+0.3+0.4.sp

Spectrum Name: K-0.3+0.2+0.5.sp

100.0

89 6.8 1

2 07 8.36
20 85.22

23 47.95

26 67 .76

80
23 45 .2 2

2 34 5.14

89 8.3 0

89 5.8 8

39 36 .14

6 49 .2 2

2 669 .6 3

2 08 0.56

2 667 .0 6

2 34 5.27

26 70 .3 8

FTIR SPECT RUM

Date: 24-6-2010
100.0

90
39 44 .7 6

2 079 .2 0

Spectrum Name: K-0.2+0.4+0.4.sp

100.0

90
2 34 5.2 4

39 29 .4 0

2 07 8.20

Spectrum Name: K-0.2+0.5+0.3.sp

100.0

90
266 9.06

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

100.0

3 932 .4 0

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

8 91 .4 2

6 48 .6 8

105 1.18

75 0.06

89 5.8 0

6 50 .6 7
10 52 .11

49 2.99

60
105 3.25

6 51 .6 4

74 9.08

49 2.34

74 9.96

1 11 7.67

49 2.77

10 51 .1 0
1 11 7.82

74 8.97

49 3.00

1 11 8.51

1 11 6.43

6 51 .2 4
74 5.95
49 5.53

50
13 22 .07

1 05 0.83

%T
13 25 .9 9

13 23 .24

11 16 .8 2

12 30 .5 5

13 25 .6 6
13 25 .9 8
123 0.51

1 43 4.78

1 43 5.85

1 43 7.52
1 43 5.39

12 35 .5 9

12 35 .8 4

17 14 .23

15 00

100 0

400.0

17 14 .99

0.0

4000.0

3000

2000

cm-1

29 41 .8 8

29 40 .3 0

0.0
2000

34 25 .7 3

17 15 .77
29 42 .2 7

3000

12 35 .3 7

34 22 .0 5

10
34 28.81

4000.0

1 43 7.48

34 23 .6 7

0.0

15 00

100 0

400.0

0.0

4000.0

3000

2000

cm-1

15 00

100 0

400.0

3 43 3.41

4000.0

cm-1

29 40 .7 1

171 1.52

29 40 .7 4

17 15 .16

0.0
3000

2000

15 00

100 0

400.0

4000.0

cm-1

3000

2000

15 00

100 0

cm-1

K-0.3+0.4+0.3.pk

K-0.3+0.3+0.4.pk

K-0.3+0.2+0.5.pk

K-0.2+0.5+0.3.pk

K-0.2+0.4+0.4.pk

K-03_0~2.SP 3601 4000.00 400.00 7.32 100.00 4.00 %T 5 1.00

K-03_0~3.SP 3601 4000.00 400.00 8.96 99.99 4.00 %T 5 1.00

K-03_0~1.SP 3601 4000.00 400.00 8.95 100.00 4.00 %T 5 1.00

K-02_0~3.SP 3601 4000.00 400.00 6.36 100.00 4.00 %T 5 1.00

K-02_0~1.SP 3601 4000.00 400.00 7.77 99.99 4.00 %T 5 1.00

REF 4000 99.19 2000 95.61 600

3932.40 91.73 3428.81 7.32 2942.27 8.60 2669.06 92.32 2345.27 89.07
2078.20 91.38 1714.23 8.63 1435.39 30.82 1323.24 45.18 1230.51 38.02
1118.51 54.93 1052.11 68.08 896.81 73.72 748.97 57.31 651.64 61.67
493.00 56.67

REF 4000 99.24 2000 97.14 600

3929.40 92.91 3423.67 19.72 2940.30 8.96 2667.06 90.27 2345.24 92.36
2079.20 93.85 1715.77 10.62 1437.52 33.55 1325.66 44.16 1235.59 30.93
1116.43 58.00 1051.10 60.53 895.88 73.70 750.06 71.39 649.22 79.20
492.99 66.81

REF 4000 99.50 2000 96.86 600

3944.76 93.92 3425.73 14.73 2941.88 10.45 2670.38 93.64 2347.95 86.76
2080.56 93.37 1714.99 8.95 1434.78 38.33 1322.07 53.22 1235.84 30.07
1117.82 60.16 1053.25 64.44 898.30 79.35 749.08 66.20 650.67 69.09
492.34 64.57

REF 4000 99.64 2000 95.36 600

3433.41 6.36 2940.71 8.57 2669.63 94.75 2345.14 90.42 2085.22 91.14
1711.52 8.75 1435.85 35.89 1325.99 51.63 1230.55 48.18 1117.67 63.40
1051.18 75.48 891.42 77.55 745.95 57.59 651.24 58.82 495.53 57.69

REF 4000 99.78 2000 97.79 600

3936.14 92.82 3422.05 19.31 2940.74 7.77 2667.76 90.61 2345.22 93.07
2078.36 94.23 1715.16 7.91 1437.48 27.77 1325.98 39.34 1235.37 27.07
1116.82 53.20 1050.83 56.99 895.80 70.96 749.96 67.67 648.68 75.98
492.77 61.40

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECT RUM

Date: 24-6-2010

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.2+0.3+0.5.sp

Spectrum Name: K-0.1+0.4+0.5.sp

100.0

26 69 .13

3 93 7.80

FTIR SPECT RUM

Date: 24-6-2010

Spectrum Name: K-0.1+0.5+0.4.sp

100.0

267 0.47

2 670 .5 5

3 94 8.8 6

3 94 3.60

20 86.15

20 87.49

20 83.81

2 34 5.9 6

23 46 .0 5

2 34 5.12

10 52 .8 9

10 52 .7 6

89 4.8 5

11 16 .8 2
11 16 .2 6

4 96.68

4 99 .3 0

1 33 0.69

744 .8 8
6 50 .3 6

13 27 .0 1

74 7.80
7 42 .59
6 50 .2 5

49 4.61
11 15 .4 7

12 34 .50

6 46 .7 7

1 05 3.57

40
1 43 4.25

1 432 .9 9

13 28 .8 8

12 35 .3 3

30
1 43 6.18

20
1 23 7.89

0.0

29 40 .5 2

29 42 .2 0

171 2.32

171 1.83

10
3 429 .0 4

34 32 .3 7

34 30 .3 1

4000.0

0.0
3000

2000

15 00

100 0

400.0

4000.0

cm-1

K-0.2+0.3+0.5.pk

29 43 .1 5

17 16 .5 8

0.0
3000

2000

15 00

100 0

400.0

4000.0

cm-1

K-0.1+0.5+0.4.pk

3000

2000

15 00

100 0

400.0

cm-1

K-0.1+0.4+0.5.pk

K-02_0~2.SP 3601 4000.00 400.00 6.47 100.00 4.00 %T 5 1.00

K-01_0~2.SP 3601 4000.00 400.00 6.37 99.99 4.00 %T 5 1.00

K-01_0~1.SP 3601 4000.00 400.00 7.60 99.95 4.00 %T 5 1.00

REF 4000 99.40 2000 95.31 600

3937.80 93.56 3430.31 6.47 2940.52 12.96 2669.13 95.06 2345.12 90.47
2086.15 91.25 1712.32 13.75 1434.25 44.34 1327.01 59.93 1235.33 44.09
1116.26 69.62 1052.76 74.12 744.88 61.21 650.36 60.87 496.68 64.50

REF 4000 99.64 2000 95.09 600

3943.60 92.37 3432.37 6.37 2942.20 15.49 2670.47 96.19 2345.96 89.23
2087.49 90.63 1711.83 17.53 1432.99 46.53 1330.69 64.45 1234.50 53.87
1116.82 71.73 1052.89 78.45 742.59 59.47 650.25 57.11 499.30 63.38

REF 4000 99.58 2000 96.45 600

3948.86 95.05 3429.04 8.74 2943.15 7.89 2670.55 94.64 2346.05 90.32
2083.81 91.98 1716.58 7.60 1436.18 30.09 1328.88 46.11 1237.89 19.22
1115.47 55.72 1053.57 54.30 894.85 77.04 747.80 60.40 646.77 61.44
494.61 59.17

309

400.0

Table - 7.27
Observations of FTIR Spectrum for
Cyclohexanone + Heptane + Ethyl Acetate mixture
S1
(Cm-1)

S2
(Cm-1)

S3
(Cm-1)

S4
(Cm-1)

*S5
(Cm-1)

3944.06
3417.59
2939.95
2669.08
2345.16
2176.67
2071.77
1713.39
1437.88
1323.22
1227.06
1118.72
1051.08
897.91
749.92
651.67
491.80
421.36

3936.07
3428.39
2942.61
2870.92
2673.75
2077.54
1713.80
1641.00
1424.92
1328.29
1225.09
1118.90
1052.79
742.95
650.23
496.89

3938.05
3417.23
2941.26
2871.55
2668.92
2343.79
2074.57
1715.16
1437.91
1322.66
1232.44
1118.22
1053.78
902.70
750.04
650.00
492.25
419.06

3935.19
3428.11
2941.62
2871.43
2669.69
2340.84
2078.34
1713.68
1435.14
1322.68
1234.32
1117.70
1054.45
901.86
748.13
649.94
493.57

3945.35
3833.35*
3501.50*
3413.85
2941.07
2872.51
2669.03
2348.24
2177.35*
2070.87
1965.04
1713.82
1438.81
1323.41
1226.25
1118.88
1055.61
902.15
750.20
651.75
491.90
419.41

S6
(Cm-1)

S7
(Cm-1)

S8
(Cm-1)

S9
(Cm-1)

3940.61
3419.72
2942.26
2669.27
2345.81
2075.38
1714.31
1438.09
1322.80
1231.33
1118.38
1052.07
898.59
749.75
651.25
492.05
422.41

3944.64
3417.01
2939.51
2669.02
2344.70
2074.65
1715.94
1438.07
1322.61
1233.34
1118.15
1050.34
900.40
750.32
650.61
491.77
419.26

3943.67
3420.18
2940.47
2669.30
2345.73
2075.56
1714.42
1436.17
1322.71
1232.34
1118.37
1051.62
898.42
749.76
650.88
492.31
424.67

3946.87
3424.23
2941.04
2670.39
2346.47
2079.66
1715.56
1435.57
1321.67
1237.15
1117.47
1052.08
900.92
749.66
649.22
492.30

* Maximum shift in the frequency has been observed.

S10
(Cm-1)

S11
(Cm-1)

S12
(Cm-1)

S13
(Cm-1)

S14
(Cm-1)

S15
(Cm-1)

S16
(Cm-1)

S17
(Cm-1)

S18
(Cm-1)

3431.37
2940.07
2669.06
2344.99
2083.01
1712.57
1435.17
1325.52
1226.18
1118.24
1049.38
891.66
746.08
651.75
495.09

3932.40
3428.81
2942.27
2669.06
2345.27
2078.20
1714.23
1435.39
1323.24
1230.51
1118.51
1052.11
896.81
748.97
651.64
493.00

3929.40
3423.67
2940.30
2667.06
2345.24
2079.20
1715.77
1437.52
1325.66
1235.59
1116.43
1051.10
895.88
750.06
649.22
492.99

3944.76
3425.73
2941.88
2670.38
2347.95
2080.56
1714.99
1434.78
1322.07
1235.84
1117.82
1053.25
898.30
749.08
650.67
492.34

3433.41
2940.71
2669.63
2345.14
2085.22
1711.52
1435.85
1325.99
1230.55
1117.67
1051.18
891.42
745.95
651.24
495.53

3936.14
3422.05
2940.74
2667.76
2345.22
2078.36
1715.16
1437.48
1325.98
1235.37
1116.82
1050.83
895.80
749.96
648.68
492.77

3937.80
3430.31
2940.52
2669.13
2345.12
2086.15
1712.32
1434.25
1327.01
1235.33
1116.26
1052.76
744.88
650.36
496.68

3943.60
3432.37
2942.20
2670.47
2345.96
2087.49
1711.83
1432.99
1330.69
1234.50
1116.82
1052.89
742.59
650.25
499.30
63.38

3948.86
3429.04
2943.15
2670.55
2346.05
2083.81
1716.58
1436.18
1328.88
1237.89
1115.47
1053.57
894.85
747.80
646.77
494.61

* Maximum shift in the frequency has been observed.

310

Fig-7.27:
mixture:

FTIR

Spectrums

for

Cyclohexanone+2-Butanone+Benzaldehyde

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 03-1 2-2009

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

Spectrum Name: SJC-Ph-D-1.sp

1 00 .0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

1018.13

3927.97

2176.04
3788.49

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-2.sp

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 03- 12-2009

413.27

1172.66

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-3.sp

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-4.sp

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-5.sp

100.0

Spectrum Name: SJC-Ph- D-6.sp

100.0

1804.84

863.72

2673.39

1054.67

3927.93

1020.15

3931.53

861 .26

1018.47

651.14

861.50

2175.76

416.20

3788.52
1018.91

2673.92

3790.58

1172.47
392 7.50
2173.53

904.11

1054.63

903.20

752.07

754.07

1054.15

3793.60

64 9.91

650.90

1314.07

2672.60

6 49.90
1055.56

904.99

60
559.8 8

903.29

863 .56

2672.36

1055.20 903.33

2 673.57

3931.42

2175.71

3928.10

2175.61

3 784.96

491.59
1119.36
1222.68

40
1448.22

862.8 0

413 .32

2175.84

751.78

50
%T

414.55

905.15

1055.28

4 91.94
111 9.05

1314.28

64 9.71
753.18
4 92.38

111 9.18

751.69
4 91.47

4 92.04

1119.36

11 19.18

587.69

111 9.18
1223.19

1222.8 9

1350.61

1 227.85

1445.16

755.49

4 93.59

1225.70

1444.00
1223.85

2865.29

1444.52

1348.36

1448.21

1444.42

30
2866.09

1350.34

3420.47

1595.46

1351.08

2865.46

1351.62

2865.6 0

2864.88

2940.99

2864.86

1353.25
3 431.36

1712.31

0 .0
4 00 0.0

3 00 0

3439.70

2 00 0

1 50 0

1 00 0

4 00 .0

294 1.24

cm-1

17 11.17

3000

2000

1500

1000

400.0

4000.0

3431.58

17 12.05

0.0

4000.0

3000

294 0.55

1500

1000

400.0

294 0.81

1595.65
17 11.36

17 11.82

3436.14

0.0

4000.0

3000

2000

1500

cm-1

294 2.42
17 12.65

0.0

2000

cm-1

1595.38

1595.16
294 0.97

0.0

SJC-Ph-D-1.pk

3420.01

1595.42

1000

400.0

1594.99

0.0

4000.0

3000

2000

1500

cm-1

1000

400.0

4000.0

3000

2000

1500

cm-1

1000

cm-1

SJB907~1.SP 3601 4000.00 400.00 7.45 99.05 4 .00 %T 5 1.0 0

SJC-Ph-D- 2.pk

SJC-Ph-D- 3.pk

SJC-Ph-D- 4.pk

SJC-Ph-D- 5.pk

SJC-Ph-D- 6.pk

REF 4000 88.78 2000 87.99 600

3927.97 85.91 3788.49 84.61 3420.47 16.33 294 0.99 11.72 2865.29 26.25
2673.39 80.60 2176.04 84.99 1804.84 79.55 171 2.31 7.45 1595.46 15.29
1448.22 39.98 1350.61 30.91 1314.28 45.22 122 2.68 48.05 1172.66 77.18
1119.36 54.46 1054.67 75.08 1018.13 79.40 905 .15 71 .81 863.72 76.49
751.78 60.58 651.14 69.69 491 .59 56 .71 413.27 80.34

SJB90 3~1. SP 3601 4000.00 400.00 6.31 99.58 4.00 %T 5 1.0 0

SJB90 F~1.SP 3601 4000.00 400 .00 7.42 98.98 4.00 %T 5 1. 00

SJC90B~1. SP 3601 4000. 00 400. 00 7.08 99. 87 4.00 %T 5 1. 00

SJC907~1.SP 3601 4000.00 400 .00 8.04 99.68 4.00 %T 5 1. 00

SJC903~1.SP 3601 4000.00 400 .00 5.30 99.43 4.00 %T 5 1. 00

REF 4 000 87.29 2000 85.89 600

3931.42 82.79 3784.96 81.45 3439.70 6.31 2941.24 11.45 2865.46 27.10
2673.92 79.58 2175.84 82.26 1711.17 8.85 1595.42 7. 48 144 4.52 40.17
1351.08 26.73 1223.19 49.72 1119.18 55.77 1055.20 73. 03 1018.91 77. 60
903. 33 70 .43 861.50 72.39 753.18 53.4 9 649.71 59.94 559.88 61. 46
492. 38 52 .58

REF 4 000 86.78 2000 86.01 600

3927.93 83.62 3790.58 81.90 3420.01 13.77 2940.97 9.61 2864.86 23.69
2672.36 78.90 2175.61 82.90 1712.05 7.42 1595.16 12.54 1448.21 38.64
1350.34 29.32 1314.07 42.85 1223.85 43.49 1119.18 50. 95 1054.15 67. 92
1018.47 74.60 904.99 68 .67 863.56 73.12 751.69 57.26 650.90 65.91
491. 47 53 .39 413.32 78.61

REF 4 000 88.63 2000 87.88 600

3931.53 85.79 3788.52 83.89 3431.58 11.94 2940.55 11. 10 2864.88 27. 74
2673.57 82.37 2175.76 84.89 1711.36 7.08 1595.65 10.34 1444.00 44.44
1351.62 31.26 1222.89 52.77 1119.36 56.47 1055.56 73. 99 1020.15 78. 02
903. 29 73 .90 861.26 78.65 754.07 61.1 6 649.91 68.43 492.04 56. 65
416. 20 81 .52

REF 4 000 89.65 2000 88.80 600

3928.10 87.41 3431.36 18.95 2940.81 13.01 2865.60 30. 40 2672.60 83. 27
2175.71 86.26 1711.82 8. 04 1595.38 20.53 1445.16 44.62 1348.36 39.86
1225.70 46.88 1119.05 58.07 1054.63 72.76 904.11 73.92 862.80 78.05
752. 07 64 .08 649.90 71.91 491.94 60.4 2 414.55 83.95

REF 4 000 81.31 2000 80.29 600

3927.50 76.71 3793.60 72.92 3436.14 5.61 2942.42 14.95 2866.09 32.34
2173.53 76.45 1712.65 11.57 1594.99 5.30 1444.42 42.25 1353.25 22.81
1227.85 48.63 1172.47 71.60 1119.18 59.91 1055.28 69. 28 903.20 70.74
755. 49 49 .41 587.69 54.57 493.59 52.0 1

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 03- 12-2009

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-10.sp

100.0

1017.87

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-9.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-8.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-7.sp

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-11.sp

Spectrum Name: SJC-Ph- D-12.sp

100.0

2174.34

100.0

1 018.97

3940.76
1871.42

862.48

3940.98

2175.11

2672.80

2175.91

2 671.50

415 .26

2103.19

863.45

861.80

2671.94
1054.2 9

1384.23

2069.77

13 14.41

1054.03

862.20

70
111 9.06

64 9.90

1052.88

651.79

904.81
2095.64

904.39

70
1055.82

904.66

65 0.73

90
2 672.91

416.46

903.09
863.95

233 7.75

1803.58

206 6.87

1173.62

1873.36

3940.75

2175.21
1805.01

1056.16
2672.24

1971.82

2457.61

3936.68

414.83

2459.49

412.58

65 1.89

111 8.83

750.76

1748.05

4 92.78

4 93.52
904.08

602.01

2948.6 8

651.46

751.67

1344.49

12 42.49
1354.17

2990.98

751.24

4 91.59
111 9.25

1053.35

751.76

1448.37

1 230.04

751.20
111 9.55

40
111 9.18

30
1443.97

1346.8 9

1444.61

1500

1000

400.0

17 10.37

1711.36

4000.0

30
294 3.19

159 0.14

1591.09

1594.55

1634.58

1593.54

294 0.25

0.0
2000

1593.12
3441.28

1712.00

2941.52

3000

1713.95

2865.7 0

2866.52
3461.11

0.0
4000.0

2946.53

1315.05

1346.39

2864.48

1227.37
1594.24

1236.96
1352.19

2868.75

1313.22

1348.45

2866.1 3

1223.68

1426.65

30
1314.96

1444.50

1449.04

4 92.68

1222.77

4 92.02

3000

2000

cm-1

3447.81

0.0
1500

1000

400.0

4000.0

294 1.12

3 446.44

1711.08

0.0
3000

2000

1500

cm-1

1000

400.0

3000

2000

1500

1000

400.0

3444.09

3 450.91

0.0

4000.0

cm-1

4000.0

0.0
3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

cm-1

SJC-Ph-D- 7.pk

SJC-Ph-D- 8.pk

SJC-Ph-D- 9.pk

SJC-Ph-D- 10.pk

SJC-Ph-D- 11.pk

SJC-Ph-D- 12.pk

SJC90F~1. SP 3601 4000. 00 400. 00 6.74 99. 65 4.00 %T 5 1. 00

SJD9 0B~1. SP 3601 4000.0 0 400.00 6. 88 99.65 4. 00 %T 5 1.00

SJD9 07~1. SP 3601 4000. 00 400. 00 5.01 100.00 4.00 %T 5 1.00

SJ8E4 F~1.SP 3601 4000.00 400 .00 6.32 100.00 4. 00 %T 5 1.00

SJ865F~1. SP 3601 4000.00 400.00 5.02 100. 00 4.00 %T 5 1. 00

SJ8E5 F~1.SP 3601 4000.00 400 .00 6.31 100.00 4. 00 %T 5 1.00

REF 4 000 88.66 2000 86.67 600

3940.76 84.43 3461.11 9. 68 2941.52 6. 87 2866.52 14.79 267 1.50 75.85
2459.49 86.83 2175.91 82.44 2066.87 82.78 1971.82 85. 56 1871.42 85. 70
1712.00 6. 74 1594.24 19 .62 1444.61 26.34 1344.49 28.76 1314.96 31.37
1227.37 26.28 1119.18 39.57 1053.35 54.35 904.08 59.03 863.95 68.44
751. 20 51 .31 650.73 63.15 492.02 43.9 6 414.83 75.36

REF 4 000 92.71 2000 91.14 600

3936.68 89.41 3441.28 11.71 2940.25 10.45 2864.48 25. 11 2672.80 84. 75
2457.61 91.64 2175.21 87.54 1805.01 83.36 1711.36 6.88 1593.12 17.15
1449.04 42.43 1426.65 44.77 1384.23 56.55 1346.89 36. 08 1313.22 45. 75
1222.77 47.09 1119.25 54.07 1054.29 77.26 1017.87 81. 61 904.66 71.89
863. 45 76 .54 751.24 59.09 651.79 67.9 4 491.59 56.32 412.58 85. 22

REF 4 000 97.62 2000 95.06 600

3940.98 94.82 3447.81 5 .01 2941.12 7. 74 2865. 70 18. 58 2672.24 87.45
2175.11 90.96 1803.58 8 4.06 1711.08 6. 06 1593.54 14.08 1443.97 32.69
1346.39 30.30 1315.05 3 8.41 1223.68 39.70 1119. 55 48.73 1055.82 74. 96
1018.97 82.81 903.09 69. 63 862.48 77 .91 751.76 55.62 651.89 64.69
492. 68 49 .14 415.26 84. 96

REF 4 000 98.52 2000 95.78 600

3940.75 96.28 3446.44 6 .32 2946.53 31.95 2868.75 41.80 2671.94 88.38
2337.75 95.09 2174.34 9 2.24 2069.77 91.69 1873. 36 96.44 1713.95 31. 60
1594.55 22.28 1444.50 4 7.28 1352.19 38.91 1236. 96 40.46 1173.62 77. 18
1118.83 64.78 1052.88 6 7.20 904. 39 81.12 861.80 86. 51 751.67 65.42
649. 90 70 .63 493.52 62. 98 416.46 89.84

REF 4 000 98.40 2000 95.00 600

3450.91 5. 02 2943. 19 31. 91 2866.13 47.66 2672.91 93.78 2095.64 91.51
1710.37 30.25 1634.58 2 7.40 1591.09 24.35 1448. 37 57.43 1348.45 49. 48
1314.41 62.31 1230.04 5 5.60 1119.06 71.11 1054. 03 79.63 904.81 84.57
862. 20 85 .71 750.76 65. 02 651.46 67.44 4 92. 78 64. 31

REF 4 000 99.52 2000 96.68 600

3444.09 6. 31 2990. 98 70. 97 2948.68 70.81 2103.19 93.89 1748.05 70.07
1590.14 25.54 1354.17 6 2.45 1242.49 67.03 1056. 16 89.49 602.01 68.68

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-16.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-15.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-14.sp

100.0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-13.sp

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Name: SJC-Ph- D-17.sp

100.0

Spectrum Name: SJC-Ph- D-18.sp

100.0

100.0
3917.86

90
2099.44

1114.15

3941.98

414 .96

1872.84

2175.32

1871.57

39 39.33

1871.85

2866.79

2174.86

2735.12

1450.41

206 9.64
2 671.91

2988.54

2866.4 4

1358.98

1350.91

1 234.39

20
158 8.95

1594.37

1000

400.0

4000.0

cm-1

1592.46

17 11.30

0.0
3000

1593.35

294 1.88

294 0.86
1711.61

1500

12 42.90

1755.07

%T
40

1236.30

10
3457.36

0.0
2000

1350.38

2945.90

1349.24

20
1594.23

10
3437.27

3000

596.99

2 992.52

50
1236.83
1447.80
2866.69

40
1445.54

2865.7 9

770.19

650.96

50
%T

1348.34

751.68

1383.31

4 92.81

1591.87

0.0
4000.0

1056.50

70
2946.69

65 0.92
751.82
4 93.75

751.75

111 8.87

40
1444.32

1053.46
1119.14

60
1053.66

50
%T

1052.50

2827.64

861.9 7

904.03

60
4 92.49

111 8.49

%T
1355.56

1172.18

2821.88

904.25

65 0.42
751.92

60
12 42.52

2067.03

64 9.01

1314.02

605.78
2949.03

2104.59
27 30.73

1223.48

26 72.75

862.19

903.61

766.39

936.37

10 53.58

206 8.05
2671.32

860.41

1018.19

112 0.17

2130.01

415.97

1055.20

1753.55

3927.75

2174.91

2732.05

2000

1500

1000

400.0

0.0

3451.61

4000.0

cm-1

3000

2000

1500

1000

400.0

3 438.84

3437.20

4000.0

0.0
3000

cm-1

2000

1500

1000

400.0

0.0

3437.82

4000.0

cm-1

3000

2000

1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

cm-1

SJC-Ph-D- 13.pk

SJC-Ph-D- 14.pk

SJC-Ph-D- 15.pk

SJC-Ph-D- 16.pk

SJC-Ph-D- 17.pk

SJC-Ph-D- 18.pk

SJ866F~1. SP 3601 4000.00 400.00 6.35 100. 00 4.00 %T 5 1. 00

SJ8E6 F~1.SP 3601 4000.00 400 .00 7.03 100.00 4. 00 %T 5 1.00

SJC-PH~4. SP 3601 4000. 00 400. 00 5.02 100.00 4.00 %T 5 1.00

SJC-PH~3. SP 3601 4000. 00 400. 00 5.05 99. 99 4.00 %T 5 1. 00

SJC-PH~2. SP 3601 4000. 00 400. 00 5.02 100.00 4.00 %T 5 0.50

SJC-PH~1. SP 3601 4000. 00 400. 00 6.34 99. 99 4.00 %T 5 0. 50

REF 4 000 99.50 2000 97.14 600

3437.27 6. 35 2988. 54 66. 60 2949.03 66.48 2732.05 93.58 2099.44 94.18
1753.55 64.20 1591.87 1 8.50 1355.56 51.26 1242. 52 58.89 1114.15 93. 28
1055.20 85.21 766.39 71. 35 605.78 68 .51

REF 4 000 98.07 2000 96.53 600

3941.98 96.46 3457.36 1 1.15 2940.86 12.17 2865. 79 27.97 2671.91 88. 97
2175.32 93.29 2069.64 9 3.13 1872.84 95.73 1711. 61 7.02 1594.23 23.26
1444.32 40.53 1348.34 3 8.57 1314.02 46.06 1236. 30 22.58 1118.49 55. 20
1052.50 54.96 903.61 75. 36 860.41 82 .10 751.92 65.83 649.01 73.55
492. 49 59 .49 414.96 87. 56

REF 4 000 98.24 2000 95.83 600

3939.33 95.78 3451.61 5 .01 2941.88 14.53 2866.44 28.76 2671.32 87.17
2174.91 91.81 2068.05 9 1.54 1871.57 95.36 1711. 30 11.36 1594.37 17. 35
1445.54 40.25 1349.24 3 5.70 1234.39 31.53 1118. 87 56.63 1053.66 62. 64
904. 03 75 .11 862.19 80. 83 751.75 61.66 6 50. 42 68. 51 492.81 58.47
415. 97 88 .65

REF 4 000 98.20 2000 95.47 600

3927.75 96.13 3437.20 5. 05 2945.90 37.35 2866.69 49.33 2672.75 89.39
2174.86 91.54 2067.03 91.49 1871.85 96.30 1593.35 15. 56 1447.80 56. 37
1350.91 40.01 1236.83 52.68 1119.14 72.14 1053.46 75. 80 904.25 82.97
861. 97 83 .61 751.82 62.22 650.92 64.6 7 493.75 62.42

REF 4 000 99.44 2000 96.21 600

3917.86 95.35 3437.82 5 .02 2946.69 72.57 2866.79 84.56 2821.88 86.71
2735.12 95.38 2130.01 9 2.80 1588.95 18.90 1450. 41 84.84 1383.31 65. 71
1350.38 56.67 1223.48 9 3.51 1120.17 94.90 1053. 58 98.38 1018.19 98. 43
751. 68 67 .32 650.96 63. 96

REF 4 000 99.87 2000 97.91 600

3438.84 6. 34 2992.52 63 .22 2827.64 82.12 2730.73 93.41 2104.59 94.91
1755.07 58.37 1592.46 15.78 1358.98 44.91 1242.90 56. 74 1172.18 88. 73
1056.50 85.87 936.37 98 .32 770.19 70.19 596.99 68.39

311

400.0

Table - 7.28
Observations of FTIR Spectrums for
Cyclohexanone + 2-Butanone + Benzaldehyde
S1
(Cm-1)
3448.51
2941.93
2866.51
2175.91
1711.69
1595.65
1446.74
1354.51
1223.18
1172.10
1118.85
1059.52
1019.13
904.76
863.73
752.08
716.03
650.23
493.63
413.44

S2
(Cm-1)
3944.67
3457.73
2942.35
2871.12
2663.62
1972.83
1711.36
1598.16
1439.93
1353.82
1226.74
1117.94
1063.44
901.77
739.67
650.62
497.50
420.09

S3 (Cm1
)
3447.86
3069.30
2942.16
2866.54
2642.71
1974.42
1708.85
1596.96
1449.87
1420.52
1352.56
1313.87
1231.92
1173.12
1117.78
1065.99
1021.08
905.75
863.20
826.87
750.48
715.61
650.48
497.45

S4
(Cm-1)
3442.82
3073.87
2943.17
2867.99
2644.84
1975.34
1920.96
1704.93
1597.19
1448.74
1351.97
1312.56
1236.81
1173.78
1117.09
1066.46
1021.27
904.97
749.43
714.94
651.02
501.89

*S5
(Cm-1)
3446.96
3069.41
2942.51
2867.15
2742.55
2645.24
1975.55
1919.41
1705.87
1596.64
1449.33
1386.36
1351.77
1311.62
1235.59
1173.04
1117.10
1067.45
1021.03
905.62
826.00
748.84
713.93
651.02
501.47

S6
(Cm-1)
3442.44
3069.80
2942.72
2865.86
2739.70
2649.95
1975.26
1918.67
1703.09
1595.96
1494.87
1450.94
1354.83
1313.83
1234.88
1172.07
1117.71
1068.72
1022.21
906.73
827.00
748.77
713.83
650.53
503.14

S7
(Cm-1)
3926.06
3450.48
3069.57
2941.99
2862.37
2822.41
2737.39
2408.08
2329.79
2139.06
1981.34
1911.16
1705.45
1595.25
1450.76
1351.60
1312.23
1207.33
1167.56
1118.28
1066.74
1015.13
905.56
826.01
748.67

S8
(Cm-1)
3455.33
2941.26
2866.19
2671.91
2176.28
1711.42
1595.73
1446.34
1348.65
1315.11
1222.86
1171.71
1118.75
1058.44
1018.73
904.55
863.84
825.63
751.01
650.44
492.78
413.29

S9
(Cm-1)
3451.98
2941.65
2865.60
2671.02
2064.06
1710.16
1595.59
1449.08
1348.01
1313.51
1224.95
1170.56
1118.54
1059.18
1018.87
905.16
863.45
826.85
750.34
716.30
650.35
493.24
413.79

* Maximum shift in the frequency has been observed.

S10 (Cm1
)
3445.37
2943.73
2869.15
2646.87
2235.09
1921.41
1708.77
1596.65
1448.97
1355.35
1314.25
1238.22
1173.78
1117.06
1067.28
1021.49
905.83
748.96
715.07
651.03
505.60

S11
(Cm-1)
3450.00
3067.15
2941.91
2861.95
2820.02
2737.46
2330.72
1980.71
1911.34
1704.46
1595.94
1452.14
1353.16
1312.09
1205.81
1167.90
1117.60
1068.66
1016.37
906.76
826.78
748.60
689.61
650.23
494.02
451.80

S12
(Cm-1)
3443.87
3069.86
2943.11
2821.83
2737.74
2332.31
1981.13
1910.46
1702.89
1595.42
1452.76
1359.16
1311.86
1206.24
1168.08
1116.39
1070.05
1015.42
910.00
826.14
748.19
689.91
650.58
451.78

S13
(Cm-1)
3442.14
3070.49
2820.81
2738.04
2328.80
2138.82
1981.46
1910.80
1702.64
1595.07
1453.62
1362.57
1311.78
1204.63
1169.08
1112.48
1072.36
1014.09
928.19
826.07
747.66
689.62
650.62
451.70

S14
(Cm-1)
3444.08
3068.00
2942.19
2865.91
2739.88
2646.16
1975.45
1707.49
1596.27
1450.50
1420.82
1350.68
1313.25
1230.72
1171.85
1117.81
1067.22
1021.42
905.97
862.67
827.38
749.38
714.07
650.24
496.48
414.26

312

*S15
(Cm-1)
3445.39
3067.32
2941.79
2865.71
2740.90
2646.23
1974.43
1919.94
1705.31
1596.41
1493.86
1451.15
1419.53
1388.43
1348.91
1313.75
1231.60
1172.15
1117.93
1067.89
1021.76
905.78
862.33
827.51
749.24
714.42

S16
(Cm-1)
3926.44
3440.64
3073.46
2943.27
2867.00
2658.64
2282.60
1975.83
1918.10
1701.63
1595.85
1448.59
1356.49
1278.98
1174.82
1117.70
1068.12
1022.47
928.17
748.77
710.69
651.80
537.31

S17
(Cm-1)
3445.86
3071.96
2943.13
2820.87
2737.69
1982.04
1912.45
1704.02
1594.93
1452.71
1358.08
1312.34
1205.19
1169.06
1116.58
1070.56
1015.70
917.22
826.11
747.67
689.74
650.24
452.51

S18
(Cm-1)
3924.88
3443.26
3073.51
2821.42
2738.01
2330.10
1980.78
1912.52
1701.43
1594.83
1453.44
1361.19
1312.78
1204.68
1169.21
1114.77
1072.11
1015.31
928.42
825.71
747.00
689.37
650.48
451.87

Fig-7.28: FTIR Spectrums for Cyclohexanone+Benzaldehyde+Ethyl Acetate

mixture:
ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08- 2-2010

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-4. sp

100.0

3935.83

197 5.66

100.0

80
1915.94

501.24

907.01

774.86

2989.93

1056.32

2666.94

1067.46

1712.80

3178.88

111 5.60
1450.63

2866.06

3000

2000

1500

1000

400.0

0.0

4000.0

cm-1

3000

2000

1500

1000

400.0

3000

2000

1500

286 5.95

1000

400.0

20
1 358.40

2867.87

3195.28
3428.99

3000

2000

1238.76

2943.12

1 708.55

1 711.18

0.0

4000.0

1500

1000

400.0

2940.78

10
1597.79

cm-1

30
715.19

1173.38

1447.95

1238.90

0.0

4000.0

cm-1

3452.4 5

751.09

3071.18

15 99.84

1706.27

1 706.59

0.0

4000.0

650 .50

1060.59

1115.66

1 359.49
2868.59

2942.14

2942.85

1594.61

0.0

1239.34

16 00.09

713 .93
1447.53

3424.79

1597.31

3069.24
2942.63

1224.50

1115.80

1226.12

1365.19
12 41.76

2651.3 2

1311.82

306 7.26

2866.34

750.05

714 .05

1171.52

1 360.06

3067 .20

749.31

3403.71

710.15
3447.33

20
1762.14

1312.17
1446.82

650.85

1064.33

749.22

60
498.41

826.84

2651.44

65 0.30

750.21

1 448.92

30
3437.28

1060.10

650.80

0.0

1707.3 2

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

cm-1

SJC-PH-D- 1.pk

SJC-PH-D-2. pk

SJC-PH-D-3. pk

SJC-PH-D-4. pk

SJC-PH-D-5. pk

SJC-Ph-D-6.pk

SJ9907~1.SP 3601 4000. 00 400.00 6.67 99.82 4.00 %T 5 1. 00

SJ9903~1. SP 3601 4000.00 400. 00 6.60 99.99 4.00 %T 5 1.00

SJC-PH~4.SP 3601 4000. 00 400.00 6.65 99. 99 4.00 %T 5 1.00

SJA90B~1.SP 3601 4000. 00 400.00 6.72 100.00 4. 00 %T 5 1.00

SJA907~1.SP 360 1 4000. 00 400.00 5.26 99.99 4. 00 %T 5 1.00

SJC-PH~4.SP 3601 4000. 00 400.00 8.54 100.00 4. 00 %T 5 1.00

REF 4 000 99.80 2000 94.10 600

3927.26 97.78 3437.28 27.46 2989.93 57.65 2832.68 65. 93 2721.34 89. 47
1762.14 23.17 1712.80 37.69 1594.61 6.67 1365.19 14.03 1241.76 15.08
1056.32 56.66 924.76 95 .95 774.86 64.59 627.14 77.93 535.01 80.78

REF 4000 98.88 2000 94. 18 600

3447. 33 33.58 31 78. 88 36. 03 3067.20 31.40 2942.63 15.20 2866. 34 27.04
2739. 08 56.28 19 75. 66 92. 30 1913.90 91.01 1706.59 6. 59 1600. 09 15.79
1448. 92 41.97 13 60. 06 31. 08 1310.35 34.76 1226.12 24.69 1116. 46 53.70
1067. 46 66.03 10 22. 88 75. 13 906.96 79.37 826.90 61.52 750.21 40.02
710.15 40.51 650. 80 54.73 501.24 76.6 5 453.53 85. 20

REF 4000 98.52 2000 94. 34 600

3935. 83 97.39 34 03. 71 42. 61 3067.26 33.29 2942.14 14.47 2866. 06 27.17
2739. 71 60.22 26 66. 94 66. 34 1974.48 92.45 1915.94 91.14 1706. 27 6.65
1597. 31 25.72 14 50. 63 39. 90 1364.00 38.32 1311.82 34.08 1239. 34 17.13
1171. 52 42.12 11 15. 60 48. 34 1060.10 55.51 907.01 73.9 1 827.76 62. 78
749.31 44.42 714. 05 40.35 650.30 54.9 9 496.78 75. 59 453.18 86.01
414.64 91.40

REF 4000 98.33 2000 93. 03 600

3424. 79 26.30 3069.24 22.97 2942.85 10.22 28 68. 59 19. 53 2651.44 53.19
1918. 05 89.27 1708.55 6.72 1599.84 19.11 1447.53 36. 01 1359. 49 29.34
1238. 90 16.85 1115.80 44.49 1064.33 54.69 90 6.53 68. 52 826.82 64. 21
750.05 47.31 713.93 37.44 650.85 54.00 501.40 69.71

REF 4000 97.91 2000 94. 89 600

3930. 26 96.69 34 28. 99 17. 89 3195.28 19.68 3071.18 19.06 2943. 12 7.07
2867. 87 14.53 26 51. 32 52. 80 1918.54 91.92 1707.32 5. 26 1597. 79 11.02
1447. 95 29.20 13 58. 40 20. 99 1238.76 11.17 1173.38 32.94 1115. 66 38.70
1060. 59 47.99 90 5.04 67.53 860.86 69.43 826.8 4 67.07 751. 09 46.45
715.19 32.75 650. 50 49.97 498.41 62.7 6 415.07 89. 00

REF 4000 98.89 2000 98. 30 600

3778. 90 95.20 3452.45 49.34 3066.93 81.09 29 40. 78 23. 02 2865.95 48.57
2738. 58 91.14 2340.54 97.27 1711.18 8. 54 1599.26 70. 56 1446. 82 60.33
1386. 63 73.36 1312.17 64.45 1224.50 51.50 11 68. 91 79. 21 1117.48 71.07
1057. 09 79.78 905.22 88.08 827.42 85 .19 749. 22 67.00 694. 44 80. 11
650.12 78.86 492.00 80.79 415.28 94.86

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

862.82

100.0

FT IR SPECT RUM
Date: 08-2- 2010
Spec trum Na me: SJC-PH-D-12.sp

100.0

862.51

1917.02

Spec trum Na me: SJC-PH-D-11.sp

100.0

416.14

3816.59

39 28.06

2673.49 217 4.97

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-10.sp

413.66

412.03

90
3935.90

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-9. sp

100.0
11 67.38 1019.71

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-8. sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-7. sp

3797.75

3929.21

197 4.15

20 84.05
3929.67

197 6.88

197 6.81

3934.40

1916.67

2724.45

1917.72

649.91
142 6.56

773.32

905.93

50
1313.52

3 068.39

40
1233.74

40
714 .19

1116.42

1311 .56

750.32

3069.18

2865.74

1 357.28

3194.15
3440.62

1231.99

4000.0

3000

2000

2942.46

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

3069.99

105 3.28

2823.57

3442.84
2864.82

2948.27

1367.83
2943.54

10
1597.80

1000

400.0

1242.13

0.0

1704.70

4000.0

1368.51

10
15 99.47

1241.38

1603.28
1703.36

1 703.01

0.0
1500

708.91

1448.37

749.71

2821.56

3000

2000

cm-1

1500

1000

400.0

0.0

4000.0

3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

cm-1

1243.62

1500

1000

SJC-PH-D-8. pk

SJC-PH-D-9. pk

SJC-PH-D-10.pk

SJC-PH-D-11.pk

SJC-PH-D-12.pk

SJA90F~1.SP 3601 4000. 00 400.00 7.01 99. 90 4.00 %T 5 1.00

SJC-PH~2.SP 3601 4000. 00 400.00 6.59 100.00 4. 00 %T 5 1.00

SJB907~1.SP 3601 4000.00 400.0 0 6.76 100. 00 4.00 %T 5 1.00

SJC-PH~3.SP 3601 4000. 00 400.00 6.66 99. 99 4.00 %T 5 1.00

SJ665F~1.SP 3601 4000.00 400.0 0 6.72 100. 00 4.00 %T 5 1.00

SJC-PH~1.SP 3601 4000. 00 400.00 7.00 99. 99 4.00 %T 5 1.00

REF 4000 97.12 2000 95. 74 600

3935. 90 94.23 34 16. 02 29. 31 2940.85 15.27 2864.32 33.49 2724. 45 87.95
2673. 49 91.24 21 74. 97 94. 27 1711.54 7.00 1595. 10 11.1 6 1449. 91 46.35
1426. 56 49.36 13 59. 72 26. 89 1313.35 48.99 1233.74 35.74 1167. 38 89.22
1118. 57 58.85 10 53. 72 65. 92 1019.71 83.14 905.36 79.6 5 862.82 84. 18
773.32 69.53 751. 54 66.92 649.91 76.3 7 491.24 69. 08 412.03 91.28

REF 4000 98.36 2000 94. 68 600

3928. 06 96.66 3438.02 30.93 3196.65 35.32 30 68. 39 33. 72 2942.46 13.74
2865. 74 25.26 2738.45 61.86 2670.32 67.27 19 17. 02 91. 58 1706.97 6. 59
1597. 14 14.57 1450.48 37.99 1419.95 42.80 13 58. 49 26. 98 1313.52 34.24
1231. 99 26.68 1171.87 46.42 1117.11 49.17 10 66. 22 63. 85 1021.67 73.00
905.93 76.08 862.51 78.05 827.65 68.45 750.06 48.08 714. 19 41.95
650.20 56.70 496.07 72.72 413.66 91.21

REF 4000 98.19 2000 92. 90 600

3934. 40 95.47 3816.59 95.94 3440.62 22.51 31 94. 15 25. 99 3069.18 24.16
2942. 93 9.12 2867.50 18.52 2662.74 57.47 1974.15 90. 54 1916. 67 89.55
1709. 41 6.76 1598.55 12.90 1447.83 34.34 1357.28 26. 76 1311. 56 30.58
1235. 60 22.08 1116.42 45.46 1065.06 57.79 10 23. 04 68. 32 905.76 73.38
827.08 64.26 750.32 43.97 712.21 39.92 650.50 54.94 497. 98 68.82
416.14 91.22

REF 4000 98.36 2000 90. 92 600

3929. 21 96.02 34 16. 52 16. 99 3188.26 16.24 3071.26 14.90 2944. 02 8.45
2868. 81 15.67 26 59. 07 41. 92 1917.72 85.04 1704.70 6. 66 1597. 80 10.62
1448. 65 31.41 13 67. 66 21. 59 1241.38 11.52 1115.06 40.96 1062. 51 47.02
909.11 63.63 826. 49 53.34 748.53 37.6 6 712.88 29. 87 651.22 44.33
507.28 66.86

REF 4000 98.68 2000 92. 61 600

3445. 88 33.77 3193.80 35.41 3066.83 31.33 29 43. 54 18. 84 2864.82 30.56
2821. 56 33.50 2738.25 52.79 1976.88 90.35 19 13. 21 88. 20 1703.01 6. 72
1599. 47 12.08 1451.63 39.01 1367.83 23.47 13 11. 74 32. 89 1242.13 10.73
1170. 47 43.20 1114.34 52.86 1056.95 48.71 90 9.35 77. 79 827.47 54. 24
749.71 36.27 714.39 40.46 650.27 47.96 498.57 77.55 452. 23 77.67

REF 4000 99.05 2000 92. 64 600

3929. 67 97.69 37 97. 75 96. 16 3442.84 30.86 3069.99 34.54 2948. 27 28.71
2823. 57 35.06 27 36. 40 54. 08 2551.39 64.57 2084.05 95.45 1976. 81 89.90
1913. 35 85.36 17 03. 36 6.99 1603.28 9. 10 1448. 37 41.29 1368. 51 16. 16
1243. 62 9.21 1110.35 54.21 1053.28 38.49 930.41 63.61 825.56 55.92
753.42 43.10 708. 91 40.20 650.92 48.7 1 541.90 69. 78 451.92 76.52

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 15-2- 2010
100.0

100.0

1823.01

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

3884.7 3

11 09.72

2331.80

3779.20

2027.35

100.0

2177.01

100.0

90
1914.63

29 93.21

829.46

2 671.87

904.70
862.99

649.23

1167.76

3067.11
2818.59

716.25

30 67.13

491.68

826.90

1055.68

753.32

649.91

1385.51

3454.09
1052.85

1171.5 0

3069.44
3433.10

2861.08

1170.48

273 8.71

1596.95

1169.05

3068.08

746.34

826.73
650 .61
691.66

40
1595.91

1208.16

1 452.81

2819.25
1383.83

708.49

1288.12

2942.94

50
650.96

747.07

1353.97

20
1596.54

2866 .44
3412.50

1445.87

0.0
1500

1000

400.0

4000.0

cm-1

1 236.66

2000

2942.13

1 238.76

1 713.33

1500

1000

400.0

4000.0

1242.74

2000

10
1703.82

0.0
3000

10
1 708.06

1 712.07

0.0

cm-1

1239.30

2942.18

1599.22

2943.33

3000

1596.97

1 357.96

2866.44
1702.57

2000

105 5.76

826.71

139 2.64

28 21.03

1117.94
746.76

12 06.48

1242.56

3000

1 451.55

3391 .68

1362.89

2865.95

1446.90

451.07
3197.19

60
27 38.87

50
%T

714 .21
1449.5 5

650.45

7 49.24
3407.23

1 117.11

1595.96

0.0
4000.0

538.82
927.44

450.97

1112.33

10 60.47

3171.11

50
%T

1315.23

1107.9 6

1911.07
2546.91

827.09

273 8.92

493.24

751.20

3068.01
688.90

30
3442.43

1981.01

1114.61
1313.30

649.77

904.77

1453.62

2333.53

542.49

1070.56

1170.70

2674.13
451.42
1060.30
2737.88
2946.73

37 79.66

923.83
1018.88

80
498.17
2545.57

70
1310.0 2

2362.24
1915 .23

198 1.84

100.0

1980.26

3778.76

2065.90
905.95

FT IR SPECT RUM
Date: 15-2- 2010
Spec trum Na me: SJC-Ph-D-18. sp

453.4 2

861.93

3934.63

1969.42

3940.45

Spec trum Na me: SJC-Ph-D-17. sp

413.81

90
2465.19
2176.60

5 44.25

FT IR SPECT RUM
Date: 15-2- 2010

Spec trum Na me: SJC-PH-D-16.sp

100.0

2068.14

90
924.24

1907.88

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-15.sp

413.97

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-14.sp

400.0

cm-1

SJC-PH-D-7. pk

Spec trum Na me: SJC-Ph-D-13. sp

650.92

75 3.42

3193.80

2868 .81

3188.26
2944.02

1709.41

cm-1

3445.88

71 4.39

1451.63

712 .88

1598.55
2942.93

0.0

2 736.40

1367.66
3416.52

1597.14
1 706.97

0.0

1500

1 448.65

1 235.60
2867.50

10
1595.10
1711.54

650.27

1170.4 7

748.53

1447.8 3

30 71.26
1 358.49

2940.85

93 0.41

825.56

1056.95

30 66.83

2551 .39

827.47

1311.74

651.22

1115.06

712.21

3196.65
3438.02

1 359.72

0.0

451.92

1110.35

2 738.25

1062.5 1

265 9.07

541.90

826.49

750.06

1450.48

1313.35

2864.32

3416.02

1117.11
1171.87

1 449.91

70
452.23

507.28
9 09.11

650.50

2662.7 4

650.20

1065.06

%T
40

1913.35
4 98.57

9 09.35

497.98

1066.22

1 419.95

2738.45

905.76
1023.0 4
827.08

2670.32

1118.57

496.07

1021.6 7 827.65

491.24

751.54

10 53.72

1 114.34

1913.21

905.36

492.00
650.12

15 99.26
905.04

826.82

2739.71

50
%T

1116.46

501.40

60
827.76

1364.00

1310 .35

2739.08

1057.09

1 117.48

826.90

905.22

2738.58

827.42

496.78

906.53
2832.68

694.44

1 386.63

860.86

453.18

1168.91

2 340.54

3066.93

3 778.90

4 15.07

1918.54

906.96

70
1022.88

415.28

90
3930.26

1918.05

1913.90

80
535.01
6 27.14

Spec trum Na me: SJC-Ph-D-6.sp

100.0

197 4.48

2721.34

FT IR SPECT RUM
Date: 15-2- 2010

Spec trum Na me: SJC-PH-D-5. sp

414.64

4 53.53

924.76

3927.26

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-3. sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spec trum Na me: SJC-PH-D-2. sp

100.0

ACIC
St.Joseph's College ( Autonomous )
Tric hy-2

FT IR SPECT RUM
Date: 08-2- 2010

Spectrum Name: SJC-PH-D-1. sp

1500

1000

400.0

4000.0

1 704.11

0.0
3000

cm-1

2000

1500

1000

400.0

4000.0

cm-1

0.0
3000

2000

1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

cm-1

SJC-Ph-D-13. pk

SJC-PH-D-14.pk

SJC-PH-D-15.pk

SJC-PH-D-16.pk

SJC-Ph-D-17. pk

SJC-Ph-D-18. pk

SJ866F~1.SP 3601 4000.00 400.0 0 7.88 99.95 4.00 %T 5 1.00

SJ6E6F~1.SP 360 1 4000. 00 400.00 5.60 100. 00 4.00 %T 5 1. 00

SJ667F~1.SP 3601 4000.00 400.0 0 6.84 100. 00 4.00 %T 5 1.00

SJ6E7F~1.SP 360 1 4000. 00 400.00 6.79 99.99 4. 00 %T 5 1.00

SJC-PH~1.SP 3601 4000. 00 400.00 6.32 99. 99 4.00 %T 5 1.00

SJC-PH~3.SP 3601 4000. 00 400.00 6.30 99. 99 4.00 %T 5 1.00

REF 4000 98.78 2000 93. 48 600

3884. 73 96.71 37 79. 20 90. 85 3442.43 33.06 3067.11 49.33 2993. 21 54.39
2946. 73 54.50 28 18. 59 49. 34 2737.88 55.46 2331.80 95.04 2027. 35 92.99
1981. 84 91.54 19 07. 88 92. 24 1823.01 91.21 1702.57 7. 87 1595. 96 32.04
1453. 62 53.56 13 85. 51 44. 19 1310.02 47.75 1242.56 18.94 1206. 48 29.38
1167. 76 50.22 11 09. 72 71. 68 1060.30 61.42 924.24 87.5 5 826.90 47. 35
746.76 29.35 688. 90 41.27 649.91 43.7 6 544.25 84. 22 451.42 68.07

REF 4000 95.76 2000 92. 11 600

3940. 45 90.69 3412.50 20.46 2943.33 5. 60 2866.44 11. 86 2674. 13 74.22
2465. 19 92.32 2176.60 90.18 2068.14 89.17 19 69. 42 89. 19 1713.33 5. 89
1599. 22 8.72 1445.87 19.67 1357.96 13.48 1315.23 23. 88 1238. 76 6.32
1117. 94 33.47 1052.85 30.09 904. 77 57.20 862. 99 68.86 753.32 48. 20
649.23 67.08 491.68 50.24 413.97 82.34

REF 4000 97.48 2000 96. 08 600

3934. 63 95.06 3454.09 30.08 3067.13 47.02 29 42. 13 9.45 2866. 44 20.94
2671. 87 77.84 2177.01 96.13 2065.90 95.73 17 12. 07 6.84 1596. 97 20.21
1446. 90 34.19 1353.97 30.71 1313.30 36.38 12 36. 66 18. 81 1170.70 56.77
1117. 11 47.39 1055.68 52.97 904. 70 74.96 861. 93 79.83 829.46 80. 66
751.20 56.67 716.25 64.15 649.77 68.55 493.24 64.63 413. 81 89.58

REF 4000 99.15 2000 95. 92 600

3407. 23 48.76 31 71. 11 47. 11 3068.01 42.29 2942.18 20.11 2865. 95 36.75
2738. 92 68.40 19 14. 63 93. 27 1708.06 6.79 1596. 54 25.3 8 1449. 55 49.25
1362. 89 39.45 12 39. 30 25. 13 1171.50 50.71 1114.61 60.44 1060. 47 65.20
905.95 83.06 827. 09 70.65 749.24 53.3 4 714.21 50. 63 650.45 64.07
498.17 82.88 453. 42 90.63

REF 4000 99.41 2000 96. 36 600

3778. 76 96.94 34 33. 10 41. 18 3069.44 44.99 2942.94 46.08 2861. 08 54.21
2821. 03 53.27 27 38. 87 63. 96 2545.57 82.67 2362.24 94.43 1980. 26 95.18
1915. 23 94.97 17 03. 82 6.32 1596.95 40.89 1451. 55 62.1 7 1392. 64 58.21
1288. 12 46.77 12 08. 16 38. 14 1170.48 55.69 1112.33 76.61 1070. 56 82.82
1018. 88 87.96 92 3.83 90.31 826.71 60.74 746.3 4 40.16 708. 49 47.60
650.96 54.86 542. 49 86.50 450.97 82.1 1

REF 4000 99.71 2000 95. 23 600

3779. 66 96.64 33 91. 68 58. 61 3197.19 62.05 3068.08 52.44 2819. 25 53.08
2738. 71 60.45 25 46. 91 86. 11 2333.53 94.76 1981.01 93.68 1911. 07 93.09
1704. 11 6.30 1595.91 40.01 1452.81 58.55 1383. 83 47.6 6 1242. 74 21.71
1169. 05 53.97 11 07. 96 73. 56 1055.76 63.69 927.44 83.9 5 826.73 53. 16
747.07 35.26 691. 66 48.70 650.61 52.0 6 538.82 87. 72 451.07 77.09

313

400.0

Table - 7.29
Observations of FTIR Spectrums for
Cyclohexanone + Benzaldehyde + Ethyl Acetate:
S1
(Cm-1)
3927.26
3437.28
2989.93
2832.68
2721.34
1762.14
1712.80
1594.61
1365.19
1241.76
1056.32
924.76
774.86
627.14
535.01

S2
(Cm-1)
3447.33
3178.88
3067.20
2942.63
2866.34
2739.08
1975.66
1913.90
1706.59
1600.09
1448.92
1360.06
1310.35
1226.12
1116.46
1067.46
1022.88
906.96
826.90
750.21
710.15
650.80
501.24
453.53

*S3 (Cm1
)
3935.83
3403.71
3067.26
2942.14
2866.06
2739.71
2666.94
1974.48
1915.94
1706.27
1597.31
1450.63
1364.00
1311.82
1239.34
1171.52
1115.60
1060.10
907.01
827.76
749.31
714.05
650.30
496.78
453.18
414.64

S4
(Cm-1)
3424.79
3069.24
2942.85
2868.59
2651.44
1918.05
1708.55
1599.84
1447.53
1359.49
1238.90
1115.80
1064.33
906.53
826.82
750.05
713.93
650.85
501.40

S5
(Cm-1)
3930.26
3428.99
3195.28
3071.18
2943.12
2867.87
2651.32
1918.54
1707.32
1597.79
1447.95
1358.40
1238.76
1173.38
1115.66
1060.59
905.04
860.86
826.84
751.09
715.19
650.50
498.41
415.07

S6
(Cm-1)
3778.90
3452.45
3066.93
2940.78
2865.95
2738.58
2340.54
1711.18
1599.26
1446.82
1386.63
1312.17
1224.50
1168.91
1117.48
1057.09
905.22
827.42
749.22
694.44
650.12
492.00
415.28

S7
(Cm-1)
3935.90
3416.02
2940.85
2864.32
2724.45
2673.49
2174.97
1711.54
1595.10
1449.91
1426.56
1359.72
1313.35
1233.74
1167.38
1118.57
1053.72
1019.71
905.36
862.82
773.32
751.54
649.91
491.24
412.03

S8
(Cm-1)
3928.06
3438.02
3196.65
3068.39
2942.46
2865.74
2738.45
2670.32
1917.02
1706.97
1597.14
1450.48
1419.95
1358.49
1313.52
1231.99
1171.87
1117.11
1066.22
1021.67
905.93
862.51
827.65
750.06
650.20
496.07

*S9
(Cm-1)
3934.40
3816.59
3440.62
3194.15
3069.18
2942.93
2867.50
2662.74
1974.15
1916.67
1709.41
1598.55
1447.83
1357.28
1311.56
1235.60
1116.42
1065.06
1023.04
905.76
827.08
750.32
712.21
650.50
497.98
416.14

S16
(Cm-1)
3407.23
3171.11
3068.01
2942.18
2865.95
2738.92
1914.63
1708.06
1596.54
1449.55
1362.89
1239.30
1171.50
1114.61
1060.47
905.95
827.09
749.24
714.21
650.45
498.17
453.42

S17
(Cm-1)
3778.76
3433.10
3069.44
2942.94
2861.08
2821.03
2738.87
2545.57
2362.24
1980.26
1915.23
1703.82
1596.95
1451.55
1392.64
1288.12
1208.16
1170.48
1112.33
1070.56
1018.88
923.83
826.71
746.34
708.49
650.96
450.97

S18
(Cm-1)
3779.66
3391.68
3197.19
3068.08
2819.25
2738.71
2546.91
2333.53
1981.01
1911.07
1704.11
1595.91
1452.81
1383.83
1242.74
1169.05
1107.96
1055.76
927.44
826.73
747.07
691.66
650.61
538.82
451.07

* Maximum shift in the frequency has been observed.

S10 (Cm-1)
3929.21
3416.52
3188.26
3071.26
2944.02
2868.81
2659.07
1917.72
1704.70
1597.80
1448.65
1367.66
1241.38
1115.06
1062.51
909.11
826.49
748.53
712.88
651.22
507.28

S11
(Cm-1)
3445.88
3193.80
3066.83
2943.54
2864.82
2821.56
2738.25
1976.88
1913.21
1703.01
1599.47
1451.63
1367.83
1311.74
1242.13
1170.47
1114.34
1056.95
909.35
827.47
749.71
714.39
650.27
498.57
452.23

S12
(Cm-1)
3929.67
3797.75
3442.84
3069.99
2948.27
2823.57
2736.40
2551.39
2084.05
1976.81
1913.35
1703.36
1603.28
1448.37
1368.51
1243.62
1110.35
1053.28
930.41
825.56
753.42
708.91
650.92
541.90
451.92

*S13
(Cm-1)
3884.73
3779.20
3442.43
3067.11
2993.21
2946.73
2818.59
2737.88
2331.80
2027.35
1981.84
1907.88
1823.01
1702.57
1595.96
1453.62
1385.51
1310.02
1242.56
1206.48
1167.76
1109.72
1060.30
924.24
826.90
746.76
451.42

S14
(Cm-1)
3940.45
3412.50
2943.33
2866.44
2674.13
2465.19
2176.60
2068.14
1969.42
1713.33
1599.22
1445.87
1357.96
1315.23
1238.76
1117.94
1052.85
904.77
862.99
753.32
649.23
491.68
413.97

S15
(Cm-1)
3934.63
3454.09
3067.13
2942.13
2866.44
2671.87
2177.01
2065.90
1712.07
1596.97
1446.90
1353.97
1313.30
1236.66
1170.70
1117.11
1055.68
904.70
861.93
829.46
751.20
716.25
649.77
493.24
413.81

* Maximum shift in the frequency has been observed.

314

Fig-7.29: FTIR spectrums for Cyclhexanone + Ethyl Acetate + 2-Butanone

mixture:
ACIC
St.Joseph's College ( Autonomo us )
Trichy-2

FTIR SPECTRUM
Date: 03-12-2009

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

Spectrum Name: SJC-Ph -D-1.sp

10 0. 0

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FTIR SPECTRUM
Date: 03-1 2-200 9

413.27

1172.66

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Na me: SJC-Ph-D-2.sp

2176.04
3788.49

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

100.0

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-4.sp

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-5.sp

100.0

Spectrum Name: SJC-Ph- D-6.sp

100.0

863.72

2673.39

1054.67
905.15

3927.93
1018.47

861 .50

80
751.78

416.20

903.29

6 49.90

650.90

1172.47
392 7.50

3793.60

1054.63

903.20

752.07

754.07

1054.15

2173.53

904.11

2672.60

64 9.91

1055.56

904.99
1314.07

2175.71

3928.10

2 673.57

70
863 .56

2672.36

60
559.88

1055.28

4 91.94
111 9.05

649 .71
753 .18
492.3 8

11 19.18

50
%T

751.69
4 91.47

4 92.04

1119.36

11 19.18

587.69

111 9.18

1 223.19

1222.8 9

1350.61

2175.76
3788.52

3790.58

70
105 5.2090 3.33

1314.28

1448.22

414.55
862.8 0

2175.61

1 018.91

2673.92
3931.42

1119.36
1222.68

861 .26

413 .32

2175 .84

3784.96

491.59

50
%T

1020.15

3931.53

651.14

FT IR SPECT RUM
Date: 03- 12-2009

Spectrum Name: SJC-Ph- D-3.sp

1804.84

1 227.85

1445.16

755.49

1223.85

1 444.52

1348.36

1448.21

1444.42

30
2866.09

3420.47
1595.46

1351.62

2865.6 0

2864.88

2864.86

1712.31

0. 0
4 00 0. 0

1350.34

1351.08

2865.46

2940.99

30 00

1 50 0

1 00 0

1353.25
3 431.36

3 439.70

2 00 0

40 0 .0

2941.2 4

cm -1

171 1.17

3420.01
294 0.97

3000

2000

1500

1000

400.0

4000.0

cm-1

3431.58

17 12.05

0.0

4000.0

1595.16

15 95.42

0.0

SJC-Ph-D-1.pk

3000

294 0.55

1500

1000

400.0

294 0.81

1595.65
17 11.36

3436.14

0.0

4000.0

3000

2000

1500

cm-1

294 2.42
17 12.65

17 11.82

0.0

2000

1595.38

1000

400.0

1594.99

0.0

4000.0

3000

2000

1500

cm-1

1000

400.0

4000.0

3000

2000

1500

cm-1

1000

SJ C-Ph-D-2.pk

SJC-Ph-D- 3.pk

SJC-Ph-D- 4.pk

SJC-Ph-D- 5.pk

SJC-Ph-D- 6.pk

REF 4000 88.78 2000 87.99 600

3927.97 85.91 37 88.49 84.61 342 0.47 16.33 2940.99 11.72 2865.29 26.25
2673.39 80.60 21 76.04 84.99 180 4.84 79.55 1712.31 7.45 1595.46 15.2 9
1448.22 39.98 13 50.61 30.91 131 4.28 45.22 1222.68 48.05 1172.66 77.18
1119.36 54.46 10 54.67 75.08 101 8.13 79.40 905.1 5 71.81 863.72 76.49
751.78 60.58 651.14 69.69 491.59 56 .71 4 13.27 80.34

SJ B90 3~1.SP 3601 4000.00 400 .00 6.31 99.58 4 .0 0 % T 5 1.00

SJB90 F~1.SP 3601 4000.00 400 .00 7.42 98.98 4.00 %T 5 1. 00

SJC90B~1. SP 3601 4000. 00 400. 00 7.08 99. 87 4.00 %T 5 1. 00

SJC907~1.SP 3601 4000.00 400 .00 8.04 99.68 4.00 %T 5 1. 00

SJC903~1.SP 3601 4000.00 400 .00 5.30 99.43 4.00 %T 5 1. 00

REF 4 000 87.29 2000 85. 89 600

39 31.42 82.79 3784. 96 81.45 3439.70 6.31 2941. 24 11 .45 2865.46 27.10
26 73.92 79.58 2175. 84 82.26 1711.17 8.85 1595. 42 7. 48 1444.52 40. 17
13 51.08 26.73 1223. 19 49.72 1119.18 55. 77 105 5. 20 73.03 1018.91 77. 60
90 3. 33 70.43 861.50 72.39 753.18 53.49 649. 71 59.94 559 .8 8 61.46
49 2. 38 52.58

REF 4 000 86.78 2000 86.01 600

REF 4 000 88.63 2000 87.88 600

REF 4 000 89.65 2000 88.80 600

REF 4 000 81.31 2000 80.29 600

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

100.0

217 5.11

863.95

4 15.26

651.79

751 .76

11 19.25

111 9.18

1426.6 5

1313.2 2

30
144 3.97

2946.53

1 315.05

1713.9 5

2943.1 9

159 1.09

1594.55

2 865.7 0

1590.14

1634.58

1593.12
3 441.28

1593.54

2940.2 5
1711.36

3 447.8 1

0.0

4000.0

171 0.37

1346.39

2864.48

0.0
400.0

1242 .49
1354 .17

13 48.45

28 66.13

40
1236.96
1352.19

1227.37

1712.00

1000

602 .01

1748.05

299 0.98

50
%T

144 4.50
286 8.75

134 6.89

1314.96
1444.61

492.6 8

1 223.6 8

1594.24
2866.52

1500

2 948.68

492.7 8

1230 .04

%T
40

1449.04

0.0
2000

750.76
1 448.37

%T
40

1222.7 7

4 92.02

2941.52

70
6 51.46

751 .67

%T
11 19.55

3000

1054.0 3 862.20
11 19.06

649 .90

11 18.83

493.5 2
491.5 9

50
%T
751.20

3461.11

1 314.4 1

651 .89

751 .24

904.08
1053.35

4000.0

90 4.81
2095.64

90 4.39

1052.88

65 0.73
1344.49

861.80

2069.77

21 03.19
10 56.16

1055.8 2
90 3.09

904.6 6

90
26 72.91

41 6.46

180 3.58
105 4.29 863.45

1384 .23

100.0

2337.75

2671.94
180 5.01

206 6.87

FTIR SPECTRUM
Date: 02-1 2-200 9
Spectrum Na me: SJC-Ph-D-12.sp

100.0

1 173.6 2

18 73.36

3940.75

217 5.21

70
2 671.50

2672 .24

2672.8 0

1971.82
2175.91

862 .48

394 0.98

2457.6 1

393 6.68

414.83

2459.49

Spectrum Na me: SJC-Ph-D-11.sp

21 74.34

1018.97
412 .58

FTIR SPECTRUM
Date: 02-1 2-200 9

Spectrum Na me: SJC-Ph-D-10.sp

1017.87

1871.42

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 02-1 2-200 9

Spectrum Na me: SJC-Ph-D-9.sp

3940.76

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 02-1 2-200 9

Spectrum Na me: SJC-Ph-D-8.sp

100.0

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 03-1 2-200 9

FT IR SPECT RUM
Date: 03- 12-2009
Spectrum Name: SJC-Ph- D-7.sp

3000

2000

1500

1000

400.0

4000.0

2941.1 2

0.0
2000

1500

cm-1

3446.44

1711.0 8

3000

1000

400.0

3000

2000

1500

cm-1

1000

400.0

3444 .09

3450.91

0.0

4000.0

0.0
3000

2000

cm-1

1500

1000

400.0

4000.0

3000

2000

cm-1

1500

1000

400.0

cm-1

SJC-Ph-D- 7.pk

SJ C-Ph-D-8.pk

SJ C-Ph-D-9.pk

SJ C-Ph-D-10.pk

SJ C-Ph-D-11.pk

SJ C-Ph-D-12.pk

SJC90F~1. SP 3601 4000. 00 400. 00 6.74 99. 65 4.00 %T 5 1. 00

SJ D90B~1.SP 3601 4000 .0 0 4 00.00 6. 88 99.65 4.00 %T 5 1. 00

SJ D907~1.SP 3601 4000. 00 400.00 5.01 100.00 4.00 %T 5 1. 00

SJ 8E4 F~1.SP 3601 40 00.00 400.00 6.32 100.00 4.00 %T 5 1.00

SJ 865F~1.SP 3601 4000.00 400 .00 5.02 100. 00 4. 00 %T 5 1.00

SJ 8E5 F~1.SP 3601 40 00.00 400.00 6.31 100.00 4.00 %T 5 1.00

REF 4 000 88.66 2000 86.67 600

REF 4 000 92.71 2000 91. 14 600

39 36.68 89.41 3441. 28 11.71 2940.25 10. 45 286 4. 48 25.11 2672.80 84. 75
24 57.61 91.64 2175. 21 87.54 1805.01 83. 36 171 1. 36 6. 88 1593.12 17.15
14 49.04 42.43 1426. 65 44.77 1384.23 56. 55 134 6. 89 36.08 1313.22 45. 75
12 22.77 47.09 1119. 25 54.07 1054.29 77. 26 101 7. 87 81.61 904.66 71.89
86 3. 45 76.54 751.24 59.09 651.79 67.94 491. 59 56.32 412 .5 8 85.22

REF 4 000 97.62 2000 95. 06 600

39 40.98 94.82 3447 .8 1 5.01 2941.12 7.74 2865.70 18. 58 2672.24 87. 45
21 75.11 90.96 1803 .5 8 84.06 1711.08 6.06 1593.54 1 4. 08 1 443.97 32.69
13 46.39 30.30 1315 .0 5 38.41 1223.68 39.70 1119.55 48. 73 1055.82 74. 96
10 18.97 82.81 903. 09 69. 63 862.48 77.91 751.76 55.62 651.89 64.69
49 2. 68 49.14 415. 26 8 4. 96

REF 4 000 98.52 2000 95. 78 600

39 40.75 96.28 3446 .4 4 6.32 2946.53 31. 95 2868.75 4 1. 80 2 671.94 88.38
23 37.75 95.09 2174 .3 4 92.24 2069.77 91.69 1873.36 96. 44 1713.95 31. 60
15 94.55 22.28 1444 .5 0 47.28 1352.19 38.91 1236.96 40. 46 1173.62 77. 18
11 18.83 64.78 1052 .8 8 67.20 904. 39 81. 12 861.80 86. 51 751.67 65.42
64 9. 90 70.63 493. 52 6 2. 98 4 16.46 89. 84

REF 4 000 98.40 2000 95. 00 600

34 50.91 5.02 2943.19 31. 91 2866.13 47. 66 2672.91 9 3. 78 2 095.64 91.51
17 10.37 30.25 1634 .5 8 27.40 1591.09 24.35 1448.37 57. 43 1348.45 49. 48
13 14.41 62.31 1230 .0 4 55.60 1119.06 71.11 1054.03 79. 63 904.81 84.57
86 2. 20 85.71 750. 76 6 5. 02 6 51.46 67. 44 492.78 64.31

REF 4 000 99.52 2000 96. 68 600

34 44.09 6.31 2990.98 70. 97 2948.68 70. 81 2103.19 9 3. 89 1 748.05 70.07
15 90.14 25.54 1354 .1 7 62.45 1242.49 67.03 1056.16 89. 49 602.01 68.68

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 02-1 2-200 9

Spectrum Na me: SJC-Ph-D-17.sp

100.0

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 02-1 2-200 9

Spectrum Na me: SJC-Ph-D-16.sp

Spectrum Name: SJC-Ph- D-15.sp

100.0

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 02-1 2-200 9

FT IR SPECT RUM
Date: 02- 12-2009

Spectrum Na me: SJC-Ph-D-14.sp

100.0

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

FTIR SPECTRUM
Date: 02-1 2-200 9
Spectrum Na me: SJC-Ph-D-13.sp

400.0

cm-1

SJB907~1.SP 3601 4000.00 400.00 7 .45 99.05 4.0 0 %T 5 1.00

Spectrum Na me: SJC-Ph-D-18.sp

100.0

100.0
3917 .86

90
20 99.44

111 4.15

2 732.05

394 1.98

217 5.32

4 14.96

18 72.84

1871.57

39 39.33

3 927.75

1871 .85

2866.79

2 174.86

2174.91

2 735.1 2

1450.41

1055 .20

2 671.91

206 9.64

2104.59
273 0.73

1 223.48

2067.03

206 8.05

860.4 1

936.37

1 018.19
1053 .58

267 2.75

2988.5 4

2671.32

1172.18

2821.88

9 04.25

2827.64

862.19

65 0.42

751 .92

60
1242 .52

1053.66

13 58.98

1 234.39

1236.30
1588.95

10
2940.8 6

400.0

4000.0

cm-1

2000

1593.35

1500

1000

cm-1

SJ C-Ph-D-13.pk

SJ C-Ph-D-14.pk

SJ 866F~1.SP 3601 4000.00 400 .00 6.35 100. 00 4. 00 %T 5 1.00

SJ 8E6 F~1.SP 3601 40 00.00 400.00 7.03 100.00 4.00 %T 5 1.00

REF 4 000 99.50 2000 97. 14 600

34 37.27 6.35 2988.54 66. 60 2949.03 66. 48 2732.05 9 3. 58 2 099.44 94.18
17 53.55 64.20 1591 .8 7 18.50 1355.56 51.26 1242.52 58. 89 1114.15 93. 28
10 55.20 85.21 766. 39 71. 35 605.78 68.51

REF 4 000 98.07 2000 96. 53 600

39 41.98 96.46 3457 .3 6 11.15 2940.86 12.17 2865.79 27. 97 2671.91 88. 97
21 75.32 93.29 2069 .6 4 93.13 1872.84 95.73 1711.61 7.02 1 594.23 23.26
14 44.32 40.53 1348 .3 4 38.57 1314.02 46.06 1236.30 22. 58 1118.49 55. 20
10 52.50 54.96 903. 61 75. 36 860.41 82.10 751.92 65.83 649.01 73.55
49 2. 49 59.49 414. 96 8 7. 56

400.0

1592.46

17 11.30

0.0
3000

294 1.88

1711.61

0.0
1000

1594.37

10
3457 .36

3 437.27

1500

1242 .90

1 755.0 7

1350.91

20
1594.23

2992.52

50
%T

1591.87

0.0
2000

596.99

1350.38

2945.90

1349.24
2866.4 4

2 865.79

7 70.19
751 .68

1 383.3 1

650.96

1445.54

1 056.50

70
2946.6 9

1236.83
1 447.80
2866.69

144 4.32

650 .92
751 .82
493.7 5

50
%T

13 48.34

861.97

751.75

111 8.87

1 052.5 0

4 92.81

11 18.49

50
%T

13 55.56

1119 .14

60
492.4 9

1053 .46

904.03

649 .01

131 4.02

605.7 8
294 9.03
17 53.55

90 3.61

7 66.39

3000

11 20.17

213 0.01

415.97

4000.0

4 93.59

1225.70

1444.00

2865.29
30

ACIC
St. Joseph's College ( Autonomous )
Tric hy-2

1018.13

3927.97

0.0

3451.61

4000.0

3000

2000

1500

1000

400.0

3438.84

3 437.2 0

4000.0

0.0
3000

2000

1500

1000

400.0

3 437.82

4000.0

cm-1

0.0
3000

2000

1500

1000

400.0

4000.0

cm-1

3000

2000

1500

1000

cm-1

SJC-Ph-D- 15.pk

SJ C-Ph-D-16.pk

SJ C-Ph-D-17.pk

SJ C-Ph-D-18.pk

SJC-PH~4. SP 3601 4000. 00 400. 00 5.02 100.00 4.00 %T 5 1.00

SJ C-PH~3.SP 3601 4000. 00 400.00 5.05 99. 99 4. 00 %T 5 1.00

SJ C-PH~2.SP 3601 4000. 00 400.00 5.02 100.00 4.00 %T 5 0. 50

SJ C-PH~1.SP 3601 4000. 00 400.00 6.34 99. 99 4. 00 %T 5 0.50

REF 4 000 98.24 2000 95.83 600

REF 4 000 98.20 2000 95. 47 600

39 27.75 96.13 3437. 20 5.05 2945.90 37.35 2866. 69 49 .33 2672.75 89.39
21 74.86 91.54 2067. 03 91.49 1871.85 96. 30 159 3. 35 15.56 1447.80 56. 37
13 50.91 40.01 1236. 83 52.68 1119.14 72. 14 105 3. 46 75.80 904.25 82.97
86 1. 97 83.61 751.82 62.22 650.92 64.67 493. 75 62.42

REF 4 000 99.44 2000 96. 21 600

39 17.86 95.35 3437 .8 2 5.02 2946.69 72. 57 2866.79 8 4. 56 2 821.88 86.71
27 35.12 95.38 2130 .0 1 92.80 1588.95 18.90 1450.41 84. 84 1383.31 65. 71
13 50.38 56.67 1223 .4 8 93.51 1120.17 94.90 1053.58 98. 38 1018.19 98. 43
75 1. 68 67.32 650. 96 6 3. 96

REF 4 000 99.87 2000 97. 91 600

34 38.84 6.34 2992. 52 63.22 2827.64 82.12 2730. 73 93 .41 2104.59 94.91
17 55.07 58.37 1592. 46 15.78 1358.98 44. 91 124 2. 90 56.74 1172.18 88. 73
10 56.50 85.87 936.3 7 98.32 770. 19 70. 19 596.99 68 .3 9

315

400.0

Table - 7.30
Observations of FTIR spectrums for
Cyclohexanone + Ethyl Acetate + 2-Butanone mixture
S1
(Cm-1)
3927.97
3788.49
3420.47
2940.99
2865.29
2673.39
2176.04
1804.84
1712.31
1595.46
1448.22
1350.61
1314.28
1222.68
1172.66
1119.36
1054.67
1018.13
863.72
651.14
491.59
413.27

S2
(Cm-1)
3931.42
3784.96
3439.70
2941.24
2865.46
2673.92
2175.84
1711.17
1595.42
1444.52
1351.08
1223.19
1119.18
1055.20
1018.91
861.50
649.71
559.88
492.38

S3
(Cm-1)
3927.93
3790.58
3420.01
2940.97
2864.86
2672.36
2175.61
1712.05
1595.16
1448.21
1350.34
1314.07
1223.85
1119.18
1054.15
1018.47
863.56
650.90
491.47
413.32

S4
(Cm-1)
3931.53
3788.52
3431.58
2940.55
2864.88
2673.57
2175.76
1711.36
1595.65
1444.00
1351.62
1222.89
1119.36
1055.56
1020.15
861.26
649.91
492.04
416.20

S5
(Cm-1)
3928.10
3431.36
2940.81
2865.60
2672.60
2175.71
1711.82
1595.38
1445.16
1348.36
1225.70
1119.05
1054.63
862.80
649.90
491.94
414.55

S6
(Cm-1)
3927.50
3793.60
3436.14
2942.42
2866.09
2173.53
1712.65
1594.99
1444.42
1353.25
1227.85
1172.47
1119.18
1055.28
587.69
493.59

S7
(Cm-1)
3940.76
3461.11
2941.52
2866.52
2671.50
2459.49
2175.91
2066.87
1971.82
1871.42
1712.00
1594.24
1444.61
1344.49
1314.96
1227.37
1119.18
1053.35
863.95
650.73
492.02
414.83

S8
(Cm-1)
3936.68
3441.28
2940.25
2864.48
2672.80
2457.61
2175.21
1805.01
1711.36
1593.12
1449.04
1426.65
1384.23
1346.89
1313.22
1222.77
1119.25
1054.29
1017.87
863.45
651.79
491.59
412.58

S9
(Cm-1)
3940.98
3447.81
2941.12
2865.70
2672.24
2175.11
1803.58
1711.08
1593.54
1443.97
1346.39
1315.05
1223.68
1119.55
1055.82
1018.97
862.48
651.89
492.68
415.26

* Maximum shift in the frequency has been observed.

*S10
(Cm-1)
3940.75
3446.44
2946.53
2868.75
2671.94
2337.75
2174.34
2069.77
1873.36
1713.95
1594.55
1444.50
1352.19
1236.96
1173.62
1118.83
1052.88
861.80
649.90
416.46

S11
(Cm-1)
3450.91
2943.19
2866.13
2672.91
2095.64
1710.37
1634.58
1591.09
1448.37
1348.45
1314.41
1230.04
1119.06
1054.03
862.20
651.46
492.78

S12
(Cm-1)
3444.09
2990.98
2948.68
2103.19
1748.05
1590.14
1354.17
1242.49
1056.16
602.01

S13
(Cm-1)
3437.27
2988.54
2949.03
2732.05
2099.44
1753.55
1591.87
1355.56
1242.52
1114.15
1055.20
605.78

S14
(Cm-1)
3941.98
3457.36
2940.86
2865.79
2671.91
2175.32
2069.64
1872.84
1711.61
1594.23
1444.32
1348.34
1314.02
1236.30
1118.49
1052.50
860.41
649.01
492.49
414.96

S15
(Cm-1)
3939.33
3451.61
2941.88
2866.44
2671.32
2174.91
2068.05
1871.57
1711.30
1594.37
1445.54
1349.24
1234.39
1118.87
1053.66
862.19
650.42
492.81
415.97

* Maximum shift in the frequency has been observed.

316

S16
(Cm-1)
3927.75
3437.20
2945.90
2866.69
2672.75
2174.86
2067.03
1871.85
1593.35
1447.80
1350.91
1236.83
1119.14
1053.46
861.97
650.92
493.75

S17
(Cm-1)
3917.86
3437.82
2946.69
2866.79
2821.88
2735.12
2130.01
1588.95
1450.41
1383.31
1350.38
1223.48
1120.17
1053.58
1018.19
650.96

S18
(Cm-1)
3438.84
2992.52
2827.64
2730.73
2104.59
1755.07
1592.46
1358.98
1242.90
1172.18
1056.50
936.37
770.19
596.99

Fig-7.30: FTIR spectrums for Ethyl Acetate + 2-Butanone + Hexane mixture:

ACIC
St.Joseph's College ( Autonomous )
Trichy-2
ACI C
St. Joseph's College ( Autonomo us )
Tr ich y-2

FTIR SPECT RUM

Date: 26-6-2009

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

ACI C
St.Josep h's Colleg e ( Autonomous )
Tr ichy-2

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

ACIC
St.Joseph's College ( Autonomous )
T richy-2

Spectrum Name: H-E-2B-1.sp

FTIR SPECT RUM
Date: 26-6-2009

100.0

FTIR SPECTRUM
Date: 26-6-2009

Spectrum Name: H-E-2B-2 .sp

392 5.08

100.0

39 22.32

23 59.43

61 4.51

2 721.6 4

23 64.66
106 1.83

1 228.66

27 19.74

1461.09

2718.6 5

1241.28

2720 .26

612.29

2719.35

612 .42

6 10.23

2978.74
3921.92

2375.56

774 .6 3

90
1065.56

2 83 2.19

23 76.47

29 61.99
3794 .87

2 966.24

FT IR SPECT RUM
Date: 26-6- 2009
100.0

100.0

39 20.42

Spec trum Name: H-E-2B-6.sp

Sp ec trum Name: H-E- 2B-5 .sp

Spec trum Name: H-E-2B-4.sp

100.0

2 72 0.35

FT IR SPECTRUM
Date: 26-6-2009

FTIR SPECTRUM
Date: 26-6-2009

Spectrum Name: H-E-2B-3.sp

10 22 .04
29 66.78

1463.43

613 .93

614 .72

12 42.25

296 1.38
1241.4 7

283 1.80

2963.90

774.51

30
34 45.96

34 57.13

3459.19

3441.22

3443.38
1 36 1.93

774.45

50
%T

2832.28

%T
40

77 4.69

2832.19

2831.7 1

774.90

2832 .02

773 .57

13 60.15
3440.28

1362.03

15 99 .6 5

4000.0

3000

2000

15 00

100 0

1362.84

159 8.26

400.0

0.0

cm-1

1 599.22

0.0

4000.0

H-E-2B-1.pk

3000

2000

1500

1000

400.0

3000

2000

1500

1000

400.0

4000.0

cm -1

2000

1000

4000.0

400.0

3000

2000

1500

1000

cm -1

H-E-2B-3.sp 3601 4000.00 400.00 5.15 99.79 4.00 %T 10 1.00

H-E-2B-4.sp 3601 4000.00 400.00 5.16 99. 63 4.00 %T 10 1.00

H-E-2B-5 .s p 3601 4000.00 400. 00 6. 37 99.82 4. 00 %T 10 1.00

H-E-2B-6.s p 3 601 400 0. 00 400. 00 6. 46 99.62 4.00 %T 10 1.00

REF 4 000 98 .6 7 2000 96. 56 600

39 20.42 95. 34 3440.28 19.68 2966. 24 71. 79 2831.80 66. 13 272 1. 64 87.67
15 98.26 6.38 1360. 15 22 .8 6 773.57 62. 99 610.23 73 .6 1

REF 4000 99.57 2000 93.81 600

3922.32 96.63 3794.87 95.25 3457.13 31.32 2961.99 74.01 2832.02 59.03
2719.74 86.77 2376.47 97.70 1599.22 5.15 1362.02 14.88 1228.66 87.25
774.51 61.60 612.42 79.54

REF 4000 99.40 2000 88.87 600

3459. 19 34.84 2963.90 71. 25 2832. 28 54.17 2719.35 84.52 2375.56 93.29
1601. 38 5.16 1463. 43 66.85 1362.84 11.79 1241. 47 76 .30 1065.56 91.01
774.90 60.53 612.29 82.33

REF 4000 99.73 2000 97.06 600

3443. 38 30.10 29 61.38 78.46 2831.71 62.58 271 8.65 88. 80 1599. 10 6.37
1461. 09 74.73 13 62.27 16.98 1241.28 86.94 774 .69 59.02 613.93 77.85

REF 4000 99.5 0 2000 9 4. 66 600

3921.92 96.19 34 41.22 29. 63 2978.74 74. 79 2832. 19 63.55 272 0. 26 88.64
2364.66 93.95 15 99.06 6.46 1362.03 18.23 1242.25 75.38 1061. 83 91 .1 4
774. 45 63.15 614. 72 78. 20

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

FTIR SPECTRUM
Date: 26-6-2009

146 5.7 5

FTIR SPECTRUM
Date: 2 7-6 -2009

FTIR SPECTRUM
Date: 26-6 -2009

1 241 .5 8

3922.83

1 094.5 4
1057.11

2 831 .8 0

3800.40

773 .4 5

2 722.24

1463 .92

2721.11

70
610.79

1244.51

2369.69
613.73

2720.66

609.81

2832.01

609.92

60
773.88

50
2832.46

1427.18

30
30

13 61.26

4000 .0
1000

3000

2000

1500

1000

400.0

H-E-2B-7.pk

400 0.0

3438.16

10
1596.57

3 000

200 0

REF 4000 99.61 2000 96.21 600

3820.17 93.89 3441.43 29.92 2831.80 67.16 2720.98 89.50 2367.12 96.20
1598.86 7.96 1465.75 75.68 1361.26 22.32 1241.58 87.34 773.45 65.76
604.21 79.31

0.0

4000.0

0 .0

15 00

10 00

400 0. 0

4 00. 0

3 00 0

2 000

15 00

1 000

3000

2000

1500

1000

400.0

4 00. 0

H-E-2B-10.pk

H-E-2B-9 .s p 3601 400 0.00 400.00 6.46 100.00 4.00 %T 10 1.00

H-E-2B~1.SP 3 601 400 0.00 400.00 6.62 99 .5 2 4.0 0 %T 10 1 .0 0

REF 4 000 99.84 2000 8 6.03 600

39 22. 83 94.26 3815.17 91.04 3439.58 27 .8 6 2963.05 66.25 283 1.80 58.67
27 20. 66 77.55 2369.69 82.16 1598.12 6. 46 1360.81 21.70 1122.61 88 .7 4
77 3. 98 64 .4 5 61 3.73 7 6.51

REF 4 000 99 .3 1 2000 92.98 600

39 25.24 95.14 380 0.40 92.20 3444.85 24.69 296 6.09 73.26 283 2.26 64. 45
27 21.11 88.79 159 8.52 6.62 1 361.11 20 .3 4 12 44.51 86 .4 9 774.3 4 61.06
60 9.92 75.0 6

3000

2000

1500

1000

400.0

cm -1

H-E-2B-11. pk

H-E-2B-9 .p k

1597.41

4000.0

cm -1

cm-1

H-E-2B-8.s p 3601 4000.00 400.00 7.96 99.90 4.00 %T 10 1.00

REF 4000 99.5 7 2000 7 9. 94 600

3451.66 27.72 29 99.34 60. 07 2832.46 56. 03 2719. 92 77.81 237 3. 04 83.10
1714.61 12.32 15 98.94 6.45 1427.18 51.15 1362.70 8.15 1226. 38 36.29
1094.54 80.43 10 57.11 80. 17 905.57 92.15 774. 95 61. 01 611.99 77.29
532. 24 68.40

1359.28

343 9.12

0.0
1598.52

1598.12

0.0

H-E-2B-8.pk

H-E-2B-7.s p 3 601 400 0. 00 400. 00 6. 45 99.74 4.00 %T 10 1.00

10
1361.11

cm-1

400.0

3444.85

1360.81

0.0

1362.70

1500

1360.37

3439.58

20
15 98.86

1598.94

cm -1

10
1714.61

20
345 1.66

774.04
1759.91

%T
40

%T
34 41.43

122 6.38

1243.11

2831.96

774.34

2831.80

29 89.65

2832.26

773.98

1056.50

2722 .18

1243.14
1122.61

2963.05

50
%T

1116.38

2966.09

3815.17

532.2 4

3921.81

1119.90

61 1.99

774.95

3919.64

3925.24

60
29 99.34

FTIR SPECTRUM
Date: 27-6-2009
100.0

237 5.34

100 .0

10 0.0

Spec trum Name: H-E-2B-12.sp

100.0

Sp ec trum Name: H-E-2B-1 0.sp

Sp ectrum Name: H-E-2B-9 .sp

604 .21

2719.92

FT IR SPECT RUM
Date: 27-6 -2009
Spectrum Name: H-E-2B- 11.sp

2 720 .98

2373 .04

2000

400.0

ACIC
St.Joseph's College ( Autonomous )
T richy-2

ACIC
St.Jo sep h's Colleg e ( Autonomo us )
Trichy-2

ACIC
St.Jos ep h's Colleg e ( Autonomo us )
Trichy-2

23 67.12

3 820 .17

905 .57

3000

1000

H- E-2B-2.s p 3 601 4000. 00 400.00 6.38 99.88 4.00 %T 10 1 .0 0

10 0.0

4000.0

1500
cm -1

H-E-2B-6.pk

Spectrum Name: H-E-2B-8.sp

FT IR SPECT RUM
Date: 26-6- 2009

2000

H-E-2B-5 .p k

Spec trum Name: H-E-2B-7.sp

0.0

3000

H-E-2B-4.pk

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

100.0

4000.0

400.0

cm-1

H-E-2B-3.pk

ACI C
St.Josep h's Colleg e ( Autonomous )
Tr ichy-2

0.0

1500

H- E-2B-2.pk

H-E-2B-1.s p 3601 4000.00 400.00 6.64 99.62 4.00 %T 10 1.00

REF 4000 99.55 2000 95.26 600
3925.08 96.42 3445.96 30.18 2966.78 77.08 2832.19 64.45 2720.35 89.14
2359.43 82.43 1599.65 6.64 1361.93 20.02 1022.04 96.01 774.63 65.20
614.51 79.17

3000

15 99.06

15 99.10

1601.38

0.0

4000.0

cm -1

13 62.27

1 362.02

0.0

H-E-2B-12.pk

H-E-2B~2.SP 3601 4000.00 400.00 6. 64 99.19 4.00 %T 10 1.00

H-E-2B~3. SP 3601 4000. 00 400. 00 6. 46 99.99 4.00 %T 10 1.00

REF 4000 98.52 2000 95.57 600

3919.64 95.75 3439.12 15.68 2832. 01 66.97 2722. 24 87. 11 2375. 34 97. 37
1596.57 6. 64 1359. 28 24.88 1243. 14 81.79 1119.90 92.09 773. 88 62. 18
610.79 71.7 5

REF 4000 99.67 2000 89.66 600

3921. 81 94.37 3438.16 19. 83 2989. 65 62.20 2831.96 63.00 2722.18 81.97
1759. 91 55.75 1597.41 6.45 1463.92 69.83 1360. 37 22 .77 1243.11 58.06
1116. 38 88.61 1056.50 82. 60 774.04 62.64 609.81 72.17

ACIC
St.Joseph's College ( Autonomo us )
Trichy-2
ACIC
St.Joseph's College ( Autonomous )
Trichy-2

ACIC
St.Joseph's College ( Autonomous )
Trichy-2

FTIR SPECTRUM
Date: 27-6-2009

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

Spectrum Name: H-E-2B-14.sp

FTIR S PECTRUM

10 0. 0

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2

Date: 27-6-2009

ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2

FTIR S PECTRUM
Date: 27-6-2009

Spectrum Name: H-E-2B-13.sp

Spectrum Name: H-E-2B-18.sp

100 .0
392 2.83

2366.92

3931.86

FT IR SPECTRUM
Date: 27-6-2009

1026.21
2721.68

236 8.82

100 .0

FT IR SPECT RUM
Date: 27-6 -2009

Sp ec trum Name: H-E- 2B-1 5. sp

1121.18

2 72 1.10

90
607.79

2831.82

2104.88

392 4.15

9 34 .2 6
2 72 1.76

2725.86

2093 .13
378 7.28

1 464.87

2365.51

1117.08

21 63.66
1464.73

2723.85

1760.57

607.34

2830.51

1 05 6.4 5

773 .34

1056.50

%T
40

29 87 .45

2 981.69

13 61 .1 4

20 00

1500

4 00 0. 0
100 0

cm-1

2 00 0

1 50 0

1 00 0

H-E-2B-1 4.pk

H-E-2B-13.pk

40 0 .0

1358.40

34 51.48

2000

1500

1000

400.0

cm-1

4000.0

40 00.0

0.0
3000

2000

1500

1000

400.0

4000.0

cm -1

3000

20 00

1500

100 0

cm-1
3000

2000

1500

1000

cm-1

H-FAD3~1.SP 3601 4000.00 400.00 6.65 100.00 4.00 %T 10 1.00

H-E-2B-1 5. pk

H-E-2B-16. pk

H-E-2B-1 7. pk

REF 4000 99.65 2000 95.11 600

3931.86 96.66 3440.19 1 9.73 2831.82 69.47 2721.68 89.44 2366.92 96.14
1596.80 6.65 1359.07 24.96 1121.18 90.89 1026.21 93.74 773.90 61.60
607.79 70.82

H-F2E3~1.SP 360 1 4000.00 400.00 6.66 100.00 4.00 %T 10 1.00

H-FAE3~1. SP 3601 4000.00 4 00. 00 6.58 99.73 4.00 %T 10 1.00

H-F2F3~1.SP 360 1 4000.00 400.00 6.91 99. 93 4. 00 %T 10 1. 00

REF 4000 99.53 2000 97.65 600

3920. 48 95.73 3788.96 90. 14 3438.89 14.76 29 91.14 62.36 2832. 10 68.26
2725. 86 86.66 2365.04 96. 71 2104.88 96.22 17 60.57 60.47 1596. 95 6. 66
1464. 87 73.16 1359.05 27. 91 1243.08 57.73 10 56.19 81.32 773.60 64 .63
610.28 69 .65

REF 4000 99.45 2000 91.85 600

3924.15 96.89 3434.53 21.99 2978. 96 65.46 2830. 51 65. 84 2723. 85 83. 18
2365.51 87.53 2163.66 90.23 1596. 72 6.58 1464.73 71.07 1358.40 24.16
1244.05 76.72 1117.08 91.18 1048. 04 89.29 773.34 59.27 607. 34 65. 87

REF 4000 99.38 2000 97.09 600

3923. 33 97.13 37 87.28 93.60 3451.48 15.57 298 1.69 41. 89 2833. 58 66.26
2724. 87 87.93 20 93.13 95.18 1760.87 21.42 159 6.84 6.91 1463.96 62.72
1364. 08 17.80 12 42.70 15.11 1172.52 77.26 105 6.50 57. 29 933.98 94.64
773.09 62 .44 615. 80 67.42

317

1 242 .7 8

0 .0

1596.84

1596.72

0.0
3000

17 59 .6 7
1 59 7.19

1364.0 8
1242.7 0

1596 .95

4000.0

1 36 6.24

10
176 0.87

3438.89

0.0

H-E-2B~4.SP 3601 4000.00 400.00 6.65 100.00 4.00 %T 10 1.00

REF 4000 99.63 2000 95.17 600
3922.83 95.68 3445.58 24.72 2832.13 63.65 2721.10 87.72 2368.82 97.28
1598.01 6.65 1361.14 20.95 774.38 62.04 611.94 75.37

20
34 52 .5 5

20
3434.53

30 00

cm -1

400.0

1359.05

20
1596.80

0. 0
1 59 8.01

3000

1359.07
3440.19

3 44 5.58

40 00.0

77 4.40

773.09
2978 .96

50
%T

0 .0

60 3.88

11 72 .34

615.80

2833.58

1243.0 8

283 3.02

1172 .52

1244.05

1 46 1.30

77 3.60
2991.14

50
%T

1 463.96

70
610 .28

2832.10

933.98
2724 .87

104 8.04

1056.19

2 09 0.6 7

8 43 .8 4

77 4.38

100.0

2365.04

773.90

28 32.13

2 48 0.0 9

Sp ec trum Name: H-E- 2B-1 7. sp

100.0

3923.3 3

3920.4 8

3788.96

6 11 .9 4

FT IR SPECTRUM
Date: 27-6-2009

Spectrum Name: H-E-2B- 16.sp

100.0

400.0

H-E-2B-18.pk
H-FAF3~1.SP 3601 4000.00 400.00 8.06 100.00 4.00 %T 10 1.00
REF 4000 99.58 2000 97.97 600
3452.55 20.96 2987.45 40.50 2833.02 69.66 2721.76 90.87 2480.09 98.55
2090.67 95.86 1759.67 12.88 1597.19 9.71 1461.30 60.62 1366.24 15.68
1242.78 8.06 1172.34 69.01 1056.45 47.87 934.26 91.78 843.84 86.86
774.40 64.13 603.88 70.44

400.0

Table - 7.31
Observations of FTIR spectrums for
Ethyl Acetate + 2-Butanone + Hexane mixture:
S1
(Cm-1)

S2
(Cm-1)

S3
(Cm-1)

S4
(Cm-1)

S5
(Cm-1)

S6
(Cm-1)

*S7
(Cm-1)

S8
(Cm-1)

S9
(Cm-1)

3925.08
3445.96
2966.78
2832.19
2720.35
2359.43
1599.65
1361.93
1022.04
774.63
614.51

3920.42
3440.28
2966.24
2831.80
2721.64
1598.26
1360.15
773.57
610.23

3922.32
3794.87
3457.13
2961.99
2832.02
2719.74
2376.47
1599.22
1362.02
1228.66
774.51
612.42

3459.19
2963.90
2832.28
2719.35
2375.56
1601.38
1463.43
1362.84
1241.47
1065.56
774.90
612.29

3443.38
2961.38
2831.71
2718.65
1599.10
1461.09
1362.27
1241.28
774.69
613.93

3921.92
3441.22
2978.74
2832.19
2720.26
2364.66
1599.06
1362.03
1242.25
1061.83
774.45
614.72

3451.66
2999.34
2832.46
2719.92
2373.04
1714.61
1598.94
1427.18
1362.70
1226.38
1094.54
1057.11
905.57
774.95
611.99
532.24

3820.17
3441.43
2831.80
2720.98
2367.12
1598.86
1465.75
1361.26
1241.58
773.45
604.21

3922.83
3815.17
3439.58
2963.05
2831.80
2720.66
2369.69
1598.12
1360.81
1122.61
773.98
613.73

* Maximum shift in the frequency has been observed.

S10
(Cm-1)

S11
(Cm-1)

S12
(Cm-1)

S13
(Cm-1)

S14
(Cm-1)

S15
(Cm-1)

S16
(Cm-1)

*S17
(Cm-1)

S18
(Cm-1)

3925.24
3800.40
3444.85
2966.09
2832.26
2721.11
1598.52
1361.11
1244.51
774.34
609.92

3919.64
3439.12
2832.01
2722.24
2375.34
1596.57
1359.28
1243.14
1119.90
773.88
610.79

3921.81
3438.16
2989.65
2831.96
2722.18
1759.91
1597.41
1463.92
1360.37
1243.11
1116.38
1056.50
774.04
609.81

3922.83
3445.58
2832.13
2721.10
2368.82
1598.01
1361.14
774.38
611.94

3931.86
3440.19
2831.82
2721.68
2366.92
1596.80
1359.07
1121.18
1026.21
773.90
607.79

3920.48
3788.96
3438.89
2991.14
2832.10
2725.86
2365.04
2104.88
1760.57
1596.95
1464.87
1359.05
1243.08
1056.19
773.60
610.28

3924.15
3434.53
2978.96
2830.51
2723.85
2365.51
2163.66
1596.72
1464.73
1358.40
1244.05
1117.08
1048.04
773.34
607.34

3923.33
3787.28
3451.48
2981.69
2833.58
2724.87
2093.13
1760.87
1596.84
1463.96
1364.08
1242.70
1172.52
1056.50
933.98
773.09
615.80

3452.55
2987.45
2833.02
2721.76
2480.09
2090.67
1759.67
1597.19
1461.30
1366.24
1242.78
1172.34
1056.45
934.26
843.84
774.40
603.88

* Maximum shift in the frequency has been observed.

318

Fundamentals Principles of Polymeric Materials
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