Like Me

"Like Me" is the official debut single by the American girl group Girlicious. It was released to iTunes on April 22, 2008, a day before the group was formed in the season finale of the reality television show Pussycat Dolls Present: Girlicious. Since Tiffanie's departure, Chrystina Sayers performs her part of the bridge and melismatic vocals.

Release

On iTunes, "Like Me" was released on April 22, 2008 one day prior to The CW's airing of the finale, allowing many fans to find out who won before the finale aired. A 1:30 preview of the song was released on their official website on April 22, 2008. On September 19, 2008 the single was sent to radio in India.

Chart performance

Without being sent to radio or a physical release, the single managed to debut at number two on the US Bubbling Under Hot 100 Singles and number seventy on the Pop 100 solely based on digital sales. In addition, during the week of May 1, 2008, "Like Me" made a "Hot Shot Debut" at number four on the Canadian Hot 100 becoming an instant hit in Canada.

Nasti Muzik

Nasti Muzik is the third studio album from American rap artist Khia. The album was released on July 22, 2008 on Thug Misses Entertainment/Big Cat Records. One of the feature producers on the album is DJ Craze, with Gucci Mane and Maceo being the featured guest artists on the album.

"What They Do" was the first single off the album but did not chart but had a successful underground and streets impact. The second single, "Be Your Lady", was produced by Tampa's Push-a-Key Productions.

Track listing

References

Like Me (musical)

Like Me - The Social Media Musical is a musical with music and lyrics by Garry Lake and book by Jon Smith. It tells the story of a group of four young adults navigating the social media minefield, looking for each other, for love, for validation and ultimately, for themselves – in amongst a cyber world populated by thousands of ‘followers’ and ‘friends’. Haunted by a lack of self-confidence and self-respect, Emma, Ashley, Luke and Charlie face physical, emotional and psychological challenges, leading them to question their very identity.

Originally conceived as a song cycle by Garry Lake and performed at the Duplex, New York and the CMO Club at the Conrad Hilton, the full-book musical was first seen in a showcase performance at the Courtyard Theatre, London October 3, 2014. Most recently, Like Me - The Social Media Musical was showcased at The Waterloo East Theatre on April 11, 2015.

Synopsis

A twist on the romantic comedy in which four young adults navigate the social media minefield, looking for each other, for love, for validation and ultimately, for themselves – in amongst a cyber world populated by thousands of ‘followers’ and ‘friends’. Haunted by a lack of self-confidence and self-respect, Emma, Ashley, Luke and Charlie face physical, emotional and psychological challenges, leading them to question their very identity. Are they hiding behind their online personae, or is there conviction in their tweets, pins, selfies, posts and status updates? Like the rest of the population, they’re digitally aware, armed with Wi-Fi enabled devices and online. Let the tagging begin.

96.1 Star FM

96.1 Star FM (ACMA callsign: 5SEF) is an Australian commercial radio station based in Mount Gambier, South Australia, owned by Southern Cross Austereo. It commenced broadcasting on May 16, 1998. Currently, the only local program broadcast on the station is the Jess and Ryan breakfast show from 6am to 9am Monday to Friday - all other programming is broadcast from Albury or Gold Coast.

References

External links

Selenium hexafluoride

Selenium hexafluoride is the inorganic compound with the formula SeF₆. It is a colourless gas described as having a "repulsive" odor. It is not widely encountered and has no commercial applications.

Structure, preparation, and reactions

Like many compounds of selenium, SeF₆ is hypervalent. The compound has octahedral molecular geometry with Se-F bond length 168.8 pm.

SeF₆ can be prepared from the elements or by the reaction of bromine trifluoride (BrF₃) with selenium dioxide. The crude product is purified by sublimation.

The relative reactivity of the hexafluorides of S, Se, and Te follows the order TeF₆ > SeF₆ > SF₆, the latter being completely inert toward hydrolysis until high temperatures. SeF₆ also resists hydrolysis. The gas can be passed through 10% NaOH or KOH without change, but reacts with gaseous ammonia at 200 °C.

Safety

Although selenium hexafluoride is quite inert and slow to hydrolyze, it is toxic even at low concentrations, especially by longer exposure. In the U.S., OSHA and ACGIH standards for selenium hexafluoride exposure is an upper limit of 0.05 ppm in air averaged over an eight-hour work shift. Additionally, selenium hexafluoride is designated as IDLH chemical with a maximum allowed exposure limit of 2 ppm.

Selenium tetrafluoride

Selenium tetrafluoride (SeF₄) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.

Synthesis

The first reported synthesis of selenium tetrafluoride was by Paul Lebeau in 1907, who treated selenium with fluorine:

A synthesis involving more easily handled reagents entails the fluorination of selenium dioxide with sulfur tetrafluoride:

An intermediate in this reaction is seleninyl fluoride (SeOF₂).

Other methods of preparation include fluorinating elemental selenium with chlorine trifluoride:

Structure and bonding

Selenium in SeF₄ has an oxidation state of +4. Its shape in the gaseous phase is similar to that of SF₄, having a see-saw shape. VSEPR theory predicts a pseudo-trigonal pyramidal disposition of the five electron pairs around the selenium atom. The axial Se-F bonds are 177 pm with an F-Se-F bond angle of 169.2°. The two other fluorine atoms are attached by shorter bonds (168 pm), with an F-Se-F bond angle of 100.6°. In solution at low concentrations this monomeric structure predominates, but at higher concentrations evidence suggests weak association between SeF₄ molecules leading to a distorted octahedral coordination around the selenium atom. In the solid the selenium center also has a distorted octahedral environment.