96.1 Star FM
96.1 Star FM (ACMA callsign: 5SEF) is an Australian commercial radio station based in Mount Gambier, South Australia, owned by Southern Cross Austereo. It commenced broadcasting on May 16, 1998. Currently, the only local program broadcast on the station is the Jess and Ryan breakfast show from 6am to 9am Monday to Friday - all other programming is broadcast from Albury or Gold Coast.
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Selenium tetrafluoride
Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
Synthesis
The first reported synthesis of selenium tetrafluoride was by Paul Lebeau in 1907, who treated selenium with fluorine:
A synthesis involving more easily handled reagents entails the fluorination of selenium dioxide with sulfur tetrafluoride:
An intermediate in this reaction is seleninyl fluoride (SeOF2).
Other methods of preparation include fluorinating elemental selenium with chlorine trifluoride:
Structure and bonding
Selenium in SeF4 has an oxidation state of +4. Its shape in the gaseous phase is similar to that of SF4, having a see-saw shape. VSEPR theory predicts a pseudo-trigonal pyramidal disposition of the five electron pairs around the selenium atom. The axial Se-F bonds are 177 pm with an F-Se-F bond angle of 169.2°. The two other fluorine atoms are attached by shorter bonds (168 pm), with an F-Se-F bond angle of 100.6°. In solution at low concentrations this monomeric structure predominates, but at higher concentrations evidence suggests weak association between SeF4 molecules leading to a distorted octahedral coordination around the selenium atom. In the solid the selenium center also has a distorted octahedral environment.
Crazy (Seal song)
"Crazy" is a song originated by English soul artist Seal, who wrote its lyrics and jointly composed its music in collaboration with producer Guy Sigsworth. The song was produced by Trevor Horn for Seal's debut album Seal (1991). Released as his debut single, "Crazy" became one of Seal's biggest hits, reaching the top five in the United Kingdom while becoming his first top ten single in the United States. It has since been interpreted by several artists, including Alanis Morissette, whose version was released as a single from her album The Collection (2005).
Background and composition
Seal wrote "Crazy" in 1990 inspired by the fall of the Berlin Wall in 1990 and the Tiananmen Square Massacre in 1989. In 2015, Seal said of the song's conception in 1990: "I felt the cycle had reached its apex. I felt the world changing and I felt profound things happening."
According to the song's producer Trevor Horn, "Crazy" was made over the course of two months: "Crazy wasn't an easy record to make, because we were aiming high".
Crazy (Neu! song)
Crazy is a 2010 12" vinyl single by German band Neu!. It was released shortly after the Neu! Vinyl Box on Grönland Records as a part of Record Store Day. It was the first Neu! single to be released since Isi in 1975 and the only single to be taken from Neu! '86. It was sold in a limited edition and was only available for a short time after 17 April 2010.
Recording & Release
The two songs were recorded during the brief studio-only Neu! reunion of 1985-6. The failure of the sessions led Klaus Dinger and Michael Rother to seal the master tapes with wax and once again disband Neu!.
The unavailability of the original three Neu! albums in the 1990s caused mass bootlegging, particularly by the Luxembourg label Germanofon, which Dinger personally attempted to contact, without success. Many music retailers were fooled by the bootlegs, and the Krautrock revival caused by Julian Cope's book Krautrocksampler put the Neu! albums in high demand. Unable to reach an agreement with Rother, Dinger released the tapes of the 1980s sessions as Neu! 4 in 1995 on Captain Trip Records, Tokyo without informing Rother. This incensed Dinger's bandmate, and the CD was soon deleted. Fan interest in the CD grew, and in 2010 Rother was forced to concede a proper release for the album on Grönland Records as Neu! '86. To coincide with this release, Crazy was put out as a vinyl limited-edition single on Record Store Day.
Crazy (Ricki-Lee Coulter song)
"Crazy" is a song by Australian recording artist Ricki-Lee Coulter, taken from her third studio album Fear & Freedom (2012). It was written by Coulter, Brian London and Johnny Jam, while the production was also handled by the latter two. The song was released digitally on 13 July 2012, as the third single from the album.
Lyrically, Coulter stated that "Crazy" is about "encouraging you [to] let go of your inhibitions, go crazy and let the music take over". Following its release, "Crazy" peaked at number four on the ARIA Dance Chart and number 46 on the ARIA Singles Chart. The accompanying music video was directed by Melvin J. Montalban and filmed in the Callan Park Hospital for the Insane in Sydney. The video features Coulter playing three characters – a nurse, patient and psychologist.
Background and release
"Crazy" was written by Ricki-Lee Coulter, Brian London and Johnny Jam, while the production was also handled by the latter two. During an interview with The Daily Telegraph, Coulter said she wrote the song "as if I was actually singing it directly to the people on the dance floor". She went on to describe it as "sensual and erotic, encouraging you let go of your inhibitions, go crazy and let the music take over". "Crazy" was released digitally on 13 July 2012. On 23 July 2012, it debuted at number 52 on the ARIA Singles Chart and number four on the ARIA Dance Chart. The following week, "Crazy" fell out of the top 100 of the ARIA Singles Chart. On 6 August 2012, the song re-entered the chart at number 46, where it peaked.
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