POF or Pof may refer to:
Phosphoryl fluoride (commonly called phosphorus oxyfluoride) is a compound with the chemical formula POF3. It is a toxic gas.
Phosphoryl fluoride combines with dimethylamine to produce dimethylaminophosphoryldifluoride (CH3)2NPOF2 and difluorophosphate and hexafluorophosphate ions.
Polonium hexafluoride (PoF6) is a possible chemical compound of polonium and fluorine and one of the seventeen known binary hexafluorides.
The synthesis of PoF6 via the reaction
was attempted in 1945, but the attempt was unsuccessful. The boiling point was predicted to be about −40 °C.
PoF6 may have been successfully synthesised via the same reaction in 1960, where a volatile polonium fluoride was produced, but it was not fully characterized.